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Sondhi RMP 69 315 1997
Sondhi RMP 69 315 1997
D. Shahar
Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544
A quantum system can undergo a continuous phase transition at the absolute zero of temperature as
some parameter entering its Hamiltonian is varied. These transitions are particularly interesting for,
in contrast to their classical finite-temperature counterparts, their dynamic and static critical behaviors
are intimately intertwined. Considerable insight is gained by considering the path-integral description
of the quantum statistical mechanics of such systems, which takes the form of the classical statistical
mechanics of a system in which time appears as an extra dimension. In particular, this allows the
deduction of scaling forms for the finite-temperature behavior, which turns out to be described by the
theory of finite-size scaling. It also leads naturally to the notion of a temperature-dependent dephasing
length that governs the crossover between quantum and classical fluctuations. Using these ideas, a
scaling analysis of experiments on Josephson-junction arrays and quantum-Hall-effect systems is
presented. [S0034-6861(97)00501-1]
Reviews of Modern Physics, Vol. 69, No. 1, January 1997 0034-6861/97/69(1)/315(19)/$12.85 © 1997 The American Physical Society 315
316 Sondhi et al.: Continuous quantum phase transitions
disorder in a conductor near its metal-insulator transi- Suzuki, 1976), dates back to the work of Hertz (1976),5 it
tion (which determines the conductivity at zero tem- remains unknown or poorly understood in the wider
perature). These and other QPTs raise new and fascinat- community, and extracting it from the literature remains
ing issues for theory and experiment, most notably the a daunting task. It is our hope here to communicate this
inescapable necessity of taking quantum effects into ac- set of ideas to a wider audience and, in particular, to be
count. helpful to newcomers to this field, experimentalists and
Exactly what quantum effects are at issue is a bit theorists alike.
subtle. As a corollary of our definition, all Our discussion is organized as follows. In Sec. II we
finite-temperature3 transitions are to be considered introduce the statistical mechanics of quantum systems
‘‘classical,’’ even in highly quantum-mechanical systems and the path-integral (Feynman, 1972) approach to it,
like superfluid helium or superconductors. It is not that which is an extremely useful source of intuition in these
quantum mechanics is unimportant in these cases, for in problems. A running theme throughout this discussion is
its absence there would not be an ordered state, i.e., the the intertwining of dynamics and thermodynamics in
superfluid or superconductor. Nevertheless, sufficiently quantum statistical mechanics. In Sec. III we describe
close to the critical point, quantum fluctuations are im- the general features of a QPT at T50 and how a non-
portant at the microscopic scale but not at the longer zero temperature alters the physics. This leads naturally,
length scales that control the critical behavior; in the in Sec. IV, to a discussion of what kind of scaling behav-
jargon of statistical mechanics, quantum mechanics is ior in experiments is evidence of an underlying QPT.
needed for the existence of an order parameter,4 but it is We illustrate this using particular examples from phase
classical thermal fluctuations that govern it at long wave- transitions in quantum-Hall systems. We end in Sec. V
lengths. For instance, near the superfluid lambda transi- with a brief summary and pointers to work on QPTs in
tion in 4 He, the order parameter is a complex-valued other interesting systems. Readers interested in a highly
field that is related to the underlying condensate wave informative discussion at a higher technical level should
function. However, its critical fluctuations can be cap- consult the recent beautiful review article by Sachdev
tured exactly by doing classical statistical mechanics with (1996).
an effective Hamiltonian for the order-parameter field
[for instance, the phenomenological Landau-Ginsburg
free-energy functional (Goldenfeld, 1992)].
