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1 1231493 The number of diagonal of a polygon of 20 sides is :

(A) 25 (B) 150 C


(C) 170 (D) 210
2 1231494 Total number of 5 digit numbers having all different digits and divisible by 4 that can be formed using the digits
{1, 3, 2, 6, 8, 9} , is equal to:

A
(A) 192 (B) 32
(C) 1152 (D) 384
3 1231495 Number of way in which 5 boys and 4 girls can be arranged on a circular Table such that no two girls sit together
and two particular boys are always together is:

(A) 576 (B) 864 D


(C) 1152 (D) 288
4 1231496 The number of even divisors of 504 is:

(A) 6 (B) 24 C
(C) 18 (D) 12
5 1231497 The number of ways in which the letters of word AGRUMENT can be arranged so that only consonants occur at
both ends is:

(A) 3! × 5! (B) 14400 B


(C) 41000 (D) None of these
6 1231498 The number of even proper divisors of 1008 is:

(A) 23 (B) 24 A
(C) 22 (D) None of these
7 1231499 Total number of 5 digit numbers, having all different digits and divisible by 3, that can be formed using the digits
{0, 1, 2, 3, 4, 5} is equal to:

D
(A) 120 (B) 213
(C) 93 (D) 216
8 1231500 If the total number of selections that can be made from n different books each having 5 copies taking at least 2
copies of each books is 256, then n =

(A) 3 (B) 4 B
(C) 5 (D) None of these
9 1231501 There are four balls of different colours and four boxes of colours, same as those of the balls. The number of
ways in which the balls, one in each box, could be placed such that a ball does not go to a box of its own colour
is:
B
(A) 4!– 1 (B) 9
(C) 3! + 1 (D) None of these
10 1231502 The number of ways in which three distinct numbers are in A.P. can be selected from the set {1, 2, 3, … , 24} , is
equal to:

B
(A) 66 (B) 132
(C) 198 (D) None of these
11 1231503 A bag contains n white and n red balls. Pairs of balls are drawn without replacement until the bag is empty. If the
number of ways in which each pair consists of one red and one white balls is 14400, then n P4 =

(A) 120 (B) 144 C


(C) 5 (D) 10
12 1231504 Out of 18 points in a plane, no three are in the same straight line except five points which are collinear. The
number of straight line formed by joining them is :

(A) 143 (B) 144 B


(C) 153 (D) None of these
13 1231505 The number of ways in which 20 rupees can be distributed among 5 people such that each person gets at least
Rs. 3 is:

(A) 26 (B) 63 D
(C) 125 (D) 126
14 1231506 In a group of boys, two boys are brothers and in this group 6 more boys are there. In how many ways they can sit
in a row if the brothers are not to sit along with each other?

(A) 30240 (B) 1410 A


(C) 2830 (D) 8420
15 1231507 A five digit number divisible by 3 is to be formed using the numbers 0, 1, 2, 3, 4 and 5 without repetition. The
total number of ways in which this can be done, is:

(A) 240 (B) 3125 D


(C) 600 (D) 216
16 1231508 If n Cr−1 = 36,
n
Cr = 84 and
n
Cr+1 = 126, then r =

(A) 1 (B) 2 C
(C) 3 (D) 4
17 1231509 A student is to answer 10 out of 13 questions in an examination such that he must choose at least 4 from the
first five questions. The number of choices available to him is

(A) 140 (B) 196 B


(C) 280 (D) 346
18 1231510 The number of ways in which 6 men and 5 women can dine at a round table if no two women are to sit together
is given by

(A) 6! × 5! (B) 30 A
(C) 5! × 4! (D) 7! × 5!
19 1231511 If n Cr denotes the number of combinations of n things taken r at a time, then the expression
Cr+1 + Cr−1 + 2 × Cr equals

n n n

(A) n+2
Cr (B) n+2
Cr+1
B

(C) n+1 Cr (D) n+1 Cr+1


20 1231512 ′
f (1) f " (1)

f ” (1) (−1)
n
f
n
(1)
If f(x) = x ,
n
then the value of f(1) − + − + ….+ is

1! 2! 3! n!
C
(A) 2n (B) 2n−1
(C) 0 (D) 1
21 1231513 Number of ways in which 5 boys and 4 girls can be arranged on a circular table such that no two girls sit together
and two particular boys are always together is…………..
288_288

22 1231514 The number of integral solutions of a + b + c = 0, a ≥– 5, b ≥– 5, c ≥ −5 must be………….


