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PERIODIC TABLE SINGLE CORRECT : +4 & -1 10. i. 12. 13. 14. Three element X, Y, Zare following Doberiner’s Triad rule. If the atomic weight of X and Y are 10 and 26 respectively, then atomic weightof Z willbe (aysa (B)40 ory (18 ‘The weight of 224 ml of diatomic gas at 0°C and 2 atm pressure is 1 gm. The atomic weight of the gas willbe (a)20 (B)25 (C)30 (0)35 ‘Total number of possible shells in uranium atom (atomic no. 2 = 92) aw (A)7 (B)1 (C6 {D) None of these $e = Rearrange the folowing (Ito IV) in the order of increasing masses. % (10.5 mole of O. (ll) 0.5.gm molecule of Nitrogen {it) 3.011 x 10 molecules of, (IV) 11.35 Lof CO, at STP @V,S*, Cr, Ar (D) NF, 0%, Ar In crystal of which of the following ionic compound, would youexpect the maximum distance between centre of cation and anion. (A) GSE (B) Cs (Cy LL (D) LF The ionic radii of F, F-, O, O% are in the order of : (AO? >F>F>O (B)F>O7>F>O (C)O*>O>F>F (D)O>>F>0>F The incorrect order of radii is (A)NLick (D) Fe" > Fo > Fe Which among the following species has the same number of electrons in its outermost as well as penultimate shell? (A) Mg* (B)0o* (re (D) Ca The ionic radii of N°, O® and F” are respectively given by: {A) 1.36, 1.40, 1.71 (B) 1.36, 1.71, (C)1.71, 1.40, 1.36 {D) 1.71, 1.36, 1.40 Which transition involves maximum amount of energy (Misa metal) (A) M~(g) —> Mig) +e {B) M(g)—> M¥ (g) +e (C) Mt (g] 9 M¥? (g) +e {D) M*? {g) > M** (a) + CHEMISTRY 1 15. 16. 17. 18. 19. 20. 21. 23. 24. 25. Which one of the following electronic configuration of an atom has the highest ionisation eneray (a) 1s"2s"2p? (B) 1s?2s"2p 63s" (C) 1s?26?2p8 (D)1s'222p° ‘The first five ionization energies of an element are 9.1, 16.2, 24.5, 35 and 205.7 eV respectively. Then number of valence electron in the atom is (Az {B)3 (cya (D)5 Give the correct order of initials T (true) or F (ase) for following statements. (1) Top positions of Lother-Mayer'satomic volume curve are occupied by Alkali metals. (ll) Number of elements presents in the fifth period of the periodic table are 32. (Ill) 2°# LP of Mg is less than the 2"* LP of Na. (IV) A p-orbital can take maximum of six electrons. (a) TFIF (B) TFFT (FFTF (O) TIFF For the element X, student Surbhi measured its radius as 102 nm, M:Gupta as 113 nm and Mr, Agarwal as 100 nm using same apparatus. Their teacher explained that measurements were correct by saying that recorded values by three students were (A) Crystal, vander Waal and covalent radii {B) Covalent, crystal and vander Waal radii {C) Vander Waal, ionic and covalent {D) None is comect Choose the incorrect statement. (A) Be and Alare not in same group. {B) Allthe transition metal correspond to d-block. {C) Be and Al are having lot of similarities in their properties. {D) The atomic radius gradually decreases from Sc to Zn. ‘Statement-1 : The ionisation potential of Snis greater than Pb. ‘Statement-2 : Usually ionisation eneray decreases down the group. (A) Statement-1 is true, statement-2 is true and statement.2 is conect explanation forstatement- {B) Statoment-1is true, statement-2 is rue and statement-2 is NOT the conect explanation forstatement:1. {C) Statement-1 is true, statement.2 is false. {D) Statement-1 is false, statement-2 is true, Statement-1 :(LE.), ofan atom is always greater than (LE.),.. (ns integer number) Statement-2 : ne/Z.ratio decreases on successive elimination of electrons. {A) Statement-1 is true, statement-2 is true and statement-2 is comect explanation forstatement-1. {B) Statement-1is tre, statement2 is true and statement-2 is NOT the conect explanation forstalement-1. {C) Statement-1 is true, statement 2 is false. {D) Statement-1 is false, statement-2 is true. Which of the following relation is comect, (A) 2 LR-EA.-EN, (B)2LP-EN. +EA =0 (C)2EN.-LP-EA. =0 (D)EN.-LP-EA. = 0 ‘The comrect order of electron affinity for the different families is (A) Halogen > carbon > nitrogen > oxygen {B) Halogen > oxygen > nitrogen > carbon (©) Halogen > nitrogen > carbon > oxygen {D) Halogen > oxygen > carbon > nitrogen Ag atoms of X (g) are converted into X* (a) by eneray Ey. Aj2.atoms of X (g) ate converted into X~(g) by energy E,. Hence ionisation potential and electron affinity of X (g) are 2E, 2E; Ep) PE 2Ey (Ey -Ep) 2E, AAS A 8) AS Ay (RA (D) None First, second and third LP. values are 100 eV,, 150 eV and 1500 eV. Element can be (A) Be (BB (OF (D)Na CHEMISTRY 2 26. 27. 