pHASE 04 09 2022 p2 S

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
ADVANCED PAPER
Time Allotted: 3 Hours Maximum Marks: 201
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
BATCHES –22-24
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1.Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2.This question paper contains Three Sections.
3.Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4.Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for
rough work.
5.Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any
form, are not allowed.
B. Filling of OMR Sheet

1.Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2.On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of
your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3.OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts given before Question.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________

JEE ADV PAPER -2
Useful Data Chemistry:

Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55,
Pb=207,
Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
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JEE ADV PAPER -3
PART – I: Mathematics
SECTION 1 (Maximum Marks: 18)
 This section contains SIX ( 06) questions.

 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories:
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : 1 In all other cases.
Q1. The area of the square formed by the lines |y| =1 - x and |y| = x +1 equals to
1 1
(A) sq. unit (B) sq. unit
6 12
(C) 2 sq. unit (D) 1 sq. units
Q2. If sinx + cosx + tanx + cot x + secx + cosecx = 7 and sin2x = a – b 7 , then ordered pair (a, b) can be,
(A) (6, 2) (B) (8, 3)
(C) (22, 8) (D) (11, 4)
Q3. If tanx – tan2x = 1, then the value of tan4x – 2tan3x – tan2x + 2tanx + 1 is
(A) 1 (B) 2
(C) 3 (D) 4
Q4. The value of cot236 cot272 is

(A) 1/2 (B) 1/3
(C) 1/4 (D) 1/5
Q5. |x2 – 1| + (x – 1)2 + x 2  3 x  2 = 0, then

(A) x = 1 (B) x = 1, 2
(C) x = 0 (D) none
Q6. The equations of three sides of a triangle are x = 5, y – 2 = 0 and x + y = 9. The coordinates of the
circumcentre of the triangle is….
(A) ( 6, 3) (B) (6, -3)
(C) ( -6, 3) (D) none
JEE ADV PAPER -4
 This section contains FOUR ( 04) questions.

 Each questions has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is(are) correct.
 Four each question, darken the bubble(s) corresponding to all the correct option(s) in
the ORS.
Full Marks : +4 If only the bubble(s) corresponding to all the correct
option(s) is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each
correct option, provided NO incorrect option is
darkened.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all
these three will result in +4 marks; darkening only (A) and (D) will result in +2 marks;
and darkening (A) and (B) will result in 2 marks, as a wrong option is also darkened.
sin  sin  
Q7. If tan   then, tan equals to
cos   cos  2
   
(A) cot tan (B) tan tan
2 2 2 2
   
(C)  tan tan (D)  cot cot
2 2 2 2
Q8. The value of1  cot 23º equals

2 2
(A) (B)
1  cot 22º 1  tan68º
2 1
(C) (D)
1  cot 22º 1  tan68º
Q9. The equationlog 2  x  3  log 2 5  x   0

(A) has a meaning if 3  x  5 (B) has two roots
(C) has only one root (D) has no root
Q10. If x satisfies | x  1 |  | x  2 |  | x  3 |  6, then

(A) 0  x  4 (B) x  2 or x  4
( C) x  0 (D) x  4
JEE ADV PAPER -5
This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02)
questions.
Each question has FOUR options. ONLY ONE of these four options corresponds to the correct
answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : −1 In all other cases.
Paragraph for Q11 & Q12

Consider the expression a cos   b sin  where a, b are real constants and  is a real variable. It’s minimum
and maximum values are  a2  b2 and a2  b2 respectively.
Now answer the following questions :
 
Q11. The maximum value of the expression 5 cos x  3cos  x   is
 3
(A) -7 (B) -4
(C) 7 (D) 10
Q12. Which of the following is negative for all real x ?


(A) sin x  cos x  2 (B) sin x  cos x 
2
(C) 3 sin x  4cos x  5 (D) 5 cos x  12sin x  13

The statement a  b  a  b is equivalent to ab  0 . Now answer the following questions:
  
Q13. The set of all possible real values of x which lie in the interval   ,  and satisfy the equation.
 2 2
x2  1  cos x  x 2  1  cos x is
    
(A)   , 1  1,  (B)  1, 1
 2   2
  
(C)   ,  (D) 1,  
 2 2
Q14. The set of all real values of x which lie in the interval  0,  and which satisfy the equation:
x2  4x  3  sin x  x 2  4x  3  sin x is
(A)  0,1  3,   (B)  0,  
(C) 1, 3  (D) 1,  
JEE ADV PAPER -6
 This section contains FOUR (04) questions. The answer to each question is a NUMERICAL
VALUE.
 For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to
the second decimal place; e.g. 6.25, 7.00, 0.33, .30, 30.27, 127.30) using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 0 In all other cases.
Q15. There are 100 students in a batch and each student was examined in Maths and Biology. It was found
that 60 students passed in at least one of the two subjects and 20 students passed in both the subjects.
If m and b are the member of students who failed in Maths and Biology respectively, then the sum m +
b = ………..
Q16. The value of

