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J Energy 2008 05 013
J Energy 2008 05 013
Energy
journal homepage: www.elsevier.com/locate/energy
a r t i c l e in fo abstract
Article history: A tube-type solar still is found to be suitable for use in desert irrigation. The effectiveness of a heat
Received 23 July 2007 accumulator with regard to distillate productivity is experimentally and numerically verified. The heat
accumulator consists of tube bundles immersed in wax in order to utilize the latent heat of wax. The
Keywords: dynamic response to stepwise variation of irradiative intensity verified the contribution of wax to an
Solar still increase of productivity only when the phase change of wax occurred. The effective distillate productivity
Irrigation was found to be 294.3 g/m2 during the cyclic stepwise change of irradiative intensity, from 200 to 600 W/m2
Solar energy and back. Velocity vectors driven by natural convection and temperature contours estimated by numerical
Heat accumulation simulation verified the effectiveness of the heat accumulator especially after peak solar intensity. The latent
heat of wax effectively contributed to a 15% increase in total distillate productivity per day. The still can
feasibly meet irrigation water supply demands above an irrigative threshold of 17 MJ/m2 d.
& 2008 Elsevier Ltd. All rights reserved.
0360-5442/$ - see front matter & 2008 Elsevier Ltd. All rights reserved.
doi:10.1016/j.energy.2008.05.013
ARTICLE IN PRESS
Nomenclature Greek
evaporation of seawater from these reservoirs by solar radiation was adopted for the still cover due to its heat-proof nature and its
leads to a humidification of the areas. Secondly, the developed resistance to solar degradation. An inner half-cut tube made of
tube-type solar stills are connected between the reservoirs, gray vinyl chloride (inner diameter 67 mm, length 1000 mm and
constituting pipelines in the network for transportation of saline 4.5 mm in thickness) was installed as the basin with its inner side
and distillate water. The stills do not need to collect the distillate coated with a black acrylic paint for effective absorption of
or irrigate water, as water condensing under the cover of the still irradiation. The inside of the outer half-cut tube was also
flows along the inner surface of the still cover and immediately blackened for the more effective absorption. The basin consisted
discharges into the ground. The plantation plan is easily designed of two parts, the heat accumulator and a separate feed water layer.
with points (solar ponds) and lines (tube-type solar stills). The heat accumulator was comprised of 7 polyethylene tubes
(6 mm in inner diameter) filled with paraffin wax and sealed into
the bottom of the basin. Both the void in the accumulator and the
3. Experimental upper part of the basin were subsequently filled with the feed
water. The latent heat of paraffin wax (Nippon Seiro Co. Ltd.,
Tests on the effectiveness of a solar still in producing distilled EP125, m.p. ¼ 52.6 1C) made it a suitable material for the heat
water from a feed solution were condensed both in the laboratory accumulator. The inner half was coaxially fixed with the outer
and outdoors. A cross-sectional view of the developed solar still tube at both edges for a uniform vapor diffusion gap.
was given in Fig. 2. A half-cut vinyl chloride outer tube (inner Only the upper half part of the tube was exposed to irradiation
diameter 100 mm, length 1100 mm and 7 mm in thickness) acted by using the shield plate. Condensing water flowed down
as the role of the insulator and supporter for the cover tube. Pyrex the inside of the glass tube and was discharged through the
glass tube (100 mm in outer diameter and 2.4 mm in thickness) drain tube, employed here for measuring the amount of
distillated water per unit tube length. The still was tilted slightly
to facilitate this collection. The distillation productivity was
A
sti
ll tu
be measured by weight of distilled water, meaning the error in this
r Seawater
s ola ty
pe result is that for the electrical balance, 1 mg. In order to minimize
of reservoir
e of fluctuations in the distillate weight due to the dropwise
typ so
e la condensation of water, 1 h was selected as the collection time
tub rs
till
A interval. An hour is the appropriate time interval for the
Plantation Plantation
productivity rate due to good repeatability within a range of
72% in spite of instantaneous fluctuation in weight estimated to
Seawater Seawater Seawater be 10 g/m2. Therefore, the maximum error for the distillation
reservoir reservoir reservoir productivity rate per hour was estimated to be 720 g/m2 h at
Plantation Plantation highest irradiation intensity. The feed was kept at the constant
A
tu level by using a head tank.
be
till
ty
pe la rs T-type thermocouples were attached at the marked positions
of f so in Fig. 2, designated as top, m-top, side, m-bottom and bottom of
so eo
la yp the glass tube, feed and the heat accumulator. All thermocouples
rs et
till Seawater tub were calibrated with a standard thermometer to within 70.1 1C
A
reservoir due to the good linear relationship. The uncertainty with respect
to temperature measurement was 70.1 1C. Two corresponding
Fig. 1. A conceptual view of a desert plantation. positions along the longitude of the still were set up. Measured
ARTICLE IN PRESS
Navier–Stokes Eqs.
