- a General Chem 144 Questions . 1 Give IUPAC e for the following : . o (ti ee (ii) [CoC] (H,0), (NH3)3}*2 ii) [Co(NH,)ICl, (iv) [Cr (en)3] ENi (CN)g] (%) Na [Ag (CN)y] (vi) [Co (H0)g] [ Co (CN),] (vii) Cu (acac), (viii) [Pt (NH), Cl NOy] SO, (ix) [CrCl (H,0) (en),] Cl, Q. 2 What is polydentate ligand ? Explain different types of polydentate ligands with illustrations, Q.3 In the coordination compound [Co(en)(dien)CIICly. (i) The coordination number of cobalt is (ii), The oxidation state of cobalt is (iii) The dentate character of different ligands are (iv) Tonic charge on comolex cation is (¥) The number of non-coordinated chlorine is [Similarly for [Co (NH3)¢JCI; or othor coordination compounds] Q. 4 What are polydentate ligands ? Give one example of each type. Q. 5 Give the systemetic formula for the following : @)_ Hexachloroplatinic (iv) acid (ii) Bromoaquotetraamine cobalt Gi) Bis (acetyl acetonato) copper (II) (iv) Dichloro argentate (1) ion. (vy) Hexamine chromium (IID) nitratre (Ans; (vi) Chloronitritotetramine platinum (i [Cr (NH3),]0NO;),) iv ) sulphate (Ans.) [Pt (NH3),NO,Cl] SO, (vii) Ammonium tetrathiocyanatodiammine chromate a (Ans.) NHy{Cr(NH,), (NCS),] Q. 6 Give IUPAC name for the following, Also Classify the above 2 rar anionic, cationic and ionic, P @ [Cr en)s}, (S04), )_[CoCl (1,0), (NH,),}*2 (it [cay CoE Fe Co cH] ‘Scanned with CamScannee-— asic Concept of Co-ordination Chemistry 145 (iv) (NH4)3 [Cr (NCS),] (9) [Co Br (0) (NH3),]*? (vi) [CoCl; (NH5)3] (vii) Na [SbCl (CgHs)] (viii) H [CoCl,] (x) [Co (H,0).] @) [Co(CN),] (xi) [(NH)s CrOH-Cr (NH3)s]Cls ‘Ans, : -hydroxobis (pentaamine) chromium (III) chloride (xii) [Co (NH3)4 (OH) (H0)] Br, Q.7. What are polydentate ligand ? How are they classify ? Explain different types of ligands giving examples. Q8 Give the name and structure for the following abbreviations. Also showing their potential coordinating atoms. Also clasify the above abbreviated ligands showing the coordinating atoms. (@ (dmg)y- Gi) nta ii) en (iv) (acac)- (v) dipy (vi) (ox)? (vii) pn (viii) iH-bn (ix) (oxin)- or (oxinate)- (9) (gly) (xi) o-phen (xii) diars or D (xiii) Big)- (xiv) dien (xy) tetramine (xvi) terpy (xvii) trien (xviii) (NTA) (ixi) (EDTA) or Y4 Q9 Just sketch the possible geometries of complexes having coordination number six or coordination No. 4. Q.10 Discuss in detail about geometry of complexes having coordination number six. QL. Give rules for the nomenclature of various coordination compounds. (or Q. 15.) QU12. Give rules for naming of the various kinds of ligands. 213. On the basis of the nature of complexes, classify complexes and give at least two illustrations of each. Also give IUPAC name of each illustration. oe Discuss the naming of ambidentate ligands. 1.15, Di. . plscuss the naming of the central metal ion and monomuclear complexes giving two ane illustration of each class. Also give IUPAC name of: ». 7 pias the naming of the negative ligand (or neutral ligands or positive ligands or nidging ligands of polynuclear complexes) GeneralChemistry/2016/18 a ‘Scanned with CamScannee146 General Chemistry Q.17. Find out simple cation and complex the following ionic complex compounds. Also (i) Ky [ptlY Clg] . ii) NH, [Cryq (SNC)4] (NH5)2 Gil) (Pe (py),4] [ptt Cly] (iv) [Colll (NHg)¢][Crl (C204)3] (¥) [pt (NH), Br] Bry (vi) [Fel (H,0)4] [(C204) $04] Q.18 Just sketch the possible geometries of complexes having coordination number (CN) 2,3, 4, 5 and 6, Also give name of each geometry and indicate its bond angle. Q.19 The shape of complexes having C.N. = 2 is and its bond angle is... Q.20 Classify the following complexes on the basis of coordination number. Also mention ‘anion (or complex cation and simple anion) from