136_136
23 1231515 If the letters of the word SCHOOL are arranged as in a dictionary, then the rank of the word SCHOOL will be
………..
303_303

24 1231516 A five-digit number divisible by 3 is to be formed using the numerical 0, 1, 2, 3, 4 and 5 without repetition. If the
total number of ways in which this can be done is n3 , then n! must be……………
720_720

25 1231517 λ

If 12 Pr = 11880, then ∑
λ
Ci must be (where λ = r + 3) ...........
127_127
i=1

26 1231518 18 18 18 20
The sum of all values of r in ( ) + 2( ) + ( ) ≥ ( ) must be ……………
70_70
r − 2 r − 1 r 13

27 1231519 The number of polynomials of the form x3 + ax


2
+ bx + c that are divisible by x2 + 1,
Where
a, b, c ∈ {1, 2, 3, … . , 9} is…………..
9_9

28 1231520 a
x
+ b
x 2/x

If a, b, ∈ {1, 2, 3, 4, 5, 6, } then the number of ordered pairs (a, b) if lim ( ) = 6 is…………..


4_4
x→0 2

29 1231521 is divisible by (9!)p! , then the greatest value of p is…………..

(9!)!
8_8

30 1231522 There are four balls of different colours and four boxes of colours, same as those of the balls. The number of
ways in which the balls, one each in a box, could be placed such that a ball does not go to a box of its own colour 9_9
is…………..

31 1233650 The compounds C2 H5 OC2 H5 and C H3 OC H2 C H2 C H3 are:

(A) chain isomers (B) geometrical isomers C


(C) metamers (D) conformational isomers
32 1233651 The geometrical isomerism is shown by:

    

(B)
(A)

(C)

(D)
33 1233652 The correct structure of trans − 2−hexenal is:

    

(A) B
(B)

(C) (D)

34 1233653 Which of the following compounds can exist in optically active form?

(A) 1-Butanol (B) 2-Butanol B


(C) 3-Pentanol (D) 4-Heptanol
35 1233654 A compound with 2 or more asymmetric carbon atoms but also having a plane of symmetry is called:

(A) racemic compound (B) meso compound B


(C) dextro compound (D) levos compound
36 1233655 The correct statement about the compounds A,B and C is:

    
D

    

(A) A and B are identical (B) A and B are diastereomers


(C) A and C are enantiomers (D) A and B enantiomers
37 1233656 Which of the following hydrocarbon is most acidic?

    
A
    

(A) 1 (B) 2
(C) 3 (D) 4
38 1233657 The correct acidity order of the following is:

    
A

    

(A) ( III) > ( IV) > ( II) > ( I) (B) ( IV) > ( III) > ( I) > ( II)
(C) ( III) > ( II) > ( I) > ( IV) (D) ( II) > ( III) > ( IV) > ( I)
39 1233658 Which one of the following carbocations is most sTable?

    

(A)
(B)

(D)
(C)
40 1233659
Product of the above reaction is:

    

(A)
(B)
C

(D)
(C)

41 1233665

Major product of the reaction given above is:

    

(A) (B) A

(D) A and B in equal amounts

(C)

42 1233673

Product of the above reaction is:

    

(A)
(B)
D

(D)

(C)

43 1233675 Among the given compound, the correct dehydration order is:

    
A
    

(A) I < II < III < IV (B) II < III < IV < I
(C) I < III < IV < II (D) I < II < III = IV
44 1233677 The structure of diborane contains:

(A) four 2C-2e bonds and two 3C-2e bonds (B) two 2C-2e bonds and two 3C-2e bonds A
(C) two 2C-2e bonds and two 3C-3e bonds (D) four 2C-2e bonds and two 3C-3e bonds
45 1233678 H 3 BO3 is:

(A) monobasic and weak Lewis acid (B) monobasic and weak Bronsted acid A
(C) monobasic and strong Lewis acid (D) tribasic and weak Bronsted acid
46 1233685 Be and Al exhibit many properties which are similar, but the two elements differ in :

(A) exhibiting amphoteric nature in their oxides (B) forming polymeric hydrides B
(C) exhibiting maximum covalency in compounds (D) forming cavalent halides
47 1233686 Duralumin is an alloy of:

(A) Al and Mg (B) Mg and Cu C


(C) Al,Mg, Mn and Cu (D) Al and Cu
48 1233689 The correct order of sTability gp. 14 hydride?

(A) C H4 < SiH4 < GeH4 < SnH4 (B) C H4 > SiH 4 > GeH 4 > SnH 4 C
(C) SnH4 < GeH4 < SiH4 < C H4 (D) C H4 < SiH 4 > GeH 4 > SnH 4

49 1233690 Which halide is least sTable and has doubtful existence?

(A) CI4 (B) GeI4 D


(C) SnI4 (D) P bI4
50 1233692 Which among the following has linear structure?