4 " #
2
qu v qu v2 qp q 1 q 1 q u 2 qv
u þ ¼ þ Pr ðruÞ þ 2 (2)
M - Bottom qr r qy r qr qr r qr r qy2 r 2 qy
2
Bottom
y [-]
6 1
1. Pyrex glass tube
2. Outer half-cut tube /insulator Tc (θ)
(gray vinyl chloride )
3. Inner half- tube /basin
0.5 v u
(gray vinylchloride )
4. Heat accumulating tubes with paraffin
5. Shield plate r
6. Drain for distilled water
Red shading is saline water 0 θ
Blue shading is condensing distilled water x[-]
• Copper-Constantan Thermocouples Tw
still without the paraffin tubes was set up as part of the laboratory without paraffin wax
600
test. Static characteristics and the effectiveness of heat accumu-
lator were evaluated with indoor experimental data, while data
obtained in the outdoor study contributed to the analysis of the
dynamic characteristics. Measured temperatures along the glass
were adopted for boundary conditions in the numerical simula- 400
tion of heat convection within the still.
" #
qv v qv uv 1 qp q 1 q 2
1 q v 2 qu Evaporated water : u ¼ v ¼ 0; T w ¼ T w;exp (6)
u þ þ ¼ þ Pr ðrvÞ þ 2 þ
qr r qy r r qy qr r qr r qy2 r 2 qy
Paraffin wax : u ¼ v ¼ 0; T p ¼ T p;exp (7)
Ra Pr T (3)
Upper part of the glass tube : u ¼ v ¼ 0; T c ¼ T c;exp ðyÞ
" #
qT v qT 1 q qT 2
1 q T at r ¼ R0O ; 0pypp=2 (8)
Energy Eq: u þ ¼ r þ 2 (4)
qr r qy r qr qr r qy2
Lower part of the glass tube : u ¼ v ¼ 0; T b ¼ T b;exp ðyÞ
Temperature profiles at the glass cover are taken to depend on at r ¼ R0O ; p=2pyp0 (9)
the circumferential angle; it is not reasonable to assume a
constant temperature profile for the outer cover since it is neither qv qT
Symmetry : u ¼ ¼ ¼0
horizontal nor flat. The profiles at the upper and lower part of the qy qy
outer tube, Tb,exp(y) and Tc,exp(y), respectively, were interpolated at 0prpRO ; y ¼ p=2 (10)
by cubic polynomials with sets of three measured temperatures,
(top, m-top, side) and (side, m-bottom, bottom) along the outer
tube. Temperatures at the sides of evaporated water (Tw,exp) and at
paraffin wax (Tp,exp) were set to be uniform; namely heat 4.2. Finite element method
convection within the water and paraffin wax were ignored. The
numerical integration is performed only to one vertical half region The Galerkin finite element method, in which isoparametric
due to symmetrical geometry. elements are applied for the coordinate and independent
The boundary conditions were set as follows: variables, was used to determine the numerical solution
of Eqs. (1)–(4) under the boundary conditions given by
Outer wall of the inner tube : u ¼ v ¼ 0; T p ¼ T p;exp Eqs. (5)–(10). Two-dimensional bilinear shape functions for
at r ¼ R0I ; yw pyp0 (5) pressure and biquadratic for the velocities were adapted for the
200 400
Distillate productivity [g / (m2 h)]
Distillate Productivity [g/(m2 h)]
150 300
100 200
0
0 0 50 100 150 200 250 300
0 50 100 150 200
Elapsed time [min]
Elapsed time [min]
200 400
Distillate productivity [g/(m2 h)]
Distillate Productivity [g/(m2 h)]
150 300
100 200
0 0
0 50 100 150 200 0 50 100 150 200 250 300
Elapsed time [min] Elapsed time [min]
Fig. 5. The dynamic response of distillate productivity with elapsed time for Fig. 6. The dynamic response of distillate productivity with elapsed time for
stepwise variation in irradiative intensity during the indoor test using infrared stepwise variation in irradiative intensity during the indoor test using infrared
lamps: (a) from 200 to 400 W/m2 and (b) from 400 to 200 W/m2. lamps: (a) from 200 to 600 W/m2 and (b) from 600 to 200 W/m2.