The physics behind the classical nature of finite-
temperature transitions is the following: phase transi- II. QUANTUM STATISTICAL MECHANICS: GENERALITIES
tions are quite generally accompanied by a divergent
correlation length and correlation time, i.e., the order Before we discuss what happens in the vicinity of a
parameter (e.g., the magnetization in a ferromagnet) QPT, let us recall some very general features of the sta-
fluctuates coherently over increasing distances and ever tistical mechanics of quantum systems. The quantities of
more slowly. The latter implies that there is a frequency interest are the partition function of the system, which is
v * associated with the critical fluctuations that vanishes governed by a Hamiltonian H,
at the transition. A quantum system behaves classically Z ~ b ! 5Tre 2 b H , (1)
if the temperature exceeds all frequencies of interest,
and, since \ v * !k B T c close to the transition, the critical and the expectation values of an arbitrary operator O,
fluctuations will behave classically. 1
This argument also shows that QPTs, where T c 50, ^O&5 Tr~ Oe 2 b H ! . (2)
are qualitatively different, and their critical fluctuations Z~ b !
must be treated quantum mechanically. In the following In writing these formal expressions we have assumed a
we will describe the language and physical pictures that finite temperature, k B T51/b . To get at what happens
enable such a treatment and that have come into com- exactly at T50 we take the T→0 limit. Upon doing so,
mon usage among practitioners in the field in the last the free energy, F52(1/b )lnZ(b), becomes the ground-
few years. Although much of this wisdom, which has its state energy, and the various thermal averages become
roots in work on quantum Ising models (Young, 1975; ground-state expectation values. From Z we can get all
the thermodynamic quantities of interest. Expectation
values of operators of the form O[A(rt)A(r8 t 8 ), where
3
In an almost standard abuse of language, we refer to non- A is a space-time-dependent operator, are related to the
zero temperatures as finite. results of dynamical scattering and linear-response mea-
4
An order parameter is a quantity which is zero in the disor- surements. For example, A might be the local electron
dered phase and nonzero in the ordered state. In systems that density (X-ray scattering) or current (electrical trans-
spontaneously break some symmetry in the ordered state, the port).
nature (and value) of the order parameter reflects this broken
symmetry. Thus, for example, in an Ising ferromagnet the mag-
5
netization is a positive or negative real number indicating the We should note that the contemporaneous explosion of
difference in populations of the up and down spins (see Gold- work on the one-dimensional electron gas (Emery, 1979) pro-
enfeld, 1992). vided important, early illustrations of these ideas.
C. Quantum-classical analogies
This specific example of the equivalence between a FIG. 4. Illustration of discrete space-time lattices with the
quantum system and a classical system with an extra same coupling K. The lattice constant in the time direction is
the same d t in both cases, but the corresponding physical tem-
‘‘temporal’’ dimension illustrates several general corre-
perature (determined from \ b 5L t d t ) for the lattice in the
spondences between quantum systems and their effec-
lower panel is half that of the lattice in the upper panel.
tive classical analogs.
Standard lore tells us that the classical XY model has temperature is not the same. The only difference is that
an order-disorder phase transition as its temperature K one lattice is larger in the time direction than the other.
is varied. It follows that the quantum array has a phase In developing intuition about this picture, it may be
transition as the ratio of its charging and Josephson en- helpful to see how classical physics is recovered at very
ergies is varied. One can thus see why it is said that the high temperatures. In that limit, the time interval \ b is
superconductor-insulator quantum phase transition in a very short compared to the periods associated with the
1-dimensional Josephson-junction array is in the same natural frequency scales in the system, and typical time
universality class as the order-disorder phase transition histories will consist of a single static configuration that
of the 1+1-dimensional classical XY model. [One crucial is the same at each time slice. The dynamics therefore
caveat is that the XY-model universality class has strict drops out of the problem, and a Boltzmann weight
particle-hole symmetry for the bosons (Cooper pairs) on exp(2bHclassical) is recovered from the path integral.
each site. In reality, Josephson-junction arrays contain The thermodynamic phases of the array can be iden-
random ‘‘offset charges’’ that destroy this symmetry and tified from those of the XY model. A small value of K
change the universality class (Wallin et al., 1994), a fact corresponds to low temperature in the classical system,
which is all too often overlooked.] so the quantum system will be in the ordered ferromag-
We emphasize again that K is the temperature only in netic phase of the XY model, as illustrated in Fig. 2.
the effective classical problem. In the quantum case the There will be long-range correlations in both space and
physical temperature is presumed to be nearly zero and time of the phase variables.14 This indicates that the Jo-
only enters as the finite size of the system in the sephson coupling dominates over the charging energy,
imaginary-time direction. The coupling constant K, the and the order parameter is not fluctuating wildly in
fake ‘‘temperature,’’ is a measure not of thermal fluctua- space or time, so that the system is in the superconduct-
tions, but of the strength of quantum fluctuations, or ing phase. For large K the system is disordered, and the
zero-point motion of the phase variables.13 This notion order parameter fluctuates wildly. The correlations de-
is quite confusing, so the reader might be well advised to cay exponentially in space and time as illustrated in Fig.
