ALLEN® Atomic Structure 1

ATOMIC STRUCTURE 3. gkbMªkstu ijek.kq ds fofHkUu d{kdksa ds fy, f=kT;k

1. ,d izksVkWu rFkk ,d Li3+ U;wfDy;l dks leku forj.k Qyuksa ds 'r' ds fo:) vkys[k uhps fn,
x;s gS %
foHko ls Rofjr fd;k x;k gSA lLi rFkk lP Øe'k%

l Li 8

4pr R n, l(r)
Li3+ rFkk izksVkWu dh Mh&czksXyh rjaxnS/;Z gSa rks
lP (A)

2
4

2
dk eku x × 10–1 gSA tgk¡ x dk eku gS ________. 0
5 10
r(Å) ¾®
(iw.kk±d mÙkj)
3

4pr R n, l(r)
2
(Li3+ dh lagfr = 8.3 izksVkWu dh lagfr) (B)

2
1

2
0
2. cksj ds ijekf.od fl)kUr ds vuqlkj :- 5 10
r(Å) ¾®

Z2 3
W dh xfrt ÅtkZ µ
(A) bysDVªku
4 pr R n, l(r)

n2 2
(C)
2

1
2

(B) bysDVªku
W dh xfr (v) rFkk eq[; DokaVe la[;k (n)
0
5 10
2 r(Å) ¾®
dk xq.kuQy 'vn' µ Z
2.0
(C) ,d d{kk esa bysDVªkWu ds ifjØe.k dh 1.5
4 pr R n, l(r)

(D) 1.0
2 2

Z3 0.5
vkofÙk µ 0
n3 5 10
r(Å) ¾®
Z3 3s d{kd ds fy, lgh vkys[k gS %
W ij dwwykWe vkd"kZ.k cy µ
(D) bysDVªku gS
n4
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(1) (B) (2) (A) (3) (D) (4) (C)

uhps fn;s fodYiksa esa ls lokZf/kd mfpr mÙkj pqfu, % 4. fuEufyf[kr esa ls ,sslh /kkrqvksa dh la[;k crkbZ;s
ftUkdk mi;ksx izdk'k oS|rq lsy esa bysDVªksM ds
(1) dsoy (C)
:i esa fd;k tk ldrk gS _______ (iw.kkZd mÙkj)
(2) dsoy (A) (A) Li (B) Na (C) Rb (D) Cs
5. ,d f}la;ksth vk;u (ijek.kq la[;k 29) dk tyh;
(3) dsoy (A), (C) rFkk (D)
foy;u esa dsoy pØ.k pqEcdh; vk?kw.kZ _______
(4) dsoy (A) rFkk (D) (BM esa) gSA

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2 Atomic Structure ALLEN®
6. rjaxnS/;Z 663 nm dk oS|qr&pqEcdh; fofdj.k /kkrq 13. uhps nks dFku fn, gSa :
A ds ijek.kq dks vk;fud djus ds fy, Bhd dFku I : cksj fl)kUr Li+ vk;u dh fLFkjrk rFkk
i;kZIr gSA /kkrq A dh vk;uu ÅtkZ kJ mol–1 esa gS mlds ykbu LisDVªe dks Li"V djrk gSA
_______. (fudVre iw.kkZad rd) dFku II : pqEcdh; {ks=k dh mifLFkfr esa LisDVªy
[h = 6.63 × 10–34 Js, c = 3.00 × 108 ms–1, ykbuksa ds foikVu dh O;k[;k djus esa cksj
NA = 6.02 × 1023 mol–1] fl)kUr vleFkZ gSA
7. d{kd ftlesa nks f=kT; rFkk nks dks.kh; uksM gSa] uhps fn, fodYiksa esa mijksä dFkuksa ds fy,
og gS % lokZf/kd mfpr mÙkj pqfu;sA
(1) 3p (2) 4f (3) 4d (4) 5d (1) dFku I rFkk dFku II nksuksa lR; gSA

8. ,d xsan ftldk Hkkj 10 g gS 90 ms–1 ds osx ls (2) dFku I vlR; gS ijUrq dFku II lR; gSA

xfreku gSA ;fn blds osx esa vfuf'prrk 5% gS (3) dFku I rFkk dFku II nksuksa vlR; gSA

rks bldh fLFkfr esa vfuf'Pkrrk gS ____×10–33 m. (4) dFku I lR; gS ysfdu dFku II vlR; gSA

