Expement No 3 Date 2nlsla

ESTIM T1ON O COPPE R IN

BRASS
AIM To detesmi ne the pescentage 6
CoPpes wm a Sample bsass

PRINCIPLE B3ass an
alloy 6o-30/.
Cop pex and dp- uo 7 zinc hen
Lhen aa kno O
know
toeafad sith nitic
aid and
heakad, Coppes and n C aA2
Covwexted mto then Coabes pondunp habaata
a3 shown
below
3 u+8 HNO >3 Cno,),+ H2o
+ 2N0

The ni bai tes and

ano ni tag e
Oxideg
the Soution present
may oxidi pe T to 2
may
Causia an inteades en ce w the lo dometaic
ausing
aueackion
 2No +4 Hi 2ot I
+2H
2N O + O
2 N O2

Not 2H+ 2I
No+ Tt Mo
Nicites and
togen oideg aRe elininaked
by heabin use

2N O
+NH2 CON H, 2 (o, +3H
When an excess
ekT s addad 6o the
Soluuion Contaang neutral D sghtly
adicmadaum uanti tatwe2 besai on o
o dine
takes Place

2 4L uTa+2
A Small amount of 2 Gebs
gebs abs orbed on the
Susdace o uI On the addi bi sm

yanate u gels desoabecd he iberated

 io dine2 i t sated agamst N42
Soution uging stastch a the ndi caksor

2 NagS t 2 Na L+Na S O

At Weig hk
Coppes"Eapinvalont weg ht e
Coppes 63.54

The Supplued Na2 S D standas dized by

6&akiva agaunst Souion
ho do
metm Call
o

k2CoO, +
7H2SO+
L 6KI e K2 SOetCr(se)
+7Hao+3
2Na S O +
T2 2 Va T + da S Oo
O
buivalenk weht
K2 C Moleclar wesght

O3

.
 CALCULATION

Weg he bsags pieca W O3

Nosma Lly CeO O. 02SN

Standaadiga tion e Sodum thiosulpha te

Kas0, Na, S Gba ch
inoliako
Volume k (r,0 Buse tte raading Voume
Souuion Pipe ted oue Tni ial
tia Ana l
Na2SQg uaed
i n m) upnmlD
lo S lo 5
2
loS lo S
ao
LoS loS
Youme e K2CsO Pipetted 26 ml
Voume Na S O e ed up (o S ml
Nosmali t K CoD Sole tioni ooSN
N ality Na Souuion
oo
NosmaLty bf ka Cs,0,x Volume ef kz
Vo ume
of Na SO
aoxO025
lo 5
N- OO7
 PROCEDURE 0 0 LAN

Paepaiaion shandaxd_pota8sium dichomake

Soukon
A standaxd solukion
K (s O, paoui de
Paouid
with

Standax die akion sodkum iosulphate

D m Pota3sium dichaomate Souui on g

Pipet ted out in to a Conal dask Adol 2om

ad HS0 o Uowed by test b e

S kT Sowkion Ttzata the &bezatd
gaingt the Na 62Pa Soubion ta ken n the

busette When the Colous oL the deai6ion

Tuxurse becomees Pale baDwn aold about

2 ol starach soulion Continue the

the

htaaki on nlil e deep blue Complex sappa

The Lghk eev Colous he Soluubion euen

ote the end point s due (o chaom

Sulphate doamao the Aeduetion

 ESTIMATlON 0f CoPPER 9Ud Eso
x Na,s, O3 Cslah odich
sL Bu aet te deading Volune o
Volume e a2t
No
Soution Pipeetesl Lui tial ina)
Na2 Og kied
Cin mi up (in m)

3 S 13 S

3 'S 3S
3
3S 3.5

Volume 6oubion pipettecd= 2om

Yolume f
Nas, o useol up 3 : 5 m
Nos mali ty Souion obu7N
Nas S3
Nosmaity a 2t b o n
go Nozmak ty
NaS, O3 XVo lume f
Na S 0
Volume S o ubon

5 o O49
o o 3 N
 aCO, Thestitaetion us ep eadad dba
ConCos daunt vaues
STIMATIONOF COppER

The bTags Sample a cusstel weghed

Qnd taans fessed
'intob aa 2so ml beahes
Ad
about I-a0 m d NO and
Wam the beake oves a iAe
wneil thebrsass pte ce 6N22
Pagses nkd souution
Add about a Pinch and Conine
heating ntil the eswes cen (e Ccas es Col he
Deakes, ano tsans fe the Coutenks toa

loom
loom f sanolas d ask though a unel
duunel y

Means a
g lass d Wagh the beake

too o tuaee wi th Small amownks

ime
timess
ano tsans te tho waghing nto a
Lwakes
Standos 4 &hsk A dol dao ps NagLo, solukion
with sha kiug i l the tux bi di ty
peass

Soukion Add di uuke acekic acd dsopwise

nkil tuebidity
ougs appears Qnol the Soauti o
becomeg cloaa hen aolol test tube o s/ k7
 Mass pe ére CoP pe
Nosmalixi valot weght a
MOT&
o03x63 s 6 Ltx
Mas's slpese
pes o Coppes in the Whole Soukro n
Nosmalby i valent weight og a
SA j
Ma.ss litae 1:26 O1969
w loy 1 3uod s

Weeht
s1e b0ags
ba gs WF O3g
essto03
.Pescentage sb&
PPexin iven Sample
boags = O 196
loo= 6S 337.
O3

: SYI
N& SA ko
vora

b A
Souhon Titocte the besated 219aunst
ho Naz Sa
Soubion ta ken the bu set te
When the Co lous Aea cuon becomes
Pala yellow aolol 2m
Souubon saach
and tha ti tsabion s Contiued unt|| whi te
Pakches appea the So ubion At
stag e aold ne test bube lo7 cNS
Souution an inten3e blue Co lous will PpaR

Cowtinue i toaion thes intense bue

Colous ssppeaas Titsabov Aepea
ked
Contoa dant vues.

RESOLT The pescentage

Cop pes
bhe gweo Sample 6 S. 33/.