pause here and contemplate it further. It may be useful 3. This indicates that the system is in the insulating
to examine Fig. 4, where we show a space-time lattice phase, where the charging energy dominates over the
for the XY model corresponding to a Josephson- Josephson coupling energy.
junction array at a certain temperature and at a tem- Why can we assert that correlations that decay expo-
perature half as large. The size of the lattice constant in nentially in imaginary time indicate an excitation gap
the time direction @ d t in the path integral in Eq. (5)] and characteristic of an insulator? This is readily seen by
K are the same in both cases even though the physical noting that the Heisenberg representation of an opera-
tor in imaginary time is
A ~ t ! 5e H t /\ Ae 2H t /\ , (10)
12
Because particle number is conjugate to the phase
@ n̂ j 52i ] / ] u j ], a state of indefinite phase on a site has definite and thus the (ground state) correlation function for any
charge on that site, as would be expected for an insulator. operator can be expressed in terms of a complete set of
13
Zero-point motion of the phase variables is caused by the states as
fact that there is an uncertainty relation between the phase and
the number of Cooper pairs on a superconducting grain. The
14
more well-defined the phase is, the larger the uncertainty in In this special 111D case, the correlations happen to decay
the charge is. This costs capacitive energy. algebraically rather than being truly of infinite range.
TABLE I. Analogies.
Quantum Classical
ture, this argument gets modified—the relevant uncer- found the simplest possible result, z51. As noted, how-
tainty in the energy is now k B T, and the characteristic ever, this is a special isotropic case, and, in general, z
time scale is \ b . In either case, the linkage between dy- Þ1.
namics and thermodynamics is clear. As a consequence of the diverging j and j t , it turns
out that various physical quantities in the critical region
close to the transition have (dynamic) scaling forms, i.e.,
their dependence on the independent variables involves
III. QUANTUM PHASE TRANSITIONS homogeneity relations of the form
We now turn our attention to the immediate neigh- O~ k, v ,K ! 5 j d OO ~ k j , vj t ! , (15)
borhood of a quantum critical point. In this region the where d O is called the scaling dimension of the observ- 18
mapping of the quantum system to a able O measured at wave vector k and frequency v . The
(d11)-dimensional classical model will allow us to meaning of (and assumption behind) these scaling forms
make powerful general statements about the former us- is simply that, close to the critical point, there is no char-
ing the extensive lore on critical behavior in the latter. acteristic length scale other than j itself19 and no char-
Hence most of the following will consist of a reinterpre- acteristic time scale other than j t . Thus the specific
tation of standard ideas in classical statistical mechanics value of the coupling K does not appear explicitly on the
in terms appropriate for d11 dimensions, where the ex- right-hand side of Eq. (15). It is present only implicitly
tra dimension is imaginary time. through the K dependence of j and j t .
