Name ................................................

Batch.................... Roll No. ............... ONLINE EXAM - NEET

02- 04 - 2022 Batch: LT-23 One Yr (G-1&2)

23V/TP/P Organic Naming, Chemical and Ionic Equilibrium

1. The IUPAC name of CH3 CH2 CH CH2CH3 is

CHO

1) 3-formyl pentane 2) 2-ethyl butanal

3) 1-methyl butan-2-al 4) 1-ethyl propanal

2. The IUPAC name of H2C CH CH CH2CH3 is

CH CH2CH3

1) 3-propyl pent-1-ene 2) 3-ethyl pent-1-ene

3) 4-ethyl hex-1-ene 4) 3-ethyl hex-1-ene

CH3

3. The IUPAC name of is

1) 1-methyl cyclohex-2-ene 2) 6-methyl cyclohexene

3) 1-methyl cyclohex-5-ene 4) 3-methyl cyclohexene
4. Which group is always taken as a substituent in the IUPAC nomenclature
1) –NH2 2) –CN 3) –NO2 4) All
5. The alicyclic compound is
1) Pyrrole 2) Benzene 3) Hexane 4) Cyclohexane
6. The group of heterocyclic compounds is
1) Phenol, benzene 2) Pyridine, pyrrole
3) Furan, phenol 4) Hexane, cyclohexane
7. First organic compound synthesised from an inorganic salt is
1) urea 2) acetylene 3) acetic acid 4) methane
8. Match the following
1) Word root a) nitro
2) Primary suffix b) amide
3) Secondary suffix c) yne
4) Primary prefix d) pent
5) Secondary prefix e) cyclo

12345 12345 12345 12345

1) 2) 3) 4)
abcde acdeb dcbea debca
23V/TP/P 2 NEET - C +B

9. Following groups are present in an organic compound

H

C  C  , –OH, C O and C O . Which of the following will be considered the principal

functional group?
1) C  C  2) OH 3) –CHO 4) C O

COOH
10. The correct IUPAC name of is
OHC
1) 5-carboxy-3-oxocyclohexane carboxaldehyde
2) 4-formyl-2-oxo cyclohexane carboxylic acid
3) 2-carboxy-5-formylcyclohexanone
4) 4-carboxy-3-oxocyclohexanal
11. CH 2  CH – is called as
1) isoethyl 2) ethenyl 3) t-ethyl 4) amyl

Br

12. The IUPAC name of CH3 - CH - CH2 - CH2 - CH2 - C - CH3 is

OH Br

1) 6,6-dibromoheptan-2-ol 2) 2,2-dibromoheptan-6-ol
3) 6,6-dibromoheptan-2-al 4) 2,2-dibromo-6-hydroxyheptane
13. Identify the compound which is homocyclic, aromatic and unsaturated

1) 2) 3) 4)
O
14. Which is incorrect statement
1) A group obtained by the removal of one H atom from an alkane is known as alkyl group
2) The chemical properties of an organic compound depends upon functional group
3) Homologous series can be represented by a general formula
4) Alkynes consist of one double bond in their molecule
15. Which name is incorrect among the following alkyl groups?
1) CH3 CH Isopropyl 2) CH3 CH CH2 Isobutyl

CH3 CH3

CH3

3) CH3 C CH2 t-Butyl 4) CH3 CH CH2 CH2 iso pentyl

CH3 CH3
23V/TP/P 3 NEET - C +B

16. The correct name of CH2 CH CH CH2 C CH

CH3

1) 3-methyl hex-1-en-5-yne 2) 4-methylhex-5-ne-1-yne

3) 4-ethenylpent-1-yne 4) 3-(2-propenyl)but-1-ene
17. IUPAC name of (CH3)3 CH is
1) butane 2) isopropyl methane
3) 2 -methyl propane 4) dimethyl ethane

18. The IUPAC name of the following compound is H2C = C - CH2 - CH3

CH - CH3
CH3

1) 2-ethyl-3-methyl but-1-ene 2) 2-isopropyl but-1-ene

3) 2-methyl-3-ethyl but-3-ene 4) ethyl isopropyl ethene
o o o
19. The number of 1, 2 and 3H atoms in 2, 5, 6 - trimethyl octane, respectively is
1) 16, 5, 3 2) 15, 6, 3 3) 16, 6, 3 4) 15, 5, 2

