REDOX WORKSHOP

María Paula León B

12B

1) Na + FeCl2→NaCl + Fe

Na(0)+ Fe(2+)Cl2(-1) → Na(1+)Cl(-1) + Fe(0)

Oxidation: Na = (Na(0) → Na(1+) + 1e-) * 2

Reduction:Fe = : Fe(2+) + 2e-→ Fe(0)

Overall cell: 2Na(0) + Fe(2+) → 2Na(1+) + Fe(0)

2) PbS +O2→SO2+ PbO

Pb(2+)S(2-) + O2 → S(4+)O2(2-) + Pb(2+)O(2+)

Oxidation: (S(2-) → S(4+) + 6e-) * 4

Reduction: (2O2(0) + 8e-→ O2(2-) + 2O(2-)) * 3

Overall cell: 4S(2-) + 6O2(0) → 4S(4+) + 3O2(2-) + 6O(2-)

3) H2+ O2→H2O

H2(0)+O2(0) → H2(+1)O(-2)

Oxidation: H2(0) → H2(1+) + 2e-

Reduction: O2(0) + 2e- → O(2-)

Overall cell: H2(0) + O2(0) → H2(1+) + O(2-)

4) Cu + HNO3→CuNO3+ H2
Cu + 2H(+1)N(+5)O3(-2) →Cu(+1)N(+5)O3(-2) + H2(0)

Oxidation: (Cu(0) → Cu(1+) + 1e-) * 2

Reduction: 2H(1+) + 2e- + H2(0)

Overall cell: 2Cu(0) + 2H(1+) → 2Cu(1+) + H2(0)

5) AgNO3+ Cu →CuNO3+ Ag

Cu + Ag(+1)N(+5)O3(-2) → Cu(+1)N(+5)O3(-2) + Ag(0)

Oxidation: Cu= Cu (0) → Cu (+1) +1e-

Reduction:Ag = Ag (1+) +1e- → Ag (0)

Overall Cell = Cu (0)+ Ag (1+)→ Cu (+1) + Ag (1+)