 3 5 7 9
 352  sin   sin   sin   sin   sin   is………..
 22   22   22   22   22 
Q17. The minimum value of 3 tan2 + 12 cot2 is ………………
 3 5 7
Q18. Value of 2(sin4 + sin4 + sin4 + sin4 ) is equal to………….
8 8 8 8
JEE ADV PAPER -7
PART – II: CHEMISTRY


is correct.
Q1. An oxide of metal have 20% oxygen by mass, the equivalent weight of oxide is :
(A) 32 (B) 40
(C) 48 (D) 52
3
Q2. An open vessel at 27°C is heated until the of the moles of the air in it has been expelled. Assuming
5
that the volume of the vessel remains constant, what is the temperature to which the vessel has been
heated
(A) 27°C (B) 300°C
(C) 477°C (D) 110°C
Q3. ASSERTION: At constant temperature, if pressure on the fixed mass of a gas is doubled, its density is
doubled.
REASON: At constant temperature molecular mass of a gas is directly proportional to the density and
inversely proportional to pressure.
(A) Both A and R are true and R is the correct explanation of A
(B) Both A and R are true but R is not the correct explanation of A
(C) A is true, R is false
(D) A is false, R is true
Q4. ASSERTION: the equivalent weight of any substance is its molecular weight divided by some factor,
depending on the nature of the substance.
REASON: The equivalent weight of any substance is always less than its molecular weight.
(A) Both A and R are true and R is the correct explanation of A
(B) Both A and R are true but R is not the correct explanation of A
(C) A is true, R is false
(D) A is false, R is true
Q5. If 0 is the threshold wavelength for photoelectric emission,  the wavelength of light
falling on the surface of a metal and m, the mass of e–, then the velocity of ejected e– is
given by
1/ 2 1/2
 2h   2hc
(A)   0     (B)   0   
 m   m 
1/2
 2hc   0    
(C)    (D) None
 m  0   
JEE ADV PAPER -8
Q6. The vapour density of a chloride of M is 104.25. What is the formula of the chloride if the equivalent
mass of M is 6.2?
(A) MCl3 (B) MCl5
(C) MCl4 (D) MCl2

the ORS.
darkened.
Q7. A volume of 10 ml of a mixture of H2 and O2 is exploded. If the final volume becomes 1ml, the
composition of original mixture may be
(A) 7ml H2, 3ml O2 (B) 6ml H2, 4ml O2
(C) 5ml H2, 5ml O2 (D) 3 ml H2, 7ml O2
Q8. A quantity of 15.8 g of KMnO4 can be decolorized in acidic medium by

(K = 39, Mn = 55, Fe= 56)
(A) 18.25 g HCl (B) 22.5 g H2C2O4
(C) 32 g SO2 (D) 38 g FeSO4
Q9. At very high pressure, the compressibility factor of 1 mole of a van der Waal’s gas can be given as
bP V
(A) Z  1  (B) Z 
RT V b
V b a
(C) Z  (D) Z  1 
V VRT
Q10. As an electron jumps from the fourth orbit to the second orbit in Be3+, its
(A) K. E. increase (B) speed increases
(C) frequency of revolution increase (D) P.E. decrease
questions.
answer.
JEE ADV PAPER -9

The behaviour of an electron in an atom is described mathematically by a wave function, or orbital. It
turns out that each wave function contains three variables, called quantum numbers, which are
represented as n, l and ml. These quantum numbers describe the energy level of an orbital and define
the shape and orientation of the region in space where the electron will be found.
Q11. Which quantum number determined orientation of the electron ?

(A) Principal (B) Secondary
(C) Magnetic (D) Spin
Q12. Orbital angular momentum is quantised and is given by -

h h
(A) l (l  1) (B) n ( n  2)
2 2
h h
(C) m ( m  1) (D) s(s  1)
2 2

Ionic bond is defined as the electrostatic force of attraction holding the oppositely charged ions. Ionic
compounds are mostly crystalline solid having high melting and boiling points, electrical conductivity in
molten state, solubility in water etc. Covalent bond is defined as the force which binds atoms of same or
different elements by mutual sharing of electrons in a covalent bond. Covalent compounds are solids,
liquids or gases. They have low melting and boiling points compounds. They are more soluble in non-
polar solvents.
Q13. The valence electrons are involved in formation of covalent bonds, by the process of:
(A) non-bonding
(B) coordination
(C) transferring
(D) mutual sharing
Q14. The amount of energy released when one mole of ionic solid is formed by packing of gaseous ion is called :
(A) Ionisation energy
(B) Solvation energy
(C) Lattice energy
(D) Hydration energy
VALUE.
 For each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off
to the second decimal place; e.g. 6.25, 7.00, 0.33, .30, 30.27, 127.30) using the mouse and
the on-screen virtual numeric keypad in the place designated to enter the answer.
Q15. A certain compound was known to have a formula which could be represented as
[Pd (Cx HyNz)](ClO4)2 and analysis showed that the compound contain 30.15 % carbon and 5 %
hydrogen. When the above compound is converted to the corresponding thiocyanate of molecular
formula [Pd ( Cx Hy Nz)] (SCN)2 the analysis showed it contain 40.46 % carbon and 5.94 % hydrogen.
Determine the sum value of x, y and z in nearest possible integers. At wt of Pd = 106
JEE ADV PAPER -10
Q16. A solution of fatty acid “X” (M = 252 gm/mol) in benzene contain 4.2 gm of acid per litre. When this
solution is dropped in a water surface the benzene evaporates and fatty acid “X” forms a monolayer
2
film.of solid type. If we wish to cover 10 m area with monolayer film of fatty acid “X” , what volume of
2 23
solution in ml should we use ? Each fatty acid molecule occupy 0.2 nm area. Given NA = 6 × 10
Q17. For 1s orbital of Hydrogen atom radial wave function is given as

