Electrochemistry JEE Main 2020 Chapterwise Hints & Solutions Chemistry qr Cu(s) + Sn?*(aq) + Cu* (aq) + Sn(s) 0 0 0 Beat = Esge+/sn — Ecut ou 0.16 — 0.34 = ~0.50V BFE a —2 x 96500(—0.50) 96500J AG° Q2 2Cn* (aq) = Cu(s) + Cu?* (aq) 0 _ BO = = 0.16V; ED, 9, = 0.52V BE = 0.52 = 0.16 = 0.36V 0 _ Fo ‘Cut /Cu “eu?* Cut a3 In general, ionic mot increases with the increase in temperature. Conductance (NaCl) > Conductance (BaSO,) sparing soluble salt a4 Pt |Hp(1bar)| HCl(pH = 1)|AgCll|Ag TH + AgCl + H* + Ag+ Cl Bay = Bly — tog") [Or] = 0.22 — 0.06 log 10°? = 0.34V Work function of Na metal = 2.3eV_ KE of photoelectron = 0.34eV Energy of incident radiation = 2.3 + 0.34 = 2.64eV Also energy of incident radiation for K metal = 2.64eV ‘#MathBoleTohMathonGo wera mathongo.comElectrochemistry JEE Main 2020 Chapterwise Hints & Solutions Chemistry Work function of K metal = 2.25eV. KE of photoelectrons = 2.64 — 2.25 = 0.39eV Een = 0.39V = 0.22 — 0.06 log [H*]* = 0.22 40.12 x pH pH ~ 1.42 = 142 x 10°? Qs Cr,07” + 14H* + 6e~ > 2Cr** + 7H2O I= 2A,t=8min Q = Best p 960 a4 | 5000 2 Moles of Cr20?- ions reduced = ott = hy Moles of Cr** ions obtained = 4°? 2x52 _ 104 or = G00 Mass of Cr°* jons actually obtained = 0.104gm Mass of Cr** ions obtained = Efficiency = Sx010100 _ g0% 06 0 _ po 0 cett = Boye pou > Ean ‘/tn = 0.34 — (0.76) =1.10V if Bert < 1.1V then Zn dissolves at anode and copper deposits if Boxy > 1.1V then Zn deposited at zinc electrodes and copper dissolves q7 Millimoles of Au~ Mole of Au+ Charge passed 0.1 x 250 = 25 4 T0009 ~ 70 Txt moles of e~ passed = x 15 x 60 = 900C 900 _ 9 e500 ~ 965 Only gold will be deposited as quantity of charge passed is less than the amount of Au” present. ‘#MathBoleTohMathonGo wera mathongo.comElectrochemistry JEE Main 2020 Chapterwise Hints & Solutions Chemistry 8 AG AG’ = Een = Qo The electrolyte (X) must be weak electrolyte. So x is CHy COOH Q10 For the concentration cell, Cu? — Cu po (CoM) (CM) 9 Era = Eo, — Sin =Fng Gibb’s energy is negative only when Ee, is positive. So, |C2 > Cy, C2 = V2C; Is correct, qu 2 x 0.34 = Ep +1 x 0.522 Ej = 0.68 — 0.522 Ej = 0.158 a2 Theory Based ‘#MathBoleTohMathonGo wera mathongo.comElectrochemistry JEE Main 2020 Chapterwise Hints & Solutions Chemistry ais 0.0591 B= -1.23— 7 log [H*]* .23 + 0.0591 x pH = —1.23 + 0.0591 x 5 23 + 0.2955 = —0.9345 V = —0.93 V Final ans = —100 x —0.93 = 93V aa At Equilibrium state. Bou = 0; E°ccu = 0.01V Sn+ Pv + Sn? + Pb sn 0-001 - 2% gg) su 0 = 298 jog) Be 2.1544 ‘#MathBoleTohMathonGo wera mathongo.comElectrochemistry Hints & Solutions 108 (7.40) sepooit = 798 Ag? +7 + Ag 1 F charge is required to deposit 1 mole of Ag —1mole 1 HO + 502+ 2H* + 20 1 2F charge deposit > >mole 1 1 F charge will deposit > mole RT Vo, = — 1, 0.08814 x 273 _ 1 gy 4 1 4 vo, = 5.675 L ‘#MathBoleTohMathonGo wera mathongo.com JEE Main 2020 Chapterwise Chemistry