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Hybridization Practice Questions by RK Sir
Hybridization Practice Questions by RK Sir
Hybridization Practice Questions by RK Sir
(c) (d) sp
26. In XeF 4 hybridization is
16. Octahedral molecular shape exists in ..........
hybridisation (a) sp 3 d 2 (b) sp 3
[DPMT 1990] (c) sp 3 d (d) sp 2 d
3 3 2
(a) sp d (b) sp d 27. In HCHO , ' C' has hybridization [AIIMS 1987]
20. For which of the following hybridisation the bond while CO 2 has not. Point out the structures which
angle is maximum [CBSE PMT 1991] best illustrate these facts [DPMT 1984; NCERT 1983; CPMT 1984]
(a) (b) sp O
(a) (b) O C O ; H O H
3 O C O; H H
(c) sp (d) dsp 2
(c) C (d) O H
21. The C H bond distance is the longest in[MNR 1990] ;H–H– || |
(a) C 2 H 2 (b) C 2 H 4 O O O C O ; O H
75. Which of the following is isoelectronic as well as 85. In sp hybridisation, shape is [Bihar MEE 1997]
has same structure as that of N 2 O [CPMT 1999] (a) Angular (b) Tetrahedral
(a) N 3 H (b) H 2 O (c) Bipyramidal (d) Linear
77. Compound having planar symmetry is [DPMT 1996] (a) Decreases gradually (b) Increases gradually
(a) H 2 SO 4 (b) H 2 O (c) Decreases considerably (d) All of these
(c) HNO 3 (d) CCl 4 87. The structure and hybridisation of Si(CH 3 )4 is
78. Which of the following compounds is not linear [CBSE PMT 1996]
[CPMT 1996] (a) Bent, sp (b) Trigonal,
(a) SnCl 2 (b) HCl
(c) Octahedral, sp 3 d (d) Tetrahedral, sp 3
(c) CO 2 (d) HgCl 2
88. The type of hybridisation of boron in diborane is
116 Chemical Bonding
[BHU 1999] (a) 1.15, 1.22 and 1.10 Å (b) 1.22, 1.15 and 1.10 Å
2
(a) sp - hybridisation (b) sp - hybridisation (c) 1.10, 1.15 and 1.22 Å (d) 1.15, 1.10 and 1.22 Å
3 3 2 99. Shape of BF3 molecule is [CPMT 2000; Pb. CET
(c) sp - hybridisation (d) sp d - hybridisation
89. Which compound does not possess linear 2002]
geometry (a) Linear (b) Planar
[RPET 1999] (c) Tetrahedral (d) Square pyramidal
(a) CH 2 CH 2 (b) HC CH
100. In the complex [SbF 5 ] 2 , sp 3 d hybridization is
(c) BeCl 2 (d) CO 2 present. Geometry of the complex is[Pb. PMT 2000]
90. Which of the following molecule does not show (a) Square (b) Square pyramidal
tetrahedral shape [RPET 1999] (c) Square bipyramidal (d) Tetrahedral
(a) CCl 4 (b) SiCl 4 101. The bond angle is minimum in
[Pb. PMT 2001; MP PET 2003; UPSEAT 2004]
(c) SF 4 (d) CF4
(a) H 2 Te (b) H 2 Se
91. Pyramidal shape would be of [RPET 1999]
(c) H 2 O (d) H 2 S
(a) NO 3 (b) H 2 O
102. The correct order of hybridization of the central
(c) H 3 O (d) NH 4 atom in the following species NH 3 [PtCl 4 ]2 , PCl5
92. What is the correct mode of hybridization of the and BCl 3 is
central atom in the following compounds : [IIT Screening 2001; BHU 2005]
NO 2 , SF 4 , PF6 (a) dsp 2 , dsp 3 , sp 2 and sp 3 (b) sp 3 , dsp 2 , dsp 3 , sp 2
[AMU 1999] (c) dsp 2 , sp 2 , sp 3 , dsp 3 (d) dsp 2 , sp 3 , sp 2 , dsp 3
2 3 2 3 3 3 2 3 2
(a) sp , sp , d sp (b) sp , sp d , sp d 103. Which of the following pairs has same structure[BHU 2001]
3
(c) sp, sp d , sp d 3 2
(d) sp, sp , sp 2 3 (a) PH 3 and BCl 3 (b) and NH 3
93. The hybridization in PF3 is [DCE 2000] (c) PCl5 and SF6 (d) NH 4 and SO 42
(a) sp 3 (b) sp 2 104. The smallest bond angle is found in [AIIMS 2001]
(a) IF7 (b) CH 4
(c) dsp 3 (d) d 2 sp 3
(c) BeF 2 (d) BF3
94. Which of the following molecule is linear[MP PMT 2000]
105. Which of the following is not linear [DCE 2001]
(a) (b) NO 2
(a) CO 2 (b) ClO 2
(c) NO 2 (d) SCl 2 (c) I 3 (d) None of these
3 2
95. The geometry of the molecule with sp d
106. Which of the following is not tetrahedral[MP PMT 2001]
hybridised central atom is [NCERT 1981; AFMC 1982; RPMT 2000]
(a) SCl 4 (b) SO 42