A. T50: Dynamic scaling
If we specialize to the scale-invariant critical point, the
scaling form in Eq. (15) is no longer applicable, since the
In the vicinity of a continuous quantum phase transi- correlation length and time have diverged to infinity. In
tion we will find several features of interest. First, we this case the only characteristic length left is the wave-
will find a correlation length that diverges as the transi- length 2 p /k at which the measurement is being made,
tion is approached. That diverging correlation lengths whence the only characteristic frequency is v̄ ;k z . As a
are a generic feature of classical critical points immedi- result we find the simpler scaling form
ately tells us that diverging lengths and diverging times O~ k, v ,K c ! 5k 2d OÕ ~ k z / v ! , (16)
are automatically a generic feature of quantum critical
points, since one of the directions in the which reflects the presence of quantum fluctuations on
(d11)-dimensional space is time. This makes sense all length and time scales.20
from the point of view of causality. It should take a The utility and power of these scaling forms can be
longer and longer time to propagate information across illustrated by the following example. In an ordinary clas-
the distance of the correlation length. sical system at a critical point in d dimensions where the
Actually, we have to be careful—as we remarked ear- correlation length has diverged, the correlations of many
lier, the time direction might easily involve a different operators typically fall off as a power law
set of interactions than the spatial directions, which lead 1
to a distinct correlation ‘‘length’’ in the time direction. G̃ ~ r ! [ ^ O~ r! O~ 0! & ; ~ d221 h d ! , (17)
r
We will call the latter j t , reserving the symbol j for the
spatial correlation length. Generically, at T50 both so that the Fourier transform diverges at small wave vec-
j (K) and j t (K) diverge as d [K2K c →0 in the tors like
manner,17
G ~ k ! ;k 221 h d . (18)
j ;udu2n,
j t; j z. (14) Suppose that we are interested in a QPT for which the
These asymptotic forms serve to define the correlation (d11)-dimensional classical system is effectively isotro-
length exponent n and the dynamical-scaling exponent
z. The nomenclature is historical and refers to the ex- 18
tension of scaling ideas from the study of static classical The scaling dimension describes how physical quantities
change under a renormalization-group transformation in which
critical phenomena to dynamics in the critical region as-
short-wavelength degrees of freedom are integrated out. As
sociated with critical slowing down (Ferrell, 1968, Ho- this is partly a naive change of scale, the scaling dimension is
henberg and Halperin, 1977). In the classical problem often close to the naive (‘‘engineering’’) dimension of the ob-
the extension was a nontrivial step, which deserves a servable, but (except at special, nongeneric fixed points) most
proper label. As remarked before, the quantum problem operators develop ‘‘anomalous’’ dimensions (see Goldenfeld,
involves statics and dynamics on the same footing, and 1992).
so nothing less is possible. For the case of the 19
For a more precise statement that includes the role of cutoff
Josephson-junction array considered previously, we scales, see Goldenfeld (1992).
20
Equivalently, we could have argued that the scaling func-
tion on the right-hand side of Eq. (15) must, for large argu-
17
Here and in the following we do not write the microscopic ments x and y, have the form O(x,y);x 2d OÕ(x z y 21 ) in or-
length and time scales that are needed to make dimensional der for the observable to have a sensible limit as the critical
sense of these equations (see Goldenfeld, 1992). point is approached.
Our considerations in this section also show us why one is often dealing with models of noninteracting or
the phase boundary (solid line) and the crossover line even interacting electrons, whose quantum coherence is
(dashed line) in Fig. 5 reach zero temperature in a sin- limited by degrees of freedom, e.g., phonons, that are
gular way as the quantum critical point is approached. not being considered explicitly. This has given rise to a
Simple dimensional analysis tells us that the characteris- tradition of thinking of l f as being a length which is set
tic energy scale (D for the insulator, T KT for the super- externally. Unfortunately, this sort of separation of de-
fluid) vanishes near the critical point like \/ j t , implying grees of freedom should not be expected to work near a
QPT, since there one needs to keep track of all relevant
interactions. If a given interaction, e.g., the Coulomb in-
teraction, is relevant then it already sits in the Hamil-
D; u K2K c u n z u ~ K2K c ! , tonian we need to solve and enters the calculation of
L f . In contrast, if an interaction, e.g., coupling to
T KT ; u K2K c u n z u ~ K c 2K ! . (22)
phonons, is irrelevant then we do not expect it to enter
the low-energy physics as it should not in general affect
the quantum-classical crossover either.
C. The quantum-classical crossover and the dephasing
Another way of formulating this is in terms of dephas-
length ing rates. Since temperature is the only energy scale
available, a generic quantum critical point will be char-
We now turn to a somewhat different understanding acterized by a dephasing rate j 21 t that is linear in T,
and interpretation of the effect of temperature that is since we expect \/ j t ;k B T. By definition, irrelevant in-
conceptually of great importance. Recall that the T50 teractions, e.g., phonons, have an effective coupling to
critical points of interest to us are gapless and scale in- the electrons that scales to zero as one examines the
variant; i.e., they have quantum fluctuations at all fre- system on larger length and time scales. Hence such cou-
quencies down to zero. Temperature introduces a new plings will produce a dephasing rate that vanishes as
energy scale into the problem. Modes whose frequencies T p with p.1 and will therefore become negligible com-
are larger than k B T/\ are largely unaffected, while pared to T at low temperatures.23
those with frequencies lower than k B T/\ become occu- Thus we conclude that L f is the unique dephasing
pied by many quanta, with the consequence that they length in the vicinity of a generic quantum critical point.