(fudVre iw.kk±d rd) 14. nh xbZ vfHkfØ;k A ® B esa 300 K ij eqDr ÅtkZ

[fn;k gS : h = 6.63 × 10–34 Js]

9. 248 nm rjaxnS/;Z dk izdk'k ,d /kkrq ftldh
nsgyh ÅtkZ 3.0 eV gS ij fxjrk gSA mRlftZr
15.
bysDVªkuW ksa dh Mh-czksXyh rjaxnS/;Z _______ Å gSA
¼fudVre iw.kk±d esa½
[mi;ksx dhft, : 3 = 1.73, h = 6.63 × 10–34 Js
me = 9.1 × 10–31 kg ; c = 3.0 × 108 ms–1 ;
1eV = 1.6 × 10–19J]
10. ,d fuf'pr d{kd ds fy, n = 4 rFkk mL = –3
esa ifjorZu –49.4 kJ mol–1 gSA vfHkfØ;k dh
,sUFkSYih 51.4 kJ mol–1 gSA vfHkfØ;k esa ,UVªkWih
ifjorZu ______ J K–1 mol–1 gSA
bysDVªkWuksa] tks fLFkj voLFkk esa gS] dks ,d
40 kV ds foHkokarj ls Rofjr djus ij] bysDVªku
W ksa
esa mRiUu rjaxnS?;Z gS x × 10–12 mA x dk eku
_______gSA (fudVre iw.kkZad esa)
fn;k gS: bysDVªkWu dh lagfr = 9.1 × 10–31 kg
bysDVªkuW dk vkos'k = 1.6 × 10–19 C
Iykad fLFkjkad = 6.63 × 10–34 Js
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gSA bl d{kd ds fy, f=kT;h; uksM+ksa dh la[;k

16. 400 nm rjaxnS/;Z ds ,do.khZ fofdj.k dk ,d
________ gSA (fudVre iw.kk±d esa)
L=kksr 10 lsdaM esa 1000 J ÅtkZ iznku djrk gSA
11. ,d d{kd ftlesa dksbZ dks.kh; uksM ugha gS rFkk
tc ;g fofdj.k lksfM;e dh lrg ij iM+rk gS]
nks f=kT;h; uksM gSa] og d{kd gS %
rks x × 1020 bysDVªkWu izfr lsdaM mRlftZr gksrs gSA
(1) 2s (2) 3s (3) 3p (4) 2p
eku fyft, dh lksfM;e /kkrq dh lrg ds
12. vkDlkbM tks pqEcdh; xq.k n'kkZrk gS og gS :
mRlftZr ds fy, 400 nm rjaxnS/;Z i;kZIr gSA
(1) SiO2 (2) Mn3O4
x dk eku ________ gSA (fudVre iw.kkZad esa)
(3) Na2O (4) MgO
(h = 6.626 × 10–34 Js)

