Chemical Kinetics JEE Main 2020 Chapterwise Hints & Solutions Chemistry a Rate = k[A]*[B)? 6 x 10? = k(0.1)"(0.1)? 2.4 x 10-® = k(0.1)9(0.2) 1.2 x 10-9 = k(0.2)"(0.1)” Solving eq (1),(2) and (3), we get a=1,b=2 6 x 107? = k(0.1)!(0.1)? fromk = 6 7.2 x 10? = 6(e)!(0.2)? > « = 0: 2.88 x 10°? = 6(0.3)'(y)? + y = 0.4 a2 Zero order reaction has complex mechanism. Zero order reaction is a multistep reaction. Q3 2A +3B + $C — 3P Tore ey adie adhe dng _ 2 dno _ A dn “@ 3a 3 db 04 Time for completion of 75% of a I®* order reacti Half life, t: = 4 x ta = % = 45min Rate constant, K = 9883 min“! 15 Time for completion of 60% of the reaction, toon = 2303 jog 10 60% = K eg a 03 x 45 = Fa lt 0.6) ~ 60 ‘#MathBoleTohMathonGo wera mathongo.comChemical Kinetics JEE Main 2020 Chapterwise Hints & Solutions Chemistry Qs A=B+O Ky) O+@ A=P Keq( overall )= KO K®) 1 1 R (300 ~ Hs, By = Rothe s14xs00515 15 = 84297.48J/mol [given Ay = em) a8 K = Aett mK =mA~— ‘#MathBoleTohMathonGo wera mathongo.comChemical Kinetics JEE Main 2020 Chapterwise Hints & Solutions Chemistry InK =nA— ar > ~=2x10 = E, = 2RkJ/mol 99 Rate = k{A]® log{Rate] = log k + nlog[A] slope = n [nis order of the reaction] ". Correct sequence for the order of the reaction is, d>b>a>c a0 k = Aer Assuming A and E,, to be independent of temperature nh =5 R 113.555 = o 168 ns = 9980.7 = 09.983 mol an 100 tox _ "ay fnl0 t50% &n2 «0.693 93 0% = 0.693 * £n10 = 10én10 = 23.03 Years a2 ‘#MathBoleTohMathonGo wera mathongo.comChemical Kinetics Hints & Solutions 2H2(g) + 2NO(g) + No(g) + 2H20(9) _ Ay _ [Na][nOP? ke [fh] [No}? Given for forward reaction , rate = k¢|NO]” [#2] For reverse reaction rate = ky[N2][H20]° /[H2] Qi3 K = Ae P/RT 10° = Ae PRP equation 2 equation 1 or 61n10 = (E- E,) /RT or (E- Ee) ET or E~ E, = 2.303 x 6RT or AE, = E. — E = —2.303 x 6RT 40° = elE-Ba/R = 2.303 x 6 Qa log k = log A — oe slope = yang > E.> Ea > E> Bs Qs ‘#MathBoleTohMathonGo wera mathongo.com JEE Main 2020 Chapterwise ChemistryChemical Kinetics Hints & Solutions Ea, = Ea, — 30 Ea, ~ 700 5Bay = 7Eaz ~ 210 Ea = = = 105 kJ/mole Activation energy of the catalysed reaction = 105 — 30 = 75 kJ/mol a Ba Arica 40) ~ 83 * 400 x 300 In(3/2) x 8.3 x 1200 = E, => BE, = 04x 8.3 x 1200 = By = 3984 J/mol. => By = 3.984 kJ/mol. ‘#MathBoleTohMathonGo wera mathongo.com JEE Main 2020 Chapterwise Chemistry