3/2
1  1
R(r)=   er /a0 Where a0 =0.529Å
  a0 
The ratio of radial probability density of finding electron at r= a0 to the radial probability density of
finding electron at the nucleus is given as (x.e  y ) .Calculate the value of (x+ y.)
Q18. Air is trapped in a horizontal glass tube by 36 cm mercury column as shown below:
Hg
1 atm
36 cm
If the tube is held vertical keeping the open end uplength of air column shrink to 19 cm. what is the
length (in cm) by which the mercury column shifts down?
JEE ADV PAPER -11
PART – III: PHYSICS


is correct.
Q1. A Horizontal force of 10 N is necessary to just hold a block stationary

against a wall. The coefficient of friction between the block and the
wall is 0.2. The free body diagram of the block is 10 N
(A) f (B) f
10 N 10 N
N N
W W
(C)` f (D) f
10 N 10 N
N N
W W
Q2. Two steel balls A and B of radii r and R respectively are placed inside a right
circular frictionless cylinder making contacts at points P, Q and R as shown in P A
R
the figure. The masses are m and M respectively. The force exerted by the floor
B
at the point Q is
 m M Q
(A) (m + M)g (B)   rg
 R 
 m M
(C)   Rg (D) Mg
 r 
Q3. A simple pendulum with a bob of mass m is suspended from the roof of a car moving horizontally with
constant acceleration ‘a’. If bob is at rest in equilibrium position with respect to car then,
(A) the string gets inclined with the vertical at an angle tan1(g/a)
 a
(B) the string makes an angle of tan1  1   with the vertical.
 g
 a
(C) the tension in the string is mg  1  
 g
(D) the tension in the string is m a2  g2
Q4. Figure shows a cube of side length ‘a’ placed on a

horizontal surface. A particle projected from A with
u a
speed u, at an angle  = tan1 5 with horizontal, just a
misses the cube at two vertices as shown. Find 
projection speed u.
A
27
(A) ag (B) 2ag
8
JEE ADV PAPER -12
8
(C) 3ag (D) ag
3
2
Q5. Acceleration of the pulley and the block B are as shown in the figure. a1 = 1 m/s
Find the value of a3. (all the accelerations mentioned in the diagram are
with respect to ground)
(A) 4 m/s2 (B) 1 m/s2
2
(C) 3 m/s (D) 2 m/s2 2
a2 = 2 m/s
B
a3
A
Q6. Block A is placed on block B, whose mass is greater than that of A. There is
A P
friction between the blocks, while the ground is smooth. A horizontal force P,
linearly increasing with time, begins to act on A. The acceleration a1 and a2 of B
A and B respectively are plotted against time t. Choose the correct graph.
(A) a (B) a
a1
a2
a1
a1
a2 a2
t t
(C) a a1 (D) a1
a
a2 a2
a1 a1
a2 a2
t t

the ORS.
darkened.
Q7. 1 kg and 4 kg blocks lie on a rough horizontal surface. The coefficient 1 kg 4 kg

of friction between 4 kg block and surface is 0.2 while the coefficient
of friction between 1 kg block and the surface is 0.6. All the pulley
1 = 0.6 2 = 0.2
shown in the figure are massless and frictionless and all strings are
massless.
(A) The frictional force acting on 1 kg block is 2 N. 2 kg
(B) The frictional force acting on 1 kg block is 6 N.
JEE ADV PAPER -13
(C) The tension in the string connecting 4 kg block and 1 kg block is 2 N.

(D) The tension in the string connecting 1 kg block and 4 kg block is zero.
Q8. A projectile is thrown horizontally from top of a building of height 10 m with a certain speed u. At same
time another projectile thrown from ground 10m away from the building with equal speed u in the same
vertical plane at an angle  with horizontal. If they collide after 1s; then :
(A) Angle of projection () for second particle is 45°
(B) Angle of projection () for second particle is 90°
(C) Initial speed, u = 10 m/s
(D) Initial speed, u = 5 m/s
Q9. A particle is projected from ground with speed u at an angle  with the horizontal. Radius of curvature:
(A) is minimum at the highest point (B) is minimum at the point of projection
u2 cos2  u2
(C) is same at all the points (D) varies from to
g g cos 
Q10. A body moves along an uneven horizontal road surface with constant speed B
at all points. The normal reaction of the road on the body is
(A) maximum at A (B) maximum at B A
C
(C) minimum at B (D) the same at A, B and C
questions.
answer.