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 ALLEN®
17. ,d Rofjr bysDVªkWu dh LihM 0.02% vfuf'prrk
ds lkFk 5 × 106 ms–1 gSA xfreku voLFkk esa bldh
fLFkfr Kkr djus esa vfuf'prrk x × 10–9 m gSA
x dk eku __________ gSA
(fudVre iw.kk±d esa)
[ mi;ks x dhft, bys D Vª k W u dh
= 9.1 × 10–31 kg, h = 6.63 × 10–34 Js, p = 3.14]
18. uhps nks dFku fn, gSa :
dFku I : jnjQksMZ dk xksYM iUuh iz;ksx gkbMªkstu
ijek.kq ds ykbu LisDVªe dh O;k[;k ugha dj
ldrk gSA
dFku II : gkbMªkstu ijek.kq dk cksj ekWMy
gkbtsucxZ ds vfuf'prrk fl)kar dk [kaMu djrk
gSA
mijksDr dFkuksa ds fy, lokZf/kd mfpr mÙkj gS]
fuEu fodYiksa esa ls gS :
(1) dFku I vlR; gS dFku II lR; gSA
(2) dFku I lR; gS dFku II vlR; gSA
(3) nksuksa dFku I rFkk dFku II vlR; gSA
(4) nksuksa dFku I rFkk dFku II lR; gSA
19. ;fn ijek.kq dk FkkWelu ekWMy lgh Fkk rks
jnjQksMZ ds xksYM dh iryh iUuh ij fd;s x,
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iz;ksx ds ifj.kke gksrs %
(1) xksYM iUuh ls lHkh a-d.k xfr esa deh fd;s
fcuk fudy tkrs gSaA
(2) a-d.kksa dk fo{ksi.k ,d foLr r ijkl ds dks.kksa
ij gksrkA
o
(3) lHkh a-d.k 180 ds dks.k ij ihNs dh vksj eqM+
tkrsA
(4) lHkh a-d.k fcuk xfr ?kVs xksYM iUuh ls
xqtjrsA
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Atomic Structure 3
20. uhps nks dFku fn, gSaA
dFku I : ijek.kq ds cksj ds ekWMy ds vuqlkj
bysDVªkWu ds osx dk ifjek.k xq.kkRed :i ls ukfHkd
ij /kukos'k ?kVus ds lkFk] c<+rk gS D;ksafd bysDVªkWu
ij ukfHkd dk dksbZ izcy ca/ku ugha jgrk gSA
la g fr dFku II : ijek.kq ds cksj ds ekWMy ds vuqlkj
bysDVªkuW ds osx dk ifjek.k xq.kkRed :i ls eq[;
DokUVe la[;k ?kVus ds lkFk c<+rk gSA
mijksDr dFkuksa ds lanHkZ es uhps fn, fodYiks esa
ls lgh mÙkj pqfu,A
(1) nksuksa dFku I rFkk dFku II vlR; gSaA
(2) nksuksa dFku I rFkk dFku II lR; gSaA
(3) dFku I vlR; gS ijUrq dFku II lR; gSA
(4) dFku I lR; gS ijUrq dFku II vlR; gSA
21. ,d /kkrq lrg ij 500 nm dk fofdj.k Mkyk x;k
gSA izdk'k fo|qr /kkjk ds fy, /kkrq dh nsgyh
vkofÙk
4.3 × 1014 Hz gSA mRlftZr bysDVªkWu dk osx
________× 105 ms–1 (fudVre iw.kkZad esa)
[iz;ksx djs: h = 6.63 × 10–34 Js, me = 9.0 × 10–31 kg]
22. gkbMªkstu ijek.kq dh f}rh; cksj d{kk esa bysDVªkuW
h2
dh xfrt ÅtkZ ds cjkcj gSA 10x dk eku
x ma 20
gS ________ ¼fudVre iw.kkZad esa½
(a0 cksj d{kk dh f=kT;k gS½A
[fn;k gS: p = 3.14]
23. 1 mW 'kfDr rFkk 1000 nm rjaxnS/;Z ds ,d o.khZ
¼,dy vkofÙk½ vojDr ijklekih ls 0.1 lsds.M esa
mkRlftZr QksVkWuksa dh la[;k x × 1013 gSA x dk eku
gS _____ A (fudVre iw.kk±d esa)
(h = 6.63 × 10–34 Js, C = 3.00 × 108 ms–1)
4 Atomic Structure ALLEN®
24. Ge(Z = 32) dh vk| voLFkk ds bysDVªkWfud

foU;kl esa ml = 0 ds x vkfcZVy iw.kZ:Ik ls Hkjs gSaA

x dk eku gS _______.

25. Zn+ vk;u ds ckáre bysDVªku

W ds fy, pqEcdh;
DokUVe la[;k dk eku gS_________A

¼fudVre iw.kk±d esa½

26. ,d 50 okWV dk cYc 795 nm rjaxnS/;Z dk ,do.khZ

yky izdk'k mRlftZr djrk gSA cYCk }kjk izfr
lsdsUM mRlftZr QksVkWuksa dh la[;k x × 1020 gSA
x dk eku gS _________. (fudVre iw.kk±d esa)

[fn;k x;k gS : h = 6.63 × 10–34 Js rFkk c = 3.0 ×

108 ms–1]

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 ALLEN® Atomic Structure 5
SOLUTION 5. Official Ans. by NTA (2)

1. Official Ans. by NTA (2) Sol. Z = 29 (Cu)

l=
h Cu2+ form [Cu(H2O)4]2+ complex ion with H2O.
Sol.
2 mqV
[Cu(H2O)4]2+ Þ Cu2+ [Ar]3d9, H2O ® WFL
l Li m p (e)V
= m Li = 8.3 m p
lp m Li (3e)(V) Cu2+
3d
l Li 1 1
= = = 0.2 = 2 ´ 10 -1 number of unpaired e– = 1
lp ´
8.3 3 5
m = 1(1 + 2) B.M.
2. Official Ans. by NTA (4)
Sol. According to Bohr's theory : m = 3 Þ 1.73 B.M. Þ round off ans. Þ 2

z 2 eV z2 6. Official Ans. by NTA (181)

