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Metwally Hamza Metwally: Prepared by
Metwally Hamza Metwally: Prepared by
Prepared By:
Metwally Hamza Metwally
Um Bogma formation had been stratigraphically divided into three main members
from below upward; Ras Samra, El-Qor, and Um Shebba members. The economic
Mn deposits are limited to Ras Samra Mb within its dolomitic rocks.
The region had been affected by faults, as the dominant structural element within
it. These faults had been grouped into three ones; NNW-SSE trending normal faults
(Red Sea trend), NW-SE trending faults (Gulf of Suez trend), E-W trending faults.
Mn deposits of the region have been divided into four facies (types); Stratiform
continental Mn-conglomerate, sandstone, and mudstone, Stratiform lagoonal to
swampy bedded manganiferous mudstone and dolostone, Stratiform pisolitic Mn
ore, and Stratabound karst Mn ore.
Geochemical studies had been done for these deposits. It had been found that
these Mn deposits are highly enriched in Pb, Cu, Zn, and Ba. And depleted of Co,
Ni, Be, Mo, Sr, and Sn, as evidence for hydrothermal origin of these Mn deposits.
Present author wishes to acknowledge
the grand professor, Dr. Moustafa
Mouhammed Mogahed, for doing his
best supervising of this paper while
working upon it. And without his
supervision, this paper would not have
come out.
Thanks a lot!
I dedicate this paper of my graduation
project to two persons, who influenced
my whole life, whether educational or public.
the first of them is my father who taught
me how to read a book and get benefited of it.
The second person is my mother, who
brought me to the life… such a beautiful life,
also, she was and still helps me,
by all she can, and encourages me forever.
Thanks, my God!
Thanks, my father!
Thanks, my mother!
Table of Contents
1. Introduction: (1-11)
1.1 Mn deposits in space and time...…………………..……………………… 2
1.2 Deposition of Mn, worldwide……...……………………………………... 3
1.3 Phanerozoic supremacy………….…………………….…………….…… 3
1.4 Role of oxygen…………………………………………………………… 4
1.5 Role of tectonic plates……………………………………………………. 4
1.6 Role of biological activity………………………………………………… 5
1.7 Role of drifting processes…………………………………………………. 5
1.8 Mn production, worldwide…………………………………………………6
1.9 Mn deposits of Egypt………………………………………………………7
1.10 Outcrops of Um Bogma region………………………………………….. 7
1.11 Chemistry of Mn and Fe…………………………………………………..9
1.12 Relations between outcrops of Um Bogma region………………………..9
1.13 Topography of Um Bogma region………………………………………. 10
1.14 Aims of study of the present paper……………………………………….11
6. Geochemistry: (28-33)
6.1 Evidence for hydrothermal origin of Mn deposits…………………………29
6.2 Evidence for sedimentary origin of Mn deposits…………….………….....30
6.3 Role of karstification and weathering processes in Mn accumulation….…30
6.4 Results of geochemical analysis of Mn ore samples by Saad (1994)…...…31
6.5 Types of Mn ore deposits according to geochemistry by Khalifa (2014)....33
Fig. 6: The stratigraphic column of the all formations of the Um Bogma region
and the stratigraphic distribution column of Um Bogma Formation itself.............23
Fig. 7: Sketches representing some modes of occurrences of the Mn-Fe ore bodies
within the three members of the Um Bogma Formation…………………............25
Fig. 8: Scatter plot showing the inverse relation between Fe203 and MnO2.....32
1
Introduction
Manganese (Mn) is the most remarkable and essential ore (in a metal form) to iron
and steel production, due to some properties which are not existed in other ores, such
as its ability to act as sulfur-fixing, deoxidizing, alloying metal. In the process of the
steel making and production, Mn ore is the most demand, presently in the range of
85% to 90% of the total. Such manganese ferroalloys, which are consisted of various
grades ferromanganese and silicomanganese, are used provide most of this key
ingredient to iron and steel making. Also, it’s widely used as products for
construction, machines making, and in a transportation. Mn ore is also a key
component of certain widely used aluminum alloys, and in oxide form, dry cell
batteries. In addition to other uses, as using as plant fertilizers, animal feed, and
colorants for brick.