behave classically. Put differently, the temperature cuts Further discussion and explicit examples of the dissipa-
off coherent quantum fluctuations in the infrared. tive dynamics near a critical point can be found in the
What we want to show next is that this existence of a article by Sachdev (1996).
quantum to classical crossover frequency (k B T/\) leads
to an associated length scale for the same crossover, as
alluded to in the previous section. We shall refer to this
length scale as the dephasing length, L f , associated
with the QPT. The temperature dependence of L f is IV. EXPERIMENTS: QUANTUM PHASE TRANSITIONS IN
easy enough to calculate. From our imaginary-time for- QUANTUM-HALL SYSTEMS
malism we recall that quantum fluctuations are fluctua-
tions in the temporal direction. Evidently these cannot We now turn from our somewhat abstract consider-
be longer ranged than the size of the system in the time ations to examples of how one actually looks for a QPT
direction, L t 5\ b . Since spatial and temporal correla- in experiments. The basic idea is relatively simple. We
tions are linked via j t ; j z , it follows that the spatial try to arrange that the system is close to the conjectured
correlations linked with quantum fluctuations are not critical point in parameter space (K;K c ) and tempera-
longer ranged than L 1/z ture (T;0) and look for mutually consistent evidence
t Since the spatial range of quan-
tum fluctuations is the dephasing length, we find of scaling with various relevant parameters. By these we
L f ;1/T 1/z . mean either the deviation of the quantum coupling con-
We use the term ‘‘dephasing’’ deliberately. Readers stant from its critical value K2K c , the temperature, or
may know, from other contexts where quantum effects the wave vector, frequency, and amplitude of a probe.
are observed, that such observation requires phase co- We call these relevant parameters since, when they are
herence for the relevant degrees of freedom. In other
words, interference terms should not be wiped out by
23
interactions with an ‘‘environment,’’ i.e., other degrees Equivalently, the associated length scale will diverge faster
of freedom (Stern et al., 1990). If dephasing takes place than L f as T→0 and hence will not control the quantum-
and the phase coherence is lost, the resulting behavior is classical crossover of the relevant degrees of freedom, since it
is the shortest length that counts. There are times when this
classical. Thus our definition of L f is in line with that
sort of reasoning can break down. These situations involve
notion. However, readers familiar with the notion of a operators that are irrelevant, i.e., decrease in the infrared, but
dephasing length l f in mesoscopic condensed matter cannot be naively set to zero, since that produces extra singu-
physics or the theory of Anderson localization might be larities. Such operators are known in the trade as ‘‘dangerous
concerned at our appropriation of this notion. The con- irrelevant operators,’’ and we will meet an example in the next
cern arises because, in the standard lore in those fields, section in the context of current scaling.
tions between neighboring phases are first order, since the fine structure constant, can be measured to high ac-
r H jumps discontinuously by a discrete amount between curacy on samples whose geometry is certainly not
them, but they are not. Qualitatively, they involve the known to an accuracy of one part in 107 .
quasiparticles of each phase, which are localized on a What we have said above is a statement about the
length scale, the localization length, that diverges as the engineering dimensions of resistance and resistivity. Re-
transition is approached from either side. However, as markably, this also has an analog when it comes to their
these quasiparticles are always localized at the longest scaling dimensions at a quantum critical point, i.e., their
length scale away from criticality, they do not lead to scaling dimensions vanish.27 Consequently, the resistivi-
dissipation ( r L 50) and do not renormalize the Hall re- ties vary as the zeroth power of the diverging correlation
sistivities of their respective phases. Exactly at the tran- length on approaching the transition, i.e., will remain
sition they are delocalized and lead to a nonzero r L . constant on either side. Precisely at criticality they will
The shift in r H on moving through the transition can be be independent of the length scale used to define them
understood in terms of either set of quasiparticles con- but can take values distinct from the neighboring phases.