give their IUPAC name. their geometry, @) Cu(CN); Gi) Cu(NH5); (ii), Ag(CN), (iv) Hg(NH)}? (vy) H,0* ; (vi) [Ni (Co),]° (vii) FeCk. (viii) [Ni (dmg),P (x) [Pt(NH)4? (%) AuCl; (xi) [Mn (CO)s] (ix) [Cu Gipy), I] (xi) Fe (CO)s (xii) NiBrs ((C)Hs)3P]) (xiii) [Cu (NH), (H,0),]*? (xiv) [Vo (acac)] (xv) [Cu(en),]? (xvi) [CuC,]3 (xvii) [Cr (HyO)s Cl}*? (xiii) Au(CN); Q. 21 What are chelates ? Give, classification and uses of chelates, Q. 22 Discuss the classification of chelates on the basis of type of linkages present int Also give at least one illustration of each type of chelates, Q. 23 Define with illustratin : (a) chelation (b) chelate effect (c) coordinatioy a salt ign Be MN compound (d) Simple (©) molecular (addition) compound (f) Lattice compounds (doable St (g) Comple® ion (h) Ligand (i) Coordination number (i) Coordinating at (k) Coordnation sphere (First sphere of attra 6 stom ction) (1 Bridging complexes) (m) Chelate compound (metal ey Gee een complex : at ligand (p) Liganey (or C. N.) questration (0) Amt ‘Scanned with CamScannee-_ pasie Concept of Co-ordination Chemistry 447 Q. 24 Describe the uses of chelates. Q. 25 Discuss the importance of chelation in coordination compounds. Q.26 Give the formula of : Mobr's salt, potash alum, potassium ferrocyanide, potassuum ferricyanide. ; Q.27 Give the dissociation into of following salt into its ions when they dissolved in water. () Mohr's salt (i) potash alum aa (ii) potassuum ferrocyanidel Q.28 Give difference between : () —Double’salt (lattice compound) and coordination compound. Q.29 Which of the following ligands having vacant type orbitals ? @ #0 (ii) NH (ii) F (iv) CO (~) NO (vi) CN (vii) unsaturated organic compound. (viii) iso cyanides (ix) a—dipyridyl _(¢e) o-phenanthroline. Q.30 Which of the following ligands having bonding electrons. @ ethylene (ii) benzene (iii) a—dipyridyl (iv) o-phenanthroline (v) cyclopentadienyl ion. Q.31 Classify the following into coordination compound and molecular compound. (i) FeSO,(NH,),S0, 6H,0 (Mohr's salt) i) potash alum (ii) Ky [Fe (CN)g] (iv) Fe (CN), () KCN Q.32 How does hard water is effectively softened ? Q.33 Give the general names of complexing agent used to reduce the hardness of water, Q.34 What is sequestration ? hi 2.35 Match the following. - Column—A’ Column-B Column-A Column-B chelation Linear Bridge complex ‘one metal ion "0 | Covalent bond Cupferron Chelate compo. Two metal ion | Coordinate bond —acidie group EDTA hexadentate Refinement of melats Same metalion | C10,” Tetrahedral CN =2 Zr and Hf Coordinating group] Trifluoro acetylacetone ‘Scanned with CamScannee— General Chemistry 148 Q. 36 Fill up the blank : @__ In symetrical bidentate ligands, the two coordinating atoms are the .. ile in unsymetrical bidentate ligands, the two coordinating atoms are the. Gi) metal ion prersent in chelate compounds. Gi) The covatent bonds are formed by the . group. (iv) The coordinate bonds are formed by the group. (v) Chelate compounds having ........... central metal ion. (vi) polynuclear complex (bridged complex) have atleast .......... central metal ions, (¥) Coordination number of "en" is wi) .. organic solvent has been used for separation of Zr and Hf metals. .. has been used for the refinement of many metals by solvent extractrion, The compound having CN. 2 has ........ geometry and it possesses ..... ligand repulsion. (ix) The geometry of [Ni (dmg),]° complex is . @®) ee (NH); SO,]* and [Co!!! (en), 80,4] complexes are ‘exibit .. absorption bands of S-O vibrations. They also showing .. character of so,” ion. Q.37 Calculate charge on each of the following complex ion. () [MnlV Fg) 1x 4+6(-1)=2 ©. [MnF,)- (2) [Cell NH) (SO3)p} 1x 3+2x042€2)=-1 — * [Cr(NHg)2 (S031 (3) (Coll! (1,0); Cl] 1x 3+5()+1xCI)=2 + [Co(H,0),CI}* (4) [Cull (NH3)4] 1x2+4(0)=2 ++ [Cu(NH),)* (5) [PtVQNH;), Cl (NO))] 1x 444(0)+1C1+1C1=+2 [Pt (NHg) CuNO,)?