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02 DIS2 Course Notes
02 DIS2 Course Notes
DIS2
Contents
Section Subject
Preliminary Pages
1 Magnetic Particle Inspection (MPI)
1.1 History of magnetism
1.2 Types of magnetism
1.3 Theory of magnetism
1.4 Electromagnetism
1.5 Magnetic Hysteresis
1.6 Definition of Terms
1.7 Flux leakage
1.8 Methods of magnetisation
1.9 Continuous and Residual Magnetisation Techniques
1.10 Detecting media, UV light and other equipment
1.11 Demagnetisation
1.12 Alternative forms of electric current applied in MPI
1.13 Verification of magnetisation
1.14 MPI test procedure
1.15 Recording indications
1.16 Factors affecting MPI sensitivity
2 Inspection Methods Available to Inspect Underwater
Structures
2.1 Visual inspection
2.2 Videography
2.3 Photography
2.4 Ultrasonic techniques
2.5 Flooded member detection (FMD)
2.6 Crack detection techniques
2.7 Taking measurements underwater
2.8 Crack depth measurement
2.9 Cathodic potential (CP) measurement
3 Corrosion
3.1 Energy considerations in corrosion
3.2 The corrosion process
3.3 Electric theory
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Contents Copyright © TWI Ltd
4 Types of Corrosion
4.1 Corrosion cells
4.2 Dissimilar metal corrosion cell (galvanic corrosion)
4.3 Concentration cell corrosion
4.4 Pitting
4.5 Intergranular corrosion
4.6 Grain boundary corrosion
4.7 Stress corrosion cracking
4.8 Corrosion fatigue
4.9 Erosion corrosion
4.10 Fretting corrosion
4.11 Biological corrosion
4.12 Other factors affecting corrosion rates
5 Corrosion Protection
5.1 Cathodic protection
5.2 Impressed current cathodic protection (ICCP) system
5.3 Using coatings to protect the structure
5.4 Inhibitors (controlling the electrolyte)
6 Corrosion Protection Monitoring
6.1 Inspection requirements
6.2 Calibration procedures for hand-held CP meters
6.3 Operating procedures
7 Welding and Welding Defects
7.1 Joining metal components
7.2 Fabricating offshore structures
7.3 Welding processes
7.4 Types of welded joint
7.5 Types of weld
7.6 Welding metallurgy
7.7 Reporting defects in welds
7.8 The Welding Institute measuring gauge
7.9 Welding Institute leg length gauge
8 Ultrasonic Inspection
8.1 Physics of ultrasound
8.2 Wavelength
8.3 Further effects of ultrasonic properties in materials
8.4 The direction of propagation of an ultrasonic wave
8.5 Generating ultrasound
8.6 Types of transducers (probes)
8.7 The sound beam
8.8 Principles of ultrasonic testing
8.9 Ultrasonic test systems
9 Cleaning for Inspection and Profile Grinding
9.1 Cleaning
9.2 Profile grinding
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Contents Copyright © TWI Ltd
The Certification Scheme for
Personnel
TWI
Is a world centre for materials joining technology and is the parent organisation
for TWI Certification.
Company profile
TWI Ltd, the operating arm of The Welding Institute, is one of the world's
foremost independent research and technology organisations. Based at Great
Abington near Cambridge since 1946, TWI provides industry with engineering
solutions in structures incorporating welding and associated technologies
(surfacing, coating, cutting, etc.) through:
Information.
Advice and technology transfer.
Consultancy and project support.
Contract R&D.
Training and qualification.
Personal membership.
Non-profit company
TWI is one of Europe’s foremost independent not-for-profit research and
technology organisations, employing 740 scientists, technologists,
administrative and support staff world-wide (540 in the UK and Europe) and
with annual (2012) group sales of £75million (€88 million) and UK/Europe
annual (2012) sales of £61 million (€72 million).
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Prelims Copyright © TWI Ltd
Global benefits
TWI works across all industry sectors with expertise in key aspects of materials,
materials joining, structural integrity, static and dynamic testing and non
destructive testing (NDT)/non destructive evaluation (NDE).
The majority of TWI’s activities (65%) are contract research, funded by industry
and built around the development of advanced technologies. TWI is also an
active participant in collaborative research programmes in Europe and the UK.
Confidential consultancy
TWI undertakes contract R&D in confidence for both industry and governments.
As a consultant it can offer individual experts or teams able to help solve
problems of all kinds related to materials joining. It will send its specialists
anywhere in the world at short notice on troubleshooting missions.
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Prelims Copyright © TWI Ltd
TWI Certification Ltd
This is a TWI Group company formed in 1993.
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Prelims Copyright © TWI Ltd
It can, therefore, be seen that CSWIP is a comprehensive scheme, which
provides for the examination and certification of individuals seeking to
demonstrate their knowledge and/or experience in their field of operation. The
scope of CSWIP includes welding inspectors, welding supervisors, welding
instructors and underwater inspection personnel.
Requirement documents
All CSWIP examination requirements documents are available free of charge
and may be downloaded from the website www.cswip.com.
Inspector categories
There are four categories of certification in the underwater inspector scheme:
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Prelims Copyright © TWI Ltd
The CSWIP 3.2U examination
The examination itself consists of two main elements, a theoretical examination
and a practical assessment.
Theory examination
This consists of two separate papers, with a total of 100 multi-choice questions.
One paper:
Contains 50 sector specific questions on 3.2U subjects relating to sub-sea
applications.
The pass mark is 70% for each paper and the time allowed is 75 minutes per
paper.
Practical examination
This will consist of the following parts:
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Prelims Copyright © TWI Ltd
28/08/2015
Introduction
Introduction Introduction
1
28/08/2015
Any Questions?
2
Section 1
1 Ferromagnetism
This is shown by materials which can be strongly magnetised and which
show good magnetic properties.
2 Paramagnetism
This is shown by materials which are weakly attracted by strong magnetic
fields.
3 Diamagnetism
This is shown by materials that are repelled by a strong magnetic field. Any
externally applied magnetic field induces a like magnetic field within the
material and repulsion occurs.
For a list of some common materials and their magnetic properties see Table
1.1.
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Magnetic Particle Inspection 1-1 Copyright © TWI Ltd
1.3 Theory of magnetism
In ferromagnetic materials, the atoms are gathered together in groups called
domains. These domains have a magnetic moment, one end acting as a north
pole, the other as a south pole. This magnetic moment is created by the
combined effort of the motion of electrons around the nucleus of the atom and
by electron spin, which is the rotation of the electron around its own axis.
When the material is un-magnetised the domains lie distributed randomly and
their magnetic effects cancel each other see Figure 1.1.
e.g
Magnetic field
When all the domains in a material are fully aligned the material is said to be in
the magnetically saturated state see Figure 1.3.
Magnetic field
Figure 1.3 Saturated state: Domains fully orientated in a strong external field.
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Magnetic Particle Inspection 1-2 Copyright © TWI Ltd
Even after the external magnetic field is removed there will be some residual
magnetism left in the material as the domains will not be totally randomised
see Figure 1.4.
1.3.1 Polarity
When the material is magnetised it has a north and a south pole. These poles
are located at opposite ends of the material and magnetism seems to be
concentrated at these points. The north or north seeking pole of a magnet is
said to be the pole pointing towards the Earth’s North Pole; the south seeking
pole pointing towards the Earth’s South Pole.
Magnetic poles show attraction and repulsion. Like poles repel one another,
unlike poles attract one another see Figure 1.5.
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Magnetic Particle Inspection 1-3 Copyright © TWI Ltd
1.3.2 Magnetic field
This is described as the area surrounding a magnet in which the magnetic
forces exist. Lines of force or lines of magnetic flux represent the magnetic
field. These lines are purely imaginary and were introduced by Michael Faraday
as a means of visualising the distribution and density (flux density) of a
magnetic field. The SI unit used to measure the flux density is the Tesla (T).
For practical MPI the minimum flux density required is 1.0(T).
1.4 Electromagnetism
The type of magnetism produced in a bar magnet is known as longitudinal
magnetism. In electromagnetism, when an electric current flows through a
conductor (copper wire or rod), a magnetic field is set up around the conductor
in a direction at 90o to the electric current. This is explained by the Right Hand
Rule.
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Magnetic Particle Inspection 1-4 Copyright © TWI Ltd
Figure 1.7 The Right Hand Rule.
If the thumb of the right hand is extended in the direction in which the current
is flowing, then the direction of the magnetic field is represented by the fingers.
When a conductor carries an electrical current, strong magnetic flux lines are
created (in the direction of the fingers as with the Right Hand Rule see Figure
1.7), this is called circular magnetism.
The field within the loop has direction: one side will be a north pole and the
other a south pole. By increasing the number of loops, a coil, or solenoid, is
created and the strength of the field passing through the coil is proportional to
the current passing through the conductor in amperes multiplied by the number
of turns in the solenoid.
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Magnetic Particle Inspection 1-5 Copyright © TWI Ltd
When a ferromagnetic specimen is placed in an energised coil, the magnetic
field is concentrated in the specimen. One end of the specimen is a north pole
and the other a south pole. This is called longitudinal magnetism; it has polarity
and is, therefore, readily detectable.
The word, Hysteresis, is derived from the Greek word for delayed and is used to
describe one quantity lagging behind another. The variation of B-H follows a
Hysteresis loop and is characteristic to a particular ferromagnetic material.
The figure below is a typical Hysteresis loop where the co-ordinates represent
magnetising force (H) on the horizontal axis and flux density (B) on the vertical
axis.
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Magnetic Particle Inspection 1-6 Copyright © TWI Ltd
The dotted line (o-a) is often referred to as the Virgin Curve. Point (a) towards
point (b) is where the hysteresis loop begins. As the Magnetising Force is
reduced the flux density does not fall back to zero but follows the line (a-b). So,
at (b) there is a zero magnetising force but a flux density (o-b) remains. The
flux is lagging behind the force and this is what gives ferromagnetic materials
their permanent magnetism.
As the negative force is reduced, point (e) is reached, exactly opposite point (b)
and reversal to a positive magnetising force achieves a zero flux density at
point (f), exactly opposite point (c).
The loop is completed by increasing the magnetising force, giving a B-H ratio
along curve (f-a). Note: Once the Virgin Curve is produced, the Hysteresis loop
does not pass through (o) again. The specimen will not be demagnetised until
special steps are taken to achieve this.
The inner of the two curves shown is characteristic of materials such as low
carbon steel defined as a soft ferromagnetic, whilst the outer would be typical
of a hard ferromagnetic material such as high carbon steel. Modern permanent
magnets are generally made from the latter and are of low permeability/high
retentivity alloys that have been subjected to large magnetising forces.
Hard
ferromagnetic
Soft
ferromagnetic
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Magnetic Particle Inspection 1-7 Copyright © TWI Ltd
Table 1.2 Soft and hard ferromagnetic material properties.
Soft Ferromagnetic Hard Ferromagnetic
Typically low carbon steel Typically high carbon steel
High permeability Lower permeability
Easy to magnetise More difficult to magnetism
Low residual magnetism High levels of residual magnetism
Flux density The number of magnetic flux lines per unit area.
Symbol = B
SI unit = Tesla = T
Symbol = H
SI unit = Ampere-turns per metre = Amps per
metre.
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Magnetic Particle Inspection 1-8 Copyright © TWI Ltd
1.7 Flux leakage
A flux leakage is a break or a discontinuity in a magnetic circuit. Any abrupt
change of permeability within a magnetic specimen will change the number of
flux lines that can flow and thus, there will be a diversion of the field.
Magnetic particle inspection relies on flux leakage fields being seen on the
surface of a ferromagnetic specimen under test. All defects produce flux
leakage but not all flux leakage fields are created by defects.
The magnetic field must run in a direction so that it can be interrupted by the
defect, thus producing a flux leakage field. Also the degree of distortion at the
leakage must allow the magnetic particles to provide an adequate degree of
contrast between the leakage and the adjacent material surface, so that it is
readily visible.
Flux lines will take the path of least resistance, hence the highest permeability.
The figure below shows flux lines flowing in a ferromagnetic bar, but having to
divert around an air gap, creating a flux leakage.
However, if ferromagnetic particles are sprinkled on the bar they will start to
form a magnetic bridge across the flux leakage and a highly preferred path.
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Magnetic Particle Inspection 1-9 Copyright © TWI Ltd
Figure 1.12 Magnetic flux leakage turns the edges of the crack into
consequential poles.
Size of defect.
Shape of defect.
Volume of defect.
Orientation of defect.
Depth below surface.
Permeability of material (hard or soft ferromagnetic).
1.7.1 Indications
Indications are any particle indications that are seen on the specimen under
test. Just as not all flux leakage fields are defects, not all indications are due to
flux leakage.
Relevant.
Non-relevant.
Spurious.
Size.
Position.
Orientation.
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Magnetic Particle Inspection 1-10 Copyright © TWI Ltd
1.7.3 Non-relevant indications
Non-relevant indications are true magnetic particle patterns formed and held in
place by leakage fields. However, they are caused by design features and the
structure of the specimen and only in exceptional cases will they affect the
fitness-for-purpose of the specimen.
Tool marks.
Abrupt changes of geometry.
Dissimilar magnetic material (HAZ or heat-treated material).
Forging flow lines.
Grain boundaries.
Cold working.
However, there is one spurious indication called magnetic writing that is a little
different. If two pieces of steel touch when one of them is in a magnetised
condition, local poles are created at the areas of contact. If magnetic particles
are then sprayed on the surface, the local poles become visible as fuzzy lines.
Figure 1.14 below shows, the magnetic lines of force are longitudinal in a bar
and thus the bar has magnetic poles. Transverse flaws will easily show; but
longitudinal defects such as seams, which are very straight, will not show.
However, it is accepted that flaws up to 30o from the flux lines will also be
shown. In fact, longitudinal flaws having a transverse component, such as
jagged cracks, will almost certainly show.
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Magnetic Particle Inspection 1-11 Copyright © TWI Ltd
(Eg Bench mag flow, yoke and coil)
Under normal circumstances, the circular field is not detected due to it having
no external poles, but a longitudinal surface flaw at 90o creates a flux leakage,
creating miniature poles (consequential poles) and is thus detectable with
magnetic particles. Figure 1.15 shows the effect of flaw orientation in a
circularly magnetised bar.
Magnetising current
(Eg Axial current flow, threader bar)
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Magnetic Particle Inspection 1-12 Copyright © TWI Ltd
1.8 Methods of magnetisation
The equipment used for MPI can be divided according to size and purpose. The
magnetising force may be supplied by anything from a small permanent magnet
to a highly sophisticated fixed installation, utilising high values of rectified
current and finely calibrated meters.
On straight work pieces like plates and cylinders, good contact between the
pole pieces and the work piece is easily obtained by having shaped pole pieces,
flat for plate and radiused for cylindrical-shaped work pieces. For more
complicated shapes, for example, when examining the weld at 12 ’clock on the
joint of a vertical diagonal member on a node, the pole pieces need to rotate as
well as being shaped in order to make good contact.
BS EN ISO 9934-1 states that a lift test should be carried out before a magnet
is used for MPI. The lift test should confirm that the magnet can lift 18kg with a
pole spacing of between 75-150mm. The inspection area is between the poles
and half the pole spacing either side.
N S
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Magnetic Particle Inspection 1-13 Copyright © TWI Ltd
Table 1.3 Advantages and disadvantages of permanent magnets.
Advantages Disadvantages
No power supply needed Direct longitudinal field only
Cling to vertical surfaces Deteriorate with wear
No electrical contact problems Have to be pulled from test surface
Cheap and ready available No control over field strength
No damage to test piece Magnetic particles attracted to poles
Lightweight Poles must have good contact
1.8.2 Electromagnets
Electromagnets are made from soft iron laminates to reduce eddy current
losses, if powered by alternating current (AC). The yoke laminates are encased
in a multi-turn coil usually powered by mains electricity, which has been
stepped down to 6 or 12V. The legs of modern equipment are normally
articulated to allow area contact on uneven surfaces.
Electromagnets produce a longitudinal field with the test area being a circle
inscribed by the poles. Defect orientation is the same as when using a
permanent magnet. BS EN ISO 9934-1 states that a lift test should be carried
out prior to using for MPI. The lift test should confirm that the electromagnet
can lift 4.5kg with a pole spacing of up to 300mm.
1.8.3 Prods
Prods induce a circular magnetic field by sending a high amperage current
(typically 1000A) through the test piece. The high amperage can cause arcing
between the electrodes and test surface. Contact points must be carefully
cleaned, and electrode materials chosen to prevent contamination of the test
piece.