(a) Square planar (b) Trigonal bipyramidal
(c) Ni(CO)4 (d) NiCl 42
(c) Octahedral (d) Square pyramidal
107. As the s-character of hybridisation orbital
96. The bond angle in PH 3 is [RPMT 2000]
increases, the bond angle [BHU 2002; RPMT 2002]
(a) Much less than NH 3 (a) Increases (b) Decreases
(b) Equal to that of NH 3 (c) Becomes zero (d) Does not change
108. The shape of IF7 molecule is
(c) Much greater than NH 3
[AFMC 2002; MHCET 2003]
(d) Slightly greater than NH 3 (a) Octahedral (b) Pentagonal
97. Which of the following has tetrahedral structure bipyramidal
[CPMT 2000] (c) Trigonal bipyramidal (d) Tetrahedral
131. The states of hybridazation of boron and oxygen (a) PCl3 (b) SO 3
atoms in boric acid (H 3 BO 3 ) are respectively [AIEEE 2004] (c) CO 32 (d) NO 3
(a) sp 3 and sp 2 (b) sp 2 and sp 3 140. The hybrdization of IF7 is [Pb. CET 2001]
2 2 3 3
(c) sp and sp (d) sp and sp (a) sp 3 d 3 (b) sp 2 d
132. The hybridisation in BF3 molecule is [Pb. PMT 2004]
(c) d 2 sp 3 (d) sp 3
(a) sp (b) sp 2
141. In which compound, the hydrogen bonding is the
(c) sp 3 (d) sp 3 d strongest in its liquid phase [Pb. CET 2001]
133. Among the compounds, BF3 , NCl 3 , H 2 S , SF4 and (a) HF (b) HI
BeCl 2 , identify the ones in which the central atom (c) CH 4 (d) PH 3
has the same type of hybridisation 142. Geometry
[Kerala of
PMT ammonia
2004] molecule and the
(a) BF3 and NCl 3 (b) H 2 S and BeCl 2 hybridization of nitrogen involved in it are[MH CET 2004]
(a) sp 3 -hybridization and tetrahedral geometry
(c) BF3 , NCl 3 and H 2 S (d) SF4 and BeCl 2
(b) sp 3 -hybridization and distorted tetrahedral
(e) NCl 3 and H 2 S
geometry
134. The molecule of CO 2 has 180° bond angle. It can (c) sp 2 -hybridization and triangular geometry
be explanid on the basis of [AFMC 2004]of these
(d) None
3 2 143. Be in BeCl 2 undergoes [MH CET 2004]
(a) sp hybridisation (b) sp hybridisation
(a) Diagonal hybridization
(c) sp hybridisation (d) d 2 sp 3 hybridisation
(b) Trigonal hybridization
135. sp 3 hybridisation is found in (c) Tetrahedral hybridization
[Pb. CET 2003; Orissa JEE 2005] (d) No hybridization
(a) CO 32 (b) BF3 144. Which of the following is non-linear molecule[DCE 2003]
(a) CO 3 (b) CO 2
(c) NO 3 (d)
(c) CS 2 (d) BeCl 2
136. Which set hydridisation is correct for the
145. The trigonal bipyramidal geometry results from
following compounds [Pb. CET 2003]
the hybridisation [UPSEAT 2004]
NO 2 , SF4 PF6 (a) dsp 3 or sp 3 d (b) dsp 2 or sp 2 d
(c) sp 3 d 2 hybrid (d) sp 2 hybrid (a) 9 sigma bonds, 1 pi bond and 2 lone pairs
149. The linear structure is assumed by [IIT 1991] (b) 8 sigma bonds, 2 pi bonds and 2 lone pairs
(c) 10 sigma bonds, 1 pi bond and 1 lone pair
(a) SnCl 2 (b) NCO
Resonance CO 32 is
[MP PMT 2000]
1. Which one in the following is not the resonance (a) 2 (b) 3
structure of (c) 6 (d) 9
(a) O C O (b)
O C O 10. Resonance hybrid of nitrate ion is [RPET 2000]
1/ 2
(c)
O C O
(d) O C O (a) O ........N ........O 1/ 2 (b) 2 / 3
O ........N ........O 2 / 3
2. Which of the following molecule contains one pair
of non-bonding electrons O 1/ 2 O 2 / 3
(a) CH 4 (b) NH 3 1/ 3
(c) O ........N ........O 1/3 (d) 2 / 3
O...... N ......
O 2 / 3
(c) H 2 O (d) HF
3. Resonance is due to[NCERT 1981; Kurukshetra CEE 1998] O 1/3 O 2 / 3
(a) Delocalization of sigma electrons 11. CO 32 anion has which of the following
(b) Delocalization of pi electrons characteristics
(c) Migration of H atoms [Roorkee 1999]
(d) Migration of protons (a) Bonds of unequal length
4. Resonating structures have different [AMU 1983] (b) sp 2 hybridization of C atom
(a) Atomic arrangements (b)Electronic arrangements (c) Resonance stabilization
(c) Functional groups (d) Alkyl groups (d) Same bond angles