* Q. 38 Write a note on structure, stability and applications of chelates, Q. 39 Choose the correct options for the following : (1) The bond that is formed between the metal ion of the transition element and neutt molecules or anions in complex compounds is called : (a) metallic bond “ (b) covalent bond () Ionic bond (@) coordiante bond, (2). According to Werner's theory a metal has ............types of valencies : (@) four (b) one (©) three @ two 3) Primary valency of a central metal ion in a complex is satisfied by : ‘Scanned with CamScanneejg concept of Co-ordination Chemistry” jas! a @) 0) (10) uy a) (12) (13) 149 wo Ligand (b) Free radical (¢) Anion Potassium ferricyanide is an example of : (a) Simple salt (d) cation (b) mganometallic compound (©) Double salt (@) complex salt. During the formation of complex compounds, ligands can act as : (a) Lewis acid (b) Arthenius acid © Arrbenius base (d) Lews base During the formation of complex compounds, metal can act as : (a) Lewis base (b) Arrhenius acid () Arthenius base (@ Lewis acid Identify Lewis base from K [Fe (CN)6] «1... (a) Kt (b) Fe*2 (©) Fe3 (@ CN- Identify Lewis acid from K, [Fe(CN),] . (a) Kt (b) Fe*3 (c) CN- (@) Fe*? Secondary valencies of metal are satistied by : (@) Anion (b) cation (c) free radical (d) Ligand The bond between transition metal ion and the ligands held by secondary valencies is called : (a) Ionic bond (b) Covalent bond . (c) metallic bond @ coordinate covalent bond. The ........ is shown by square bracket [ ] in the formula of the complex compound : (a) complex salt (b) complex compound (©) Double salt (@) complex ion A Complex having a ring structure formed between a polydentate ligand and metal ion is referred to as a: (@ Monodentate ligand (b) polydentate ligand (©) None of the.above (@)chelate The electrical charge of edta is : @ 2 (@-1 os 4 Complexes containing two or more different kinds of Hgands aN on (b) Tridentate ligand (@) polynuclear complex © Hexadentate ligand Complexes which contain two or more ©) Mixed ligand (@) Mixed - ligand central metal ions are called : (b) Tridentate ligand ‘Scanned with CamScanneeGeneral Chemistry 150 (0) Hexadentate ligand (d) polynuclear complex (15) Which of the following compound is not a coordintion compound ? (@)_K; [Ce (CN),] (b) Na Fe Cl, © Fe (H,0),Cl, (d) Fe SO, (NH4)2 SO (16) Which of the following geometries are-passible with coordination number 4. (a) Tetrahedral (b) Square planar (©) octahedral 7 (@ Both (a) and (b) (17) Identify the ligand from K,[Ni(en)4] (@) kK () Ni (©) CN- (d) None (18) The co-ordination number of cobalt in [Co(en)2 Cl] Cl is : @ 5 (b) 3 ©4 @6 (19) The valency of y in the complex [Ni (CN),)’ is : @ 0 (b) #2 ©4 @-2 (20) The oxidation state of iron in Ka[Fe(CN)g] is @) +1 (b) +2 (©) +4 @+3 (21) The IUPAC name of [Ni(CO)4] is : (a) Tetra carbonyl nicketate (11) (b) Tetra carbonyl nicketate (0) (©) Tetra carbonyl nicketate (1) (A) Tetra carbonyl nicket (0) (22) The number of halide ions in (Mn(NH)3 ClpBr] Cl is : @) 3 (4 ()2 @1 (23) The coordination number of Ma in [Mn(en);]Cl, is : @ 2 (b)4 (©)2 @6 (24) The coordination numbner of Cr in NH, [Cr(H0),Cl4] is ....... @ 3 (oe) 4 (c)2 6 (25) Which of the following represents a chelating ligand ? (@) H,0 (b) NH (©) OH- (@) edta (26) In which of teh following complex, nickel metal is in highest oxidation state ? (a) [Ni (CO),] (©) Ky ENIFe] ©) Ky ENi(CN)g] (a) [Ni (NHS )ICs (27) The correct name of the compound [Cu(NH)4](NO3), according to TUPAC system is (2) Cuprammonium nitrate (b) Tetrammine copper (III) dinitrate (0) Tetramine copper (UD) dinitrate (@) Tetraamine copper (Il) nitrate (28) Which of the following is non “ionizable ? (@) [Co (NH), Ch] Cl (b) None ‘Scanned with CamScannee eetasic @) (30) Gl) (32) (3) (4) (5) Concept of Co-ordination Chemistry (0) [Co (NH); Cl] Cl, @oai 151 Which is the central metal ion in Fe(H,0),3 +9 Hs) Cl, @ Fe (b) H,0 (c) None (d) Fe3+ All legands are : Ui (a) Lewis acid (b) Neutral a In K{Fe(CN)] the anion bonded by pinay any is: oa (@) [Fe(CN)g]* (b) 6CN- © [Fe(CN)g (a CN- The secondary valency of metal ion in a NH, [Cr (10), Cly]* ion is : (a)3 (b) -3 ©o, @6 Which of the following is a chelate ? ‘ (@) K3[Fe(CN)g] (b) K[Mn0,} (©) [Ag(NH3).]OH (@ [CrCl (en),] NO, The oxidation number of Fe in the complex [Fe(CO).] is : @A (b)2 @s5 (d) zero The correct name for the complex K3[Fe(C,0,),] is : (a) Patassium ferric oxalate BI (b) Potassium iron (II) trioxolate ab (©) Potassium trioxalato iron (III) (@) Potassium trioxalato ferrate (III) The correct name for the complex [Pt(NH3),C14] is" (a) Platinum diamminetetrachlorate (b) Tetrachlorodiammine platinate (III) i (©) Platinum tetrachloridediammine (4) Tetrachlorodiammine platinum (IV) n What is the oxidation number of Co in [Co(NH3),Cl0NO2)] ? (43 (b) +5 © i @er TUPAC name of Naj[Co(NO,)6] is : ©) Sodium cobaltnitrite ©) Sodium hexanitro cobalt (111) The oxidation number of platinan in [PUNHs)s (b) Sodium hexanitrito cobaltate (1) (d) Sodium hexanitrito cobaltate (III) Ci] Ch is: @2 (3 io c oF Coordination number of Ni in [Ni(C24)sl 6 (a3 4 @5 : : SO, Give the oxidation number of Fe in [Fe(NH3),CO«80« ‘Scanned with CamScannee152 (42) 43) (44) (45) (46) (47) (48) (49) (50) G) (52) 3) (54) ag General Chemisty (a) +1 (b) +3 (c) +4 @ +2 How many coordination sites are in ptn ? @1 (b)2 6 @3 Which of the following is hexadentate ligand ? @en (b) ptn (©) None (d) edta What is the charge of edta ? @-l (b) -2 ©-3 @4 What is the coordination number of C6?* in K2[CoCl3] complex compound. (@2 (b)4 ©)3 @6 What is oxidation number of Co in K3[Co(Cl)g] «. (@ +6 (b) #2 (© +4 (@) +3 Ptn is the type of ligand (a) Bi-dentate (b) Tridentate anion (c) Bi-dentate anion (d) Tridentate netural The name of the ring structure (cyclic) complex compound formed between metalion and poly dentate irgand is ........ (a) Natural complex (b) simple complex (c) Polynuclear complex @ chelate Which one of the following is the structural formula of potassion hexacyano ferrate @. (@) K; [Fe(CN),] (b) K3[Fe(CN), Cl,] (© Ky [Fe (CN)4] (@ Kg [Fe(CN),] What is secondary valency (co-ordination number) of Cr metal ion in the complex [Cr (en) Cl] NO; ?” @4 1 ©3 @6 Mention the charge on {Cr"! (CO), (CN)4] complex ion. (a) +2 @)+ 0 @-1 Mention the primary Valency (oxidation state) of Co in the complex [Co(NH3)s! Cl. anne @uv @)IV ©@o @m What is the oxidation state of Fe in [Fe(NO) (CN).}2- complex ion ? @) +6 + © zero @+3 What is the number of chlorine combined by secondary valency # [Fe(NH,)4Cly] Cl? ‘Scanned with CamScanneeasic Concept of Co-ordination Chemistry @1 (3 (58) Which of the following is not an exampi ©@o @2 ple Of negative bidentate ligand ? () oxalato : i @) ethylenedi in Which of the foll i sleeydiony (66) ‘ol’owing complex is potassium bis (oxalato) diammine cobaltate (IM) 7 (a) carbonato (© sulphato (a) K,[Co (NH), (Ox),] b) K (©) Ky{Co (NH), (Ox) ea (OC) (67) Which of the following ligands is a bidentate : aaemeel ae (©) Ammonia (¢) Acctate__() Ethylenediamine (58) Which of the following Tepresents IUPAC name of [Co(NH;),] Cl. (a) Cobalt (II) hexamine tetrachloride _(b) Cobalt hexamine chloride (¢) Hexamine cobalt chloride (4) Hexammine cobalt (II) chloride (59) The oxidation number of Pt in [Pt(NH3); Cl,]-is (a) +1 (b) +3 (©) +4 . @+2 (60) Coordination number and oxidation number of Cr in K3[Cr (C,0,)3] are respectively ? (@) 4 and +2 (b)3and+3 (3 and (@) 6 and +3 (61) Correct IUPAC name of K,; {Fe(CN)g] is : (a) Tetra potassium ferri cyanide (c) Potassium ferro cyanide (©) Oxidation Number of Cobalt in K[Co(CO),] is : On (b) +3 @3 @- (63) The name of the complex [Pt(NH3)6] Cly is (@) Hexammine platinum (11) chloride (b) Tetrachloro hexamine platinum (IV) (c) Tetrachloro hexammine platinate q@ (@) Hexamine platinum (IV) chloride (4) a is the veidation umber of Co in [Co(NH3)4 CHNO2)] ? onl (45 @4 (4) #2 (65) Chemical formula for iron (11) bet CN (@) Fe (CN)¢ (a Fey (CN 6) (©) Fe; [Fe(CN)g]4 - TUPAC name of Nag[Co(NOz)6] is (a) Sodium cobaltinitrite (©) sodium hexanitro cabatt (1) (b) Potassium hexacyanide (@ Potassium hexacynoferrate (11) Gone "2!Chemisty/2016/20 ‘Scanned with CamScannee—xy 184 Genoral Chemistry (c) sodium hexanitro cobaltate (111) (@) sodium hexanitrito cobaltate (II1) (67) The primary valency of iron in [Ky Fe(CN)g] is = (a1 (b) 3 4 @2 (68) Coordination number of Ni in [Ni(C,0,)3]-? (a)3 (b) 4 (c)5 6 (69) The primary valency of iron in K, [Fe(CN)g] is : (a) 5 (b) 3 (4 @2 (70) The oxidation number of cobalt in K[Co (CN)4] (@ #2 (b) 3 (@-1 (@) +3 (71) TUPAC name of K3 [Fe(CN)g] is : (a) Potassium hexacyanoferrate (II) (b) hexacyanoferrate (IID) (c) potassium ferricyanide (d) Potassium hexacyano ferrate (III) (72) The oxidation state of Fe in K,[Fe(CN)¢] is (a) 2 (b) +4 () +6 (d) #2 (73) The oxidation number of Cr in [Cr (NH), Cl,]* is : (a) #2 @)H (0 @+3 (74) Ammonia group in a coordination compound is named as (a) Ammonia (b) Ammonium — (c) Amine (a) Ammine (75) Identify monodentate ligand from the following ? (a) edta (b) en (©) pin (@) H,0 (76) A ligand which form a single coordinate covalent bond by donating one electron-pait to a metal ion is called a : (a) Bidentate ligand (b) Tridentate ligand (©) Polydentate ligand (@) monodentate ligand (77) What is the charge on pentacarbonyl iron (0) complex. (a) one (b) five (©) three (d) zero (78) Which of the following cannot behave as ligand ? (a) NH; (b) NOs” (©) H,CO (@ CO, (79) In complex compounds which type of bond is present 2 (@) Ionie bona (®) Covatent bond (© Metallic bond (d) coordinate covalent bond (80) Potassium ferricyandie is an example of : (a) Double salt (b) simpl (©) None of these ) simple salt (d) complex salt ‘Scanned with CamScanner- Basic Concept of Co-ordination Chemistry 155 el) Secondary valencies of metal are satisfied by : (2) Anion (b) cation (©) none of these (d) ligand (82) Oxalate ion is a type of ligand ........... (@) Monodentate (b) Tridentate (c) Hexadentate (d) Bidentate (83) Which is not a ligand from the following ? @cr () co;? (NH, @Ch (84) Identify monodentate ligand from the following. (a)en (b) ptn (©) edta (d) H,0 (85) Which is the simple salt ? (@) [Cu(NH,)4]*? () CHsNH, (c) None of abovel (d) NaCl : (86) Valency of “NO” ligand is ; | @t+1 )-1 @-2 (@ Neutral (61) Which one of the following is an example of an octahedral complex ? (a) INi(CN,)}* (b) [Zn(NH,)4}*2. (©) [CuNH,)4]*? (@) Fel? (88) Charge on Co ion in {Co(CNg I> is__. (@)-6 3 ©+6 (+3 (89) The number of unpaired electron in Ni(CO), is ——. @1 (b)3 @4 @o (90) Which of the following have square planner structure ? (@) [Ni(CO),]"2 (b) NiCl, (©) NiO), @ [Ni(CN),]*? (1) [EDTA] is a ___. (@) Monodentate ligand (b) Bidentate ligand (©) Quadridentate (@ Hexadentate ligand (2) From the given compounds, which one is the lattice compound ? (Nac! (0) NakSO, 6 eI K4lFe(CN)6] Ti a SO, 6H,0 ich one of the following is a bidentate (@) Aquo () Carbonyl (©) lodo (d) Carbonato 9 Btiyene diamine isa — lean (o) Tridentate (4) Bidentate 65) @) Monodentate 0) Polya jon compound central metal . According to Wemer’s theory ina co-ordination comp ion acquires ies ? ae valencies ? oe @3 (@2 NT ‘Scanned with CamScanneeGeneral Chemistry 156 (96) Ina co-ordination compound primary valency of a central metal ion is satisfied by : (a) Ligand (b) Cation (©) Radical @ Anion (97) Secondary valency of a metal ion in a co-ordination compound is satisfied by : (a) ion (b) Salt (c) Molecule (d) Ligand (98) Which of the following represents a chelating ligand ? (@) NH; (b) CH;NH, (c) N(CH3)2 @ edta, (99) Which of the following is a hexadentate ligand ? (a) en (b) ptn (©) acac (d) edta (100) What is the oxidation state of Fe ion in [Fe(NO)(CN)s}* (a0 (+1 (©) 42 (d) +3 (101) Mention the charge on complex [Cr!"(CO)s(CN)4] (ao (b) +2 @+1 @-l Q. 40 Answer the following’: (1) In the co-ordination compound [Co (en) (dien) Cl] Cl ANSWER Chloro ethylenediammine diethylenetriammine cobalt (ll) chloride 1 1 The oxidation state of cobalt is +3 2. The co-ordination number of cobalt is 6 3. The dentate character of different ligands are en-bidentate 4, Tonic charge on complex cation is — 5. The number of non co-ordinated chlorine is (2) In the co-ordination compound [Ag(NH;),]* Diammine silver (1) ion ; 1. The oxidation of argenium (silver) is 2. The co-orclination number of argenium (silver) is 3. The dentate character of ligands is —— 4. Tonic charge on complex is (3) In the co-ordination compound [Co(NO,); (NH3)3] Trinitro triammine cobalt (III) 1, The oxidation state of cobalt is 2. The co-ordination number of cobalt is —— 3 The dentate character of different ligands are Cl - monodentate dien - tridentate +2 2 +1 2 NH; monodentate sp] +3 6 NO,-monodentate ‘Scanned with CamScanneeasic Concept of Co-ordination Chemistry @ 4 Ionic charge on complex is —_ In the co-ordination compound [Tid,0) 613 Hexaaquo titanium (III) ion 1. The oxidation state of Titanium is —__ 2. The co-ordination number of Titanium is —_ 3. The dentate character of ligands is —__ 4, Tonic charge on complex is In the co-ordination compound [Cu(acac)s] Bis acetylacetato copper (II) 1, The oxidation state of cobalt is 2. The co-ordination number of cobalt is 3. The dentate character of different ligands are 4. Tonic charge on complex is In the co-ordination compound [Co (NH3),]Cl5, Hexaammine cobalt (III) chloride 1, The oxidation state of cobalt is 2 The co-ordination number of cobalt is 3 The dentate character of ligand is 4. Tonic chage on complex cation is 5. The number of non co-ordirlated chlorine is. In the co-ordination compound [Cr (en)3] [Ni(CN)¢] Tris {ethylenedigmmine} chromium (II) Hexacyano nickélate (II) 1. The oxidation state of chromium is ————— 2. The oxidation state of nickel is ——— 3. The co-ordination number of chromium is ~~ 4. 5. The co-ordination number of nickel is ———~ The dentate character of different ligands are ——— 6. Tonic charge on complex cation — i a Tonic charge on complex anion is C1NO,] SO4 © tothe co-ordination compound [Pt(NFs)4 ite Choro nitro tetraammine platinum (TV) supte 157 NH3-monodentate 0 +3 6 H,O-monodentate +23 +2 ee L Acac-monodentate 0 3) 6 NH,-monodentate +3 3 +3. +3 6 6 en-bidentate CN - monodenlate +3 3 I ‘Scanned with CamScannee158 1. The oxidation state of platinum is 2. The co-ordination number of platinum is 3. The dentate character of different ligands are ——— 4 Ionic charge on complex cation is 5. The number of non co-ordinated sulphate is In the co-ordination compound Na [Ag (CN),] Sodium dicyano argenate (1) The oxidation state of argenium (silver) is The co-ordination number of argenium (silver) is The dentate character of ligands is Ionic charge on complex anion is