densing into a fluid state, as there is an underlying dual- In this fashion we have recovered from a purely scal-
ity in this description. ing argument our earlier conclusion that even though
In our description of the QH phases and phase tran- the quantum-Hall transitions are continuous, the resis-
sitions we have employed a common language for all of tivities at T50 differ from the quantized values only at
them. We should note that this does not ipso facto imply critical points. Detecting the continuous transitions then
that all quantum-Hall transitions are in the same univer- requires measurements at a nonzero temperature, fre-
sality class; however, experiments, as we discuss later, do quency, or current, all of which lead to a more gradual
seem to suggest that conclusion. The reason for this cau- variation, which can then be examined for scaling behav-
tion is that different QH states can arise from quite dif- ior. Below are some examples of how that works.
ferent physics at the microscopic level. States with inte-
ger n B arise, to first approximation, from single-particle A. Temperature and frequency scaling
physics. An electron in a plane can occupy a Landau
level which comprises a set of degenerate states with Consider the caricature of a typical set of data shown
energy (n11/2)\ v c . These reflect the quantization of in Fig. 8. Note that r H interpolates between its quan-
the classical cyclotron motion having frequency tized values over a transition region of nonzero width,
v c 5eB/m and the arbitrariness of the location of that while r L is peaked in the same region but is extremely
motion in the plane. When an integer number of Landau small outside the region. The change in the shape of
levels are full (corresponding to an integer filling factor) these curves with temperature can be understood on the
excitations involve the promotion of an electron across basis of the finite-size scaling form
the cyclotron gap, and we have the commensuration/gap
r L/H ~ B,T, v ! 5f L/H ~ \ v /k B T, d /T 1/n z ! , (24)
nexus necessary for the observation of the (integer)
QHE. In contrast, fractional filling factors imply frac- where d [(B2B c )/B c measures the distance to the
tional occupations of the Landau levels, with attendant zero-temperature critical point. This form is equivalent
macrosopic degeneracies, and they exhibit a gap only to the general finite-size scaling form in Eq. (21) except
when the Coulomb interaction between the electrons is that we have assumed the limit k50 and used the pre-
taken into account (the fractional QHE).26 Readers in- viously cited result that the scaling dimension of the re-
terested in the details of this magic trick are encouraged sistivity vanishes in d52 (Fisher et al., 1990; Cha et al.,
to peruse the literature. 1991). The first argument in the scaling function here is
Before proceeding to the details of experiments, we the same as the second in Eq. (21). The second argu-
need to discuss two important points about the units of ment in the scaling function here is simply a power of
the quantities measured in electrical transport where the third argument in Eq. (21). This change is inconse-
two spatial dimensions are rather special. Experiments quential; it can be simply absorbed into a redefinition of
measure resistances, which are ratios of total voltages to the scaling function.
current, and these are related to local resistivities by ra- First, let us consider a DC or v 50 measurement. In
tios of cross-sectional ‘‘areas’’ to lengths. In two dimen- this case our scaling form implies that the resistivities
sions, a cross-sectional area is a length, and conse- are not independent functions of d (or B) and T but
quently no factor of length intervenes between the instead are functions of the single scaling variable
global and local quantities. In the QH phases this has d /T 1/n z . Hence the effect of lowering T is to rescale the
the important implication that no geometrical factor af- deviation of the field from its critical value by the factor
fects the measurement of the Hall resistance, which is T 1/n z . It follows that the transition appears sharper and
why the ratio of fundamental constants h/e 2 , and hence sharper as the temperature is lowered; its width vanishes
26 27
This leads to the remarkable feature that, while the quasi- See (Fisher et al., 1990; Cha et al., 1991). This is analogous
particles of the integer states are essentially electrons, those of to the behavior of the superfluid density at the classical
the fractional states are fractionally charged and obey frac- Kosterlitz-Thouless phase transition (Chaikin and Lubensky,
tional statistics. 1995) and leads to a universal jump in it.
as a universal power of the temperature, DB;T 1/n z . In tering or relaxation rate associated with this coupling.