3
of manganese in only Archean basins of Proterozoic type and tectonism, in addition
to the oxygen in both atmosphere and hydrosphere during the late Archean.
4
Phanerozoic eon, and there is a large-scale development of sedimentary manganese
deposits in the Mesozoic era.
5
Fig. 1: False color composite Landsat image of Um Bogma area, west-central Sinai, Egypt,
after Bishta 2009.
Fig. 2: Map showing distribution of the Lower Carboniferous in the Um Bogma area, west-
central Sinai, Egypt, according to Kora and Jux.
8
1.11) Chemistry of Mn and Fe
Manganese oxides, like iron oxyhydroxides, show debate in their genesis, i.e.,
accretion as colloids from ambient sea water, precipitation from sediment pore-fluids
and/or ascending hydrothermal solutions associated either to volcanic activity or to
fault zones. Manganese is very similar to iron in chemistry where the two elements
are mostly associated to each other in the different rocks. The manganese, like iron,
has two important valence states, Mn+2 and Mn+4. In the divalent state (Mn+2),
manganese forms soluble compounds and can be transported in solution. In the
tetravalent state (Mn+4), however, it forms insoluble compounds, any solution
containing Mn in solution will quickly precipitate a tetravalent compound such as
pyrolusite (MnO2) by oxidation.
9
Fig. 3: Paleozoic Outcrops of Um Bogma Region, Sinai, Egypt. By Kora 1981.
11
Geologic
Setting
12
Geologic Setting
Um Bogma Formation and the enclosed Mn ore which occurs within the lower
dolomitic part of this formation, are both of limited distribution and restricted only to
the Um Bogma Region. In other places, Um Bogma Formation does not expose.
Otherwise, the Abu Thora Formation of the same age of the Um Bogma appears.
Such in the southern part of the Um Bogma Region, at Wadi Ferin, Wadi Mokattab,
and Gebel Abu Durba, Um Bogma Formation is completely missing and the
overlying Abu Thora Formation overlies directly the Cambrian Naqus Formation
(Klitzsch, 1990 and El Barkooky, 1992). Also, in the northern part of Wadi Qena,
Eastern Desert, the Abu Thora Formation rests directly on the Cambrian Naqus
Formation (Abdallah et al, 1992). At Wadi Araba, along the western side of Gulf of
Suez, the Um Bogma Formation is also missing, while the others are exposed, such
as the Upper Carboniferous-Permian shallow-marine and continental successions of
Rod El Hamal, Abu El Darag, and Eheimar Formations. These previous geological
field facts are the very remarkably excellent indications, which can reflect the
tectonic instability of the Um Bogma Region during the Lower Carboniferous time
(El Aref, 1994).
Fig. 4: Simplified structural map of Um Bogma Region showing the geologic setting and the
geologic distribution of the recognized facies of the lower Mn ore member of Carboniferous
Um Bogma Formation.
14
Mn ore facies
(types)
15
Mn Ore Facies (Types)
The Economic Mn Ore deposits are limited only within the Lower Carboniferous
succession of the Um Bogma Formation, and these deposits take the shape of
stratabound to stratiform, as the field observation, in the Um Bogma Region, West-
central Sinai, Egypt. These Mn-ore types have been deposited under a synergistic
action of that subaerial to shallow marine conditions, along with the Carboniferous
paleokarstification which is with a relation to intra-Carboniferous uplifting phase, sea
level fall, and deep weathering processes.
16
indication to north and westward debauching of the land-derived Mn-rich materials
into Lower Carboniferous Sea. So, paleohighs, in east and southeast of the Um
Bogma Region, have probably played an important role, under humid paleoclimate,
in accumulation the detritus Mn and Fe materials, such as clast and suspensions, as a
suggestion in the light of the previously mentioned case.
17
investigations had been done for the Mn ore deposits, and finally reflect their
continental source.