28. 29. 31. Find the highest ratio of IP values of given pair of elements : (A) He: Ne (B) Ne: Ar {C) He: Xe (D) Kr: Xe. Which of the following case the size ratio is minimum : (ALF / Li (BH (C) Na“ /Na {D) Can not be predicted The most acidic oxide is : {a)SO, (B)P,0, (cyclo, ()P,0, According to Born-Habers eyck, the enthalpy of formation of ionic compounds can be detentnined. The formation of NaClinvolves following steps: {() Nafs) ——S____y Nala) {th Naig) ——___5 Na*igh + &* Energy of sublimation Tonsaton potent D E AIM) CLG) ond aissviation energy 219) AM) Cla) + © Ficeton-atiny CS) v (W)CTIg) + Natta) ee eneray NACH(S) The enthalpy of formation of NaCI will be D D (A) aH,=S + b> -E-U (B) AH,=S + +> -E-U J 2 4 2 E E (Cal =-S-LD+ 540 (D) aH = -S-LD-5-u Choose the correct order of the following: (A) N-H > Sb-H > As-H > P-H : Polarity order {B) Mq?*(aq) > $i2* (aq) > Be?* (aq) : Hydrated radius order {C) Mg** (aq) > Si** (aq) > Ba** (aq) : lonie mobility order {D) NaF > MgO > S10 : Lattice eneray order Which of the following process is associated with best possibility of the eneray release. (AL Lit Fe BO +e 0" (c)cr'+e— cl (D) Be +e —> Be" ‘Statement-1 : F> is having highest hydrated radius among the other halide ions Statement-2 : Electronegativity of fluorine (F) is maximum in the periodic table. (A) Statement.] is true, statement-2 is true and statement-2 is correct explanation for statement-1 {B) Statement] is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1 {C) Statement-1 is true, statement.2 is false. {D) Statement-1 is false, statement-2 is true. ‘Statement-1: Nitrogen atom has higher ionization energy than fluorine atom. Statement-2: Nitrogen atom has extra stable electronic configuration due to half filed p-subshell (A) Statement-1 is true, statement-2 is true and statement.2 is conect explanation forstatement- {B) Statement] is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1 {C) Statement-1 is true, statement.2 is false. {D) Statement-1 is false, statement2 is true. CHEMISTRY 3 37. 39. 4. Which of the following statement is not correct: {A) lonic mobility of Na* (aq) is greater than Mg?*(aq) (B) The E.A. of F atom is more than ‘CI atom (C) Second LP of 'B' atom is greater than that of 'C’ atom, (D) LE. of O" is less than that of 'O' atom. Which of the following species of Mn has lowest electronegativity? (A) Mill) (B) Mn(Iv) (©) Mn(VI) (D) Mn(vily The EN. of H, X, O are2.1, 0.8 and 3.5 respectively comment on the nature of the compound H-O-X, that is: (A) Basie (B) Acidic (C) Amphoteric (D) Canttbe predicted IfX - ¥ -Z is a compound and X, Y, Z are of comparable size & electronegativity of X = 3.0, Y = 3.5, Z = 0.8 then the bond which will break first in gas phase. Bea Je (ayX-¥ (B)Y-Z {C)bothsimultaneously (D) Can'tbe predicted. SE, Element P, Q, R and S belong to the same group. The oxide of P is acidic, oxide of Q and R are amphoteric while the oxide of § is basic. Which of the following elements is the most electropositive ? ) (A) P (B) (Cc) R (D) S \ CN (a) (BQ © 1S ae ob ie Which of the following is an amphoteric oxide ? Ne? (a) Mg (B) ALO, (€) SiO, (0) P,0, The first ionisation potentials of four consecutive elements present in the second period of periodic table are 8.3, 11.3, 14.5 and 13.6 eV respectively which one of the following is the first ionisation potential of nitrogen ? (A) 13.6 (8) 14.5 (cy 113 (0) 83 Which of the following is wrong ~ (A) NH, < PH, < AsH, = Acidic character (B) Li < Be Nal Which of the following is comect statement ? {A) SO, is anhydride of sulphuric acid {C) CL, is anhydride of perchloric acid V ‘Strongest reducing agent among the following is « (a) (B) cr Which of the following statements are correct ? (A) TP* salts are oxidising agents {C) Pb* salts are better oxidising agents, Which statement is correct ? {A) Sn** is more stable than Sn?+ {C) Both (A) and (B) The size of the species, Pb, (A) Pb > Pb2* > Pb (C) Pb > Pb > Pb?* (C) Na=K (D) None of these SO.+ H,9 —? 1,509, {B) NO, is anhydride of nitric acid {D) N,O is anhydride of nitrous acid eh) NOq + HiO —> HNO, tig OAL * (C) Br Or Uy04 H,0 HOD, {B) Ga* salts are reducing agents {D) All of these {B) Pb?* is more stable than Po** {D) None of these . Po?*, Pot decreases as - {B) Pb > Pb?* > Pht {D) Po** > Pb > Pb? The first ionisation energy of Mg, Al, P and S follows the order - (A) Mg < Al< P< (C)Al< Mg

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