Fig. 9 we show the pioneering data of Wei et al. (1988) Since the coupling is irrelevant, it will, as noted earlier,
that indeed shows such an algebraic dependence for sev- give a scattering rate that vanishes as AT p where p is
eral different transitions, all of which yield the value greater than unity and A is nonuniversal (Sondhi and
1/n z'0.42. These transitions are between integer Kivelson, 1992) (e.g., it depends on the precise value of
quantum-Hall states. Remarkably, this temperature- the electron-phonon coupling constant for the material).
scaling behavior seems to be ubiquitous at quantum- In contrast, what is observed is that the relaxation rate
Hall transitions and suggests that there is a single under- obeys 1/t 5Ck B T/\, where C is a universal (Sachdev,
lying fixed point for all of them. It was shown by Engel 1996) dimensionless constant of order unity.
et al. (1990) that it holds at transitions between two frac- It is important to note that frequency scaling does not
tional quantum-Hall states. Subsequently, Wong et al. give us any new information on exponents that we did
(1995) found the same scaling for the transition between not already have from the temperature scaling. The
a Hall state and the insulator. In Fig. 10 we show some main import of frequency scaling is its ability to confirm
recent data of Shahar (1995) near another such transi- the quantum critical nature of the transition by showing
tion, plotted both as a function of the magnetic field at that the characteristic time scales have diverged, leaving
several values of T and against the scaling variable the temperature itself as the only frequency scale.
d /T 1/n z . This illustrates the data collapse characteristic of
the critical region.
Consider now the results of measurements at nonzero B. Current scaling
frequencies. In their full generality these require a two-
variable scaling analysis (Engle et al., 1995), but we fo- A third relevant parameter that is experimentally use-
cus instead on two distinct regimes. In the regime ful is the magnitude of the measuring current or, equiva-
\ v !k B T we expect that the behavior of the scaling lently, of the applied electric field. In talking about re-
function will be governed by its v 50 limit analyzed pre- sistivities we have assumed that there is an ohmic regime
viously, i.e., at small v we expect the scaling to be domi- at small currents, i.e., a regime in which the voltages are
nated by T. In the second regime, \ v @k B T, we expect linear in the current. In general, there is no reason to
the scaling to be dominated by v and the scaling func- believe that the nonlinear response can be related to
tion to be independent of T. In order for the tempera- equilibrium properties, i.e., there is no fluctuation-
ture to drop out, the scaling function in Eq. (24) must dissipation theorem beyond the linear regime. However,
have the form in the vicinity of a critical point we expect the dominant
nonlinearities to come from critical fluctuations. At
f ~ x,y ! ;f˜ ~ yx 21/n z ! (25) T50 the electric-field scale for these can be estimated
for large x so that the scaling variables conspire to ap- from an essentially dimensional argument. We start by
pear in the combination defining a characteristic length l E associated with the
from coupling to some irrelevant degree of freedom From this we find that the nonlinear DC resistivities for
were important, one would expect the crossover to take a 2D system obey the scaling forms
place when v t '1, where 1/t is some microscopic scat-
r L/H ~ B,T,E ! 5g L/H ~ d /T 1/n z , d /E 1/n ~ z11 ! ! . (30)
This is a very useful result because it tells us that
28 electric-field scaling will give us new information not
The conductivities scale in exactly the same fashion as the
resistivities. available from temperature scaling alone. From tem-
exponent n '2.3 is consistent with numerical calcula- ductivity (Chakravarty et al., 1989; Sachdev and Ye,
tions of the behavior of noninteracting electrons in a 1992; Chubukov and Sachdev, 1993; Chubukov et al.,
strong magnetic field (Huckenstein, 1995). Also, the 1994; Sachdev, 1994; Sachdev et al., 1994; Sachdev,
critical resistivities at the transition from the n B 51 state 1996), and magnetic transitions in metals (Altshuler
to the insulator are also consistent with these calcula- et al., 1995; Hertz, 1976; Millis, 1993). This list is by no
tions (Huckestein, 1995). This agreement is still a puzzle means exhaustive, and we are confident that it will con-
at this time, especially as the value of the dynamic scal- tinue to expand for some time to come!