re Rene —eq General Chemistry +4 6 NH,-monodentate Cl-monodentate NO,-monodentate +2 1 +1 2 CN-monodentate -1 5 Ionic charge on simple cation Na is +1 (10) In the co-ordination compound [Co(H,0)¢] [Co(CN) ¢] Hexaaquo cobalt (III) Hexacyano cobaltate (III) 1, The oxidation state of cobalt in complex cation is ———— +3 2. The oxidation state of cobalt in complex anion is +3 3, The co-ordination number of cobalt in complex cation is 6 4 The co-ordination number of cobalt in complex anion is — 6 5 The dentate character of different ligands are ——_ 6 — Ionic charge on complex cation is ——— 7. Ionic charge on complex anion is ——— (11) In the co-ordination compound [Cr Cl (H,0) (en),]Cly Chloro aquo bis {ethylenediammine} chromium (Ill) chloride 1, The oxidation state of chromium is ——____ 2. The co-ordination number of chromium is —___ 3. The dentate character of different ligands are 4, Tonic charge on complex cation is —_____ (12) In the Tris co-ordination compound [Cr(en). al (S0,), Tris {ethylenediamine} chromium (U1) sulphate H,0-monodentate CN-monodentate +3 3 +3 6 Cl-monodentate H,0-monodentate en-bidentate +2 ‘Scanned with CamScanneeiS asic Concept of Co-ordination Chemistry The oxidation state of chromium is ——_____ The co-ordi nation number of chromium is The dentate character of ligands is Ionic charge on complex cation is Tonic charge on simple anion is 6 The number of non co - ordinated sulphate is (13) In the co-ordination compound [CoCl, (H,0), (NH3)9] Dichloro diammine diaquo cobalt ({I1) ion 1. The oxidation state of cobalt is 2. The co-ordination number of cobalt is 3. The dentate character of different ligands are WRene 4 Tonic charge on complex is (14) In the co-ordination compound (NH4)3 [Cr (NCS)] Ammonium hexaisothiocyanato chromate (III) 1. The oxidation state of chromium is 2 The co-ordination numoer of chromium is 3. The dentate character of different ligands are ——— 4. Ionic charge on simple cation is 5. Tonic charge on complex anion is (15) In the co-ordination compound [CoBr(H,0)(NH3)4 Bromo tetraammine aquo cobalt (111) ion 1. The oxidation state of cobalt is - 2. The co-ordination number of cobalt is ~~~ —~ 3. The dentate character of different ligands are le 4. Tonic charge on complex is ~~~ (16) tn the coordination compound [CoCl3 (NH3)3] Trichloro triammine cobalt (1) 1. The oxidation state of cobalt is s 2 The co-ordination number of cobalt is ——— i igands are ——— 3. The dentate character of different ligan a 4. Tonic charge on complex 'S Cig ()In the co-ordination compound Na(SbCls (Ces phenyl antimonale Sodium pentachloro +6 6 en-bidentate +6 -2 3 +3 6 Cl-monodentate H,0- onodentate NH; - monodentate 4 +3 6 NCS-monodentate +1 +3 +3 6 Br-monodentate H,O-monodentate NH3-monodentate +2 43 6 Cl-monodentate NH3-monodentate 0 ‘Scanned with CamScannee160 General Chemistry +4 6 Cl-monodentate C¢Hs-monodentate 1. The oxidation state of antimony is 2. The co-ordination number of antimony is 3. The dentate character of different ligands are 4. Ionic charge on simple cation is Hl 5. Tonic charge on complex auion is a (18) In the co-ordination compound H; [CoCIg] Hydrogen hexachloro cobaltate (III) OR Hexachloro cobaltic (III) acid 1. The oxidation state of cobalt is +3 2. The co-ordination number of cobalt is 6 3. The dentate character of ligands is Cl-monodentate 4, Tonic charge on simple cation is 41 5. Tonic charge on complex anion is 3 (19) In the co-ordination compound [Co(H,0)}*3 | Hexaaquo cobalt (Ill) ion 1, The oxidation state of cobalt is ————— +3 2 The co-ordination number of cobalt is 6 3. The dentate character of ligands is H,0-monodentate 4 Tonic charge on complex is mo | 20) In the co-ordination compound [Co (CN)? Hexacyano