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Magnetic Particle Inspection 1-14 Copyright © TWI Ltd
Prods produce a distorted circular magnetic field with defects showing at a
maximum when orientated along a line between the prod tips.
As with all Current Flow Inspection techniques, particular care has to be taken
to avoid surface damage of the component under test due to arcing or
contamination.
OIS of Great Yarmouth manufacture and supply a composite MPI unit that is
purpose designed and built for underwater use, see Figure 1.19.
Figure 1.19 OIS mark 2 subsea MPI unit and Current Flow Prods.
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Magnetic Particle Inspection 1-15 Copyright © TWI Ltd
1.8.4 Flexible Coil
In this technique the current-carrying cable is wound tightly around the
component. It is a longitudinal magnetisation method and will find defects lying
parallel to the cable. The area to be tested is considered to lie between the
turns of the coil.
This method is widely used offshore and two practical applications will serve to
show how the technique may be applied.
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Magnetic Particle Inspection 1-16 Copyright © TWI Ltd
The current requirement for this technique is determined from the formulas:
Y2
I dc = 7.5 T+
4T
Where:
Y2
I ac = 7.5 10+
40
Where:
I = Required current (AC). 10 = Constant.
Y = Coil spacing. 7.5 = Constant.
As AC will produce magnetic flux only on the skin of the work piece, the
thickness of the material is of no consequence, therefore another constant, 10
replaces T.
16 r
Ipeak ac
ac
N
Where:
Ipeak = Peak current value (AC).
r = Radius of the coil (mm).
N = Number of turns in the coil (minimum 3).
16 = Constant.
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Magnetic Particle Inspection 1-17 Copyright © TWI Ltd
The distance either end of the coil where minimum field strength of 1.0 Tesla
should be present, is given by the formula:
30
Where:
d = Width of the inspection area (where field strength = 1.0T).
N = Number of turns in the coil.
I = Peak current (Amps).
30 = Constant.
This produces a transverse field between the two sides of the loop. The loop has
to be positioned so that the current in the two sides of it is moving in the same
direction, otherwise the magnetic fields will tend to cancel instead of reinforce.
Furthermore, the return cables not forming the parallel loops must be a
minimum of 10d away from the inspection area, as shown in Figure 1.23. The
direction of the field may be ascertained by applying the Right Hand Rule. The
required current may be found by applying the formula:
Ipeak (ac) = 30 x d
The OIS mark 2 sub-sea MPI unit may be used for this technique. Current up to
1000 amps can be used see Figure 1.24.
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Magnetic Particle Inspection 1-18 Copyright © TWI Ltd
Table 1.6 Advantages and disadvantages of coils.
Advantages Disadvantages
Cables can be positioned relatively Relatively weak field is produced
easily
Large areas can be inspected with Large, heavy step-down transformers
one placement of the coil or loop are required
Field strength and thus flux density Isolating transformers are required
can be adjusted on deck
Demagnetising is easily achieved Long cables required
Flexible cables
connected that
may be used as
parallel
conductors or
encircling coils.
For example, leakage fields from the coil wrapped around the work piece and
flux leakage in the vicinity of a prod from spurious indications, such as grain
boundaries, due to high flux density in these regions. The closer the magnetic
field is to saturation the more sensitive it is to flux leakage due to small order
inhomogeneities in the material, see Figure 1.25. The recommended flux level
for satisfactory crack detection is between one third and full saturation.
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Magnetic Particle Inspection 1-19 Copyright © TWI Ltd
Figure 1.25 Variation of types of defects giving indications as the field strength
increases.
The particles used are fine ferrous-oxides that are much lighter than iron filings
and will go into suspension in water more easily while remaining suspended
much longer. A fluorescent powder (usually green coloured) is mixed with the
particles so that they will fluoresce under ultraviolet light making them easier to
see.
The method of use is to apply the magnetic field and while the test surface is
magnetised the ink is applied. Any flaws cause flux leakage with a resultant
build-up in flux density. The ferrous-oxide in the ink will be attracted to this
strong magnetic field and will collect there. Using a suitable ultraviolet light the
indication can be viewed, interpreted and reported.
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Magnetic Particle Inspection 1-20 Copyright © TWI Ltd
Ink properties
Ink properties are required to meet a certain standard. The current standard for
MPI ink is BS EN ISO 9934-2. This standard states that inks must be non-toxic,
free from contaminants, not cause discomfort to users and be non-corrosive to
the work piece. Additionally, the ink should have the following properties:
The sample is required to undergo a settling test to confirm the ink has been
made up to the correct concentration.
Settling test
The test is completed to the following procedure:
Draw off a 100ml sample into a calibrated settling flask (called a Sutherland
or thistle Flask) see Figure 1.26.
Allow the sample to settle for 60 minutes.
Read off and record the quantity of solids that will have collected in the
bottom of the flask.
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Magnetic Particle Inspection 1-21 Copyright © TWI Ltd
Figure 1.26 Settlement flask.
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Magnetic Particle Inspection 1-22 Copyright © TWI Ltd
Safety considerations with ultraviolet light
Ultraviolet light can be harmful to health causing burns, cataracts and cancer if
not used under controlled conditions.
This type of bulb is put into a housing and a Wood’s Filter is placed in front of it,
which blocks the harmful wavelengths of UV light while allowing UVA at 365-
400nm to pass through.
Care should still be exercised when using ultraviolet light to avoid looking into it
or shining it into anyone else’s eyes.
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Magnetic Particle Inspection 1-23 Copyright © TWI Ltd
Figure 1.27 OIS underwater black light with attached Burmah Castrol Strip.
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Magnetic Particle Inspection 1-24 Copyright © TWI Ltd
It must be emphasised that these meters are only for measuring residual field
strength. They are far too sensitive to measure the magnitude of the induced
field applied for inspection and will be damaged if they are used for such.
Prior to MPI to prevent the possibility of vector fields that would reduce the
sensitivity of the inspection. A vector is the result of an opposing or
differently oriented field interfering with the applied field.
On offshore structures because they are fixed in the Earth’s magnetic field,
subject to constant vibration and may be weakly magnetic.
After the inspection so as not to interfere with any sensitive electronic
equipment.
Prior to welding so as to avoid arc blow.
1.11 Demagnetisation
Looking at a typical Hysteresis loop for a ferromagnetic material, after the initial
magnetising force is applied and then removed, it is virtually impossible to end
the test with a zero flux density. Even if a negative coercive force is applied it
will only keep the flux density at zero, as long as it continues to be applied.
Figure 1.29 shows that the key to demagnetisation is that a reversing and
reducing magnetising force must be applied, so that the Hysteresis loop reduces
until all the parameters achieve zero. There are a number of ways to achieve
this.
Field strength
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Magnetic Particle Inspection 1-25 Copyright © TWI Ltd
1.11.2 Electromagnetic yoke
A most useful way to remove local residual fields on components in situ, on a
structure that cannot easily be moved or removed, is by means of a portable AC
powered electromagnet. The energised yoke is pulled over and off the
component, to a distance of about 450mm and then switched off. If the level
achieved is not adequate, the operation is repeated in the same way and
direction until the residual field is removed.
Approximately
450mm
then switch off
AC yoke
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Magnetic Particle Inspection 1-26 Copyright © TWI Ltd
Table 1.7 Advantages and disadvantages of DC current.
Advantages Disadvantages
Can find sub-surface defects No agitation
Availability from batteries Less sensitive to surface defects
Field Strength
Distance
Flux Leakage
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Magnetic Particle Inspection 1-27 Copyright © TWI Ltd
As the current is constantly reversing, no single value for the current can be
measured. To determine a single measured value for an AC current the root
mean square (RMS) value, as seen in Figure 1.33, is calculated. To calculate the
RMS value, all that is required is to divide the peak value by the constant
1.414. The normal situation is that an amperage reading indicates the current
being applied. The meter will be indicating an RMS value. Therefore, to obtain
the peak value, multiply the meter reading by 1.414.
strength
Field
Skin
Distance
Flux Leakage
Portable flux indicators, such as the Burmah Castrol Strip are common and
simple to use, giving a clear visual indication of the direction of the surface
field. They provide only a guide to the magnitude and direction of the tangential
field strength and as such, should not be used to verify the acceptability of the
field strength.
They are a rough guide to the magnitude of the surface field. (This is only true
if the flux indicator abuts intimately with the test specimen).
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Magnetic Particle Inspection 1-28 Copyright © TWI Ltd
Flux indicators are made with high permeability magnetic materials with low
coercivity and low remanence so that a flux can be easily induced into them,
yet without permanently magnetising them. Opinion differs on their efficacy
when used with permanent magnets and DC electromagnets. In every case
when a permanent magnet or electromagnet is used, good area contact of the
poles is imperative or the flux indicator is useless. Results may be misleading
when indicators are used in a coil.
Segment type.
Foil type.
The eight segment type, with a fixed foil is popular in the US.
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Magnetic Particle Inspection 1-29 Copyright © TWI Ltd
The simulated discontinuities in a magnetic flux indicator are arranged in three
parallel lines. These foils are less than 0.2mm thickness and flexible, which
gives them a significant advantage over the segment type.
They are placed on the test object as it is being inspected, ideally at 90o to the
possible defect orientation. The number of linear indications and thickness of
the slot indications produced on the strips, gives the Inspector a general idea of
the magnetic field strength in that particular area.
They are relatively easily applied to the component and can be successfully
used with both wet and dry inspection media, using the continuous method of
magnetisation. The results are fairly repeatable as long as the same orientation
of the magnetic field is applied and maintained.
Disadvantages of these strips are that they cannot be bent to complex shapes
and are not suitable for multi-directional field systems since they only indicate
defect indications in one direction only.
Figure 1.37 Combined Gauss Meter, white light and black light meter.
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Magnetic Particle Inspection 1-30 Copyright © TWI Ltd
1.14 MPI test procedure
General procedure that may be applied or adapted for offshore use would be:
1.14.3 Pre-inspection:
Establish the datum and place tape measure, mark up the weld.
Complete a close visual inspection (CVI). Identify any areas that may cause
spurious indication during the MPI.
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Magnetic Particle Inspection 1-31 Copyright © TWI Ltd
1.14.5 Post inspection
Demagnetise.
De-rig and recover all equipment to the surface.
Wash all equipment with fresh water.
Flush out the ink system.
Report the results to the client.
Cancel work permits.
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Magnetic Particle Inspection 1-32 Copyright © TWI Ltd
The method of operation is to break the internal barrier and mix the contents
by manipulating the bag. This takes approximately 45 seconds and the contents
will take on a grey colour.
Apply the bag to the test site. The contents will remain liquid for 100
seconds.
Apply the magnetising force during this period.
The defect indication will be recorded as a white mark in the packet.
Leave the packet in place until the liquid sets (approximately 5 minutes).
The packet can then be removed and the indication length and breadth can
be measured. These dimensions will give an indication of defect length and
depth.
1.15.3 Video
Some video cameras will capture the visible light of the fluorescent particles
when the ultraviolet light is directed on them. This signal can be recorded on
disc.
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Magnetic Particle Inspection 1-33 Copyright © TWI Ltd
Figure 1.39 An example MPI data report sheet.
1 Diver inspector.
2 Equipment being used.
3 Conditions on site.
For maximum efficiency of the operation, the diver inspector should, as well as
being comfortable and well equipped for the dive as possible:
Have confidence in his ability to use the equipment for a particular test.
Be confident in his ability to detect defects with it.
Be sure of the value of his contribution to the efficiency and safety of the
plant or structure he is inspecting.
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These last three points are obtained from the competence and confidence
imparted to the inspector by good training and an active involvement in the
inspection function.
The sensitivity of the MPI test will depend on several factors, some of which will
be within the control of the inspector and others not. The sensitivity of
detection depends ultimately on the contrast that can be produced between the
defect and its surroundings and the definition, which tells the size, shape and
orientation of the defect.
Figure 1.40 shows some of the factors that will affect the performance. Like a
chain, it will only be as good as its weakest link.
An explanation for each of the numbered points from Figure 1.40 that affect the
sensitivity of a Magnetic Particle Inspection follows.
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1.16.5 Factors affecting definition
The following factors are important when considering definition.
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History of Magnetism
Magnetism Ferromagnetism
1. Ferromagnetism.
2. Paramagnetism.
3. Diamagnetism.
Paramagnetism Diamagnetism
Materials which are weakly attracted by strong Materials that are repelled by a strong magnetic field.
magnetic fields
An externally applied magnetic field induces a like magnetic
field within the material and repulsion occurs.
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When the material is magnetised it has a north and a south pole. These Magnetic poles show attraction and repulsion
poles are located at opposite ends of the material and magnetism
seems to be concentrated at these points.
The north or north seeking pole of a magnet is said to be the pole that
Like poles repelling
points towards the Earth’s North Pole. The south pole of the magnet
pointing towards the Earth’s South Pole.
Unlike poles
attracting
Domains aligned due to application of Material in a magnetised state
external magnetic field
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Not cross.
Seek the path of least resistance.
Be in constant tension.
Decrease in density (they spread out) when Magnetic field
they move from an area of higher permeability surrounding a
bar magnet
to an area of lower permeability.
Prefer to travel in materials that easily accept
magnetic fields.
N S
Magnetic flux density describes the 10cm The unit of flux density (B) is defined as the
amount of magnetism within a specimen
and is abbreviated by the letter B. ....... density of a magnetic field in which a conductor
....... 10cm
carrying 1 ampere at right angles to that field
When a magnetising force is applied, has a force of 1 Newton per metre acting on it.
lines of force of magnetism will be This unit is called a tesla (T).
created within the specimen, the number Low flux density
of lines depends on the size of the
magnetising force.
When a magnetic field is induced in a work piece
1cm by an electric current flowing in a cable,
These lines represent the magnetic force .......
arranged either as a coil or parallel conductors,
and the flux density is the term applied .......
1cm the input electrical force is called the
to the quantity of them that emerge per magnetising force (H).
unit cross section of the specimen. High flux density
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When magnetising a piece of steel using and electrical The previous graph shows the flux density
magnetising force, there is not a uniform increase in values for a magnetising current for a field being
flux density with a uniform increase in magnetising set up in one direction by a DC supply.
force.
If the field is set up by an AC supply then the
magnetic field will experience a complete
reversal of direction for each cycle and
successive cycles will trace out a loop for the
relationship between the magnetising force and
DC Supply flux density.
The flux density rises rapidly to point A and thereafter rises less rapidly This is known as the hysteresis loop.
as the condition approaches saturation of the magnetic field.
Permeability:
The ease with which a material can be
magnetised.
Retentivity:
Virgin curve
A measure of a material’s ability to retain
magnetism when the magnetising force is
removed.
Coercive force:
A measure of the amount of reverse magnetic
force needed to return a material’s magnetic
field to zero.
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Reluctance: B B
AC magnetising source
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Demagnetising can be accomplished by heating MPI is based on the phenomenon that the path
the component up to the curie point (700– of the magnetic flux in a ferromagnetic material
720oC). is distorted because inhomogeneities like cracks,
blowholes, inclusions and grain boundaries have
This method is not applied offshore. different magnetic properties to a greater or
lesser degree than the surrounding material.
It is possible to demagnetise by vibrating or
beating the component but this has no practical All systems of MPI need some method of
application. detecting this distortion of the magnetic flux,
most often called flux leakage.
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Advantages: Disadvantages:
All permanent magnets loose strength with age.
Magnets are cheap and readily available. They only produce a direct longitudinal field.
No power supply is required for permanent magnets. There is no skin effect.
There are no contact problems with the poles and The magnet will have to be physically removed from
the work piece, thus arcing or damage to the surface the work piece.
is avoided. There is no control over field strength, the magnet
They will be self-supporting and can be used only has one value.
overhead easily. The magnetic poles on the magnet may attract the
They are relatively lightweight. iron particles in the indicating medium.
Good pole contact is extremely desirable to ensure
maximum flux density in the work piece.
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Electro-magnet Electro-magnet
Advantages: Disadvantages:
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Advantages:
Disadvantages:
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Combined Gauss
meter with white
light and black light
Berthold gauge meter
Visual detection is achieved by observing the distortion of Ink properties are required to meet standards for
the magnetic field as shown by the patterns in magnetic composition, content, safety and toxicity. The current
particles distributed over the test surface. These magnetic standard for MPI inks is BS EN ISO 9934-2:2002.
particles are available as a liquid suspension these water-
based inks are the type used underwater. This standard states that inks must be non-toxic, free of
contaminants, not cause discomfort to users, and be non-
The particles used are fine ferrous oxides that are much corrosive to the work piece.
lighter than iron filing and therefore will go into suspension
in the water more easily and remain suspended much The ink grains should be fine enough to reduce
longer. gravitational effects to go easily into suspension but not
be so fine as to coagulate in the liquid.