18
Stratigraphy of
Mn-Bearing Um Bogma Formation
19
Stratigraphy of Mn-Bearing
Um Bogma Formation
Um Bogma Formation, in west-central Sinai, Egypt, varies in its thickness from
0-10 m, in southeastern and northeastern parts, and reaches its maximum thickness
of about 30-40 m, in the northeastern part between Gebel Nukhul and Wadi Khaboba.
The Um Bogma Formation is essentially a pink-grey dolostone sequence. Most of the
aforementioned rocks of these dolostone beds are very hard, but ones that occupy the
middle part of the formation under study, are of different marly dolostones and
earthly limestone which alternate with other rocks of soft yellowish siltstone in
composition. Quartz grains which are in the size of the sand and the silt, with few
pebbles, are also recorded within the whole succession, and the southeastern part of
the area is considered to be related to the terrigenous facies, which is more typical in
this limited area, of the whole region of Um Bogma. In most beds of the Um Bogma
succession, veinlets of Mn and Fe are common, but the most existed and the highly
economic ones are confined to the lower member of the Um Bogma Formation. Um
Bogma Formation had been divided into three main members (Fig. 5), after Kora
(1994), they are from base upward; Ras Samra, El-Qor, and Um Shebba members.
Fig. 5: A photo showing the three main members of Um Bogma Formation, from below
upward; Ras Samra, El Qor, Um Shebba Members.
20
4.1) Ras Samra Member
This member is the basal unit within the Um Bogma Formation (Fig. 6), it
consists mainly of hard, bedded, pinkly brown, and coarse-grained crystalline
dolostones, containing pores and cavities filled with calcite (Kora, 1994). And
towards the bottom, it compositionally changes into sandy and pebbly dolostones. In
the light of paleontological characters, the middle part of this member contains
Crinoids and tabulate Coral (Kora, 1994). The member reaches its maximum
thickness of about 17 m, in the western part of the Um Bogma region, in Ras Samra
section, and gradually decreases towards the east. Also, this aforementioned
thickness reduces hugely at Um Shebba in the extreme northwestern part of the are
under study. There is a severe-sharp contact between Mn-Fe ore bodies and their host
rock. Calcareous shale, kaolinitic clays, siltstone and sandstone rocks surround the
Mn-Fe oxides as thin layers. The shales of this member had been deposited in the
time of Early Carboniferous, on an eroded surface, existed between the Adedia
Formation and the Um Bogma Formation (Weissbrod, 1969). The massive
dolostones and the overlying sandstones series play an important role in the flow of
the shales of this member, due to putting their loads upon these shales, and then their
flow takes place, so the thickness varies. Also, bending and contortion can be
considered as remarkable reasons for the thickness variation. These shales may be
considered as the representing the subsoil and topsoil of a paleosol profile (El
Sharkawi et al, 1990). The topsoil of this paleosol profile contains sediments which
are considered to be continental in origin, and deposited under subaerial pedogenetic
conditions, in the duration of karstification process of the lower dolostones of the Um
Bogma Formation.
22
Fig. 6) A photo showing the stratigraphic column of the all formations of the Um Bogma
region, west central Sinai, and focusing upon the three main members of the formation
under study, after Kordi et al (2017).
23
Stratigraphic
Distribution of
Mn-Fe Deposits
24
Stratigraphic Distribution of
Mn-Fe Deposits
Mn-Fe Deposits are widely distributed within the whole members of the Um
Bogma Formation, but which have an economic impact is only limited within the
basal lower member (Ras Samra Member). The stratigraphic relations of the Mn-Fe
Ore Deposits are summarized as being outlined below, according to Kora et al (1994).
Fig. 7: Sketches representing some modes of occurrences of the Mn-Fe ore bodies within
the three members of the Um Bogma Formation, in Sinai, a) Abu Thora Area, b) El-Qor
Area, c) Um Rinna Area, By Kora et al (1994).