20. The correct name of CH3 CH2 is

CH2
C C CH

1) hex-3-yne-5-ene 2) hex-5-en-3-yne 3) hex-3-yne-1-ene 4) hex-1-en-3-yne

21. Which is the correct name of the compound

1) 3, 3- dimethyl - 1 - hydroxy cyclohexane

2) 1, 1 - dimethyl - 3 - hydroxy cyclohexane
3) 3, 3 - dimethyl - 1 - cyclohexanol
4) 1, 1 - dimethyl - 3 - cyclohexanol

22. IUPAC name of  CH 3 3 C  CH  CH 2 is

1) 3,3,3 - trimethyl - 1 - propene 2) 1,1,1 - trimethyl - 2 - butene

3) 3,3 - dimethyl - 1 - butene 4) 2,2 - dimethyl - 3 - butene

23. Give the IUPAC name of

1) 3, 3 – dimethyl - 5 - ethylheptane
2) 5 - ethyl - 3, 3, - dimethyl heptane
3) 3 – ethyl - 5, 5, - dimethyl heptane
4) 5, 5 - dimethyl - 3 - ethylheptane
23V/TP/P 4 NEET - C +B

24. 2 - Methyl - 2 - butene will be represented as

CH3 CH3  C  CH  CH3

| |
1) CH3  CH  CH 2 CH3 2)
CH3

3) CH3  CH 2  C  CH 2 4) CH3  CH  CH  CH 2
| |
CH 3 CH 3

25. The correct decreasing order of preference of functional groups during the IUPAC nomenclature of
polyfunctional compounds is;
i) -COOH ii) -CHO iii) -OH iv) -NH2
1) ii > i > iii > iv 2) i > ii> iii > iv 3) iv > i > iii > ii 4) i > iii > ii > iv

26. Law of Mass action was proposed by

1) Henry & Wage 2) Guldberg & Waage
3) Ostwald & Dalton 4) Dalton & Guldberg
27. The rate constants of forward and backward reactions are 8.5x10-5 & 2.125 x 10-4 units respectively. The
equilibrium constant is (unit excluded):
1) 0.35 2) 0.48 3) 2.5 4) 0.4
28. Which of the following will favour the reverse reaction in a chemical equilibrium
1) Increasing the concentration of the reactants
2) Removal of at least one of the products at regular intervals
3) Increasing the concentration of one or more of the products
4) Increasing the pressure
 2NH (g) H  94kJ mol1 . The concentration of H at eqm can
29. For the reaction N2(g) + 3H2 (g)  3 2
be increased by
I) Lowering the temp II) Increasing the volume of the system
III) Adding more N2 at constant volume IV) adding more H2 at constant volume
1) I & II 2) II & III 3) II & IV 4) III & IV
 2NO (g). At a fixed temp, the volume
30. Consider the following eqm in a closed container. N2O4 (g)  2
of the container is halved. For this change, which of the following statements is true regarding the eqm
constant (KP ) and degree of dissociation () ?
1) neither Kp nor  changes 2) both Kp &  change
3) Kp changes, but  does not 4) Kp does not change, but  changes
31. The equilibrium which is not affected by change of pressure among the following is :

1) H 2  I 2  2HI 2) PCl5 g   PCl3  Cl 2

 g  g  g 
g   g

3) 2SO 2 g   O 2g   2SO3 g  4) N 2O 4 g  2NO 2 g 

23V/TP/P 5 NEET - C +B

32. Which of the following will not be a reversible process?

1) Heating PCl 5 in a sealed container

2) Heating NH 4 Cl in a sealed tube

s

3) Heating CaCO3 in a sealed container

4) Heating HI in an open vessel

33. For a homogeneous chemical reactions, K p  K C when

1) n  0 2) n  1 3) n  2 4) n  3
34. At equilibrium, on adding heat, the equilibrium will shift to
1) High enthalpy side 2) Low enthalpy side
3) Zero enthalpy side 4) No change

35. The decomposition of pure HNO3 occurs as 4HNO3g   4NO 2 g   2H 2O g   O 2g  at a given tempera-
ture and pressure (P). Then at equilibrium
7 3
1024  Po 2  1024  Po 2 
1) Kp  4 2) Kp  4
 P  7Po 2   P  Po2 
7