For underwater use a fluorescent powder is mixed with the
particles so that they will fluoresce under ultra-violet light. The grains should have an elongated shape to facilitate
polarisation.
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The ultraviolet light must be a minimum of Wavelengths between 365-400nm produce UVA
1000mW/cm2. which is why they are used for MPI testing.
The wavelength of the light should be 365-400nm.
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Alternative Forms of
Cleaning Standard Electric Current Applied in MPI
The inspection area must be cleaned to a minimum Direct current.
SA2½. Alternating current.
Half wave rectified alternating current
For a weld this must be for at least 75mm either side (HWAC).
of the weld.
Full wave rectified alternating current (FWAC):
Single phase.
Additionally sufficient general cleaning (SA1) must
be completed to allow intimate contact for
Three phase full wave rectified alternating
magnetising apparatus. current.
Surface checks:
Obtain the necessary work permits, hot work may
be required.
Ensure that an isolating transformer is in the
circuit.
Test all circuit breakers or residual current devices
(RCD).
Check integrity of all electric cables.
Confirm rigging and buoyancy is correct.
Ensure the ultraviolet light is to BS EN ISO
3059:2001 specifications.
Ensure the ink is to BS EN ISO 9934-2:2002
(settling test).
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Rig the transformer safely as close as possible Position the gauss meter ready to monitor
to the test site. the induced field strength.
Switch on the ultraviolet light. Switch on the current on the diver
Confirm that ambient light is less than 20lux. inspector’s command, record current.
Rig the coils, parallel loops, prods or magnet Read out the indicated field strength on the
on the test site. gauss meter, 1T minimum.
Demagnetise the work site.
Confirm the ink is constantly agitated. Apply ink as required to the weld and
complete the inspection.
As the inspection progresses confirm
adequate field strength at each cardinal
clock position.
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The actual MPI indications may be recorded in a The sensitivity of MPI is primarily dependent on:
number of ways Operator ability.
Equipment used.
Ultra violet photography. Environmental conditions.
Foil packets, trade name: Magfoil.
CCTV. For maximum efficiency the diver inspector should be
Rubberised tape transfer, only useful in a habitat. comfortable and as well equipped as possible for the
dive:
Have confidence in his ability to use the equipment.
Be confident in his ability to detect defects.
Be sure of the value of his contribution to the
efficiency and safety of the structure he is
inspecting.
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17
Section 2
The datum for the GVI is given to the diver-inspector by the inspection
controller (by reference to the client’s procedure) and will comprise of a 12
o’clock datum for clock positioning and a reference datum for distance
positioning. The diver-inspector may then report the location of features
according to their clock position and an estimation of the distance from a
datum.
For example: At the 6 o’clock position, 3m from leg Charlie, there is an area of
impact damage. It is approximately 1m long by ½m wide and is 20mm deep.
DIS2-30815
Inspection Methods Available to Inspect
Underwater Structures 2-1 Copyright © TWI Ltd
Figure 2.1 Diver conducting a GVI with helmet-mounted video and video
pointer.
Again, the datum for the CVI is given to the diver-inspector by the inspection
controller (by reference to the client’s procedure). It is often marked by three
punch-marks near the weld. The diver-inspector may then report the location of
features according to their start and stop positions on a tape laid with zero at
the datum. As such, distances are measured to the nearest millimetre (ie to +/-
½ mm accuracy).
For example: From 1330-1345mm we have porosity on the cap of the weld.
DIS2-30815
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Underwater Structures 2-2 Copyright © TWI Ltd
Figure 2.2 A weld set for a CVI.
It is important to note that visual inspection does not generate a record of the
inspection – a separate recording technique must be employed. This could
simply be the diver’s memory or notes and sketches on a scratch-board. Most
often, videography and photography are used.
2.2 Videography
Videography is often used in conjunction with visual techniques to record their
results.
Offshore, IMCA guidance recommends that all divers wear HMTV cameras as a
matter of safety. Cameras may also be mounted on ROVs or have fixed
installations on the structure.
2.3 Photography
There are two commonly used photographic techniques for underwater
inspection:
The optics of the camera can be used to magnify the subject to elicit greater
detail. Linear subjects, such as welds, will require multiple overlapping
photographs (30-50% overlap) to be taken to form what is termed a photo-
mosaic.
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2.3.2 Stand-off photography
Stand-off photography is when the camera lens is more than 1 metre from the
subject.
For reasons of picture quality, the maximum stand-off from the subject to the
camera lens is limited to one-third of the underwater visibility.
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Inspection Methods Available to Inspect
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The DTM filters out all minor signals and displays only the distance to the major
reflector on the digital display, making it relatively easy and quick to use. It is
commonly employed for wall thickness measurement and basic lamination
checking.
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2.5 Flooded member detection (FMD)
It is important to gauge whether the inside of a structural member is wet or
dry. If the member is wet, then further investigation as to the cause of the
flooding will be required.
Both diver-inspectors and ROVs can test for flooded members by using
ultrasonic FMD probes. The equipment makes use of the fact that an ultrasonic
beam is blocked by a gas – ie a dry space. A low frequency ultrasound of
0.5MHz is used.
An ROV may also be fitted with radiographic FMD equipment. This fires gamma
radiation, using Caesium 137, through the structural member and meters the
amount of radiation that passes through the enclosed space – a high reading
would indicate a dry void.
Eddy current technique will detect the presence of a surface-breaking crack, but
will not give any indication of its depth.
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Inspection Methods Available to Inspect
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2.6.3 Radiography
Although X-ray radiation is used for topside inspections, the equipment is too
complex to use underwater - gamma radiation is employed instead. Gamma
radiation is produced by the radioactive decay of radioisotopes such as Iridium-
192.
Gamma radiography may detect planar defects within the material if the
radiation pathway is carefully aligned to the same expected orientation as the
defect. Volumetric defects are more easily detected by radiography as the user
does not need to align the radiation pathway.
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Figure 2.7 A Vernier caliper used to measure weld width.
Weld gauges may be used to measure small scale linear features such as
undercut, excess weld material and fillet leg-length. They may also be used to
measure angles of up to 90 degrees.
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Figure 2.9 A LAM gauge.
For large scale linear measurements we may use an open reel tape-measure,
position referencing using underwater transponders or narrow-beam
ranging sonar that may be mounted on an ROV or hand-held by the diver-
inspector.
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Inspection Methods Available to Inspect
Underwater Structures 2-9 Copyright © TWI Ltd
2.7.5 Photogrammetry
Measurements may be obtained by computer analysis of photographs in a
technique termed photogrammetry. This is an especially useful method of
measuring marine growth, anode wastage, damage, etc.
The ACPD probe is calibrated and then placed so as to span the known crack
position. The potential drop measured by the equipment indicates the depth of
the crack. Thus, ACPD will not locate a crack in a material but it will indicate the
depth of a crack whose position is known.
The CP value can imply the state of the corrosion protection being offered to the
structure.
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Inspection Methods Available to Inspect
Underwater Structures 2-10 Copyright © TWI Ltd
Figure 2.11 A diver using a Bathycorrometer.
A carefully taken cast may be put into an electron microscope to reveal detail of
grain-sized features.
Used to build up a series of cross-sections and the results traced onto a dive
slate or scratch-board.
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Inspection Methods Available to Inspect
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Small-to-large scale surface profiles may be recorded using stereo-
photography.
Large scale surface profiles may be recorded using a taut-wire survey. In this
technique, a wire is anchored at either end and stretched tight along eg a
damaged brace. Regular measurements are made along the wire to create a
profile of the deformation. If performed twice along perpendicular planes then a
three-dimensional representation of the deformation may be gained.
DIS2-30815
Inspection Methods Available to Inspect
Underwater Structures 2-12 Copyright © TWI Ltd
Bibliography
ASME Boiler and Pressure Vessel Code: Non-destructive Examination – Section
V, ASME International, Washington, D.C (2011), https://www.asme.org.
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990, ISBN 13:
9780419135401.
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28/08/2015
Inspection Methods
This is because:
• It is cheap and readily available.
CSWIP 3.1U Course • Many features of engineering importance can be seen
on the surface of the material or structure.
Inspection Methods Available • It generally precedes any non-destructive testing (NDT)
To Assess Underwater Structures that is to be carried out on the component.
We have two approaches to conducting underwater visual For example: At the 6o’clock position, 3m from leg Charlie,
inspections: there is an area of impact damage. It is approximately 1m
long by ½m wide and is 20mm deep.
1. General visual inspection (GVI)
The aim of the GVI is to provide the client with a general
Features that are likely to be reported during a GVI
impression of the underwater state of the structure. The
include:
area inspected is often not cleaned as an assessment of
marine growth is commonly conducted as part of the GVI.
• Structural features, eg welds, pad eyes, intersecting
members, etc.
The datum for the GVI is given to the diver by the
• Imperfections, eg impact damage, debris, tool marks,
inspection controller (by reference to the client’s
etc.
procedure) and will comprise of a 12 o’clock datum for
• Marine growth – type, thickness and extent.
clock positioning and a reference datum for distance
• Paint coatings – type, condition and cover.
positioning. The diver-inspector may then report the
• Corrosion damage, etc.
location of features according to their clock position and an
estimation of the distance from a datum.
2. Close Visual Inspection (CVI) • Distances are measured to the nearest mm (ie
The aim of the CVI is to provide the client with an accurate
report of detailed features such as those seen on a weld. The
to +/- ½ mm accuracy).
area is cleaned prior to conducting a CVI – the specific cleaning
requirements will be detailed in the client’s procedure, but for • For example: From 1330-1345mm we have
weld inspection these are generally; clean to SA2½ the weld porosity on the cap of the weld.
cap and 75mm either side.
Again, the datum for the CVI is given to the diver by • Features that are likely to be reported during a
the inspection controller (by reference to the client’s CVI include:
procedure). It is often marked by three punch-marks − Normal features, eg stop/start, other
near the weld. The diver may then report the intersecting welds, etc.
location of features according to their start and stop − All imperfections, whether specified in the
positions on a tape laid with zero at the datum. client’s CNC or not.
− Corrosion damage, etc.
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Video
Videography is often used in conjunction with visual techniques
to record their results.
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The A-scan flaw detector displays major and minor signals Flooded member detection (FMD)
on a graphical screen. Interpreting the display requires It is important to gauge whether the inside of a structural member is
wet or dry. If the member is wet, then further investigation as to the
skill and can be time-consuming. cause of the flooding will be required.
The A-scan is typically used for thickness measurement,
lamination checking and for ultrasonic weld inspections. A Both diver-inspectors and ROVs can test for flooded members by using
ultrasonic FMD probes. The equipment makes use of the fact that an
frequency of 5MHz is commonly used (A-scan & DTM). ultrasonic beam is blocked by a gas – ie a dry space. A low frequency
ultrasound of 0.5MHz is used.
An ROV may also be fitted with radiographic FMD equipment. This fires
gamma radiation, using caesium 137, through the structural member
and meters the amount of radiation that passes through the enclosed
space – a high reading would indicate a dry void.
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Many topside measuring tools may be used Weld gauges may be used to measure small
successfully underwater with little or no scale linear features such as undercut, excess
modification. weld material and fillet leg-length. They may
Linear measurements also be used to measure angles of up to 90°.
The linear-angular measurement (LAM) gauge may be Rulers or tape-measures are simple and practical
used to measure many small linear and angular features small-to-medium scale measuring tools.
as per the weld gauge. The LAM gauge is superior to the
weld gauge in that it may be used on a curved surface and
Magnetic tape-measures are especially useful in
is particularly accurate when measuring the depths of underwater close visual inspection.
remedial grinds.
For large scale linear measurements we may use
an open reel tape-measure, position referencing
using underwater transponders or narrow-beam
ranging sonar that may be mounted on an ROV
or hand-held by the diver-inspector.
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Recording shapes and surface profiles Small-to-medium scale surface features may be recorded
On the microscopic-to-small scale, surface profiles may be by taking a series of spot measurements with a Vernier
recorded using a casting material. These are pressed onto caliper along an area of impact damage or by using a
the surface of the material and allowed to take up the profile gauge.
shape of any defects present. The resulting cast is
removed and then analysed.
6
Section 3
Corrosion
3 Corrosion
3.1 Energy considerations in corrosion
With time most materials react with their environment to change their
structure. The reaction in metals is called corrosion, in polymers (plastics)
degradation and in concrete weathering.
This change in the metal will be expected if the thermodynamics (energy state)
of the system is considered.
It must release free energy from the system to the surrounding at constant
temperature and pressure.
Take the case of a metal, such as iron or aluminium as an example; both are
found in nature as ores which, when analysed, are found to be a chemical
compound including oxygen and carbon amongst other elements. This
necessitates the extraction of the metal itself from the other elements before it
can be used in fabrication.
The process whereby the metal is extracted requires either the smelting of the
ore (iron) or an electrolysis process (aluminium). The final metal produced is,
therefore, at a higher energy level than the ore from which it was extracted ie
energy is added to the system.
One of the fundamental laws of equilibrium is that all systems try to reduce
their energy level to a minimum. That is why water runs downhill, thus reducing
its potential energy level as it flows. In similar fashion metals tend to reduce
their energy and, therefore, obey the rule imposed by the second law. So free
energy is released.
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There are numerous forms of energy but the energy causing corrosion is
chemical energy that is utilised to form lower energy chemical compounds, like
metal oxide, which resemble the original ore. Because steel (iron alloys of
various types) is such an important material in building and industry the
corrosion of iron has a special term, rust.
Figure 3.1 Changes in energy levels of a typical metal extracted from ore.
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The overall charge on the atom is zero and an atom, so composed, has a
negative charge of electrons equal to the positive charge of the nucleus.
However, electrons can be added to or taken from the group that surrounds
each atom. When this happens, the overall charge on the atom is no longer
zero. This condition of the atom is called ionic.
So, if the atom loses an electron it becomes a positive ion, which means that
the atom now has a positive charge. If the atom gains an electron it becomes a
negative ion and now has a negative charge.
The first step in the corrosion process is that metal atoms change their state
from being metallic (that is no charge on the atom) to being ionic (that is
having a charge on the atom) by losing at least one electron from the outer
shell. The process of corrosion then goes on at the atomic level, each atom
losing one or more (usually no more than three) electrons to become an ion.
The anodic reaction for iron releases two electrons, as shown in Figure 3.4
which represents a freely rusting iron surface immersed in seawater (the
electrolyte).
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Figure 3.4 Anodic sites on surface of iron exposed to seawater.
This is one part of the reaction in electrochemical corrosion that takes place in
the presence of an electrolyte; that is often water or a water-based solution of
ionic compounds, such as acids, bases or salts. The metal ion passes into
solution and the electron passes through the metal, that is not actually being
corroded, that is; an electric current flows as indicated in Figure 3.4.
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Typically, a complete reaction is for the free electrons to be taken up by
positive ions and atoms of oxygen in the electrolyte. This gives the oxygen a
negative charge. Oxygen, however, readily accepts the free electrons because
for its electron stability it needs eight electrons in its outer valence shell, yet
occurs naturally with only six.
Free electrons move through the metal cathode to its surface where negative
ions form and subsequently emit free electrons into the electrolyte where they
combine with elements creating different compounds. The site of this reaction is
known as the cathode.
The actual reduction reaction at the cathode will vary according to the
composition of the electrolyte. Hydrogen evolution is a common reaction when
the electrolyte is acidic. Oxygen reduction is also very common, since any
aqueous solution in contact with air is capable of producing this reaction. It is,
of course, the reaction encountered in seawater. Metal ion reduction is less
common and is normally found in chemical process streams. The common
denominator with all these reactions is that they consume electrons and this is
the most important point to note.
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For corrosion to take place four criteria must apply:
These four elements are shown diagrammatically in Figure 3.7 below and all
electrochemical corrosion takes place by setting up cells like this.
Electricity can also pass through suitable aqueous solutions, but the electrical
charge is then carried by ions.
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In the MKS (metre, kilogramme, second) system, one ampere is defined as
that constant current which, if maintained in each of two infinitely long
straight parallel wires of negligible cross-section; placed 1m apart, in a
vacuum, will produce between the wires a force of 2 x 10-7 Newtons per
metre length.
The driving force causing this current to flow is the potential difference between
two points and is measured in volts, which has the symbol V.
The MKS system defines the unit of electrical resistance as being the
resistance between two points of a conductor when a constant potential
difference of 1V, applied between these points, produces in the conductor a
current of 1A.
