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HPBOSE Model Test Paper

First Terminal Examination- Nov 2021


M.M: 50
Chemistry +1(Theory) Time: 3 Hours
Note :
1. All Questions are compulsory.
2. Q.N. 1 to 20 carry 1 marks each.
3. Q.N. 21 to Q.N. 29 carry 2 marks each.
4. Q.N.30 to 33 carry 3 marks each.

1. How many significant figures are there in 0.0405?


a. 5
b. 3
c. 4
d. None of these
2. The number of electrons in an ion M2+ will be (Atomic number =12)
a. 7
b. 10
c. 4
d. None of these
3. Go through Statement – I and Statement – II carefully
Statement I : The equation PV = nRT does not apply to real gases at all conditions of
temperature and pressure.
Statement II: For real gases the attractive forces between the molecules cannot be neglected.
Use the following Key to choose the appropriate answer.
(A) If both Statement- I and Statement- II are true, and Statement - II is the correct
explanation of Statement– I.
(B) If both Statement - I and Statement - II are true but Statement - II is not the correct
explanation of Statement – I.
(C) If Statement - I is true but Statement - II is false.
(D) If Statement - I is false but Statement - II is true.
4. One mole of Methane contains:
a. 4 atoms of Hydrogen
b. 6.02 × 1023 atoms of hydrogen
c. 2.408 × 1024 atoms of hydrogen
d. None of these
5. An orbital in which n=4, l=3 is expressed as?
a. 4s
b. 4p
c. 4d
d. 4f
6. The series of hydrogen spectrum which lies in visible region is
a. Lyman
b. Balmer
c. Paschen
d. Brackett
7. The number of groups in d- block elements is
a. 6
b. 2
c. 10
d. 14
8. Which is correct in the following -
a. Radius of Cl atoms is 0.99 Å, while that of Cl+ ion is 1.54 Å
b. Radius of Cl atoms is 0.99 Å, while that of Na atom is 1.54 Å
c. Radius of Cl atoms is 0.95 Å, while that of Cl– ion is 0.81 Å
d. Radius of Na atoms is 0.95 Å, while that of Na+ ion is 1.54 Å
9. The elements of groups, 1, 2, 13, 14, 15, 16 and 17 are collectively called -
(A) Noble gases
(B) Representative or normal elements
(C) Transition elements
(D) Inner transition elements
10. The correct order of atomic size of C, N, P, S follows the order -
(A) N < C < S < P
(B) N < C < P < S
(C) C < N < S < P
(D) C < N < P < S
11. Match list-I with list-II and select the correct answer using the codes given below -
List-I List-II
Ion Radius (in pm)
(I) Li+ (a) 216
(II) Na + (b) 195
(III) Br– (c) 60
(IV) I – (d) 95
Codes :
I II III IV
(A) a b d c
(B) b c a d
(C) c d b a
(D) d c b a
12. The combination of atoms occur because they want :
(A) To decrease number of electrons in the outer most orbit
(B) To attain an inert gas configuration
(C) To increase number of electrons in the outer most orbit
(D) To attain 18 electrons in the outermost orbit
13. Which condition favours the bond formation:
(A)Maximum attraction and maximum potential energy
(B) Minimum attraction and minimum potential energy
(C)Minimum potential energy and maximum attraction
(D) None of the above
14. According to Fajan’s rules necessary condition to form covalent bond is:
(A) small cation and large anion
(B) small cation and small anion
(C) large cation and large anion
(D)large cation and small anion
15. The hydrogen bond is strongest in:
(A) O – H - - - S
(B) S – H - - - O
(C) F – H - - - F
(D) O – H - - - O
16. Which of the following statements is not correct?
(A) Double bonds is shorter than a single bond
(B) – bond is weaker than bond
(C)Double bond is stronger than a single bond
(D) Covalent bond is stronger than a hydrogen bond
17. Which of the molecule is trigonal bipyramidal :
(A) BF3
(B) CH4
(C) PCl5
(D) SF6
18. In the gas equation PV = nRT, the value of universal gas constant would depend only on -
(A) The nature of the gas
(B) The pressure of the gas
(C) The temperature of the gas
(D) The units of measurement
19. At 100ºC a gas has 1 atm. pressure and 10 L volume. Its volume at NTP would be -
(A) 10 litres
(B) Less than 10 litres
(C) More than 10 litres
(D) None
20. The total pressure of a mixture of two gases is -
(A) The sum of partial pressures of each gas
(B) The difference in partial pressures
(C) The product of partial pressures
(D) The ratio of partial pressures.
21. State & Explain Law of definite proportions.
22. Calculate the volume occupied by 22g of CO2 at N.T.P.
23. Draw and discuss the shape of p- orbitals.
24. State & Explain Heisenberg’s uncertainty principle.
25. Explain a) Modern Periodic Law b) Diagonal relationship
26. Give reason: Size of anion is larger than parent atom.
27. What is the difference between sigma and pi bond?
28. NH3 molecule has net dipole moment whereas BH3 molecule does not have, explain.
29. State and explain Dalton’s law of partial pressures.
30. An organic compound contains 48% carbon, 8% Hydrogen, 28% Nitrogen & 16% Oxygen. Write
its empirical formula.
31. a. What is the difference between orbit & orbital?
b. Half-filled and completely filled orbitals have extra stability, why? 2,1
32. At 25 and 760 mm of Hg pressure, a gas occupies 600 mL volume. What will be its pressure at
a height where the temperature is 10 and volume of the gas is 640mL?
33. Define hybridization. Explain the geometry of water molecule on the basis of hybridization.

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