ARTICLE IN PRESS
isoparametric elements. The computational domain was divided 5. Results and discussion
into 30 discrete quadrangular elements in the radical and angular
directions, respectively, as shown in Fig. 3. The velocity and 5.1. Indoor experiments
temperature fields were calculated by applying the Newton–
Raphson method. 5.1.1. Static characteristics
The application of the finite element method was verified by Fig. 4 shows the effect of irradiative intensity using infrared
the close agreement with the simulated velocity and temperature lamps on distillate productivity at the steady state with and
results for the common problem of natural heat convection in a without paraffin wax in the indoor test. The larger heat capacity of
two-dimensional cavity. The Boussinesq’s approximation for the paraffin wax as compared to air did not contribute to a significant
natural heat convection in which physical properties except increase in distillate productivity. Thus, the latent heat of paraffin
density in the buoyancy term are set up to be independent of wax at the steady state had no effect on distillate productivity.
temperature, was employed to verify the conservation of
momentum and energy. The number of discrete elements, 900
was sufficient to estimate similar results due to the use of 5.1.2. Dynamic characteristics
biquadratic elements for velocity. The convergence criterion Fig. 5 shows the dynamic response of distillate productivity
adopted was 1.0 103 for the relative error of iterated velocity with elapsed time for positive (from 200 to 400 W/m2) and
and temperature values. All convergent results were acquired negative (from 400 to 200 W/m2) stepwise variation in irradiative
within the maximum number of iterations (100) even when the intensity. The temperature of paraffin wax exposed to an
relaxation factor for the iteration was set to be 0.5. irradiative intensity of 400 W/m2 did not reach the melting point
70 1000
Top
Side
Bottom
60 800
Feed
Paraffin
SolarIntensity
50 600
40 400
30 200
20 0
5:20 7:20 9:20 11:20 13:20 15:20 17:20 19:20
Time [hr]
500 1000
Distillate
Intensity
Solar intensity [W/m2]
300 600
200 400
100 200
0 0
5:20 7:20 9:20 11:20 13:20 15:20 17:20 19:20
Time [hr]
Fig. 7. (a) Temperature at each measuring point, the solar intensity and (b) distillate productivity over time on September 3, 2006 in Japan.
ARTICLE IN PRESS
of 52.6 1C. Consequently, there was no significant observable fell below its melting point. Constant distillate productivity was
difference in distillate productivity between stills with and observed during the phase change (Fig. 7(b)), after which distillate
without the wax for a stepwise change of irradiative intensity. productivity increased despite a reduction in solar intensity. The
However, paraffin wax changed from solid state to liquid state increase in productivity for several hours after solar maximum
when exposed to 600 W/m2. Fig. 6 shows the dynamic response of was due to heat retention by wax; that is, the latent heat of the
distillate productivity with elapsed time for positive (from 200 to wax. The total distillate productivity per day was 2.59 kg/m2 for
600 W/m2) and negative (from 600 to 200 W/m2) stepwise the total solar intensity per day, 22.6 MJ on September 3, 2006 in
variation in irradiative intensity that cover this phase change. Japan. This performance is adequate to meet the demands of
The difference in distillate productivities between stills with and irrigation.
without the wax were 55.8 g/m2 for an increase in irradiation
(Fig. 6(a)) and +350.1 g/m2 for a decrease in irradiation (Fig. 6(b)). 5.2.2. Temperature profiles along the glass cover
Consequently, the paraffin wax contributed to a substantial Velocity vectors driven by natural convection and temperature
increase in distillate productivity equal to 294.3 g/m2 during the contours within the still are essential for validating the effect of
cyclic stepwise change of irradiative intensity of the infrared the heat accumulator by simulation. Fig. 8 shows the temperature
lamps. The effectiveness of the latent heat of the wax during distribution at each point of the still cover over a time during
phase change on distillate productivity was, therefore, recognized. 1 day as well as the range of temperatures of the brine and
paraffin wax. From these observations, the assumption of uniform
5.2. Outdoor experiments water and paraffin wax temperatures for the simulation is
reasonable. The temperatures distributed along the circumferen-
5.2.1. Temperature profiles and distillate productivity during 1 day tial angle of the glass cover of the outer tube were approximated
The dynamic characteristics observed during the indoor in the simulation by a cubic polynomial interrelationship with the
experiment verified that the paraffin wax was effective for circumferential angle. The observed temperature profiles along
improving the productivity of the heat accumulator. This result the circumferential angle, from cover bottom to top, essentially
is reinforced in the case of using a dynamic energy source like support this assumption. Moreover, there was a gradual tempera-
solar energy. The outdoor experiment was performed only for the ture increase with increasing distillate productivity until 13:20,
solar still employing the paraffin wax as part of the heat later than the peak value of the solar intensity, after which the
accumulator. Fig. 7 shows the temperature at each measuring temperature of the cover top decreased. Latent heat on 14:20
point, the solar intensity and distillate productivity over time contributed to increase the temperature of the top cover.