When a particle is projected at some angle with the horizontal, the path of the particle is parabolic. In the
process the horizontal velocity remains constant but the magnitude of vertical velocity changes. At any instant
during flight the acceleration of the particle remains g in vertically downward direction. During flight at any point
the path of particle can be considered as a part of circle and radius of that circle is called the radius of curvature
of the path.
Consider that a particle is projected with velocity u = 10 m/s at an angle  = 60º with the horizontal and take
value of g = 10 m/s2: Now answer the following questions.
Q11. The radius of curvature of path of particle at the instant when the velocity vector of the particle becomes
perpendicular to initial velocity vector is
20 10
(A) m (B) m
3 3 3 3
40 80
(C) m (D) m
3 3 3 3
Q12. The magnitude of acceleration of particle at that instant is

2
(A) 10 m/s (B) 5 3 m/ s2
2
(C) 5 m/s (D) 10 3 m / s2
JEE ADV PAPER -14
Three blocks m1 = 3 kg, m2 = 2 kg, m3 = 5 kg, lie on an inclined

frictionless surface as shown in the figure. (Take g = 10 m/s2) m3
m2
Q13. What force (F) parallel to the incline is needed to push the blocks m1
up the plane with an acceleration a = 2 m/s2 F 30
(A) 50 N (B) 60 N
(C) 70 N (D) 80 N
Q14. The contact force between m1 & m2, when the blocks are moving up with an acceleration of 2 m/s2 up
the inclined, is
(A) 50 N (B) 48 N
(C) 49 N (D) 80 N
VALUE.
 For each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off
to the second decimal place; e.g. 6.25, 7.00, 0.33, .30, 30.27, 127.30) using the mouse and
the on-screen virtual numeric keypad in the place designated to enter the answer.
Q15. A particle is thrown with relative velocity 10 m/s from an inclined 2

10 m/s
plane, which is also moving with acceleration 10 m/s2 vertically
1
upward. The time after which it lands on the plane is s . The value 30
n
of n is (g = 10 m/s2)
 
Q16. Two particle having position vectors r1  3iˆ  5ˆj meters and r2  (5iˆ  3ˆj) meters are moving with
 
velocities v1  (4iˆ  3ˆj) m/s and v 2  (a ˆi  7ˆj) m/sec. If they collide after 2 sec, find the value of a.
Q17. Figure shows the force F (in newton) acting on a body as a function F (N)
of x (displacement), then select correct options. (Assuming mass is
1 kg, velocity is zero at origin). If at x = 4m, velocity is 15 m / s , 10 N
then the value of  is………….
x(m)
1 2 3 4
Q18. Two blocks of masses 7 kg and 3 kg are connected by

spring of stiffness 1000 N/m and placed on a smooth
horizontal surface. They are acted upon by horizontal 32 N 7 kg 3 kg 72 N
forces of 72 N and 32 N in opposite directions as shown in
the figure. When acceleration of the blocks are equal and constant the extension of the spring is
…………cm
JEE ADV PAPER -15
ANSWER: Test-Phase-I-Paper-2
Mathematics CHEMISTRY PHYSICS
Ans1. C Ans1. B Ans1. C
Ans2. C Ans2. C Ans2. A
Ans3. D Ans3. C Ans3. D
Ans4. D Ans4. C Ans4. C
Ans5. A Ans5. C Ans5. A
Ans6. A Ans6. B Ans6. C
Ans7. B,C Ans7. AB Ans7. A,C
Ans8. B,C Ans8. AB Ans8. B,C
Ans9. A,C Ans9. AB Ans9. A, D
Ans10. C,D Ans10. ABCD Ans10. A, C
Ans11. C Ans11. C Ans11. A
Ans12. B Ans12. A Ans12. A
Ans13. A Ans13. D
Ans14. C Ans13. C
Ans14. A
Ans15. 120 Ans15. 46 Ans14. C
Ans16. 11 Ans15. 3
Ans16. 5
Ans17. 12 Ans16. 8
Ans17. 3 Ans17. 4
Ans18. 3 Ans18. 9 Ans18. 6
JEE ADV PAPER -16
SOLUTION: Test-Phase-I-Paper-2
Mathematics
Sol1. Area of the fig. is 2 = 2   2
Sol2. sinx + cosx + tanx + cotx + secx + cosecx = 7

 1  sin x  cos x 
 (sinx + cosx) +   7
 sin x cos x  sin x. cos x
 2   2 
 (sinx + cosx)  1    7  
 sin 2x   sin 2x 
 4 4  4 28
 (1 + sin2x)  1  2
  = 49 + 2
 (squaring both sides)
 sin 2 x sin 2x  sin 2x sin 2 x
 sin 2x – 44 sin22x + 36 sin2x = 0
3
 sin2x = 22 – 8 7 .
4 3 2
Sol3. tan x – 2 tan x – tan x + 2tanx + 1
tan4x + tan2x – 2tan3x + 2tan x – 2tan2x + 1
2 2 2
= (tan – tanx) + 2(tan x – tan x) + 1= 4.
Sol4. cot2 36 cot2 72 = (cot2 36 cot2 72 – 1) +1

 cos 2 36 0 cos 2 72 0  sin 2 36 0 sin 2 72 0 
=   1
sin 2 36 0 sin 2 72 0 
 
 
 1  cos144 1  cos 72  1  cos144 1  cos 720
= 
0 0
 
0
    1
 4 sin2 360 sin2 720 
 
cos144 0  cos 720
= 1
2 sin2 36 0 sin2 720
=
cos 108 0 cos 36 0
 1 =
 cos 72 0 cos 36 0
 1 = 1
cot 36 0 cot 72 0  2
sin 2 36 0 sin 2 72 0 sin 2 36 0 sin 2 72 0 cos 36 0 cos 72 0
= 1

