The document discusses the 14 Bravais lattices that describe the 3-dimensional crystal systems, noting that in 3D there are 14 crystal systems compared to 5 in 2D, with the 3D systems having 32 point group symmetries and 230 space groups compared to the 2D systems' 10 point groups and 17 plane groups. It also provides brief descriptions of the 7 crystal classes in 3D and defines the 4 types of Bravais lattices.
The document discusses the 14 Bravais lattices that describe the 3-dimensional crystal systems, noting that in 3D there are 14 crystal systems compared to 5 in 2D, with the 3D systems having 32 point group symmetries and 230 space groups compared to the 2D systems' 10 point groups and 17 plane groups. It also provides brief descriptions of the 7 crystal classes in 3D and defines the 4 types of Bravais lattices.
The document discusses the 14 Bravais lattices that describe the 3-dimensional crystal systems, noting that in 3D there are 14 crystal systems compared to 5 in 2D, with the 3D systems having 32 point group symmetries and 230 space groups compared to the 2D systems' 10 point groups and 17 plane groups. It also provides brief descriptions of the 7 crystal classes in 3D and defines the 4 types of Bravais lattices.
Department of MSE, KUET BRAVAIS LATTICES AND CRYSTAL SYSTEMS In 3D the symmetry elements required are: 1) Point symmetry elements 2) Translational symmetry elements (like glide lines in 2 dimensional case) These are the same elements as 2D. For 3 dimensional case some additional symmetry elements are required: Additional point symmetry elements: Centers of symmetry Mirror planes (instead of lines) Inversion axes Additional translational elements: Glide planes Screw axes
In 2D there were: In 3D there are:
5 Crystal systems 14 Crystal systems
10 Point group Symmetries 32 Point Group Symmetries!
17 Plane groups 230 Space Groups!!!
7 3-DIMENTIONAL CRYSTAL CLASSES
No rotation axes for which
lattice is invariant.
180 degree rotation possible
when two angles are equal to 90 degrees.
60 degree rotation axis along the c
direction 120 degree rotation along body diagonal leaves the crystal invariant.
Three 180 degree rotational axes going through the
centers of each faces.
Single rotational axis of 90 degrees going through the
centers of the opposite square faces and a 180 degrees rotation angles through the center of the opposite non- square faces. 90 degree rotation around any axis normal to one of the face and going through center of the face. 120 degree rotational symmetry along body diagonals. 180 degree rotational symmetry along any axis going through the centers of the edges. It has mirror symmetry also. 14 BRAVAIS LATTICES The systematic work of describing and enumerating the space lattices was done initially by Frankenheim, who in 1835 proposed that there are 15 space lattices. Unfortunately, two of his lattices were identical, a fact first pointed out by Bravais in 1848. It was, to take a two-dimensional analogy, as if Frankenheim had failed to notice that the rhombic or diamond and the rectangular centred plane lattices were identical! Hence, to this day, the fourteen space lattices are usually, and perhaps unfairly, called Bravais lattices!! 14 BRAVAIS LATTICES P= Primitive I= Body centered (Innenzentriarte) F= Face centered C= Base centeres (Faces are intersected by c-axis) REFERENCES
1) Hammond C., The basics of crystallography and diffraction, chapter 3
2) Graef and McHenry, Structure of Materials: An Introduction to Crystallography, Diffraction, and Symmetry, chapter 3.