25
5.1) Mn-Fe deposits within the Ras Samra Member
a. The Mn-Fe Ore Deposits take the shape of stratiform lenticular bodies,
occurring within the lower part of the Um Bogma Formation (Ras Samra
Member), and its extension is in SW–NE direction through its central and
southern parts, this type of Mn-Fe Deposits has the following varieties:
1) The ore overlies and gets with a direct contact with the Adedia Formation
(Fig. 7. a), in some areas, such as in that of Ras El Homara, Abu Hamata,
Abu Zarab, Abu Thora Areas.
The ore has also an uncommon mode of occurrence as lenticular bodies
with intercalated with dolostones of the Ras Samra Member, as mainly
appeared in some areas, as in that of Ras Samra, Dakran, El Habla, Sid
El Banat, and Gebel Ghorabi Areas.
2) There is another uncommon occurrence of the Mn-Fe ore Deposits, which
overlies directly the dolostones of Ras Samra Member, in another areas,
such Abu Thora and El Kobra Areas.
3) In southeastern parts of the Um Bogma Region, the deposits under study,
are occupying the position of the Ras Samra Member, exactly such as in
case (a), but it’s overlain by silty shales and these by the sandstones of
the Abu Thora Formation.
26
2) In Wadi Khaboba, the ore is restricted to the contact of El-Qor and Um
Shebba Members, and this occurrence had been recorded in the El-Qor
and Um Rinna Areas (Fig. 7. c).
3) The ore is interbedded with the Um Shebba Member in surface outcrop,
in the eastern side of Wadi Kharig.
4) The ore is overlain by sandstones of the Abu Thora Formation and it’s
underlain by the middle El Qor Member of the Um Bogma Formation.
And this case is being considered as uncommon occurrence of Mn-Fe Ore
Deposits, and it’s recorded only in Um Rinna Area.
c. In Zobeir and Dakran localities, the deposits under study, are considered to be
of vein-like type, and these deposits of such a vein-like type are encountering
in two aforementioned localities only. These Ore Deposits are associated with
fissures and faults. At Dakran, the vein extends about 4 m vertically. And at
Zobeir, the thickness of the vein is about 0.4 m and extends for about 3 m
normal to the bedding.
27
Geochemistry
28
Geochemistry
The geology and the mineralogy of the Mn deposits of the Um Bogma Region, in
west central Sinai, had been previously studied by some investigators, such as; Mart
and Sass 1972, Magaritz and Brenner 1979, Saleeb et al. 1987, Khalil 1988, Saad et
al. 1994, and Khalifa 2014. There is a dispute between investigators about the origin
of these most economic Mn ore deposits in Egypt, locating in the Um Bogma Region.
29
foraminiferal tests of Fusilina sp. are shown to be completely replaced by
polianite with their internal structures mostly obliterated (Saad et al., 1991).
30
in the Mn ore deposits can be act as strong evidence of a karst-related mineralization.
The ore body varies in composition from pure manganese ore to pure iron ore, but it
generally represents a mixture of the two ores in variable concentrations. Mart and
Saas (1972) had divided the Mn ore deposits lenses which are larger than 50 m, into
three main mineralogical zones, they are outlined as; 1) an inner manganiferous zone,
2) an intermediate ferruginous-manganese zone, and 3) an outer ferruginous zone.
There is a transition between the ore bodies and the surrounding dolomite, and this
transition phase is abrupt and distinguished by an enrichment of quartz-sand grains,
up to 73% (Saad et al. 1994).
31
Fig. 8: Scatter plot showing the inverse relation between Fe203 and MnO2, in the Umm
Bogma region, west central Sinai.
32
6.5) Types of Mn ore deposits according to geochemistry by
Khalifa (2014)
There are three main types of Mn-Fe ore deposits, which had been detected by
field observations, MnO and Fe2O3 content, and MnO2/Fe2O3 ration, such as; 1)
Mn-rich ore, 2) Fe-Mn rich ore, and 3) Fe-rich ore (Khalifa, 2014). Also, it’s
investigated that there is a strikingly strong negative correlation between MnO and
Fe2O3, it reflects the precipitation of these deposits under different environmental
conditions (Saad et al. 1994; Khalifa, 2014). The components K2O, Al2O3, MgO, Co,
Cu, Zn, Sr, and Sn are all positively correlated with Mn and with a negative one with
Fe (Saad et al. 1994). Positive correlation had been investigated for Ba and Cu with
MnO, with correlation coefficients of; r=0.75 between Ba and MnO and r=0.63
between Cu and MnO (Khalifa, 2014), it reflects that these Ba and Cu had been
selectively adsorbed on manganese oxides. The positive correlation coefficients
between some trace elements, such as Co-Ni (r=0.63), Co-Cu (r=1.00) and so on,
indicates that these Mn deposits are of hydrothermal in origin (Saad et al. 1994;
Khalifa, 2014).