(A) KE = 13.6 Þ KEa
n 2 atom n2
hc N A
Sol. E = ´
– z l 1000
(B) speed of e a
n
6.63 ´ 10- 34 ´ 3 ´ 108 ´ 6.02 ´ 10 23
=
\ v´ naz 663 ´ 10 -9 ´ 1000

= 3 × 6.02 × 10 kJ
v –
(C) Frequency of revolution of e =
2pr = 180.6 kJ

z2 7. Official Ans. by NTA (4)

\ frequency a
n3 Sol. n – l – 1 = 2
kq1q 2 kze2 ì n2 l=2
(D) F = = 2 ír a
r2 r î z
n–2–1=2
z
Þ Fa 2 n=5
æ n2 ö
ç ÷ 8. Official Ans by NTA (1)
è z ø
5
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z3 Sol. Dv = 90 ×
Þ Fa 100
n4

3. Official Ans. by NTA (3) = 4.5 m/s

Sol. Number of radial nodes = n – l – 1 h

Dv. Dx =
4pm
=3–0–1=2
h
Therefor corresponding graph is (D) Dx =
4pm.Dv
Hence answer is (3)
6.63 ´ 10 -34
=
4. Official Ans. by NTA (1) 4 ´ 3.14 ´ 0.01 ´ 4.5
Sol. Cs is used as electrodes in the photoelectric cell. = 1.17 × 10–33

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6 Atomic Structure ALLEN®
9. Official Ans. by NTA (9) 12. Official Ans. by NTA (2)
hc Sol. Mn3O4 shows magnetic properties.
Sol. Energy incident =
l
13. Official Ans. by NTA (2)
6.63 ´ 10 - 34 ´ 3.0 ´ 10 8
= eV Sol. Statement-I is false since Bohr's theory accounts
248 ´ 10 -9 ´ 1.6 ´ 10 -19
for the stability and spectrum of single
6.63 ´ 3 ´ 100
= electronic species (eg : He+, Li2+ etc)
248 ´ 1.6
= 0.05 eV × 100 = 5 eV Statement II is true.

Now using 14. Official Ans. by NTA (360)

E = f + K.E. Sol. Given chemical reaction:

5 = 3 + K.E. A ¾¾ ¾® B [DG]P, T = -49.4 kJ/mol

T 300 K

–19
K.E. = 2eV = 3.2 × 10 J DHrxn = 51.4 kJ/mol
h DSrxn = ?
for debroglie wavelength l =
mv Þ From the relation [DG]P, T = DH – TDS
1 2
K.E = mv DH rxn - [ DG]P,T
2 Þ DSrxn =
T
2KE
so v = [51.4 - (-49.4)] ´ 1000 J
m =
300 mol K
h
hence l = Þ DSrxn = 336
J
2KE ´ m mol K
6.63 ´ 10 -34 15. Official Ans. by NTA (6)
=
2 ´ 3.2 ´ 10 -19 ´ 9.1 ´ 10 -31 Sol. De-broglie-wave length of electron:
- 34 - 10
6.63 10 66.3 ´ 10 m ìïQ e - is accelerated
= ´ - 25 = h
7.6 10 7.6 le = í from rest
2m(KE) ïÞ KE = q ´ V
= 8.72 × 10
–10
m î

» 9 ´ 10 -10 m h
l=
2mqv
= 9Å
10. Official Ans. by NTA (0) 6.63 ´ 10 -34
=
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Sol. n = 4 and ml = –3 2 ´ 1.6 ´ 10 -19 ´ 9.1 ´ 10 -31 ´ 40 ´ 103

= 0.614 × 10–11 m
Hence, l value must be 3.
= 6.14 × 10–12 m
Now, number of radial nodes = n – l – 1 Nearest integer = 6
OR
=4–3–1=0
12.3
11. Official Ans. by NTA (2) l= Å
V
Sol. l = 0 Þ 's' orbital
12.3
n–l–1=2 = = 6.15 ´ 10 -12 m
200
n –1=2
Ans. is 6
n=3