2 sin 360 cot 360 cot 720
= 1
2
4 sin 360 cot 360 cot 720  
2
2 sin 360 cos 360 cos 720 sin1440

 cot2 36 cot2 72 = 1 – 4cot2 36 cot2 72
2 2
 5 cot 36 cot 72 = 1
1
 cot236 cot272 = .
5
Alternate:
cosA  B
cotA . cot B = +1
sin A. sin B
cos 108 0
 cot360. cot720 = +1
sin 36 0. sin 72 0
 sin18 0 1 1
= 0 0 0
+ 1= 1  2 0
 1
sin18 . cos18 .cos18 2 cos 18 1  cos 360
5 1
cos 36 0 4 5 1 1
= = = 
1  cos 36 0
1
5 1 
5 1 5  5
4
1
= cot2360. cot2720 =
5
Sol5.
JEE ADV PAPER -17
Sol6. Since the given triangle is right angled at (2, 5), therefore the middle point of the hypotenuse is
the circumcentre.
sin 2  sin 2  (cos   cos) 2  (1  cos 2 )(1  cos 2 )

Sol7. sec 2   1  
(cos   cos) 2 (cos   cos ) 2
cos   cos 
 cos  
1  cos  cos 
Using componendo and dividendo
1  cos  (1  cos )(1  cos )

1  cos  (1  cos )(1  cos)
  
tan 2  tan 2 tan 2
2 2 2
  
tan   tan tan
2 2 2
cot A cot B  1
Sol8. 45º  22º 23º . Use cot( A  B ) 
cot B  cot A
Sol9. (A) is correct since, we must have x  3  0, 5  x  0  x  3, 5
Again the equation is log 2  x  35  x   0
 x  35  x   1  x = 4
Thus choice (A), (C) are correct.
Sol10. For x  1, the given inequation becomes 1 – x + 2 – x + 3 – x  6
 –3x  0  x  0
and for x  3, the given equation becomes
x  1  x  2  x  3  6  3 x  12  x  4
x 1 2  x  3  x  6   x  4  6
For 1 < x  2 we get
i.e.  x  2  x  2 not possible.
For 2 < x < 3, we get x  1  x  2  3  x  6  x  6, not possible.
Hence solution set is (–, 0]  [4, ) i.e. x  0 or x 4.
 
5 cos x  3cos  x  
 3
Sol11.
2 2
13 3 3  13   3 3 
 cos x  sin x,       7
2 2  2   2 
Sol12.  2  sin x  cos x  2

5  3 sin x  4 cos x  5
and 13  5 cos x  12 sin x  13
 
 x  , cos x  0
Sol13. For 2 2
 
 cos x  cos x 2  x
, given equation  x  1  0 but 2 2.
JEE ADV PAPER -18
0  x  , sin x  0  sin x  sin x

Sol14. For
2
Given equation  x  4x  3  0 but 0  x   .
n M  B   60
Sol15. ,
n M  B   20
,
m  n M' 
b  n B' 
m  b  n M'   n B' 
100  n M  100  n B 
 200  n M  n B 
………..(i)
n  M  B   n M   n  B   n  M  B 
Also,
60  n M  n B   20
 n M  n B   80
……….(ii)
(i) and (ii)  m  b  120
 3 5 7 9
sin sin sin sin sin
Sol16. 22 22 25 22 22
10  8 6 4 2
 cos cos cos cos cos
22 22 22 22 22
 2 3 4 5
 cos cos cos cos cos
11 11 11 11 11
 2 4 8 16
 cos . cos . cos . cos cos
11 11 11 11 11
32
sin
 11  1 
 32 352
32sin  11
11 required value = 32 .
1
Sol17. A.M.  G.M  (3tan2 +12 cot2)  6
2
 3 tan2  + 12cot2 has minimum value 12.
 7 3 5
Sol18. sin 4  sin 4  sin 4  sin 4
8 8 8 8
 4  3     
= 2 sin  sin4   2 sin4  cos4 
 8 8   8 8
  2   1 
= 2 1  2 sin . cos2   21  sin2 
 8 8  2 4
 1 3
= 2 1    .
 4 2
JEE ADV PAPER -19
CHEMISTRY
Sol1. Number of equivalent of metal = number of equivalent of oxygen.
Sol2. n1T1  n2 T2
Sol3. PM = dRT
T – const
When P is doubled then d will be doubled
T- const.
dP.M
molecular weight
Sol4. Equivalent weight =
n  factor
Equivalent weight  molecular weigth
c hc
Sol5. h   1/ 2mv 2
 0
1 1  2hc  1 1 
 hc     1/ 2mv 2     v
  0  m   0 
Sol6. Let the formula of chloride is MCln
Mol. mass of chloride is 2  V.D = 2  104.25 = 208.5
At mass of M + n  35.5 = 208.5
or, E  n + 35.5 n = 208.5
or, 6.2  n + 35.5 n = 208.5
or, n(6.2 + 35.5) = 208.5
208.5
or, n  5
41.7
 Formula of chloride = MCl5
Sol7. 2H2  O 2  2H2 O