During the majority of this section all discussion and illustrations will be in
terms of electron or ion flow and, as far as possible, positive and negative
notations will be avoided so as to avoid confusion, which often occurs when
corrosion is studied. This confusion arises because of an historical accident that
resulted in producing what is now called conventional current.
Electron flow is exactly opposite to conventional current, this is what causes the
confusion as studies in corrosion so often involve discussion on electron or ion
flow. To avoid such problems for the rest of this discussion on corrosion only
electron flow will be considered. Figure 3.8 illustrates the two types of flow.
Conventional Flow Electron Flow
Battery
Anode
A Cathode
+ ‐
Anode Cathode
+ A ‐
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Bibliography
Porter L K, A Handbook for Underwater Inspectors, HMSO (Stationery Office
Books), 1988, ISBN 13: 9780114129118.
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The first law of thermodynamics states: For example consider the case of iron, it is found in nature
as an ore which when analysed is found to be a chemical
Energy can neither be created nor destroyed. compound including oxygen and carbon amongst other
elements. It is necessary to extract the metal itself from
Therefore when spontaneous changes occur they must follow a the other compounds before it can be used in fabrication.
rule:
The process whereby the metal is extracted requires the
Whenever a spontaneous change occurs it must release free smelting of the ore. The final metal produced is now at a
energy from the system to the surrounding at constant higher energy level than the ore from which it was
temperature and pressure. extracted. Energy is added to the system.
Which is a way of stating the second law of thermodynamics: A fundamental law of energy is that all systems try to
reduce their energy level to a minimum. Metals do this and
When corrosion occurs naturally it releases free energy, as it is therefore obey the rule imposed by the second law. Hence
a spontaneous process. free energy is released.
There are numerous forms of energy but the energy Knowing there is a driving force for the process makes it
causing corrosion is chemical energy that is utilised necessary to consider the mechanism by which corrosion
to form lower energy chemical compounds, like the can take place.
metal oxide which resembles the original ore.
An atom is a positive nucleus
surrounded by negatively
charged electrons.
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However electrons can be added or taken from The first step in the corrosion process is that
the group that surrounds each atom. When this metal atoms change their state from being
happens the overall charge on the atom is no metallic, no charge on the atom, to being ionic,
longer zero. This condition of the atom is termed having a charge on the atom, by losing at least
ionic. one electron from the outer shell.
So if the atom loses an electron it becomes a The process of corrosion then goes on at the
positive ion and now has a positive charge. This atomic level, each atom losing one or more,
may be referred to as a cation. usually no more than three, electrons to become
an ion.
If the atom gains an electron it becomes a
negative ion and now has a negative charge.
This may be referred to as an anion.
The reaction in which the metal is changed from its metallic The anodic reaction for iron releases two electrons,
state to its ionic state is known as the anodic reaction. It is
part of an overall reaction involving the metal and other
shown in this diagram, which represents a freely rusting
species present in the environment. This process is also called iron surface immersed in seawater.
oxidation.
The free electrons formed in the anode reaction must be Typically a complete reaction is for the free electrons to be
used up if the reaction is to proceed. This part of the taken up by positive ions and atoms of oxygen in the
reaction takes place at the site where the free electrons electrolyte. This gives the oxygen a negative charge.
are neutralised and is known as the cathodic reaction. Oxygen however readily accepts these free electrons
because for its electron stability it needs eight electrons in
its outer valence shell yet occurs naturally with only six.
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Any Questions?
3
Section 4
Types of Corrosion
4 Types of Corrosion
4.1 Corrosion cells
Corrosion cells, using the corrosion process outlined in Section 3, can be set up
by many different means, but they all operate because there is some
dissimilarity between the anode and the cathode, such as:
Dissimilar metals.
Dissimilar phases in the grains of the metal.
Dissimilar energy levels between the grain and the grain boundary of the
metal.
Dissimilar ion concentrations.
Dissimilar oxygen concentrations.
This can be demonstrated easily by placing two rods of different metals in water
and connecting a voltmeter between them. The voltmeter measures a voltage
and current flows from the anode to the cathode via the outside connection.
The cell acts as a very basic, low powered battery and in battery terms the
anode is the negative and the cathode the positive. Electrons flow from the
negative terminal to the positive terminal in the external circuit. Figure 3.8
Section 3 refers.
It is possible to determine which of the two metals will be the cathode and
which the anode by reference to Galvanic Series. The rule is that metals found
lower in the series are anodic to any metal above them. For example, zinc is
lower in the series than mild steel; therefore, if zinc is connected to mild steel
and immersed in seawater, zinc will be the anode and corrode and mild steel
will be the cathode and not corrode.
If, on the other hand, mild steel, in the form of a ship’s hull is connected to
manganese bronze, the ship’s propeller, the mild steel now becomes the anode
and corrodes and the propeller is the cathode, which does not corrode.
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Table 4.1 Galvanic Series in seawater.
Gold
Silver
18-8 (3%Mo) Stainless steel (passive)
Monel
Nickel (passive)
Copper
Red brass
Aluminium bronze
Admiralty brass
Yellow brass
Nickel (active)
Manganese bronze
Lead
18-8 Stainless steel (active)
50-50 Lead-tin solder
Cast iron
Wrought iron
Mild steel
Cadmium
Alcad
Aluminium 52Sh
Galvanised iron
Zinc
Magnesium alloys
Magnesium
Corrosion will at first occur over the entire surface of the exposed metal at a
slow rate, both inside and outside the crevice. During this period of time the
electrolyte may be assumed to have a uniform composition and normal anodic
and cathodic processes take place. Under these conditions positive metal ions
and negative hydroxyl ions are produced, so as to maintain equilibrium within
the electrolyte.
This process consumes the dissolved oxygen, which results in the diffusion of
more oxygen from the atmosphere at any surface where the electrolyte is in
contact with air. In turn then, the oxygen in the bulk of the electrolyte is
replaced more easily at metal surfaces rather than in any small crevices. This
creates a low oxygen situation within the crevice, that in turn impedes the
cathodic process and the production of hydroxyl ions is therefore reduced.
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This results in excess positive ions accumulating in the crevice, which causes
negative ions to diffuse there from the bulk of the electrolyte outside in order to
maintain minimum potential energy overall. The metal ions, water molecules
and chloride all react in complicated chemical reactions forming complex ions,
which it is thought, react with water in an hydrolysis reaction, resulting in
corrosion products.
4.4 Pitting
Pitting is localised corrosion that selectively attacks areas of a metal surface,
once formed corrosion pits propagate in the same way as crevice corrosion.
Consider the case of a water drop laying on the surface of a sheet of clean mild
steel.
The corrosion process initiates uniformly on the surface of the steel under
the water. This consumes oxygen by the normal cathode reaction in what is
a neutral solution at this stage.
This causes an oxygen gradient to form within the water drop. It is obvious
that the wetted area around the water/air interface has more oxygen
diffusion from the air than the centre of the drop.
This concentration gradient anodically polarises the central region, which
dissolves.
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The hydroxyl ions generated in the centre of the drop at the cathode diffuse
inwards and react with iron ions diffusing outwards, causing the deposition
of insoluble corrosion product around the depression, or pit.
This further retards the diffusion of oxygen, accelerates the anodic process
in the centre of the drop and causes the reaction to be autocatalytic.
Long Path Air
Oxygen Depletion Layer
General corrosion with many local anodes and cathodes
Air
Water
Short Path
OH‐ OH‐
Fe2+ Fe2+
Rust Rust
Cathode Cathode
e‐ Anode e‐
As the process continues, the corrosion products accumulate over the pit and its
immediate surroundings, forming a scab and isolating the environment within
the pit from the bulk electrolyte. It is thought that the autocatalytic process is
assisted by an increased concentration of chloride ions within the pit. This type
of corrosion would be possible in the splash zone of a structure, if it were not
protected with a coating such as paint or Monel sheathing.
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Compounds
These are formed between metals and non-metallic elements, such as;
hydrogen, carbon, silicon, nitrogen and oxygen.
Iron carbide and manganese sulphide, which are both important
constituents of steel, are both cathodic to ferrite (iron).
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Weld decay, or preferential corrosion, is an example of this type of decay. In
this case the boundary is the fusion boundary that forms along the toe of the
weld and is a region of higher energy. This region becomes the anode and
corrosion sets in, often giving quite significant visual indications of its presence.
Tensile stress.
Suitable environment.
Sensitive metal.
Appropriate temperature and pH range.
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Figure 4.6 Example of SCC.
Problems with pipes and tubes are common because of the hoop residual
stresses that are the result of the fabrication process. Stress-relieving heat
treatments are a vital part of the quality control for these components because
of this.
Fatigue affects all metals causing failure at stress levels well below the UTS.
Corrosion fatigue can occur in any of the three states indicated by the Pourbaix
diagram, see Section 5 Figure 5.1. It can also occur at stress levels much lower
than those for stress corrosion cracking (SCC). It is also true that, while SCC
growth rates are independent of the stress intensity factor during much of the
crack growth, fatigue crack growth is always effected by it.
It is thought that the use of CP systems that place the metal in the immune
state and over time cause calcareous deposits to form, tend to inhibit crack
growth, ensuring that the structures are resistant to corrosion fatigue.
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Soft metals, such as copper, brass, pure aluminium and lead are particularly
vulnerable.
Where the increased flow replenishes aggressive ions, such as chloride and
sulphide, this has a detrimental effect and corrosion rates increase.
If the flow contains any solid particles, protective layers may be scoured
away causing excessive corrosion.
The alternative to this is that it is sometimes possible in pipes for the
deposit of silt to be prevented, thus preventing the formation of any
differential-aeration cells in the crevices beneath.
A possible beneficial effect is that more oxygen is carried to the area, which
minimises the formation of differential-aeration cells that are normally a
common cause of attack.
Another possible beneficial effect is where a steady supply of inhibitor is
concentrated within the flow, as in a pipeline for example.
Taking the case of turbulent flow, however, the situation is much more
straightforward. The fluid molecules now impinge directly on the metal causing
wear. This obviously increases the corrosion rate.
This effect can easily occur inside a pipe because turbulence can be caused by
sudden changes in bore diameter, or direction (ie pipe bends), a badly fitted
joint or gasket, circumferential welds or silt deposits.
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4.10 Fretting corrosion
Fretting corrosion describes corrosion occurring at contact areas between
materials under load; subjected to vibration and slip. In appearance, it shows
pits and grooves in the metal surrounded by corrosion products.
This type of corrosion could occur in the metal adjacent to clamps and collars of
risers, conductors and caissons if there is the slightest movement underneath
them.
Figure 4.8 Possible fretting corrosion between riser and riser clamp.
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4.11 Biological corrosion
Biological corrosion is also referred to as microbiologically-induced corrosion
(MIC), emphasising the effect of living organisms (referred to as bacteria).
Temperature.
Water flow rate.
The pH of the water.
4.12.1 Temperature
Most chemical reactions are speeded up by an increase in temperature. Hot
risers, exhaust and cooling-water dumps are all sites that can and do corrode
more quickly than other sections of offshore structures. Therefore, these
components being more susceptible must be inspected more regularly.
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4.12.3 The pH value of the water
The corrosion rate of metals is directly affected by the pH value of the
electrolyte. Steel, for example, corrodes least when in a solution that has a pH
of between 11 and 12.
Water is a neutral molecule in which two atoms of hydrogen combine with one
atom of oxygen (H2O). There is a limited amount of dissociation (separation of
positive and negative charged ions in solution) into hydrogen ions and hydroxyl
ions.
Water represents a neutral substance as it contains both acid H+ and alkali OH-
in equal amounts. This can be noted in the form of an equilibrium:
H2O H+ + OH-
The relationship between these elements forms the basis of a scale of acidity.
All acids have one common property: that is the presence in aqueous solution
of the hydrogen ion, whereas, alkali has hydroxyl ions.
The opposite of acid is alkali or basic, which means that acids are neutralised by
alkalis.
The method of defining acidity is by means of a term called pH, which indicates
the amount of hydrogen activity. It is measured on a scale of 0-14.
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Bibliography
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990, ISBN 13:
9780419135401.
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Now consider the case of a water drop laying on Now consider the case of a water drop laying on
the surface of a sheet of clean mild steel: the surface of a sheet of clean mild steel:
In this process the water (electrolyte) under the As with crevice corrosion, hydroxyl ions are
water drop initiates uniform corrosion consuming generated in the centre of the water drop.
oxygen. A depression and then a pit will form under the
Outside the water drop oxygen is readily available water drop.
and replaces that used by the corrosion process. Once again the process is self-sustaining once
This imbalance of relative oxygen diffusion causes initiated.
the centre of the water drop to become anodic This type of corrosion is most likely in the splash
while the outside is cathodic. zone on unprotected steel.
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This is due to the higher energy regions of the grain Weld decay or preferential corrosion
Cathode
Anode
Stress corrosion is a form of inter-granular This occurs at contact areas between materials
corrosion seen on structural members carrying under load subjected to vibration and slip.
high tensile loads. The rate of corrosion is much
faster compared to any similar member carrying There must be:
lighter loads.
An interface under load.
Vibration or cyclic motion sufficient to produce slip or
deformation on the surfaces.
Stress Stress Load must be sufficient to produce slip or deformation
Grains
Load Load to the surfaces.
Two theories for fretting corrosion Fretting corrosion occurs where surfaces that
Wear-oxidation are in contact, move slightly. This may occur
Wear-oxidation is based on the concept that cold welding between risers and clamps.
or fusion occurs at the interface between metal surfaces
under pressure and during the subsequent relative motion,
these contact points are ruptured and fragments of metal
are removed.
Oxidation-wear
Oxidation-wear is based on hypothesis that metal surfaces
are protected by a thin, adherent oxide layer. When
metals are placed in contact under load and subjected to
repeated relative motion, the oxide layer is ruptured at
high points and results in oxide debris. It is assumed that
the exposed metal re-oxidizes and the process is repeated.
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Erosion corrosion has two main forms: Turbulent flow is comparable with fretting
1. Corrosion caused by laminar flow. corrosion but the movement is provided by fluid.
2. Damage caused by impingement in turbulent
conditions.
Biological Corrosion
4
Section 5
Corrosion Protection
5 Corrosion Protection
There are numerous methods for preventing corrosion including, coatings,
inhibitors (controlling the electrolyte), selective design, anodic protection and
CP. Before considering these methods, a brief examination of the way in which
the corrosion process is influenced by the two main variables; the electrode
potential and the pH of the electrolyte, will assist in understanding the
various protection methods.
14
pH
It can be seen from the Pourbaix diagram, that there are three distinct possible
states of corrosion depending on electrode potentials (measured against a
standard hydrogen reference electrode) and pH values:
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5.1 Cathodic protection
The three stages indicated in the Pourbaix diagram show it is possible to
determine basic strategies for preventing corrosion.
These two points are more likely to occur with an ICCP system but are still quite
valid, making the choice of between -800 to -1100mV a valid design parameter
in all cases for offshore platforms.
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Figure 5.2 Sacrificial anode system.
The anode must be selected from the appropriate Galvanic Series. The most
appropriate metals are zinc, aluminium and magnesium. Aluminium is often
selected for uncoated structures because of its higher current output and zinc
for coated ones (BP North Sea). Magnesium would provide the highest current
but may not last long enough to provide adequate protection for the design
lifetime of the structure. In practice, a balance between the level of protection
and the length of time the structure will need protecting will be needed. It
should be mentioned that the anodes will not be pure zinc or aluminium but
these will be their main constituent.
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5.2 Impressed current cathodic protection (ICCP) system
An impressed current cathodic protection (ICCP) system works on the same
principle as the sacrificial system in that the structure is made to be the
cathode. However, in the case of the ICCP system, the necessary potential and
current flow is provided by a DC generator rather than by a galvanic coupling.
In both cases, the reference electrode provides the means of monitoring the
potential, which varies proportionally according to the current. Figure 5.3 shows
the system.
The anode material is selected from the top of the Galvanic Series, not the
bottom. Materials such as titanium, platinised niobium and lead/silver alloys
are used. The anode and supply cables are insulated from the structure to
prevent any of the problems associated with over-protection.
Potentiostat
Reference
Eelectrode
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5.2.1 Practical considerations for installing ICCP systems
Anodes made from the materials previously mentioned, are capable of
supplying high current densities and it would be possible to protect a structure
with a few large anodes supplied with a high current. However, in practice,
anodes are usually distributed at regular intervals over the whole structure. This
is because:
The high current density that would be present in the immediate vicinity of
a single large anode could damage paint surfaces and possibly cause
embrittlement. The use of more, smaller anodes reduces the current density
for each one and reduces the probability of this type of damage.
Offshore structures have a reasonably complicated geometry that makes it
difficult for corrosion engineers to predict the total distribution potentials.