1024 PNO 2 
4) Kp 
7
3) Kp  1024  Po 2  4
P  P O2

36. For the reaction , the equilibrium constant Kp changes with

1) Total pressure 2) Catalyst
3) Amount of H 2 & I 2 present 4) Temperature
37. For the reaction N2(g) + 3H2(g) 2NH3(g) equilibrium constant will change if:
1) Pressure is applied 2) More nitrogen is added
3) Catalyst is changed 4) Temperature is changed
38. What is the equilibrium expression for the reaction?
 P O ?
P4(s) + 5O2(g)  4 10(s)

PO
4 10 1
1) K c  P O 5 2) K c  O 5
4 2 2

P O 
4 10
3) K c  O 2 5 4) K c  5  P  O 
4 2

 CO is
39. Kp/Kc for the reaction CO(g) + 1 2 O2(g)  2(g)

1) 1 2) RT

3) 1 RT 4) (RT)1/2
23V/TP/P 6 NEET - C +B

40. In what manner will increase of pressure affect the following eqm :

 CO  g   H 2 ( g ) ?
C  s   H 2 O ( g ) 

1) A shift in the forward direction 2) A shift in the reverse direction

3) Increase in the yield of H2 4) Increase in the yield of CO
41. A mmonium carbamate vapour (NH 2 – COONH4) when heated to 200oC dissociates into a mixture of
NH3 & CO2 vapours with a V.D. of 13. From this data, the degree of dissociation of ammonium. carbam-
ate at 200oC is
1) 0.5 2) 1.5 3) 1 4) 0.75

 A (g) + 2B (g). 5 moles of AB were heated in a closed vessel to constant temperature.
42. 2AB2 (g)  2 2 2
Eqm was attained by the time 2 moles of it dissociated. If the eqm pressure was 12 atm, the KP of the
reaction is
1) 0.72 2) 0.9 3) 0.27 4) 0.6
43. Equimolar concentrations of H2 and I2 are heated to eqm. in a closed container. At eqm, the forward and
backward rate constants are found to be equal. What % of the initial concentration of H2 reacted and got
consumed at eqm?
1) 66% 2) 50% 3) 40% 4) 33%
44. KP and KC are related as

1) K P  K C (RT) n 2) K C  K P (RT) n

3) K P  K C  (RT) n 4) KC = KP

 2NH (g) at 750 K is 49, then the eqm. constant

45. The eqm. constant of the reaction N2(g) + 3H2 (g)  3

 1 3
for the reaction NH3 (g)  N 2 (g)  H 2 (g) at the same temp is
2 2

1) 1/49 2) 7 3) 49 4) 1/7
Name ................................................

Batch.................... Roll No. ............... ONLINE EXAM - NEET

02- 04 - 2022 Batch: LT-23 One Yr (G-1&2)

23V/TP/P Organic Naming, Chemical and Ionic Equilibrium

1. 2
2. 4
3. 4
4. 3
5. 4
6. 2
7. 1
8. 3
9. 3
10. 2
11. 2
12. 1
13. 2
14. 4
15. 3
16. 1
17. 3

1 2
18. 1 H2C = C - CH2 - CH3

3 CH - CH3
4CH3

19. 2

5
1
20. 4 CH3 CH2
6 CH2
4 C C CH
3 2

21. 3
22. 3
23. 2
24. 2
25. 2
26. 2

Kf 8.5x105
27. 4 K   0.4
K b 2,125x10 4
23V/TP/P 2 NEET - C +B

28. 3
2
29. 2 SnS2  Sn 4  2S K sp  Sn 4   S 

30. 4
31. 1 Equilibrium is not affected of n  0
32. 4 For reversible reaction , all components should exist together (ie closed system)
33. 1
34. 1 On increasing the temperature, equilibium is shifted towards high enthaply side and vice versa
4 4

Kp 
P  P 
NO 2 H2 O PO 2
35. 1 4
P  HNO 3

36. 4 Kp varies only with temp

37. 4 Equilibrium constant depends on temperature
38. 2 P4 (s) + 5O2(g)

39. 3 
ng  1 1  1
2   1/ 2 ; Kp /Kc = (RT) n = (T) –1/2
= 1 RT

40. 2
41. 3
42. 2
43. 4
44. 1
45. 4