(A) VH2 left  1mL
(B) VO 2 left  1mL
(C) VO 2 left  2.5mL
(D) VO 2 left  5.5mL
15.8
Sol8. KMnO 4   5  0.5 eq
158
18.25
HCl   1  0.5 eq
36.5
22.5
H2 C2O 4   2  0.5 eq
90
32
SO2   2  1.0 eq
69
38
FeSO4   1  0.25 eq
152
 a 
Sol9. At very high pressure,  P  2   P
 V 
b.P
 Z  1
RT
JEE ADV PAPER -20
PV P Z V
and Z    Z
RT RT V V b
z2
Sol10. K.E   n decreases , K.E increases
n2
z
u  n decreases , speed increases
n
z2
f  3  n decreases , frequency increases
n
z2
P.E   2  n decreases , P.E decreases
n
Sol11. Definition based
Sol12. Formula based
Sol15. Let mol.wt of [ Pd (Cx HyNz)](ClO4)2 = M
12 x
\ × 100 = 30.15 -- -(I)
M
y
& × 100 = 5 ------(II)
M
Mol wt of [Pd (Cx HyNz)](SCN)2
= M – 199 + 116 = M – 83
12 x  24
\ × 100 = 40.46 ---(III)
(M  83)
y  100
and = 5.94 --- (IV)
(M  83)
12 x  24
\ = 0.4046
M  83
12 x  24
or = 0.4046
1200 x
 83
30.15
or x = 14
1200 x
M= = 557
30.15
and y = 28
106 + 12 × 14 + 1 × 28 + 14 × z + 199 = 557
or 501 + 14 z = 557
or z = 4
10
Sol16. The no. of fatty acid molecule required = 18
= 5 × 1019
0.2 10
5
The no. of moles of fatty acid “X” required = × 10–4
6
5
Wt of fatty acid required= ×10–4×252 = 2.1 × 10–2 gm.
6
vol. of fatty acid solution in benzene required
2.110 2
= litre = 5 × 10–3 litre = 5 ml
4.2
Radial probability density at r = a0 R2 (a0 )
Sol17.  2
Radial probability density at r = 0 R (0)
JEE ADV PAPER -21
3 /2
For 1s orbital:R(r)= 1  1  er /a0

  a0 
2 3 2  /a 0
= R (a0 )  (1/ a0 )e  e2
R2 (0) (1/ a30 )e0
36 112
Sol18. Pf  1   atm. Final height=19 cm
76 76
Pi  1 atm,initial length= hi cm
Boyle’s law= PV i i  Pf Vf
112
1 x hi A  x 19A
76
hi  28 cm
JEE ADV PAPER -22
PHYSICS
Sol1.
Chapter: NLM fS
Chapter: FBD
N 10N
Sol2.
FBD of A NQ
NAB
NAB cos   mg 
NAB sin   NP …(1)
NP
NR
FBD of B 
NAB cos   Mg  NQ NAB
mg
NAB sin   NR …(2) Mg
From (1) and (2)
eliminating NAB cos 
We get
N  (M  m)g
Chapter: NLM
Concept: FBD
Sol3. Draw FBD of the bob
T

a y
m
mg
x
From ground frame
T sin  = ma …(i)
T cos  – mg = 0 …(ii)
T  m a 2  g2 .
Alt: From non-inertial frame of the car (having an acceleration of a the bob would appear stationary.

