Assignment KS

AEP
1. The product formed when ethyl chloride reacts with dry Ag2O
1) Ethene 2) Ethyne
3) Etheneoxide 4) Diethyl ether
2. Incorrect statement is
1) Ethers are inert toward most of the reagents, due to this they act as solvent in organic
synthesis.
2) Ethers have much lower boiling points than alcohols of similar molecular mass.
3) p-nitro phenol is more acidic than o-nitrophenol
4) p-nitro phenol is more volatile than o-nitrophenol
3. Phenol is also known as
1) Carbonic acid 2) Carbolic acid 3) Wood spirit 4) Marsh gas
4.

1) 2)

3) 4)

5. Which alcohol is obtained when 2 -methoxy-2-methyl propane reacts with one

equivalent of concentrated HBr?

1) methanol 2) isopropyl alcohol 3) ter-butyl alcohol 4) iso-butyl alcohol

6. Major product formed is

1) 2) 3) 4)
7. Choose the correct acidic order for the compounds

1) 2)

3) 4)

8. The number of moles of HI consumed if 1 mole of anisole reacts with excess of HI

1) 0 2) 1 3) 2 4) 3

9. Diethyl ether and methyl propyl ether are

1) Chain isomers 2) Position isomers 3) metamers 4) Tautomers

C H O  Na  ( excess )
 2 
5
   
C2 H 5OH ( anhydrous )
10.
Predict the major product formed in the above reaction

1) 2) 3) 4) C2H5OC2H5

11. Products A & B respectively are

1) 2)

3) 4)

12. the product ‘B’ is

 1) 2)

3) 4)

13. Most acidic one is

1) 2) 3) 4)

14. The byproduct formed when (cumene hydroperoxide) treated with

dilute acid is

1) Ethanol 2) Acetaldehyde 3) Acetone 4) Dimethyl ether

15. The compounds A & B are respectively

1) 2)
 3) 4)
16. Electrophile in Reimer-Tiemann reaction is
1) Trychloro carbanion 2) Dichloro carbine
3) Tetrachloro carbon 4) All of these
17.

1) 2)

3) 4) Cleavage of ether does not takes place

18. The best method to prepare is

1) 2)

3) 4)

19. Phenol reacts with

1) Na-metal 2) NaNH2 3) NaOH 4) all the above

20. Which has maximum boiling point?

1) 2) 3) 4)

21. The major product formed in the following reaction is

 1) o-cresol 2) m-cresol 3) p-cresol 4) Anisole
22. White precipitate among the following is
1) Picric acid 2) 2, 4, 6- tribromo phenol
3) Phenol 4) Anisole
23. Convertion of Phenol to benzene is achieved by
1) Li-metal 2) Na-metal
3) Ag-powder 4) Zn-dust
24. Which gives tribromo derivative upon reaction with 3eq of in
1) o-cresol 2) m-cresol 3) p-cresol 4) All of these

25. Electrophile in Kolbe’s reaction is

1) 2) 3) 4)
26. Which of the following reaction wouldn’t yield anisole?
1) 2)

3) 4)

27. Which of the following ethers can be prepared by williamson’s synthesis

1) 2)

3) 4)
28. The product formed when ethyl alcohol reacts with concentrated at

1) Ethene 2) Diethyl ether

3) Etheneoxide 4) 1,4-dioxane

29. Characteristic colouration with neutral FeCl3 solution is given by

1) Phenol 2) Anisole 3) Toluene 4) Diphenyl ether

30. Phenol and anisole can be distinguish by

1) Neutral test
2) 10% aqueous
3) Anhydrous and concentrated HCl
4) All the above
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