Therefore, it is prudent to use more anodes, each one protecting a smaller
area, thus minimising the areas at risk of inadequate protection.
When designing the system if the corrosion engineers have any doubts
about protecting any particular area of the structure, sacrificial anodes may
be installed to work in conjunction with the ICCP system.
The ICCP system installed on the Claymore platform was designed to provide
160mA/m2 (milli-amps per square metre), using 55 platinum-iridium anodes
and 12 reference electrodes. Also the Murchison platform uses 100 anodes and
50 reference electrodes. In general, in the North Sea, the most common anode
materials are platinum-sheathed titanium and lead/silver alloys.
It is vitally important that the power supply is connected with correct polarity.
The negative terminal must be connected to the structure and the positive
terminal must be connected to the anode (conventional electrical circuit
notation). Should these connections be reversed, the structure would corrode
catastrophically.
Platform based.
Remote from the structure.
Platform based
In this method numerous anodes are attached to the structure at intervals
around it; in a similar fashion to sacrificial anodes but ensuring that they are
insulated from the structure.
Two problems are associated with this method. One is the possibility of
shadow areas where inadequate protection is provided. This problem can be
solved by the use of sacrificial anodes supplementing the ICCP system as
indicated earlier.
The second problem is the possibility of current flowing directly from the anode
to the adjacent structure. This could cause embrittlement, as discussed earlier,
but to avoid this dielectric shields are used to insulate the structure
electrically. Also, the current is limited by design, because each anode is
positioned to provide adequate protection for the local area only. This limits the
possibility of embrittlement and coating damage.
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Figure 5.4 Dielectric shield.
There is also a diver safety consideration in that these anodes are at about 80V
potential with some 1000A current. If divers are used adjacent to any of the
anodes, they should be isolated from the system. Normally, only the anodes in
the immediate work area are switched off.
There is a safety issue with divers but, as the anodes are some distance away
from the structure, it may be possible to ensure safety by imposing an
exclusion zone around the anode (Figure 5.5).
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Figure 5.5 An ICCP system with anodes remote from the structure.
Advantages Disadvantages
Anodes are smaller so there is less There are ongoing running costs
weight loading
A high current density could lead to
overprotection, which could cause
hydrogen embrittlement and coating
damage
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Reference electrodes are vital components of any ICCP system. They determine
the current required from the power source. Without them, the system cannot
provide a quantifiable degree of protection (Figure 5.6).
Paint
Is applied to a metal surface where it presents a barrier to air, moisture and
ions aggressive to the metal. However, paint cannot provide a complete barrier
to oxygen or water. In time, these will penetrate through to the surface of the
metal. Any paint system used underwater must have a strong bond onto the
metal surface and therefore, high quality metal surface preparation is required,
such as SA3.
The bonding between successive coats must also be strong and the topcoats
must provide as impervious a barrier to the electrolyte as is possible. This last
is achieved by ensuring the constituents making up the topcoats have very low
water absorption and transmission coefficients.
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Zinc coatings
Utilising a combination of zinc dust and complex silicates with a solvent-based
self-curing binder, give good protection to steel surfaces. These coatings are
frequently over-painted by another system and are used on components such
as ladders in a marine environment.
Concrete
Is used to provide a protective coating to pipelines where it provides a passive
environment for the steel pipe as well as adding weight.
Metallic coatings
Such as galvanising, using zinc, impose a continuous barrier between the metal
surface being protected and the surrounding environment. These coatings may
be applied in a number of ways.
Electroplating
Uses a bath of salts as an electrolyte. The component and rods of the plating
metal are immersed in the electrolyte and a potential is applied between the
component and the rods. The component becomes the cathode and the rods the
anode, so metal ions of the plating material deposit from the solution onto the
component.
Hot dipping
Involves the component being immersed in a bath of molten coating metal.
Galvanising is accomplished by this method (Figure 5.7).
Spray coats
Use a specialised torch that is fed with wires of the coating metal that are
melted and blown out by it. The molten metal is expressed in the form of
droplets travelling at 100-150ms-1 that flatten and adhere on impact with the
component.
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Cladding
Uses metal skins laminated onto the component. The skin can be applied by:
Rolling.
Explosive welding.
Buttering (building up a welded coat on the surface to be protected).
Sheathing.
Diffusion
Requires the component to be heated to just below the melting point of the
coating metal, in the presence of the coating in powder form and in an inert
atmosphere. The component is allowed to baste for several hours and the
coating diffuses into the surface of the component.
Monel cladding
Is used on some offshore risers; it is cupronickel alloy sheathing.
This section will outline methods for changing the electrolyte. The properties of
the electrolyte that can be affected by using inhibitors are:
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5.4.1 Corrosion protection by design
The methods used to protect structures from corrosion can be summarised
thus:
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Bibliography
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990, ISBN 13:
9780419135401.
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Anodes made from the materials previously The anodes and the supply cables must be
mentioned are capable of supplying high current insulated from the structure to prevent high
densities and it would be possible to protect a density current flowing directly to the
structure with a few large anodes supplied with a structure.
high current. However, in practice anodes are
usually distributed at regular intervals over the The high current density that would be present
whole structure. in the immediate vicinity of a single anode
could damage paint surfaces and possibly
cause embrittlement.
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System Remote from the Structure System Remote from the Structure
Reference electrodes are commonly: Coatings form a barrier between the electrolyte and the
surface of the protected structure. They may be paints,
organic films, varnishes, metal coatings or enamels and
Zinc. even sheathing.
Silver/silver-chloride (Ag/AgCl). Paint applied to a metal surface presents a barrier to air,
Copper/copper-sulphate (CSE). moisture and ions aggressive to the metal.
Coal tar epoxides are used extensively. They consist
of coal tar and epoxide resin for the binder. These
These are vital components of
coatings are highly impermeable to water and
any ICCP system. resistant to attack by most chemicals and hydroxyl
They determine the current ions, produced by the cathodic reaction.
Zinc coatings utilising a combination of zinc dust and
required from the power source. complex silicates with a solvent-based self-curing
Without these the system can not provide a binder give good protection to steel surfaces and are
quantifiable degree of protection. often over-painted.
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Electroplating.
Hot dipping.
Hot metal spraying.
Diffusion.
Cladding.
The pourbaix diagram indicates three methods for The methods employed to protect structures
preventing corrosion: from corrosion can be summarised thus:
1. Making the electrode more positive. Avoid:
2. Making the electrode more negative. All unnecessary bimetallic corrosion cells: Avoiding
3. Changing the electrolyte pH. galvanic or dissimilar metal corrosion.
Differential-aeration cells: Crevices, debris traps,
Properties of the electrolyte that can be affected by
inadequate drainage.
using inhibitors are: Stray currents from electrical machinery or conductors.
These can be quite powerful and make parts of the
The conductivity of the electrolyte.
structure anodic with obvious results.
The pH of the electrolyte.
The interaction of the electrolyte with the metal surface, Choose:
attacking or strengthening passive films. The material with the best properties for the
environment.
Any Questions?
6
Section 6
Since the amount of current required for the protection of any structure cannot
be accurately predicted or distributed evenly throughout the structure, the
method of checking for adequate protection is to measure the potential and
current density around the structure at various places.
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The potential measurements usually referred to as cathode potential (CP)
readings are obtained by:
Taking current density readings normally with an ROV mounted sensor and
usually for a specific requirement. This method is not used for regular
inspections.
Monitoring potential and current through remotely mounted electrodes
incorporated into the impressed current system.
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6.1.3 CP readings using silver/silver-chloride (Ag/AgCl) electrodes
The most common reference electrode used in offshore corrosion monitoring is
silver/silver-chloride. This electrode is used extensively for both contact and
proximity applications, whether diver or ROV deployed.
The probe contact tip is placed on the cathode and the meter gives the readout
in mV of the electrical potential between it and the half-cell.
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The proximity method is normally used by ROV’s. When taking proximity CP
readings it is vital that a good electrical connection is made between the
structure and the positive terminal of the surface control room installed meter,
a maximum of 100mm is maintained between the probe and the structure, as
shown in Figure 6.4.
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Figure 6.5 A monitored anode.
The electric connector is provided so that the cells can be proven as described
below.
6.2.2 Procedure
The first part of the procedure proves that the K-series cells are chemically
saturated and sufficiently stable enough to be used as reference cells.
There are different types of cells available. One type is specifically designed for
use with a Bathycorrometer. This type has a solid polymer body protecting the
K-series. The procedure outlined below also applies to this type of cell;
however, it is not possible to visually confirm they are fully saturated with
solution. They are sealed and to confirm they are saturated it is necessary to
unscrew a sealing cap to gain access to the solution reservoir.
Visually inspect the electrodes to ensure they are undamaged and full of
solution. The solution is potassium chloride (KCl) and if the solution is
saturated or supersaturated solid crystals may be seen in the phial.
Commonly the phials are glass or clear plastic.
Label the electrodes and their wires 1, 2 and 3.
Soak the electrodes in the bucket for 24 hours, being careful to immerse
each one only as far as the filling hole in the phial.
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While the electrodes continue to soak, connect electrode 1 to the negative
terminal of the voltmeter and electrode 2 to the positive terminal and record
the reading.
Repeat the test with each permutation of electrodes.
1 and 3.
2 and 3.
Acceptable readings between any pair of electrodes is 0 ± 2mV.
If all the readings are within this range any electrode may be used.
If one reading is out of this range the electrode not in that pair is the one to
use.
If one reading is in range either of the electrodes in that pair can be used.
If all of the readings are out of range either replace all the K-series cells or
flush out the phials with pure distilled water, obtain a new saturated
solution of potassium chloride, refill the phials and re-test.
The second part of the procedure confirms the calibration of the CP meter.
Calibration of a Bathycorrometer
The calibration checking procedure is slightly different if the meter being
calibrated is a Bathycorrometer with the specifically designed screw-on cells. In
this case the following procedure applies.
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Once satisfied that the electrical components are functioning correctly:
Fully charge the CP meter batteries and soak in fresh seawater (not drawn
from the fire main).
Remove the contact probe tip and white Delrin probe cone from the meter.
Screw the K-series reference electrode onto the Bathycorrometer in place of
the Delrin probe and probe cone tip.
Immerse the meter in the bucket at least far enough to submerge the semi-
permeable membrane. Gently shake the unit to remove any air bubbles
lodged in the holes. (The meter display may be left out of the water to
assist taking readings.)
Allow time for the meter to stabilise (approximately 10 minutes).
The voltage potential between the reference electrode and the meter’s own
Ag/AgCl cell is read off the meter display directly.
Record the reading on the log.
Acceptable readings are between +42mV +/-5. It should be noted that values
will vary dependent upon salinity and temperature of the seawater, see Figure
6.7.
1 2 3
4 5 6
Screw in K-Series electrode Immerse meter for 10 minutes Record reading in log
Note: If the reference electrode used are Calomel Cells (as opposed to K-series)
then the expected readings will be 0 to -10mV.
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Overall calibration of any CP meter
Select the proven K-series electrode and immerse the tip for 30 minutes
into a plastic bucket on deck.
Take a zinc block, attach a clamp and electric wire and place the block into
the same bucket.
Connect the K-series electrode to the negative terminal of a high resistance
voltmeter via the electric cable attached to the electrode.
Connect the zinc block to the positive terminal of the voltmeter via its
electric connector. (Immerse only the zinc, not the clamp or connector).
Take a reading from the voltmeter. Acceptable readings are between -1.0V
±5mV (ie -950 to -1050mV). Record the reading on the log.
Remove the zinc block and disconnect it from the clamp.
Soak the CP meter assembly in a bucket of fresh seawater for 30 minutes.
Place the zinc block into the same bucket as the CP meter and make
submerged contact between the probe tip and the zinc.
Take a reading from the CP meter. This reading should be the same as that
recorded from the K-series ±10mV (ie -940 to -1060mV). This proves the
CP meter by comparison.
Record the reading on the log.
DIS2-30815
Corrosion Protection Monitoring 6-8 Copyright © TWI Ltd
Calibration of Ag/AgCl proximity probes
Before initiating this procedure, ensure the insulation on the conductors for the
proximity cell is intact. This may be achieved by using an insulation test meter.
The cable must be properly insulated to avoid any possibility of the copper
conductor being exposed to seawater and affecting the readings.
Select a proven K-series cell and immerse the tip in a bucket of fresh
seawater for 30 minutes.
Immerse the Ag/AgCl proximity probe in the same bucket for the same
time.
Connect the negative terminal of the high resistance voltmeter to the
Ag/AgCl half-cell.
Connect the positive terminal of the voltmeter to the K-series electrode.
Take the reading. Acceptable readings are 42mV ± 5mV.
Remove the K-series electrode and immerse the zinc block (only) positioned
100mm from the Ag/AgCl half-cell. The zinc block is connected to the
positive terminal of the meter system via the clamp and electrical
connection.
Take the reading. Acceptable readings are -1000-1050mV.
Note: If the reference electrode used is a Calomel Cell, then the reading in
stage 3 above will be 0 to -10mV.
DIS2-30815
Corrosion Protection Monitoring 6-9 Copyright © TWI Ltd
6.3 Operating procedures
To ensure that accuracy is maintained and that repeatable results are obtained,
CP monitoring methods follow the procedure below.
Ensure self-contained meters are fully charged and keep a charging log.
(Usual requirement for charging batteries is 15 hours from fully discharged.
This will give approximately 60 hours of continuous use).
Ensure the probe tip for contact meters is sharp (hand-held meters are
usually supplied with spare tips).
Soak meters and half-cells for a minimum of 30 minutes before use. (This
allows time for ion penetration through the semi-permeable membranes).
Confirm the calibration of the system in use according to the appropriate
calibration procedure. Record the results on the appropriate log sheet.
Record meter serial number and any other specified details on the
appropriate log sheet.
Take a reference reading on zinc at the inspection site prior to starting the
survey.
For each contact reading, ensure there is correct metal-to-metal contact
between the probe tip and the cathode surface.
With proximity probe surveys, ensure there is a solid electrical connection to
the structure from the positive terminal of the surface instrument.
For proximity probe readings, ensure the standoff between the probe and
the cathode is correct, no more than 100mm away.
During the course of the survey, ensure that each reading is correctly
recorded on the appropriate log.
On completion of the survey take another reference reading on zinc.
Recover the equipment, wash in fresh water, dry and store. Charge any
battery-operated equipment as necessary and complete the battery-
charging log.
Note:
Morgan-Berkley meters can be left soaking in a solution of silver chloride,
on trickle charge continuously if required.
If a large number of readings are being taken it is prudent to take check
readings periodically during the survey.
DIS2-30815
Corrosion Protection Monitoring 6-10 Copyright © TWI Ltd
Bibliography
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990, ISBN 13:
9780419135401.
DIS2-30815
Corrosion Protection Monitoring 6-11 Copyright © TWI Ltd
28/08/2015
Since the amount of current required for the Monitoring or inspection requirements for
protection of any structure cannot be accurately corrosion protection systems are as follows:
predicted, the method of checking is to measure
the potential and current density around the Visual inspection of anodes for wear.
structure at various places. Visual inspection of electrical connections.
Potential measurements to ensure the structure is still
the cathode.
Current density measurements.
Visual and ultrasonic inspection for corrosion damage.
CP readings are obtained by: The cathode potential is measured by using a reference
electrode incorporated into an instrument that has a
A diver taking contact readings with a hand-held CP readout calibrated in mV (1 Volt = 1000mV).
meter or by mounting a contact probe on an ROV.
Taking proximity readings with an ROV probe. These electrodes are commonly:
Monitoring proximity readings via remotely mounted
permanent sensors with a readout in a surface control High purity zinc.
room. Silver/silver-chloride (Ag/AgCl).
Copper/copper-sulphate (CSE).
Current density measurements and monitoring are
obtained by: This is more favoured for concrete structures.
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-0.850
2
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3
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+42mV
+/-5mV
4 5
-1000mV
to
-1050mV
100mm
4
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Any Questions?
5
Section 7
The knowledge of how the welding was achieved in the first place is of great
assistance when inspecting welded joints because; all techniques have certain
faults that are common to that technique. It is, therefore, important to have
some knowledge of the main types of welding.
From the point of view of offshore structures and underwater inspection, the
following welding processes are the most widely used, either in the construction
of the structure itself or in the manufacture of the major components.
DIS2-30815
Welding and Welding Defects 7-1 Copyright © TWI Ltd
7.3.1 Flux-shielded arc welding
This is the most widely used of all the welding processes. An arc is formed
between a consumable electrode and the work; the heat thus formed melts and
fuses the joint together. The electrode provides the filler metal and the flux is
used to prevent contamination. For example:
The gun assembly itself consists of a gas shroud through which the shield gas,
either active or inert, is fed to protect the molten weld pool; an electrical pick-
up, through which the electrode wire is fed and at the same time energised,
and a trigger, which when operated, controls the gas and wire feed.