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 ALLEN® Atomic Structure 7
16. Official Ans. by NTA (2) 19. Official Ans. by NTA (4)
Sol. Total energy provided by Sol. As in Thomson model, protons are diffused
(charge is not centred) a- particles deviate by
1000
Source per second = = 100J small angles and due to repulsion from protons,
10
their speed decreases.
hc
Energy required to eject electron = 20. Official Ans. by NTA (3)
l
Sol. Velocity of electron in Bohr's atom is given by
-34
6.626 ´ 10 Z
= -9
´ 3 ´ 10 8 Vµ
400 ´ 10 n
Number of electrons ejected Z = atomic number of atom, corresponds to +ve
100 charge so as Z increase velocity increases so
=
6.626 ´ 10 -34 ´ 3 ´ 10 8 statement-I is wrong.
400 ´ 10 -9 and as 'n' decreases velocity increases so
statement-II is correct.
400 ´ 10 -7 ´ 10 26
=
6.626 ´ 3 21. Official Ans. by NTA (5)

40 ´ 10 -20 e–
= l=500nm
6.626 ´ 3
Sol.
= 2.01 × 1020
17. Official Ans. by NTA (58)
0.02 u : speed of electron having max. K.E.
Sol. Dn = ´ 5 ´106 = 103 m / s
100 Þ from Einstein equation : E = f + K.E.max
h hc 1
Dx . Dn = Þ =u
h 0 + mv2
4 pm l 2
-34
Þ 6.63 ´ 10 ´ -39´ 10 = 6.63 ´ 10 -34 ´ 4.3 ´ 1014 + 1 mv 2
8
6.63 ´ 10–34
3
x ´ 10 ´ 10 =
–9
500 ´ 10 2
4´ 3.14 ´ 9.1´10 –31 -20
6.63 ´ 30 ´ 10 1
Þ = 6.63 ´ 4.3 ´ 10 -20 + mv 2
x × 10–9 × 103 = 0.058 × 10–3 5 2

0.058 ´ 10 –6 1
x= = 58 Þ 11.271 × 10–20 J = × 9 × 10–31 × u2
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10 –9 2

18. Official Ans. by NTA (4) Þ u = 5 ´ 10 5 m / sec.

Sol. Rutherford's gold foil experiment only proved 22. Official Ans. by NTA (3155)
nh
that electrons are held towards nucleus by Sol. mvr =
2p
electrostatic forces of attraction and move in
n2 h 2 4h 2
K.E. = =
circular orbits with very high speeds. 8p2 mr 2 8p m(4a 0 )2
2

Bohr's model gave exact formula for 2

æ 4 ö h
=ç 2 ÷ 2
simultaneous calculation of speed & distance of è 8p ´ 16 ø ma0
electron from the nucleus, something which was Þ x = 315.507
deemed impossible according to Heisenberg. Þ 10x = 3155 (nearest integer)

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8 Atomic Structure ALLEN®
23. Official Ans. by NTA (50)
Sol. Energy emitted in 0.1 sec.
J
< 0.1 sec .≥10 -3 = 10–4 J
s
If 'n' photons of l = 1000 nm are emitted,
hc
then ; 10 -4 < n ≥
κ
n ≥6.63≥10 -34 ≥3≥108
Þ 10 -4 <
1000 ≥10 -9
Þ n = 5.02 × 1014 = 50.2 × 1013
Þ 50 (nearest integer)
24. Official Ans. by NTA (7)
1s2 2s2 2p6 3s 3p6 4s2 3d10 4p2
Sol.
m = 0 0 –1 0 +1 0 –1 0 +1 0 –2 –1 0 +1 +2
(1) (1) (1) (1) (1 (1) (1)

Completely filled orbital with ml = 0 are

= 1+1+1+1+1+1+1
=7
So Answer is 7
25. Official Ans. by NTA (0)

Sol. Zn+ ® 1s22s22p63s23p63d104s1

Outermost electron is in 4s subshell
m=0
26. Official Ans. by NTA (2)
Sol. Total energy per sec. = 50 J
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n ´ 6.63 ´ 10 –34 ´ 3 ´ 108

50 =
795 ´ 10 -9
n = 1998.49 × 1017 [ n = no. of photons per second]
= 1.998 × 1020
; 2 × 1020
= x × 1020
x=2