CHEMICAL MOLECULAR ORBITAL THEORY (MOT)

BONDING Q. Compare Bond order, bond length, bond strength of O2 , 𝐎− −𝟐

𝟐 , 𝐎𝟐 .

Superoxide

Sol. O2 , O− −2
2 , O2
Peroxide

No of e. 16 17 18
Bond order 2 1.5 1
Magnetic nature para para dia

Order of Bond order and bond strength :- O2 > O–2 > O−2
2

Order of Bond length :- O2 < O–2 < O−2

2
CHEMICAL
BONDING
CHEMICAL
BONDING
CHEMICAL MOLECULAR ORBITAL THEORY (MOT)
BONDING Q. CHEMICAL BONDING
Which of the following molecule have only p bond ?
(1) N2 (2) F2 (3) O2 (4) C2

2p 2p

2s 2s

B2 & C2 having net p bond only

1s 1s
CHEMICAL MOLECULAR ORBITAL THEORY (MOT)
BONDING CHEMICAL BONDING
Remember :- If different molecular ions of a molecule having same bond
order then the molecular ion having less no of electrons in ABMO will be
more stable.

Q. Compare stability of 𝐍𝟐 , 𝐍𝟐+   &  𝐍𝟐–

Ans. N2 > N2+ > N2–

CHEMICAL MOLECULAR ORBITAL THEORY (MOT)
BONDING Q.
CHEMICAL BONDING
In Which of the following pair of species both species do not exist ?
(1) Li2 , B2 (2) Be2 , He2
(3) CO, NO (4) 𝐇𝟐+  ,  𝐇𝐞+
𝟐

Ans. (2)
Remember :- If total electrons are 4, 8 & 20 then B.O. is zero and
molecule doesn't exist.
CHEMICAL MOLECULAR ORBITAL THEORY (MOT)
BONDING Q. CHEMICAL BONDING
Number of s and p bonds in compound CaC2 are respectively :-
(1) 2,1 (2) 1,3
(3) 1,2 (4) 2,2

Ans. (3)
CHEMICAL
BONDING
CHEMICAL COORDINATE BOND / DATIVE BOND
BONDING •
CHEMICAL BONDING
Unlike covalent bond it is formed by unequal contribution of electrons
between two atoms .
• Shared electron pair is contributed by one atom only (donor-Lewis base).
• Other atom (acceptor-Lewis acid) only provides vacant orbital
• Necessary condition is that one atom should have lone pair while other
atoms should have vacant orbital.
CHEMICAL COORDINATE BOND / DATIVE BOND
BONDING CHEMICAL BONDING
CHEMICAL COORDINATE BOND / DATIVE BOND
BONDING Q.
CHEMICAL BONDING
Which of the following species does not have coordinate bond ?
(1) 𝐍𝐎−
𝟑

(2) 𝐈𝟑−
(3) 𝐂𝐎−𝟐
𝟑

(4) H3O+

Ans. (3)
CHEMICAL COORDINATE BOND / DATIVE BOND
BONDING Q.
CHEMICAL BONDING
Which of the following compound has ionic, covalent as well as
coordinate bond ?
(1) NaNO2
(2) HNO3
(3) NH4Cl
(4) KCl

Ans. (3)
CHEMICAL WEAK FORCES
BONDING CHEMICAL BONDING

Weak Forces

Hydrogen Bond Vander Waals force

CHEMICAL WEAK FORCES
BONDING •
CHEMICAL
Ion-Dipole force
BONDING
Between Ion and Polar molecule
e.g. Na+ and H2O

• Ion-Induced dipole force

Between Ion and Non polar molecule

e.g. I— and I2
Li+ and Cl2
CHEMICAL WEAK FORCES
BONDING CHEMICAL
Vander Waals force :- BONDING
• Dipole-dipole (Keesome force)
Between polar and polar molecule
e.g. HCl and HCl
• Dipole-Induced dipole(Debye force)
Between polar and non polar molecule
e.g. HCl and Cl2
• Instantaneous Dipole-Induced dipole (London / Dispersion Force)
Between Non-polar and Non-polar molecule
Between atoms of an inert gas
e.g. Cl2 and Cl2
Xe and Xe
H2 and H2