DIS2-30815
Welding and Welding Defects 7-2 Copyright © TWI Ltd
Figure 7.2 MIG/MAG welding.
Gases used for MIG/MAG welding will vary, typically they are:
100% CO2.
Argon/CO2 mixes.
It produces particularly high quality welds, not only in steel, but is also used for
joining aluminium and other alloys. It is a slow process and requires a high
standard of operator skill. Root welds in high quality, high pressure pipe-work
are often carried out using this system.
DIS2-30815
Welding and Welding Defects 7-3 Copyright © TWI Ltd
Figure 7.3 Tungsten inert gas welding.
Like MIG/MAG, TIG can also be used with different shielding gases:
Argon
For stainless steel, high carbon steel, aluminium, and magnesium.
Helium/argon mixes
For carbon steel, stainless steel, aluminium, copper and magnesium.
Variations
Include adding nitrogen to helium/argon mixes for welding copper and adding
hydrogen to helium/argon mixes for welding austenitic stainless steels.
Developed in the Soviet Union during WW2, this is a fully automatic welding
system. It is particularly useful for welding thick steel sections and used
extensively where long continuous weld runs are to be made. The following
photograph and drawing best illustrate the equipment and process.
DIS2-30815
Welding and Welding Defects 7-4 Copyright © TWI Ltd
Figure 7.4 Submerged arc welding (SAW).
The flux is in the form of powder or granules continually fed over the work area,
and the electric arc is formed underneath so is totally submerged, giving the
process its name. Because of this, personnel do not need eye protection as the
arc is not visible.
The process uses amperages in the range of 100-2000amps, giving very high
current density to the electrode wire, which produces the deep penetration and
weld dilution needed for thick section steel.
Figure 7.5 Submerged arc welding: Tandem arc with two wires.
DIS2-30815
Welding and Welding Defects 7-5 Copyright © TWI Ltd
7.4 Types of welded joint
There are approximately 110 different welded joint variations; the majority of
which are not seen in the construction of offshore structures. So it is necessary
to have knowledge of only five types of joint.
7.4.2 T joint
The two components are fitted together at an angle of 5-90o. This configuration
is found on offshore jackets at nodes and in numerous other areas.
DIS2-30815
Welding and Welding Defects 7-6 Copyright © TWI Ltd
7.4.4 Corner joint
The two components are connected at the ends to make a joint at an angle
between 30-135o.
Parent plate
Parent plate1 1
Parent plate
Parent plate 22
Parent plate 3
DIS2-30815
Welding and Welding Defects 7-7 Copyright © TWI Ltd
7.5 Types of weld
The two types of weld most frequently inspected on offshore structures are the
butt weld and the fillet weld.
The bulk of a fillet weld is contained outside the parent metal planes or
thickness.
The fillet weld has less strength than the butt weld.
a Single V butt.
As fillet welds are not used for structural joints that must withstand high
stresses, the butt weld will be the type of weld most frequently inspected
offshore. All nodes, including safety critical nodes on the structure, will be
constructed using butt welds.
DIS2-30815
Welding and Welding Defects 7-8 Copyright © TWI Ltd
The prime factor in welding is temperature. The various welding processes,
types of weld and types of joint are all designed so that the heat generated
during the welding process can be dissipated uniformly as the molten metal
cools after the weld metal is deposited.
At point 1 within the molten weld pool, the temperature will be above the
melting point of the filler rod metal. The welding current and technique of the
welder determine this temperature.
The main heat flow away from the weld pool will be along the parent plate.
Between points 1 and 2, the temperature must raise above the parent metal
melting temperature so that fusion (ie melting the parent plate and mixing with
the weld pool metal), occurs.
This region (between points 1 and 2), is known as the fusion zone and can be
readily seen if a sample of the weld is sectioned, polished and etched.
The temperature then reduces from point 2-3, which is a region of the parent
metal that has sufficient heat input to cause grain structure modification, known
as the heat affected zone (HAZ).
HAZ
One of the means of making a material softer (often called annealing) is to heat
it up and allow it to cool slowly. A common example of this is copper pipes for
domestic water systems that are softened in this way in order to bend them to
required shapes.
To achieve this softening effect a material has to be heated above its re-
crystallisation temperature (Trecry). Above this temperature, grains in the
material will reform and grow.
DIS2-30815
Welding and Welding Defects 7-9 Copyright © TWI Ltd
Figure 7.12 shows the temperature is reached at point 3, so that the material
between point 2 and 3 that has been raised above the re-crystallisation
temperature will be liable to a change of properties. This region can also be
seen on a polished and etched sample of the weld.
Fusion zones
Note: If the cooling rate is not properly controlled and the material is allowed
to quench, it has the opposite effect to annealing outlined above.
Defects, such as porosity, often arise in welds due to gas penetrating the weld
pool protection. Gases that are likely to be present in the weld are hydrogen,
oxygen and nitrogen. These are derived from the atmosphere, water,
hydrocarbons (usually in the form of grease and oil) and other oxides present in
the vicinity of the weld because of a lack of care in preparation, not ensuring
that the weld area is clean and dry.
These products get into the arc and provide a supply of gas that can be
dissolved in the liquid metal of the weld pool. On cooling, the solubility of the
dissolved gas in metal reduces and the gas comes out of solution to form
bubbles trapped in the weld metal; or sometimes, the gas diffuses into the
parent metal. Hydrogen diffusing into the HAZ will cause hydrogen
embrittlement, which may lead to cracking.
DIS2-30815
Welding and Welding Defects 7-10 Copyright © TWI Ltd
The different temperatures in the regions around the weld will cause differential
expansion. On cooling, if cracking does not immediately occur in the weld or in
the HAZ, the material is put under a permanent stress, unless a stress relieving
procedure is specified. This state of stress is referred to as residual stress.
DIS2-30815
Welding and Welding Defects 7-11 Copyright © TWI Ltd
Parent plate
The metals that are to be joined by the weld.
Prepared face
The bevelled portion of the parent plate prior to welding.
Root gap
Separation between the parent plates to be joined.
Root face
The un-bevelled portion of the parent plate adjacent to the root gap.
Prepared angle
Included angle and included angle
Prepared angle
Prepared face
Root face
Root Gap
Single V Butt Weld Single Bevel Butt Weld
DIS2-30815
Welding and Welding Defects 7-12 Copyright © TWI Ltd
Toe of the weld
Junction between the cap and the parent plate.
Root
Point where the back of the weld intersects the back face of the parent plate.
Weld zone
Area containing the weld and both HAZs.
Throat thickness
Total thickness of the weld metal.
Weld width
Shortest distance between the toes of the weld.
Toe blend
Transition between the weld material and the parent plate.
DIS2-30815
Welding and Welding Defects 7-13 Copyright © TWI Ltd
Figure 7.17 Weld feature terminology on a fillet weld.
Filler bead
When the weld is made up of more than one pass of a filler rod the successive
passes are called filler beads.
Run or pass
Weld metal laid down in a single pass from a filler rod.
Weldment
An alternative term to describe the weld zone.
Fusion zone
The edge of the parent plate along the prepared face and the root face, along
which the weld metal fuses with the parent plate.
Root bead
Weld bead laid into the root that protrudes beyond the back wall of the parent
plate.
DIS2-30815
Welding and Welding Defects 7-14 Copyright © TWI Ltd
Figure 7.18 Weld process terminology.
In this case the International Institute of Welding (IIW) and BS EN ISO 5817:
2007 apply. In the same way that welding terms are defined in this standard,
weld defect terminology is also defined.
1 Cracks.
2 Cavities.
3 Solid inclusions.
4 Lack of fusion or penetration.
5 Imperfect shape.
6 Miscellaneous.
(mnemonic - CCSLIM).
Planar defects
Have a large surface area but small volume, such as cracks and laminations and
are essentially two dimensional.
Volumetric defects
Inclusions, porosity and other internal flaws, that have a large volume
compared to surface area, are in this category. They are three dimensional and
will also include undercut and lack of penetration. This category of defect is
caused during fabrication, not in-service; while planar defects may be caused
by in-service deterioration.
Only a certain number of these standard terms apply to defects that may be
found on the surface of the weld accessible to the underwater inspector, but
knowledge of a representative sample of standard terms, from all categories,
will assist any inspector when reporting findings and conversing with engineers,
welders or weld inspectors.
DIS2-30815
Welding and Welding Defects 7-15 Copyright © TWI Ltd
7.6.6 Cracks
These are linear discontinuities produced by fracture, cracks may be:
Longitudinal.
Transverse.
Crater.
Centreline.
Toe.
HAZ.
7.6.7 Cavities
A number of flaws are covered by this category.
Elongated cavities
A string of gas pores parallel to the weld axis.
Shrinkage cavity
A cavity caused by shrinkage of the weld metal while it is in a plastic state.
Crater
A depression caused by shrinkage at the end of a run if the heat is removed
quickly.
Crater pipe
A hole in the centre of a crater, caused by shrinkage.
DIS2-30815
Welding and Welding Defects 7-16 Copyright © TWI Ltd
Figure 7.20 Cavities.
DIS2-30815
Welding and Welding Defects 7-17 Copyright © TWI Ltd
7.6.9 Lack of fusion and penetration
Lack of fusion
The weld metal has not bonded.
Excess penetration
Excess weld metal protruding through the root.
Root concavity
A shallow groove in the root.
DIS2-30815
Welding and Welding Defects 7-18 Copyright © TWI Ltd
Undercut
A groove in the toe of the weld where the parent plate is gouged due to the
welding current.
Overlap
Weld metal spilled over from the cap onto the parent plate outside the line of
the toe that has not fused with the parent metal.
Burn through
This is a collapse in the weld pool caused by excessive penetration resulting in a
hole in the weld.
Misalignment
Not a standard term but internationally understood, poor fit-up resulting in the
parent plates being out of alignment either laterally or angularly.
DIS2-30815
Welding and Welding Defects 7-19 Copyright © TWI Ltd
7.6.11 Miscellaneous
Stray flash or arc strike
Burn marks on the parent metal caused by striking arcs with the welding rod off
the line of the weld; can sometimes be caused by arcing of the weld supply
cable if the insulation is damaged.
Excessive dressing
Grinding away too much weld metal and leaving the weld below the level of the
surface of the parent plate.
Grinding mark
Grooves or marks on the parent plate caused by poorly controlled grinding or
surfacing tools.
Tool mark
Marks indented into the parent plate caused by chipping hammers or similar
hand tools.
Torn surface
Surface irregularity caused by breaking off temporary attachments, colloquially
known, though not always accurately, as dog scars see below.
Surface pitting
Small depressions on the weld or parent plate.
Spatter
Spots of weld metal thrown out from the weld pool and attaching themselves to
the parent plate.
DIS2-30815
Welding and Welding Defects 7-20 Copyright © TWI Ltd
7.7 Reporting defects in welds
As diver inspectors are concerned with in-service inspections, volumetric
defects will seldom be identified, as they are usually caused during fabrication.
Planar defects may be observed as these could be caused by stress or fatigue
failure leading to crack-like features becoming evident.
This type of discontinuity will be of most concern in the toe of the weld, which is
also the zone where it is most likely to be found. This is because at this point
there is a region that has been heated and melted causing grain structure
changes as outlined earlier.
Also in this area the geometry of the weld changes, which may create a notch
effect; that is an area where stress is increased above the average for the rest
of the component.
Type of defect
Describe the defect with correct terminology.
Location
State the global location, ie what component is damaged, where on the
component the damage is (state the clock and or tape position relative to a
known datum), give the relative location, ie is it on the HAZ, in the toe, on the
weld cap or in the parent plate.
Dimensions
State the start position and give length. If the defect is a crack-like feature
state whether it is continuous or branching, the orientation and if it is
measurable give width and depth.
Description
Describe the feature, if it is a crack, is it branching, if so state the orientation of
the branches.
Welding inspectors will confirm that the welds meet these requirements and for
the visual elements of the inspection requirements there are a number of
measuring gauges, templates and devices employed. These instruments are
available for in-service inspections and a review of a selection will be of interest
for underwater applications.
DIS2-30815
Welding and Welding Defects 7-21 Copyright © TWI Ltd
7.8 The Welding Institute measuring gauge
A gauge specially designed to accurately measure weld reinforcement height,
leg length, throat thickness and depth of lack of fill.
DIS2-30815
Welding and Welding Defects 7-22 Copyright © TWI Ltd
Bibliography
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990, ISBN 13:
9780419135401.
DIS2-30815
Welding and Welding Defects 7-23 Copyright © TWI Ltd
28/08/2015
1. Machining.
2. Casting.
CSWIP 3.2U Course 3. Forging.
4. Fabrication.
Welding and Welding Terminology
Offshore structures are fabricated and in this
process welding is used extensively.
There are 35 welding processes classified Flux shielded arc welding (6) is the most widely
into seven groups used process.
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shielding gas.
The process is classified as a semi-automatic welding Common faults
process but may be fully automated.
The wire electrode can be either bare, solid wire or flux-
Porosity. Excessive penetration.
cored hollow wire. Excessive spatter. Cracking.
Lack of fusion. Arc strike.
Incomplete penetration. Undercut.
Tungsten Inert Gas (TIG) Welding Tungsten Inert Gas (TIG) Welding
The process:
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Tungsten electrode
Electrode collet
Collet holder
Torch cap/tungsten housing
Torch body
Ceramic nozzle
On/off switch
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Parent plate 1
Parent plate 2
Parent plate 2
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Parent plate 2
Parent plate 3
A tension resisting weld in which the bulk of the The bulk of a fillet weld is contained outside the
weld metal is contained within the planes or parent metal planes or thickness.
thickness of the joined parent metals.
Therefore fillet welds tend to have less strength.
Weld metal
Weld Metal
If the heat flow into and out of the weld is not properly
managed the weld may fail in-service.
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One of the means of making a material softer, often called Temperature management is as important for cooling as it is for
annealing, is to heat it up and allow it to cool slowly. To heat energy input into the weld. The cooling rate must be as
achieve this softening effect a material has to be heated controlled as the heat flow during the actual welding. In general
above its re-crystallisation temperature (Tecry). fast cooling rates (quenching) make the material harder and
less able to withstand crack propagation.
In the previous diagram, this temperature is reached at
point 3 so that the material between point 2 and 3 that While the heat input and cooling rate control may be of
has been raised above the re-crystallisation temperature paramount importance to the finished quality of a weld, there
will be liable to a change of properties. are several other factors that must also be considered.
Defects, such as porosity, often arise in welds due to gas
Above this temperature the grains in the material will penetrating the weld pool protection. Gases that are likely to be
reform and grow. This is known as the heat affected zone present in a weld are hydrogen, oxygen and nitrogen. These are
(HAZ). derived from the atmosphere, water, hydrocarbons (grease or
oil) and other oxides present in the weld vicinity, due to lack of
care in preparation.
These products get into the arc and provide a supply of gas that BS EN 13622:2002 defines all the standard
can be dissolved in the liquid metal of the weld pool. On cooling
the solubility of the dissolved gas reduces and the gas comes out
terms used to describe a weld. There are 25
of solution to form bubbles trapped in the weld metal or terms that apply to this course.
sometimes the gas diffuses into the parent metal. Hydrogen
diffusing into the HAZ will cause hydrogen embrittlement which These terms may be grouped into categories:
may lead to cracking.
Plate edge preparation.
Weld features.
Welding terminology.
Effective throat
thickness
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Run or pass.
Throat thickness Weld metal deposited in a single pass of a filler
rod.
Root
Root bead.
Fusion Zones
Weld bead protruding beyond the back wall of
the parent plates.
Fusion zone.
Filler beads and
The point at which parent plate melts and mixes weld beads making HAZ
with weld metal. up the bulk of the
weld
Offshore structures are constructed mainly of An inspector must be capable of not only recognising a fault in
tubular members. Connections of these members a weld but be able to describe it accurately. In common with
welding terminology this has been internationally agreed and
may be either nodes or nozzles. defined terms.
1. Cracks.
2. Cavities.
3. Solid inclusions.
4. Lack of fusion and penetration.
5. Imperfect shape.
6. Miscellaneous.
C.C.S.L.I.M.
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Cracks Cracks
Cracks Cracks
8
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Gas pore
<1.5mm.
Root piping Blow hole
>1.6mm.