cobaltate (IM) ion 1. The oxidation state of cobalt is 3 2. The coordination number of cobalt is ————— 6 3. The dentate character of ligands is CN-monodentate 4. Tonic charge on complex is 3 (21) In the co-ordination compound [(NH3); Cr OH Cr (NH3)s] Cl, -Hydroxo bis {pentaammine chromium (IlI)}chloride 1. The oxidation state of chromium is ————— +3 2. The co-ordination number of chromium is ——— 6 3. The dented character of different ligands are ——— OH- monodentate NH; - monodentate 4, The bridge ligand in co-ordination compound is — OH-Hydroxo ‘Scanned with CamScanneegasie concept of Co-ordination Chomiety 5, Ionic charge on complex anion —_ * 6, Tonic charge on simple anion is —___ ‘ 7. The number of iron Co-ordinated chlorine is —_ F (2)In the co-ordination compound [Co(NHy), (O4) ( 0)) Bi , Hydroxo tetraammine aquo cobalt (Il) bromide ° ° 1, The oxidation state of cobalt is —__ 2 The co-ordination number of cobalt is ——__ ie 3 The dentate character of different ligands are OH- monodentate H,0- monodentate NH, ~ monodentate +2 -l 2 4. Tonic charge on complex cation is 5 Ionic charge on simple anton is 6. The number of non co-ordinated bromine is (23) In the co-ordination .compound (Co Br HO (NH3)4] (NOs), Bromo aquo tetramine cobalt (III) nitrate 1. The oxidation state of cobalt is ————— +3 2. The co-ordination number of cobalt is 6 3. The dentate character of different ligands are Br-monodentate H,O-monodentate NHy-monodentate 4 Tonic charge on complex cation is ——— 7 2 5 Ionic charge on simple anion is —__. ; 6. The number of non co - ordinated nitrate 1s ——~ (24) In the co-ordination compound [Cr(NH3)6] (NO3)3 Hexammine chromium (III) nitrate : 3 1. The oxidation state of chromium 1s ~~~ ; 2 The co-ordination number of chemin is ——_ ii nosras 3. The dentate character of ligands is iq 4. Ionic charge on complex cation i 4 5. onic charge on simple anion i — ; 6 The number of non co-ordinate mono) 1% "9a he co-ordination compound [Pt cl po ‘Scanned with CamScannee162 Chloro nitrito tetraammine platinum (IV) sulphate 1. The oxidation state of platinum is 2. The co-ordination number of platinum is 3. The dentate character of different ligands are 4 Ionic charge on complex cation is 5. Ionic charge on simple anion is - 6. The number of non co-ordinated sulphate is (26) In the co-ordination compound NH, [Cr (SCN), (NH3)9] Ammonium tetrathiocyanato diammine chromate (III) 1. The oxidation state oftchromium is 2. The co-ordination number of chromium is 3 The dentate character of different ligands are 4 Ionic charge on simple cation is ———___ 5 Ionic charge on complex anion is ———__ @7) In the co-ordination compound H [Pt Clg] Hexachloroplatinic (IV) acid 1, The oxidation state of Platinum is ——_ 2 The co-ordination number of Platinum is —__ 3. The dentate character of ligands is —__ 4, Tonic charge on simple cation ig ——_. 5. Ionic charge on complex anion is ——— (28) In the co-ordination compound [AgCl3]~ Dichloro argentate (1) ion 1, The oxidation state of argenium (silver) is —___ 2. The co-ordination number of argenium (silver) is —__ 3. The dentate character of ligands is —___ 4 Ionic charge on complex is —— Q.41 Answer the following ; 1, Give the rules for nomenclature of vari 2. Thes hape of the complexes having CN. 3. Discuss the importance of chelation 4 Give the formula of Mohr’salt, Potash alum, ferricyanide. 5 Give the dissociation into ions =2is when i G Gi) Potash slum (i) ae ae dissolved ji +4 Cl- monodentate ONO- monodentate NH; - monodentate +2 2 1 +3 6 SCN- monodentate NH - monodentate +1 -l +4 6 Cl-monodentate +1 2 +1 2 Cl-monodentate a lous co-ordination compounds. 2 —— and its bond angle is —_— In co-ordination compounds. ‘Scanned with CamScannee j