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Thermodynamics & Thermochemistry

#BOUNCEBACK
Sakshi Vora
IIT Roorkee

❏ 7+ years Teaching experience

❏ 10th, 12th CBSE State Topper

❏ KVPY fellow
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Introduction
Intensive &
extensive
property
Types of
processes
Heat capacity
Internal Energy
Zeroth law of
thermodynamics
first law of
thermodynamics
Calculation of
work
[Main Sep. 04, 2020 (II)]
A. CV (T2 - T1)

B. -RT (V2 - V1)

C. -RT in V1/V1

D. Zero
[Main Jan. 08, 2020 (I)]
Calculation of
heat
[Main Jan. 08, 2020 (II)]
A. Cyclic process : q = -w [Main April 8, 2019 (I)]

B. Adiabatic process : ΔU = -w

C. Isochoric process : ΔU = q

D. Isothermal process : q = - w
A. [Main April 8, 2019 (II)]

B.

C.

D.
Calculation of
enthalpy
Relation
between
enthalpy and
internal energy
A. C.
[Main Jan. 12, 2019
(I)]

B. D.
A. -4 RT

B. -3 RT [Main April 10, 2019 (II)]

C. 4RT

D. 3 RT
A. 4152.6
[Main 2018]
B. -452.46

C. 3260

D. -3267.6
A.

B.
[Main April 15, 2018 (I)]
C.

D.
A. ΔH = ΔU ≠ O

B. ΔH = ΔU = O
[Main April 8, 2017]
C. |ΔH| < |ΔU|

D. |ΔH| > |ΔU|


[Main Sep. 02, 2020 (I)]
Adiabatic
process
[Adv. 2020]

A.

B.

C.

D.
[Adv. 2018]

A.

B.

C.

D.
Entropy
Second law of
thermodynamics
[Main Jan. 09, 2020 (II)]
A.

B.

C.

D.
Third law of
thermodynamics
A. Dissociation of CaSO4(S) to CaO(s) and SO2(g)

B. Sublimation of dry ice


[Main Jan. 10, 2019 (II)]
C. Dissolution of iodine in water

D. Synthesis of ammonia from N2 and H2


A. C(diamond) ⟶ C(graphite)

B. N2(g. 1atm) ⟶ N2 (g.5atm)


[Main April 16, 2018]
C. N2 (g.273 K) ⟶ N2 (g, 300K)

D. H2(g) ⟶ 2H(g)
[Adv. 2020]
Gibbs free
energy
[Main April 9, 2019 (I)]

A. (B) and (C)

B. (B) , (C) and (D)

C. (A) and (D)

D. (A) , (B) and (C)


[Main Seo. 05, 2020 (II)]
Thermochemistry
[Main Sep. 04, 2020 (I)]
A. (1) And (3)

B. (2), (3) and (4)

C. (3) and (4)

D. (1) , (3) and (4)


[Main Sep. 04, 2020 (I)]

A. A-D has the shortest bond length

B. A-A has the largest bond enthalpy

C. D is more electronegative than other atoms

D. A-B has the stiffest bond


A.
[Adv. 2019]

B.

C.

D.
[Main Sep. 02, 2020 (II)]
[Main Jan. 07, 2020 (II)]
A. -780 kJ mol-1

B. 780 kJ mol-1
[Main Sep. 05, 2020 (II)]
C. -784 kJ mol-1

D. 784 kJ mol-1
A. is x = y

B. does not exist


[Main Jan. 09, 2020 (I)]
C. is x > y

D. is x < y
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