33
General
Remarks
34
General Remarks
Um Bogma region is a most important spot for Manganese deposits of an
economic impact, that’s only because that its reserve of Mn is very high and
consequently an economic, and get exploited since ancient time. So, this
aforementioned region had been studied geochemically, petrologically, structurally
by many investigators. The results and the properties of these studies are outlined
below:
o By and general, Mn depostis were remarkably restrained in the Archean period,
but reversely, the Fe deposits were dominantly appeared in this time,
worldwide. That’s a result of the paucity of Mn in the volcanic/hydrothermal
exhalations, in the duration of the Archean. Otherwise, Mn deposits had been
considered to be economic and exploitable in Proterozoic and Phanerozoic,
within volcanogenic massive sulfide (VMS) deposits, because the magma of
these two last periods was highly enriched in Mn, but during the Archean
period, the magma was poor in it.
o Due to the ongoing evolution of the crust of the earth, in addition to the
evolution of the earth’s spheres, especially lithosphere, the economic
manganese deposits had appeared for first time, worldwide, only around 3000
Ma, in the iron ore group in India.
o Oxygen had increased in the Proterozoic era, and get being too much, that’s as
result of photosynthesis process by biota in such period, this oxygen had
consequently oxygenated the atmosphere and hydrosphere, and then facilate the
deposition of Mn deposits, in general.
o Tectonic regime, in the Phanerozoic eon, had been controlled by the plate
motions of converging and diverging in nature, and then, this controlled the
processes of deposits forming. So, this controlled regime facilate the producing
of such deposits as Mn, as a remarkable example, in the aforementioned eon.
o Only Mn ore deposits had been enclosed within the lower part of Um Bogma
formation, exactly in the dolomitic one, in the Um Bogma region only, because
Um Bogma formation does not expose in other areas, otherwise, Abu Thora
formation exactly exposes.
o Structurally, the faults are the notable structures in such region, as the most
predominant structural elements existed in this region of Um Bogma. There are
35
three main groups of these faults, according to the direction of their trending.
NNW-SSE trending faults, NW-SE trending faults, and E-W trending faults.
Due to the presence of these faults, vertical displacement occurs in such region,
reaching up to 100m.
o Mn ore deposits within the Lower part of the Um Bogma formation have been
grouped into four types; a) Stratiform continental Mn-conglomerate, sandstone,
and mudstone, b) Stratiform lagoonal to swampy bedded manganiferous
mudstone and dolostone, c) Stratiform pisolitic Mn ore, d) and Stratabound
karst Mn ore. The first indicates two cases… to surface slope deposits,
accumulated through mudflow regime, and to derivation Mn- and Fe-rich
materials such as clasts from contiguous sources. The second type subjects to
be deposited into a restricted lagoonal environment, with high salinity. And the
third type can be used an indication to deposition during cyclic shoaling
regimes. Finally, the hast refers to the process of sea regression after the effect
of weathering processes such as karstification.
o Surface processes, such as the most important one of weathering play an
important role in accumulation of Mn deposits during the mature stage of the
Carboniferous karstification. The presence of quartz-sand grains in the Mn ore
deposits can be considered as acceptable evidence for this case.
o Mn ore deposits of Um Bogma are highly enriched in Pb, Cu, Zn, and Ba. And
depleted of Co, Ni, Be, Mo, Sr, and Sn. In addition, and according to
geochemical analysis, there is an inverse relation between Fe 2O3 and MnO2,
with a most notable indication to the happening of the fractionation process
between two these elements, during their deposition. Also, an according to the
Fe-Mn-[10x (Cu+Ni+Co)] ternary diagram, the manganese of the Um Bogma
is of hydrothermal in origin.