ma
mg
The tension in the string is m a2  g2
a

Topic: Laws of motion

Concept: FBD
Sol4.
JEE ADV PAPER -23
v cos   ucos  v
2v 2 sin  cos  
a
g u
2 2 2 2 
v sin  u sin 
a 
2g 2g A
By equation (1), (2) and (3)
4  2
2 
u sin2   2ag [u2 cos2 ]  a2
g 
a2 g2
 u4 sin2  cos2   (2agcos2 )u2  0
4
2agcos2   4a2 g2 cos4   a2 g2 sin2  cos2 
 u2 
2sin2  cos2 
 2  4  tan2  
 ag  
 2sin2  
 u  3ag
Concept involved: Projectile Motion [ Kinematics]
Sol5.
Let Y1, Y2, Y3 be the distance of pulley, block B and block A from the a1 = 1 m/s2
ground Level. Let L be the length of string.
Using constraint relationship
Y2  Y3  L  2Y1
Differentiating twice w.r.t time, we get a2 = 2 m/s
2
a2  a3  0  2a1 , L is constant B y1
a3
Now given that y2 A y3
a2  2m / s 2
a1  1 m / s 2
 (2)  a3  2  1  a2 is in downward direction.
a3  2  2  4
a3  4m / s2
Concept: Kinematics
Grade: Easy
Sol6.
Let m and M be the mass of blocks A and B  A P
respectively. Force of friction mAg
B
Now if P < mAg
Then, Block B will move in forward direction,
since P < mAg. So A can not slide over B.
So a will also move with B with same f A P
acceleration as that of B.
If P > mAg. f
Then Force acting of B will be mAg in
B
forward direction and force on a will be (P -
mAg).
So one P = mAg, after that B with move will
constant acceleration and if P increases a
a1
time, acceleration of A goes on increasing a2
with increasing time. a1
a2
Topic: Frictional Force
t
Grade: Easy
JEE ADV PAPER -24
Sol7.
f1max  1m1g 1 kg T2 4 kg T1
= 0.6 × 1 × 10 T1
= 6N 1 = 0.6 2 = 0.2
f2max  2m2 g  0.2  4  10  8N
Also 2T1  2  10  T1  10N System is in rest 2 kg
But f1max  f2 max  6  8  14N
 T1  10N and T1  f2max  T2
10 = 8 + T2  T2 = 2N
Also f 1 = T2 = 2N
Grade: Good
Sol8.
Since both collide after t = 1 sec. B u
Horizontal direction
(u  ucos )t  10m 10m
u
 u(1  cos )  10 …(1) usin

O 10m ucos A
Also, vertical direction
1 2 1
gt  (usin   gt 2 )  10 m
2 2
 u sin  = 10 …(2)
 1 + cos  = sin 
  = 90°
So, u = 10 m/s.
Sol9.
y
2 u v
gcos  
R
V2 Vx2  Vy2  
R  x x
(gcos  ) gcos  
g
(ucos  )2  (u sin   gt)2
R
(gcos  )
(ucos )2  (u sin   gt)2

R
 ucos  
g 
  
Also ucos    cos 
 ucos  
 cos    
 v 
3/2 3 /2
(ucos  )2  (usin   gt)2 
R  
u 2
 g2 t 2  2u sin gt 
ugcos  (ugcos )
We see that ugcos is a constant value and for f(t)  2a sin  
2 t 
u2  g2 t 2  2usin gt u is always +ve let us t0  g 
consider function f(t) = g2t2 – 2usingt
 f(t) decreases to a maximum value when
2u sin   u sin  
t and then increases to a minimum t 
g  g 
2usin 
value when t  or t  0 (symmetry)
g
JEE ADV PAPER -25
usin  u
u cos
R is min at t  = height point of projectile
g g
motion 
(ucos )2 u2 cos 2 
Rmin = 
g g
u
2usin 
and R is minimum at t = 0 or t   start
g u
and and of projectile motion.

g
u2 u2
gcos  and Rmax 
Rmax gcos 
Topic: Projectile motion
Sub Topic: Radius of curvature
K2
Concept Involved: a  , Writing equations of a projectile motion i.e. Vx and vy at any time t.
R
Mathematical – finding maxima and minima of a function.
Increasing and decreasing function
Moderate
Sol10.
mv 2 B
NA 
RA
A
C
mg
mv 2
At A NA  mg 
RA
mv 2
NA  mg 
RA
NB
mv 2

RB
mg
mv 2
At B mg  NB 
RB
mv 2
NB  mg 
RB
NC
mv 2

RC
mg
mv 2
At C NC  mg 
RC
mv 2
NC  mg 
RC
RC  RB  R A
 NA > NB NA > NC NC > NB
 NA > NC > NB
JEE ADV PAPER -26
 Maximum at A
minimum at B
Sol(11-12).

u  5i  5 3j

after t sec. v  5i  (5 3  10t)jˆ 
   
The velocity v becomes r to u after t sec. given by v.u  0 gcos g
2
 25  75  50 3t  0  t  sec.
3
 5 ˆ 1
v  5i  j tan x     30 (clock wise)
3 3
v2 v2
At that instant acceleration is and is equal to gcos  
R R
v2 100 / 3 20
or R    m.
gcos  5 3 3 3
Acceleration is always g = 10 m/s 2 vertically down for a projectile.
Chapter: Kinematics
Concept: Projectile Motion
Sol(13-14).
From FBD of system m1 + m2 + m3 a

N
F
F  (m1  m2  m3 )gsin   (m1  m2  m3 )a (m1+m2+m3)gsin
 F = 70 N
(m1+m2+m3)gcos
Chapter: NLM
Concept: FBD
From FBD of m, a
N1
F
F  m1gsin   Fm2m1  m1a
m1gsin
 Fm2m1  49N 
m 2gcos
Fm2m1 
Chapter: NLM
Concept: FBD
Sol15.
JEE ADV PAPER -27
with respect to incline y

2v y
T
ay 10 m/s
25 1 10 + g
  s
10 3 3 30 (10 + g) cos 30
x
Concept involved: Relative Motion [ Kinematics]
 