ing exponent z'1 strongly suggests that Coulomb inter-
actions are playing an important role. The evidence for a ACKNOWLEDGMENTS
super-universality of the transitions, however, does have
some theoretical support in the form of a set of physi- It is a pleasure to thank R. N. Bhatt, M. P. A. Fisher,
cally appealing ‘‘correspondence rules’’ (Kivelson et al., E. H. Fradkin, M. P. Gelfand, S. A. Kivelson, D. C. Tsui,
1992). Unfortunately, their a priori validity in the critical and H. P. Wei for numerous helpful conversations. We
regions is still unclear (Lee and Wang, 1996). In sum- are particularly grateful to K. A. Moler, D. Belitz, S.
mary, theorists have their work cut out for them! Nagel, T. Witten, T. Rosenbaum, and U. Zuelicke for
comments on early versions of the manuscript. D.S. was
V. CONCLUDING REMARKS supported by the NSF, the work at Indiana was sup-
ported by NSF grants DMR-9416906, DMR-9423088,
Let us briefly recapitulate our main themes. Zero- and DOE grant DE-FG02-90ER45427, and S.L.S. was
temperature phase transitions in quantum systems are supported by the NSF through DMR-9632690 and by
fundamentally different from finite-temperature transi- the A. P. Sloan Foundation.
tions in classical systems in that their thermodynamics
and dynamics are inextricably mixed. Nevertheless, by
APPENDIX
means of the path-integral formulation of quantum me-
chanics, one can view the statistical mechanics of a In this Appendix we briefly outline the derivation
d-dimensional T50 quantum system as the statistical (Wallin et al., 1994) of the expression for the matrix el-
mechanics of a (d11)-dimensional classical system with ements
a fake temperature that is some measure of zero-point
fluctuations in the quantum system. This allows one to M[ ^ $ u ~ t j11 ! % u e 2 ~ d t /\ ! H u $ u ~ t j ! % & (A1)
apply ideas and intuition developed for classical critical appearing in Eq. (6). The Hamiltonian contains a ‘‘ki-
phenomena to quantum critical phenomena. In particu- netic energy’’
lar this leads to an understanding of the T Þ 0 behavior
of the quantum system in terms of finite-size scaling and
to the identification of a T-dependent length scale L f
T5
C
2 (j V 2j 5 2C (j
E
S 2i
]
]uj D 2
, (A2)
that governs the crossover between quantum and classi-
cal fluctuations. The identification of QPTs in experi- where E C [(2e) 2 /C, and a ‘‘potential energy’’
ments relies upon finding scaling behavior with relevant V[2E J cos~ û j 2 û j11 ! . (A3)
parameters. These are the temperature itself and the fre-
quency, wavelength, and amplitude of various probes. For sufficiently small d t we can make the approximation
Additional signatures are universal values of certain di- e 2 ~ d t /\ ! H 'e 2 ~ d t /\ ! T e 2 ~ d t /\ ! V . (A4)
mensionless critical amplitudes, such as the special case
of resistivities at critical points in conducting systems in Inserting a complete set of angular-momentum eigen-
d52, and, more generally, amplitude ratios. states u $ m k % & (defined for a single site by
In this Colloquium we have illustrated these ideas in ^ u k u m k & 5e im k u k ) yields
the context of a single system, the two-dimensional elec-
tron gas in the quantum-Hall regime. The ideas them- M5 ( ^ $ u ~ t j11 ! % u e 2~ d t /\ !Tu $ m k % &
$m%
selves are much more widely applicable. Interested
readers may wish to delve, for example, into work on 3^ $ m k % u e 2 ~ d t /\ ! V u $ u ~ t j ! % & . (A5)
the one-dimensional electron gas (Luther and Peschel,
We can now take advantage of the fact that V is diago-
1975; Emery, 1979), metal-insulator transitions in zero
nal in the angle basis and T is diagonal in the angular-
magnetic field (‘‘Anderson-Mott transitions’’) (Belitz
momentum basis to obtain
and Kirkpatrick, 1994), superconductor-insulator transi-
( e 2~ d t /2\ !E ( m e im [ u ~ t
tions (Chakravarty et al., 1986, 1989; Weichman, 1988; 2
M5 C k k k j11 ! 2 u k ~ t j ! ]
Weichman and Kim, 1989; Batrouni et al., 1990; Wen $m%
k
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