36
References
37
References
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39
املستخلص
40
تقع منطقة أم بجمة في غرب وسط سيناء ،بجمهورية مصر العربية ،وقد جذبت هذه المنطقة انتباه الكثير من
الباحثين لدراستها ،نظر ا ألهميتها االقتصادية ،باعتبارها نقطة اقتصادية محورية هامة لرواسب المنجنيز في
مصر ،حيث تعت َبر هذه المنطقة مشاعا اقتصاديا لرواسب العالم ،حيث تمثل نسبة مهمة من النسب االقتصادية
لرواسب الخامات في قارة أفريقيا على حد العموم ،وفي دولة مصر خصوصا.
قس َِم متكون أم بجمة استراتجرافيـا إلى ثالثة أعضاء ،من األسفل لألعلى؛ راس سمرا ،الكور ،وأم شيبه ،وتظهر
رواسب المنجنيز في ك ٍل ِمن الثالثة أعضاء ،ل ِك َّن الرواسب االقتصادية التي لها جدوى وأهمية تتركز في العضو
الذي باألسفل (راس سمرا) وذلك من خالل انتشار رواسب المنجنيز خالل صخوره الدولوماتـيـتـية.
قد تأثرت منطقة أم بجمة بمجموعة من العمل يات الجيولوجية والحركات التكتونية ،وتعد الصدوع العنصر
التركيبي األعم الذي تأثرت به المنطقة ،وقد ق ِس َمت العناصر البنائية السائدة (الصدوع) بالمنطقة حسب اتجاهاتها
إلى؛ صدوع في اتجاه شمال شمال غرب -جنوب جنوب شرق (في اتجاه البحر األحمر) ،واتجاه شمال غرب
-جنوب شرق (في اتجاه خليج السويس) ،وأيضا صدوع في اتجاه شرق -غرب.
أجر َيت العديد ِمن الدراسات الجيوكيميائية لعينات المنجنيز المقتلَعَه ِمن متكون أم بجمة ،بمنطقة أم بجمة ،بغرب
وسط سيناء ،فو ِجدَ أنها غنية جدا بعناصر الرصاص ،النحاس ،الزنك ،والباريوم ،وفقيرة في الكوبلت ،النيكل،
البريليوم ،المولبيديوم ،السرانشيوم ،القصدير .وو ِجد أن هناك عالقة سالبة (عكسية) بين أكسيد المنجنيز وأكسيد
الحديد ،وو ِجدَ أيض ا أن أكسيد البوتاسيوم ،أكسيد األلمونيوم ،أكسيد الماغنسيوم ،النحاس ،الكوبلت ،الزنك،
السرانشيوم ،والقصدير على عالقة موجبة (طردية) مع المنجنيز ،وسالبة (عكسية) مع الحديد ،وعلى عكس ذلك
و ِجدَ أن أكسيد السيليكون (الكوارتز) ،البريليوم ،المولبيديوم على عالقة طردية مع الحديد ،وسالبة مع المنجنيز.
ومن المقارنة بين رواسب المنجنيز هذه (ألم بجمة) ،مع الرواسب الحديدومنجنيزيه ،تلك التي تتواجد في بيئات
اليوم المعاصرة المتنوعة ،فو ِجدَ أن المحاليل الحرمائيه هي المسؤول األول عن تكون رواسب المنجنيز في
منطقة أم بجمة.
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دراسة الخواص الجيوكيميائية ونشأة رواسب المنجنيز،
بمتكون أم بجمة ،بمنطقة أم بجمة ،بغرب وسط سيناء،
بجمهورية مصر العربية :مقالة مرجعية
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أ.د /مصطف محمد مجاهد
أستاذ علم الصخور والجيوكيمياء ،بقسم الجيولوجيا،
بكلية العلوم ،بجامعة بنها ،بنها ،مصر