Sol16. r1  3iˆ  5ˆj , r2  5iˆ  3ˆj
  
 r  r1  r2  8iˆ  8ˆj
 
v1  4iˆ  3ˆj , v 2  a ˆi  7ˆj

v  (a  4)iˆ  4ˆj

 r
v 
t
1
(a  4)iˆ  4ˆj  (8iˆ  8ˆj)
2
 a=8
Sol17.
F = 10 x  a = 10 x (m = 1 kg) F (N)
v1 1
vdv
dx
 10x   vdv   10xdx
0 0 10 N
2
v  10; v1  10 m / s
1
For 1 to 3 m
F = 10 N  a = 10 x(m)
at x = 2 V2 = V1 + at or V22  V12  2a.s 1 2 3 4
V22  10  2.10.1  30  V2  30 m/s

2 2
Also V  V  2.10.2
3  V3  50 m/s
1
For 3 to 4m
F = 10 (4 – x)  a = 10(4 – x)
V4 4
4
V42  V32  x2 
 vdv   10(4  x)dx   10  4x  
V3 3
2  2 3
V42  50   9 
 10 (16  8)   12     10 0.5   5
2   2 
V42  10  50  60  V4  60 m/s.
Concept used: Kinematics and Graph

Grade: Good (high calculations and good concept)
Sol18.
Acceleration of the blocks will be equal and constant
when there is no further extension in the spring. Let that
extension be x. a
72  32  10  a 32 N 7 kg 3 kg 72 N
2
 40 = 10 a  a = 4 m/s
a 32 N 7 kg 72 N
7 kg 3 kg
32 N 7 kg Kx
w
Kx  32  7a  1000 x  32N  7  4 N
m
JEE ADV PAPER -28
N 60
 1000 x  60  x  m
m 1000
x = 6 cm
Answer is wrong
Topic: Newton’s law of motion

Sub Topic: Spring mass system
Concept Involved: F.B.D. Newton’s law (F)net = ma

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 201

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts given before Question.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

Useful Data Chemistry:

 This section contains SIX ( 06) questions.

Q4. The value of cot236 cot272 is

Q5. |x2 – 1| + (x – 1)2 + x 2  3 x  2 = 0, then

circumcentre of the triangle is….

(A) ( 6, 3) (B) (6, -3)

(C) ( -6, 3) (D) none

SECTION 2 (Maximum Marks: 16)

 This section contains FOUR ( 04) questions.

Q8. The value of1  cot 23º equals

Q9. The equationlog 2  x  3  log 2 5  x   0

Q10. If x satisfies | x  1 |  | x  2 |  | x  3 |  6, then

SECTION 3 (Maximum Marks: 12)

Paragraph for Q11 & Q12

Q12. Which of the following is negative for all real x ?

Paragraph for Q13 & Q14

SECTION 4 (Maximum Marks: 12)

Q16. The value of

Q17. The minimum value of 3 tan2 + 12 cot2 is ………………

PART – II: CHEMISTRY

 This section contains SIX ( 06) questions.

SECTION 2 (Maximum Marks: 16)

 This section contains FOUR ( 04) questions.

Q8. A quantity of 15.8 g of KMnO4 can be decolorized in acidic medium by

SECTION 3 (Maximum Marks: 12)

Paragraph for Q11 & Q12

Q11. Which quantum number determined orientation of the electron ?

Q12. Orbital angular momentum is quantised and is given by -

Paragraph for Q13 & Q14

SECTION 4 (Maximum Marks: 12)

Q17. For 1s orbital of Hydrogen atom radial wave function is given as

PART – III: PHYSICS

 This section contains SIX ( 06) questions.

Q1. A Horizontal force of 10 N is necessary to just hold a block stationary

(D) the tension in the string is m a2  g2

Q4. Figure shows a cube of side length ‘a’ placed on a

SECTION 2 (Maximum Marks: 16)

 This section contains FOUR ( 04) questions.

Q7. 1 kg and 4 kg blocks lie on a rough horizontal surface. The coefficient 1 kg 4 kg

(C) The tension in the string connecting 4 kg block and 1 kg block is 2 N.

SECTION 3 (Maximum Marks: 12)

Paragraph for Q11 & Q12

Q12. The magnitude of acceleration of particle at that instant is

Paragraph for Q13 & Q14

Three blocks m1 = 3 kg, m2 = 2 kg, m3 = 5 kg, lie on an inclined

SECTION 4 (Maximum Marks: 12)

Q15. A particle is thrown with relative velocity 10 m/s from an inclined 2

Q18. Two blocks of masses 7 kg and 3 kg are connected by

Sol1. Area of the fig. is 2 = 2   2

Sol2. sinx + cosx + tanx + cotx + secx + cosecx = 7

Sol4. cot2 36 cot2 72 = (cot2 36 cot2 72 – 1) +1

sin 2 36 0 sin 2 72 0 sin 2 36 0 sin 2 72 0 cos 36 0 cos 72 0

2 sin 360 cos 360 cos 720 sin1440

sin 2  sin 2  (cos   cos) 2  (1  cos 2 )(1  cos 2 )

Batch :__ Date of Examination :_