Cavities Cavities
Porosity
Root piping
Porosity
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Cavities
Cavities
Weld crater
Crater pipe
Crater pipe is a shrinkage defect and not a gas Non-metallic inclusions caused by some welding
defect, it has the appearance of a gas pore in processes:
the weld crater. Causes
Slag originates from
Crater cracks Causes: welding flux.
(Star cracks) Too fast a cooling MAG and TIG welding
rate. process produce silica
Deoxidization Slag inclusions Lack of sidewall fusion inclusions.
with associated slag Slag is caused by
reactions and liquid
inadequate cleaning.
to solid volume Other inclusions include
change. tungsten and copper
Crater pipe Contamination. inclusions from the TIG
and MAG welding
Lack of interrun fusion with
slag processes.
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Lack of Fusion
Lack of Fusion
Lack of sidewall
fusion
Lack of root
penetration
Causes
Contamination.
Slow travel speed.
Incorrect welding
technique.
Current too low.
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Poor stop/starts
Undercut.
An irregular groove at the toe of a weld run in the
parent metal.
Causes
Excessive amps/volts.
Excessive travel speed.
Incorrect electrode
angle.
Excessive weaving.
Incorrect welding
technique.
Electrode too large.
Intermittent cap undercut
Arc length too high.
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Spatter:
Excessive current or voltage.
Slag:
Poor workmanship: Inadequate cleaning.
Miscellaneous Miscellaneous
Causes Causes:
Excessive current. Accidental striking of
Damp electrodes. the arc onto the
Contamination. parent material.
Incorrect wire feed Faulty electrode
speed when welding holder.
with the MAG welding Poor cable insulation.
process. Poor return lead
Arc blow. clamping.
Arc strike
Spatter
Miscellaneous Miscellaneous
Grinding.
Hammering.
Chiselling.
Chipping.
Breaking off welded attachments, torn
surfaces.
Using needle guns to compress weld capping
runs. Mechanical damage/grinding mark
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Miscellaneous Miscellaneous
Angular misalignment is
measured in degrees.
Note: Unequal leg lengths on a fillet weld may
be specified as part of the design in which case it Angular misalignment
will not be considered as a defect.
Miscellaneous Miscellaneous
This image cannot currently be display ed.
Linear misalignment
Linear misalignment
Any Questions?
14
Section 8
Ultrasonic Inspection
8 Ultrasonic Inspection
8.1 Physics of ultrasound
Sound is made when something vibrates. You can twang a ruler on a table or
flick a stretched elastic band to verify this. The stretched surface of the rubber
band or the ruler vibrates and sets up a series of vibrations, sound waves, in
the air. As the surface of the band or ruler pushes into the air, the air molecules
are forced together and a region of high pressure forms; compression.
As the surface moves back, the air molecules move apart, forming a low
pressure area or rarefaction. As the surface vibrates, alternate compressions
and rarefactions are set up in the air and travel out from the surface to form a
sound wave. The air molecules don’t move with the wave - they vibrate to and
fro in time with the vibrating surface.
If we plot the displacement of the particle against time it will produce a sine
wave as shown below.
Wavelength
The sound wave so produced travels through the air at a speed of about
332m/sec, at 0°C, at sea level. We hear the sound when it hits a membrane in
our ear and causes it to vibrate.
Sound will travel through any medium that has molecules to move, but it
travels faster in more elastic materials because the vibrations are passed on
more quickly. Sound travels faster in water or metal than it does in air, as
liquids and solids are more elastic than air. The speed of sound increases with
the stiffness, (elasticity) and decreases with density, in fact, it’s actually the
square root of the stiffness divided by the density.
8.1.1 Frequency
As sound is a series of vibrations, one way of measuring it is to count the
number of vibrations per second - the frequency. Frequency is measured in
Hertz. One vibration in one second is one Hertz. Two vibrations in one second is
two Hertz. Ten vibrations in one second is 10 Hertz and 1000 vibrations in one
second is 1000 Hertz or one kilohertz (kHz). One million vibrations in a second
is one Megahertz (MHz).
DIS2-30815
Ultrasonic Inspection 8-1 Copyright © TWI Ltd
The higher the frequency - the higher the note sounds - the higher the pitch. If
you twang the ruler or the rubber band hard, the noise is louder, it has greater
amplitude, but the note remains the same. If, however, you shorten the ruler or
tighten the rubber band, they vibrate more quickly and the note given out is
higher, the frequency is greater. To raise the pitch of their instrument, guitar
players move their fingers down the frets, thus shortening the string and
making it vibrate more quickly.
We can only hear sounds between certain frequencies - more than 16Hz and
less than 20,000 Hertz. If you were able to move your arm up and down 20
times a second, it would sound like a very low hum. You cannot move your arm
this fast, so you cannot hear the vibrations in the air caused by your moving
arm. A dog whistle vibrating at 25,000 Hertz cannot be heard by humans, but it
can be heard by the sensitive ears of a dog.
FREQUENCY SPECTRUM
Sound Waves
Frequency Electro-magnetic Waves
(Travelling at the speed of
(kHz) (Travelling at the speed of light)
sound)
Infrasound
10-3
Less than 16Hz
10-2
10-1
Human hearing range 1
(16 to 20,000Hz) 10 VLF
102 LF
Ultrasound – frequencies
above 20,000Hz up to 103 MF
Radio frequencies
10MHz 104 HF
106 UHF
107 SHF
It rarely occurs to us that there is a whole world of sound that we cannot hear.
Other animals can hear sounds at higher frequencies - bats can hear sound at
100,000 Hertz and others like snakes, have worse hearing than we have.
A sound with frequencies above the upper range of human hearing is called
ultrasound. Sound below about 16 Hertz is called infrasound. Therefore the
definition of ultrasound is; sound with a frequency greater than 20kHz.
However, there is an advantage for the lower frequencies. The lower the
frequency, the more penetrating a sound wave is - that is why foghorns give
out very low notes and why the low throbbing notes from your neighbour’s
stereo come through the wall rather than the high notes. Elephants and hippos
can communicate over distances of up to 30 kilometres using infrasound, while
whales can communicate through water across an ocean!
For most practical ultrasonic testing, the frequency range used is between 0.5-
6MHz; the lower frequencies between 0.5-1.5MHz are used for materials with
large grain structures, such as concrete or cast iron. Frequencies from 2-6MHz
are used for testing materials with fine grain structures including steel.
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Ultrasonic Inspection 8-2 Copyright © TWI Ltd
8.1.2 Velocity
So far, only the effects of the wave passing one point in the material have been
considered. However, the wave itself is passing through the material. Like a
surface wave on water, the water at any point goes up and down, but as well as
this the wave travels forward.
Ultrasonic waves travel through a material at the speed of sound for a given
type of wave in a given material. That is, the speed of sound is different for
different types of wave and the speed of travel is different in different
materials.
The three types of surface wave have no application underwater and will not be
discussed further. The two types of wave that propagate through a solid are
discussed below.
Longitudinal/Compression waves
This type of wave is denoted by the symbol L, with the addition of a letter V -
VL we indicate the velocity of propagation of longitudinal/compression waves.
With this type of wave propagation, the direction of oscillation of the atoms is
the same as the wave propagation see Figure 8.3.
Transverse/Shear waves
This type of wave is denoted by the symbol T, with the addition of a letter V –
VT we indicate the velocity of propagation of these waves. With this type of
wave propagation, the direction of oscillation of the atoms is at 90o to the wave
propagation see Figure 8.4.
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Ultrasonic Inspection 8-3 Copyright © TWI Ltd
Figure 8.4 Transverse/Shear wave.
In order that ultrasonic sound waves can be used to measure depths and sizes
within any material, it is a fundamental principle that the velocity of the sound
wave remains constant for different samples of the same material. This is in
fact the case; and furthermore, the ultrasonic wave obeys the Laws of Light and
we can, therefore, predict its behaviour.
Note: Blank spaces in the VT column, this is because Shear waves cannot be
produced in liquids, solids or polymers such as Perspex and concrete.
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Ultrasonic Inspection 8-4 Copyright © TWI Ltd
8.2 Wavelength
A wave in the sea is a vibration of energy. As the wave passes a fixed point it
produces a constant rise and fall of energy. A complete vibration is a change in
energy from maximum to minimum and back to maximum.
A wavelength is the distance a stress wave moves forward during one complete
cycle. It varies with the speed of sound and with the frequency. Wavelength is
represented by the Greek letter Lambda (). We can work out wavelength if we
know the speed and frequency of a sound wave. Wavelength is the velocity in
metres per second divided by the frequency.
5,940,000
= =2.97mm
2,000,000
If we want to know the wavelength of a shear wave of 2MHz in steel we can use
the formula again, but this time we use the shear speed of sound in steel which
is 3,250m/sec.
An easy way to remember how this formula works is to split it down within a
triangle - with the velocity, wavelength and frequency at the corners.
The velocity must be placed at the top (Note: How it forms a diamond shape)
and the wavelength and frequency at either of the bottom two corners.
λ f
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Ultrasonic Inspection 8-5 Copyright © TWI Ltd
V V
=
f
λ f
V
V= xf
λ f
V V
f=
λ f
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Ultrasonic Inspection 8-6 Copyright © TWI Ltd
8.4 The direction of propagation of an ultrasonic wave
It has been established that the ultrasonic wave travels at a known speed in a
straight line and that it obeys the Laws of Light. In order to predict the direction
that the wave travels as it passes through an interface into a different material,
it is necessary to determine what happens when a wave meets an interface.
An interface will include the outside edges of a component and the back surface
which is referred to as the back wall. Similarly, the surfaces of a crack or
porosity bubble are also boundaries.
At these interfaces, in accordance with the laws of light, the direction of travel
of the wave after meeting the interface will be determined by the Law of
Reflection and the Law of Refraction.
When the angle of incidence is 0°, the reflected angle is also 0°, so the wave is
reflected back along the incident direction. The wave is travelling in the same
material; therefore, there will be no change in wavelength of the signal or the
mode of travel of the wave. This is the ideal condition for thickness
measurements using ultrasonic compression waves.
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Ultrasonic Inspection 8-7 Copyright © TWI Ltd
Figure 8.7 Law of Refraction (Snell’s Law).
It was later discovered that by varying the thickness of crystals and subjecting
them to a voltage, they could be made to vibrate at different frequencies.
Frequency depends on the thickness of the Piezo-electric crystal.
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Ultrasonic Inspection 8-8 Copyright © TWI Ltd
Figure 8.8 The Piezo-electric effect.
There are a number of different types of probes, some designed for specific
tasks. However, in our sphere of NDT we need only be familiar with the main
types.
Single crystal.
Twin crystal.
Compression or zero degree.
Angle.
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Ultrasonic Inspection 8-9 Copyright © TWI Ltd
8.6.1 Single crystal probes
These probes are designed to utilise a single Piezo-electric crystal that both
transmits and receives the ultrasonic signal. The crystal must transmit the
signal, stop ringing, ring down to rest, pick up any reflected signal, ring up to
produce electric energy to pass to the receiver amplifier.
The material properties of the crystals are quite different from those of the
single crystal probe because the two crystals are not required to ring down to
receive. One is constantly transmitting while the other is constantly receiving.
The electric isolation is achieved by provision of two co-axial connectors, one
for transmit and one for receive, while the acoustic barrier is generally a thin
layer of cork.
A twin crystal probe is designed to minimise the problem of dead zone. A twin
crystal probe has two crystals mounted on perspex shoes angled inwards
slightly to focus at a set distance in the test material. Were the crystals not
angled, the pulse would be reflected straight back into the transmitting crystal.
DIS2-30815
Ultrasonic Inspection 8-10 Copyright © TWI Ltd
Figure 8.10 Twin crystal probe.
Advantages Disadvantages
Good power output Poor near zone resolution
Greater penetration Cannot measure thin plate
Advantages Disadvantages
Good near zone resolution Less power output
Can measure thin plate because dead Less penetration
zone is contained within the shoe
Can be focused
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Ultrasonic Inspection 8-11 Copyright © TWI Ltd
Figure 8.11 Angle probe.
8.6.6 Couplant
Ultrasonic testing cannot be carried out in air without the use of a suitable
coupling agent between the probe and the test surface. This is because the
mechanical pulses cannot travel across the small air gap that exists between
the two surfaces, because of the mismatch in acoustic impedance between the
shoe of the transducer and the air. For underwater inspection the seawater acts
as a couplant and aids the passage of ultrasound into the material.
Probe
Couplant
An acoustic sound wave has also previously been described as being a single
sinusoidal wave propagating through a material. These analogies do not
however present a totally true picture.
The sound produced from an ultrasonic crystal does not originate from a single
point but rather it is derived from many points along the surface of the Piezo-
electric crystal. This results in a sound field with many waves interacting or
interfering with each other.
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Ultrasonic Inspection 8-12 Copyright © TWI Ltd
Far Zone
Exponential decay
Intensity
Distance
Figure 8.14 Variations in sound intensity.
After a time, the shock waves, or pulses, even out to form a continuous front.
The area between the crystal and the point where the wave front evens out is
what we call the Near Zone. Inside the Near Zone signals from a reflector bear
no accurate relation to the size of the reflector, as the sound vibrations are
going in all directions. This affects the accuracy of flaw sizing of small reflectors
inside the Near Zone.
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Ultrasonic Inspection 8-13 Copyright © TWI Ltd
Near Zone
The Near Zone of a crystal varies with the material being tested, but it can be
worked out by a formula:
D2
Near Zone NZ=
4
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Ultrasonic Inspection 8-14 Copyright © TWI Ltd
Figure 8.17 Pulse Echo Technique.
The major disadvantage is that pulse echo inspection is reliant upon the defects
having the correct orientation relative to the beam in order to generate a
returning signal to the probe and is not, therefore, considered fail safe. If the
sound pulse hits the flaw at an angle other than 90o, much of the energy will be
reflected away and not return to the probe with the result that the flaw will not
show up on the screen.
Figure 8.18 Pulse echo testing with a zero degrees compression wave probe.
Figure 8.19 Pulse echo testing with an angle shear wave probe.
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Ultrasonic Inspection 8-15 Copyright © TWI Ltd
8.9 Ultrasonic test systems
An ultrasonic test system should be able to measure either the amplitude of the
signal if a through transmission test is used, or the time required for the
ultrasonic signal to travel between specific interfaces if the Pulse Echo
Technique is employed.
A versatile test system in fact measures both the amplitude and the time
simultaneously. For thickness measurement, the main use of ultrasonic testing
is the measurement of the time the signal takes to travel between specific
interfaces, and the instrument is referred to as either a Digital Thickness Meter
or an A-scan flaw detector.
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Ultrasonic Inspection 8-16 Copyright © TWI Ltd
Figure 8.21 Simplified block diagram of Digital Thickness Meter.
A DTM is only designed to give a single readout for each application of the
probe and, as such, can only give a readout from the major reflector, which is
its main limitation. This is different from an A-scan instrument, which is
designed to display multiple reflections simultaneously.
DIS2-30815
Ultrasonic Inspection 8-17 Copyright © TWI Ltd
8.9.2 Advantages of DTMs
Quick and easy to use.
Divers and ROVs can use them.
Only a small amount of training is necessary to use one.
Only isolated cleaning is required.
The Cygnus DTM will take readings through firmly adhered paint.
A-scan: Shows real time depth of the defect, or distance along the beam
path.
B-scan: Holds the reflector and shows cross-sectional views.
C-scan: Illustrates using a plan view and traces the defect.
P-scan: Adds all of the above together and gives a 3-D computer
impression.
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Ultrasonic Inspection 8-18 Copyright © TWI Ltd
Figure 8.23 Baugh and Weedon PA 1011 control panel.
The ultrasonic flaw detector, the UT set, sends a voltage down a coaxial cable
to the probe. The Piezo-electric crystal in the probe is hit by the voltage and
vibrates. The vibration creates an ultrasonic pulse, which enters the test
material. The pulse travels through the material until it strikes a reflector and is
reflected back to the probe.
It re-enters the probe, hits the crystal and vibrates it, causing it to generate a
voltage. The voltage causes a current which travels back to the flaw detector
along the cable. The set displays the time the pulse has taken through the test
material and back and the strength of the pulse as a signal on the CRT screen.
This is basically how a UT set works. It transmits energy into material via a
probe and measures the time in microseconds that the sound pulse takes to
return to the probe. The controls on the UT set are almost entirely concerned
with presenting a display on the CRT screen for the operator to interpret.
The cathode ray tube is a device for measuring very small periods of time. The
CRT displays electrical pulses on a screen in a linear time/distance relationship.
That is, the longer the distance on the screen time base (the X-axis), the longer
the time that has been measured.
