EXPERIiMENT NO DATE 74|2)

ESTIMATI DN OE TOTAL HARDNESS

OF wA TER

AlM
To esmatee tha to tal haRdness. e a
A

Sample wates You

You hawe been Sup p hod wlh
wth
appvoZima t ely MIoO So ub om
ED TA and
Puse
Mag nagium Sulphate
Mg SD 7
H,o mo leular Mass 246 33

PRINCIPLE Hasdneas wate? s dua to the

P egence dssowed
Diabonfes, chlori des
Qnd sulphates caliumn and mag nenum he
almo unt
aleium and magmegi um
wtes
Cn be es6mates by the Comple Xomeiaic
&ing EDTA mekhod
the Comp lexing ent EDTA
Can bee ap desenk ed he dOTuWa
HOOC-H, C CH2- CooH

NcH,Ci
Hooc-H2
CH,- Co oH
 es

OBSERVATION AND ALCULA T/oNS B

weighk o the weghing bottle + =16 6S
gs 6outien
weiqht the
weghing bottle = 16 oS
alone
egh Mgso, tstal w o6
Mo lsib
g so4 Sotien,M= wx
2 4o 6 3
6 6x
246 3

Standar dsaionOf EDTA

SL Voume g Buette Readings Volue
Voume
g soso ubon EDTA sed up
Lni ial inal
Pipetted vin m
2t
17S 17S
20

20 17 S
S

dkesiu
 EDTA behawes dicaboryic aluol toth

aps hith Con be ep aegede!

as Y Tho
d odium 3n4 of EDTA
most
Commoy And g epepeulod

NaH2Y wih helde HV Souhon

he melal 1ong oat u9a th
th 1
oanr
Comple x e

2
M 2H
Ln genpRA M
M n-)
he. end pont
the ti taah on an be

dete'snm neo nginy

oe s t , Gddhnma
Black-r lEeT) . ohan the inolator aooleol
lo theSample had wadea a ne Aad
Coloude
Colouded meta nditor Complex F2
at a
pH o L9hen ths titai

CDTA SoluGm,
the oee a ansl M
Comp lexod ths heng the shable
Comple ohen qll he sce. mela
ao Complened ke 1 tte hexk d'aD P
Voume k mag negi um Sulphete

Ppetted 20m

Voume a EDTA sed pP 7 Sm

Nolassby g so 7H,0 5oukov =

Mo&iby EDTA =Molai Mg S

Volume d MS D,-
Voume ED TA

o 0 74 4 Y 20
7 S

Esbimation etotal has dnas watex Sampla

SA Voume o hasd ter Buaette Readings Voluma *
Pipetted in m Initial nal EDTA 8 e
w m

po
o
 EDTA aslded takes up matal ns daom the

mekal 'inodica to complexres to doam s ng ex

Maiol EDT
Metol
Complexeg Lebuch ae Coloua ess
At t e end Point ohon
Le metal- indestoa
all

COmplexes Changeinto motal- EDTA Comp lox the

e di cator wes bluue Co lou&
a

IM EBT Complex + EDTF Buffes eHe

1fa+/MgEDTA)
Complex+
BT

EDTA Soukion Gan be stanolerdiz ed usin Mg sD 1

wsh Eochaome Bock- T a3 ndi ca koD
2
Me y 2 2H

oH
Stauctuae
CaDchaDme blaue -T

PRocEDURE Psepatn kion sanderol Mag neghum

Sulphake sotion (o.o2s mob) About o61SS
s 7420 Cayslela axa ehed outd
to a 2so m tandasod lask dis sowedJ
and mude 6 he maak
ter p
 Volume
Volume ot hasl wlas Pipet led ' om

Vbluma ED TA hae P

fno had aad Ln Jo

Voumo EDr
DTA

Voumo, h93

loo
Mo leula7 weght

Ca C Ilitne haad woterr

O
Moloaly o haadalos r Maleulor toG
Oo 3 o 6 X(o O
Harsdne2s 20 67
he wen
sample
Sample watet
wabe"
weqht G Co in
hee wke ol
O 30 6 lodo
mg 360
mplL
36 6pp
 Stanolas di zah on o Ep TAS6 ltio- s R nl o Hhe
SAdgd mag ne9um Sulb hateSouki On u pipeted
utnkoa Conical logk 22 m
m bule
Soubo1(NH +NM,O) and 2-3 daps
taichabme black Tn di cako&
Sowti evn ag asa addas e
tadod agamst EDTA GU th
me 30d Co lou tteshed to bue. litarhon
42 depeatad dos Con Lor dant
Lwatex us
luesHax d he3s
eppses3 ed te nme l o u t k
Cabonade
Pahig Pes the
Sample
Estmatien e to talhax dhess e e Sample
wete 40 m the wen
3 wates Sample
Pp e t t e
wwto
Con Cal lask
2m bufhe Soukion CNHL C+N H) dnod
2 dao ps F Eai chaomn black T inoli Cak
aRe adJa hee souion s
tikaaked aagé
EDTA IUh e Aad Colous
pe Ttackons ficanaalto
aRa Aapaska Co n Lo dant

valuesHasdu e3s waker us xpaegsed

tems Calcium Caa bonate PaRts pe
tthe Sample

RESUL1 Had ne2s he e n samplee

wak ex
306 PPm