on September 3, 2006 in Japan. The maximum solar intensity
and water temperature were reached on the same time, 12:20 5.2.3. Natural heat convection by numerical analysis
(Fig. 7(a)), while the maximum paraffin wax temperature and Fig. 9 shows the simulated results of velocity vectors driven by
distillate productivity peaked 1 and 2 h later, respectively. All natural convection and temperature contours on September 3,
temperature profiles had the shape similar to that of the solar 2006 in Japan. The simulation was performed using the experi-
intensity and only in case of paraffin wax were a temperature mental temperature data obtained along the outer tube to set the
reached that was greater than the brine. The phase change for boundary conditions. The direction and number of the circulation
paraffin wax (from solid to liquid) began at 11:20 and, although patterns classify the heat convection into four categories of
both brine and wax temperature began to decrease after 13:20. circulation patterns. The convection circulation direction at 10:20,
The temperature difference between water and paraffin wax was 11:20, 14:20 and 16:20 is counterclockwise. The counterclockwise
reduced to zero by 15:20, after which the temperature of the wax circulation transports colder air from the bottom into the upper
70
10:20 11:20 12:20 13:20 14:20 15:20
16:20 Tw (10:20) Tw (11:20) Tw (12.20) Tw (13:20) Tw (14:20)
Tw (15:20) Tw (16:20) Tp (10:20) Tp (11:20) Tp (12:20) Tp (13:20)
Tp (14:20) Tp (15:20) Tp (16:20) 10:20 11:20 12:20
13:20 14:20 15:20 16:20 Tw (10:20) Tw (11:20)
Tw (12.20) Tw (13:20) Tw (14:20) Tw (15:20) Tw (16:20) Tp (10:20)
60
Tp (11:20) Tp (12:20) Tp (13:20) Tp (14:20) Tp (15:20) Tp (16:20)
10:20 11:20 12:20 13:20 14:20 15:20
16:20 10:20 11:20 12:20 13:20 14:20
Temperature [C]
15:20 16:20
50
Tp
Tw
40
30
0 0.5 1 1.5 2 2.5 3
Circumferential angle [rad]
Fig. 8. Temperature distributions and approximated curves along the glass cover at each time on September 3, 2006 in Japan.
ARTICLE IN PRESS
1
1 I=765.6 [W/m2]
I=644.7 [W/m2]
d=0.010 [m] d=0.010 [m]
Y-Coordinate [-]
Y-Coordinate [-]
T T
0 1 0 1
0.9 0.9
0.8 0.8
0.7 0.7
0.6 0.6
0.5 0.5
-0.5 0.4 -0.5 0.4
0.3 0.3
0.2 0.2
0.1 0.1
0 0
-1 -1
0 0.5 1 0 0.5 1
X-Coordinate [-] X-Coordinate [-]
1 1
I=865.0 [W/m2] I=735.0 [W/m2]
d=0.010 [m] d=0.010 [m]
Tc=45.18 [C] Tc=41.31 [C]
Tb=40.64 [C] Tb=38.25 [C]
0.5 0.5
Tw=56.91 [C] Tw=51.76 [C]
Tp=51.01 [C] Tp=49.88 [C]
Y-Coordinate [-]
Y-Coordinate [-]
T T
0 1 0 1
0.9 0.9
0.8 0.8
0.7 0.7
0.6 0.6
0.5 0.5
-0.5 0.4 -0.5 0.4
0.3 0.3
0.2 0.2
0.1 0.1
0 0
-1 -1
0 0.5 1 0 0.5 1
X-Coordinate [-] X-Coordinate [-]
1 1
I=492.3 [W/m2] I=76.4 [W/m2]
d=0.010 [m] d=0.010 [m]
Tc=39.70 [C] Tc=38.25 [C]
Tb=38.44 [C] Tb=33.54 [C]
0.5 0.5
Tw=47.44 [C] Tw=36.84 [C]
Tp=47.79 [C] Tp=41.11 [C]
Y-Coordinate [-]
Y-Coordinate [-]
T T
0 1 0 1
0.9 0.9
0.8 0.8
0.7 0.7
0.6 0.6
0.5 0.5
-0.5 0.4 -0.5 0.4
0.3 0.3
0.2 0.2
0.1 0.1
0 0
-1 -1
0 0.5 1 0 0.5 1
X-Coordinate [-] X-Coordinate [-]
Fig. 9. Temperature contours and velocity vectors at (a) 10:20, (b) 11:20, (c) 12:20, (d) 13:20, (e) 14:20 and (f) 16:20 on September 3, 2006.
part of the still. Two circulations are indicated at 13:20, which be clearly seen, the time lag experimentally observed between
contributes to the peak in distillate productivity because the hot peak times of solar intensity and distillate productivity is
vapor is prevented from flowing down under the basin. Tempera- dependent on the velocity vectors driven by natural convection
ture contours clarify the hot and cool parts within the still. As can and the temperature contour.
ARTICLE IN PRESS