On the Y-axis (vertical) the amplitude of the returning signal is indicated, the
higher the amplitude of this signal, the greater the strength of the reflected
signal. Of course, in the case of thickness measurements this will be the back
wall echo.
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Ultrasonic Inspection 8-19 Copyright © TWI Ltd
8.9.5 Calibration and reference blocks
A-scan type instruments all require calibration before being used for testing.
Normally calibration will require the use of a calibration block, however a
reference block may be used if this is either specified or agreed by the client.
Reference blocks
These are manufactured for the client to agreed specifications and surface finish
and are used solely for a particular job and are not intended for any other
purpose. This is usually because they are intended for use on specialised steels
that would have different velocities.
Calibration blocks
There are several different calibration blocks available for ultrasonic testing.
The two most popular are the IIW V1 and IIW V2 calibration blocks. A
calibration block is manufactured to standard specifications and to international
standards. It is produced from specified material and is machined to close
tolerances and laid down standard of surface finish.
All the dimensions on the block are also specified and it is used to calibrate
ultrasonic flaw detectors in general. V1 blocks are used on the surface to
calibrate A-scan units and V2 blocks are used subsea by divers for calibration
checks.
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Ultrasonic Inspection 8-20 Copyright © TWI Ltd
Figure 8.25 IIW V1 block. Figure 8.26 IIW V2 block.
A step wedge as shown in Figure 8.27 it is a type of calibration block used for
thickness measurement.
W
Wh
Couplant
CRT display
Adjust the focus and brilliance of the spot on the CRT screen. The spot will
normally not be visible, but will, however, appear as a line across the screen.
Use the delay control to adjust the time base to display the initial pulse (the
first transmitted pulse) on the screen.
Position the course range control to the required range. (This may be between
10mm and 1m depending on the actual instrument). Select and connect the
required probe. (For thickness measurement and lamination testing, this will be
a zero degrees or normal angle compression probe – either single or twin
crystal).
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Ultrasonic Inspection 8-21 Copyright © TWI Ltd
Linearity of amplification
Set the reject or suppression control to off or zero. Place the probe over the
1.5mm diameter hole on a V1 calibration block. Adjust the gain controls to
display the height of the reflected signal to 80% full screen height (FSH).
Use the fine (2dB or 1dB) gain control to increase the signal by 2dB.
This represents the difference in height between 80-100% that is a ratio of 4:5,
which will increase the signal on the screen by one quarter of its displayed
height and the signal should be at full screen height.
Readjust the fine gain control to attenuate the signal back to 80% full
screen height.
Attenuate the signal by 6dB.
This represents a decrease of a half and the signal therefore should reduce to
40% of full screen height.
This represents a decrease of one quarter of the displayed signal and the height
should then be 10% of the full screen height.
If the gain adjustment does not produce these results the amplifier is not linear
and the instrument must be recalibrated internally, which involves stripping it
down to readjust internal trim settings.
A number of back wall echoes should be displayed on the CRT screen. Adjust
the gain settings as necessary to display the second echo signal amplitude to
75% full screen height.
Adjust the fine range and delay controls to alter the screen display so that four
back wall echoes are shown, all equally spaced across the x-axis.
As the screen on the CRT has a graticule that is divided into 10 equal segments,
the four echoes are adjusted to 2.5, 5, 7.5, and 10 divisions along the x-axis.
DIS2-30815
Ultrasonic Inspection 8-22 Copyright © TWI Ltd
Figure 8.28 A-scan flaw detector calibrated for 100mm.
The procedure will require that the gains be adjusted so that a reflected signal
from the smallest identifiable defect is displayed discretely on the screen and is
not lost in background clutter.
The general practise for scanning with compression probes for laminations is to
adjust the gain setting so that the first back wall echo from the parent plate is
displayed at full screen height.
An alternative method is to adjust to full screen height the first back wall echo
from a specified (say 1.5mm diameter) hole drilled horizontally into a reference
block at the maximum range for the test.
DIS2-30815
Ultrasonic Inspection 8-23 Copyright © TWI Ltd
Setting resolution
The final process in the calibration procedure is setting resolution. This is
adjusting the gain controls so that the CRT display is capable of displaying
several reflected signals from the smallest detectable flaws at the maximum
range of the test. This may be accomplished using an agreed and specified
reference block.
The common method is to display the three signals reflected from the step, cut
out and back wall on the V1 block, Figure 8.29.
The probe is then manipulated around the defect area until the signal displayed
on the screen reduces in amplitude.
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Ultrasonic Inspection 8-24 Copyright © TWI Ltd
The probe is manoeuvred to a position where the initial echo signal is reduced
to half the maximum that was obtained. This represents a 6dB reduction in
signal strength, which gives this method its name. The reason for this reduction
at this point is that now only half the flaw echo signal is being reflected from
the flaw while the remainder of that signal is now not reflected but continues on
its transmission path through the material.
The centre point where the probe is now positioned is marked accurately on the
surface of the test piece and this procedure is continued until the entire outline
of the lamination is plotted on the surface of the plate.
25mm
60mm
Most frequently these will lie on the fusion boundary of a weld and therefore the
probe angle will be the same as the angle of preparation. This will ensure that
any signal reflected from a flaw will be returned along the same path as the
transmission signal because the angle of reflection will equal the incident angle.
There are standard probes available for 45o and 60o as these angles are
common preparation angles in structural welds. Other angles may be calculated
by trigonometry and the application of Snell’s Law, Figure 8.7 refers.
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Ultrasonic Inspection 8-25 Copyright © TWI Ltd
Figure 8.31 Angle probe scanning the preparation face of a weld.
The probe is traversed along the weld until the signal from the flaw is
maximised. Further traversing of the probe will drop the signal height on the
CRT in the same manner as for a 6dB drop but with angle probes the signal is
reduced to one tenth using a 20dB drop. This point can be plotted and the
defect size obtained by numerous such manipulations of the probe.
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Ultrasonic Inspection 8-26 Copyright © TWI Ltd
8.9.12 Advantages and disadvantages of A-scan ultrasonics
Advantages:
Can find and size subsurface defects.
Possible to record the results via a computer system, photograph or video
the CRT screen.
Accurate thickness readings can be carried out on thinner material than with
DTMs.
Areas of pitting on the back wall can be assessed.
Very adaptable, various probes can be fitted ie shear and compression
probes as well as twin and single crystal probes.
More than one person can view the results either by looking at the same
unit or by setting up repeaters.
Real-time results, no waiting for films to be developed.
Disadvantages:
Requires highly trained operators to set up and interpret the results.
Relies on accurate calibration.
High level of cleaning required SA2.5 or SA3.
Special arrangements have to be made for recording the results.
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Ultrasonic Inspection 8-27 Copyright © TWI Ltd
Bibliography
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990. ISBN 13:
9780419135401.
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Ultrasonic Inspection 8-28 Copyright © TWI Ltd
28/08/2015
Ultrasonic Inspection
Audible sound:
10-1
16-20,000Hz 1
Ultrasound – frequencies above
Sound waves within the range of human 20,000Hz up to 10MHz 10 Radio VLF
frequencies
Ultrasonic frequencies 102 LF
1
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The ultrasonic sound wave range of frequency is The number of atomic particle oscillations it causes per
from 20kHz up to approximately 10MHz. second determines the frequency of a signal.
Graph for an alternating voltage A sound wave can be compared to the previous
graph in that as the sound wave train passes
through a material it propagates a stress front
that causes the atoms within the crystal lattice
structure of the material to be alternatively
tensely and compressively stressed and relaxed.
Its not usual to include all the zeros with the numbers related to
frequency. Normally the writing is reduced by the use of prefixes.
The stress variation with time at a point in a solid, The frequency calculated above would normally be written as
subjected to an ultrasonic impulse from an ultrasonic transducer 10kHz.
2
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1,000 103 kilo K Ultrasonic waves travel through a solid at the speed of
sound for a given type of wave in a given material.
1 1
The speed of travel of a sound wave is different for
0.001 10-3 milli m different types of wave and different in different materials.
There are two types of wave that propagate VL denotes the velocity of propagation of
through the solid material and three types that longitudinal or compression waves.
propagate as surface waves along the surface
skin of the material. With this type of wave the direction of oscillation
of the atoms is the same as the direction of the
wave propagation.
Wave front
Second wave front Wave front Wave
Wave front moves moves past the front
particle particle moves on
3
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1. Raleigh waves.
2. Lamb waves.
3. Love waves. Longitudinal Longitudinal
Used for
Passes through thickness and
or VL That is in the Yes
the large bulk of lamination
Compression direction of wave
material measurement
propagation
s
VL = Longitudinal. VT = Transverse.
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The wavelength indicates how far the ultrasonic For example, to calculate the wavelength for a
stress wave moves forward during one complete 20kHz ultrasonic compression wave in
stress cycle and has to be considered when the aluminium:
maximum sensitivity of any ultrasonic test is being
assessed.
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The amount of signal attenuation is given by the For example what is the attenuation of the ultrasonic
curve that joins up the peaks of the graphs and the signal between the first and second echoes for the
signals The
shown?
attenuation in decibels (dB) is given by: first echo is 12 units high Applying the
formula gives:
= 20 Log10
(12/6).
The second is
6 units high = 20 Log10 (2).
P1 and P2 can be any successive two peaks. = 20 x 0.3010.
= 6.02 dB.
A standard formula that is applied to the attenuation of an
ultrasonic signal propagated in any material under test is:
The calculated result is most important as it is used in
20 Log10 V1/ V2 dB practical material testing. It should be remembered that
if the signal is halved that is a 6dB drop.
6
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The angle the reflected wave makes with the normal angle to At an interface part of the ultrasonic wave is reflected and the
the interface from which the wave is being reflected is the same rest will pass into the second material. The path in the second
as the angle that the incident wave makes with the same normal material will still be a straight line but the direction of this
angle. wave will not be continuous with the direction of the incident
wave. It would have been turned through an angle that can be
The angle of incidence is equal to the angle of reflection determined by Snell’s Law.
Material 2 is denser
than material 1
When the angle of incidence is 0° the reflected angle is also 0°
this is the ideal condition for thickness measurements using
ultrasonic compression waves.
The Piezo electric transducer crystal is made When switch is closed the When the crystal is squeezed by
from a range of synthetic crystalline and ceramic potential across the crystal the returning sound an electrical
will cause it to change shape potential will be produced
materials.
There are a number of different types of probes, These probes are designed to utilise a single Piezo electric
some designed for specific tasks. However, we only crystal that both transmits and receives the ultrasonic signal.
need to be familiar with the main types. The acoustic characteristics of this transducer are quite specific
and the selected crystals possess particular characteristics.
All probes are designed to transmit an ultrasonic
signal into a test specimen with maximum efficiency. The crystal must transmit the signal, stop ringing, ring down to
The configuration of any probe is dependant on the rest, pick up any reflected signal, ring up to produce electrical
actual task it is designed for. energy that is passed on to the receiver amplifier.
There are broadly four types of probe: So the natural frequency of the crystal needs to be very widely
separated from the ultrasonic frequency being used for the test.
1. Single crystal probes.
2. Twin crystal probes.
3. Compression or zero degree probes.
4. Angle probes.
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Advantages: Advantages:
Disadvantages: Disadvantages:
8
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Probe
Probe
Couplant
The pulse/echo technique (2). There are several types of units that can be used in this system
Based on the reflection of energy from a flaw or depending on the method employed for timing and indicating
interface. the pulses of energy.
This is the method used in A-scan ultrasonic
inspection and digital thickness meters and is the For flaw detection the indicator is a (cathode ray tube) CRT as
basis of a majority of ultrasonic test systems. this presents all the information available in the echo system.
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Calibration block.
There are several different calibration blocks available
for ultrasonic testing.
All the dimensions on the block are also specified and it is used
to calibrate ultrasonic flaw detectors in general.
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25mm
60mm
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Possible Causes of
Advantages of DTMs
False Readings With DTMs
Quick and easy to use.
Divers and ROVs can use them.
Only small amount of training is necessary to
get results.
Only isolated cleaning required.
A Cygnus DTM will take readings through
firmly adhered paint.
Can find and size subsurface defects. Requires highly trained operators to set up
Possible to record the results via computer, and interpret the results.
photograph or video the CRT screen. Relies on accurate calibration.
Accurate thickness readings of thin material. High level of cleaning required SA2½ or SA3.
Areas of pitting on the back wall can be Special arrangements have to be made for
assessed. recording the results.
Very adaptable, all types of probe can be
fitted.
More than one person can view the results
either by looking at the same unit or by
setting up repeaters.
Real time results, no waiting for films to be
developed.
12
Section 9
In either case only discrete areas of the structure will be cleaned, not the entire
jacket. A number of methods for cleaning exist and are tabulated in Table 9.1
DIS2-30815
Cleaning for Inspection and Profile Grinding 9-1 Copyright © TWI Ltd
Figure 9.1 Hughes HP water jet.
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Cleaning for Inspection and Profile Grinding 9-2 Copyright © TWI Ltd
9.1.2 Diving Medical Advisory Committee (DMAC) advice
The DMAC has published the following advice on managing any accident that
might occur while using this type of equipment.
The wound caused may appear insignificant and give little indication of the
extent of the injury beneath and the damage to deeper tissue. Large quantities
of water may have punctured the skin, flesh or organs through a very small
hole that may not even bleed.
Initial mild damage to the wall of an organ may result in subsequent rupture,
particularly if infection has been introduced. The development of subsequent
infection is particularly important in abdominal injuries.
The development of fever and a rising pulse rate suggest the injury is serious,
together with the persistence or occurrence of pain. On evacuation, the diver
should carry the following card, which outlines the possible nature of the injury.
This person has been involved with high pressure water jetting up to
14,500psi (100MPa, 1000 bar, 1019Kg/cm) with a jet velocity of 900mph
(1440Km/hr).
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Cleaning for Inspection and Profile Grinding 9-3 Copyright © TWI Ltd
The specifications from these standards normally applied offshore are as
follows:
SA3: Very thorough blast cleaning to bright shiny metal. This is good for
most inspection but will reflect light and is, therefore, not such a
good surface if video and photography are employed. Most
commonly used for A-scan ultrasonic inspections.
For CVI and MPI the area cleaned to SA2½ should include the weld cap and an
area 75mm either side of it, measured from the weld toe. Also, an area large
enough to allow access for the inspection equipment and the diver inspector
should be cleaned to SA1 either side of the weld, see Figure 9.2.
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Cleaning for Inspection and Profile Grinding 9-4 Copyright © TWI Ltd
9.2 Profile grinding
9.2.1 General comments
Profile grinding may be required during the fabrication stage of the structure’s
life as a means of improving the profile of fabrication welds that may have
process faults, such as, excessive weld metal, undercut, poor restart, stray arc,
spatter or any other fabrication flaws.
Regarding the in-service stage for any structure the need to employ profile
grinding may be dictated by:
The need to establish whether or not any indications identified during MPI or
EMD investigations are actually cracks.
The requirement to grind out any cracks that are actually confirmed during
inspection activities.
The practice of removing identified notches or stress raisers discovered
during the normal IMR cycle.
DIS2-30815
Cleaning for Inspection and Profile Grinding 9-5 Copyright © TWI Ltd
Figure 9.3 Remedial and profile grinding.
DIS2-30815
Cleaning for Inspection and Profile Grinding 9-6 Copyright © TWI Ltd
Bibliography
Bayliss M, Short D, Bax M, Underwater Inspection, CRC Press, 1990, ISBN 13:
9780419135401.
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Cleaning for Inspection and Profile Grinding 9-7 Copyright © TWI Ltd
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On evacuation the diver should carry the following SA1: Light cleaning, removal of gross fouling for GVI.
card which outlines the possible nature of the injury: SA2: Cleaning to paint coat including removal of loose
This person has been involved with high pressure water paint and corrosion products.
jetting up to 14,500psi (1000bar) with a jet velocity of SA2½: Thorough blast-cleaning with grit entrainment
900mph (1440kmh). resulting in dull matt metal finish. This is the most
widely adopted cleaning level applied offshore as
it leaves a surface that does not unduly reflect
Please take this into account when making your diagnosis. light. It is sometimes referred to as stippled. It is
an excellent surface for CVI, MPI CCTV,
Unusual infections with micro-aerophilic organisms photography and all other NDT.
occurring at low temperatures have been reported. These SA3: Thorough blast cleaning to bright shiny metal.
may be gram negative pathogens such as those found in This is good for most inspection but will reflect
sewage. Bacterial swabs and blood cultures may therefore light and is therefore not such a good surface if
be helpful. CCTV and photography are employed.
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Crack
Weld
Pit gauge
Weld
Final Profiling
Area ground to
maximum agreed and
profiled to relieve stress