(A) C3 O2 (B) N2 O5 A
(C) N O2 (D) SO2
51 1233709 When Sn(I V ) chloride is treated with excess of conc. HCl, the complex [SnCl6 ]2− if formed. Find the oxidation
state in this complex. If answer is x, then 10x = ?
40_40

52 1233711 How many B-O bonds in diborate ion? If answer is y , then 2y/5 =?
2.4_2.4
53 1233712 The covalency of B in BF − … …

4 4_4

54 1233713 The value of n in the molecular formula Ben Al2 S i6 O18 is:
3_3
55 1233715 How many nucleophiles may be classified as strong amongst those given below?
C H3 O

, C H 3 OH, C H 3 SH, RCOOH, RCOO

, RO

, ROH, C H 3 COOH, C H 3 COO

.
2_2

56 1233717 Among those given below, how many solvents are protic?
HCOOH, C H 3 COC H 3 , C H 3 CN , HCON H 2 , S O2 , N H 3 , (C H 3 )3 N , (C H 2 OH )2 .
4_4

57 1233719 How many of the given species will behave as an electrophile? If answer is z then 5z/2 =?

⊕ ⊖ ⊕ ⊕ ⊖
12.5_12.5
CC l2 , Br, BF3 , AlC l3 , OH, N H 4 , C H 3 , N H 3 , C H 3

58 1233722 The number of resonance structures for N is:

    
9_9

59 1233725 The total number of stereoisomers that can exist for M is

    
2_2

60 1233728 The total number( s) of sTable confermers with non-zero dipole moment for the following compound is ( are):

    
3_3

61 1235422 Length of a string tied to two rigid supports is 40 cm. Maximum length ( wavelength in cm) of a stationary wave
produced on it is

(A) 20 (B) 80 B
(C) 40 (D) 120
62 1235423 Tube A has both ends open while tube B has one end closed, otherwise they are identical. The ratio of
fundamental frequency of tube A and B is

(A) 1 : 2 (B) 1 : 4 C
(C) 2 : 1 (D) 4 : 1
63 1235424 A tuning fork arrangement(pair) produces 4 beats/sec with one fork of frequency 288 cps. A little wax is placed
on the unknown fork and it then produces 2 beats/sec. The frequency of the unknown fork is

(A) 286 cps (B) 292 cps B


(C) 294 cps (D) 288 cps
64 1235425 A wave y = a sin(ωt − kx) on a string meets with another wave producing a node at x=0. Then the equation
of the unknown wave is

(A) y = a sin(ωt + kx) (B) y = −a sin(ωt + kx)


B

(C) y = a sin(ωt– kx) (D) y = −a sin(ωt– kx)

65 1235426 When temperature increases, the frequency of a tuning fork

(A) increases (B) decreases B


(C) remains same (D) increases or decreases depending on the material
66 1235427 The displacement y of a wave travelling in the x –direction is given by
π
−4
y = 10 sin (600 t − 2x + ) metres
3

where x is expressed in metres and t in seconds. The speed of the wave-motion, in ms−1 , is
A
(A) 300 (B) 600
(C) 1200 (D) 200
67 1235428 A metal wire of linear mass density of 9.8 g/m is stretched with a tension of 10 kg-wt between two rigid supports
1 metre apart. The wire passes at its middle point between the poles of a permanent magnet, and it vibrates in
resonance when carrying an alternating current of frequency n. The frequency n of the alternating source is
A
(A) 50 Hz (B) 100 Hz
(C) 200 Hz (D) 25 Hz
68 1235429 A tuning fork of known frequency 256 Hz makes 5 beats per second with the vibrating string of a piano. The beat
frequency decreases to 2 beats per second when the tension in the piano string is slightly increased. The
frequency of the piano string before increasing the tension was
C
(A) 256 + 2 Hz (B) 256 – 2 Hz
(C) 256 – 5 Hz (D) 256 + 5 Hz
69 1235430 The displacement y of a particle in a medium can be expressed as,
π
y = 10
−6
sin (100t + 20x + )m where t is in second and x in meter. The speed of the wave is

4 B
(A) 20 m/s (B) 5 m/s
(C) 2000 m/s (D) 5π m/s

70 1235431 A sonometer wire of length 1.5 m is made of steel. The tension in it produces an elastic strain of 1%. What is
fundamental frequency of steel if density and elasticity of steel are 7.7 × 103 kg/m3 and 2.2 × 1011 N /m2
respectively?
B
(A) 188.5 Hz (B) 178.2 Hz
(C) 200.5 Hz (D) 770 Hz
71 1235432 An observer moves towards a stationary source of sound, with a velocity one-fifth of the velocity of sound. What
is the percentage increase in the apparent frequency ?

(A) 0.5 % (B) zero C


(C) 20 % (D) 5 %
72 1235433 A whistle producing sound waves of frequencies 9500 HZ and above is approaching a stationary person with
speed v ms−1 . The velocity of sound in air is 300 ms−1 . If the person can hear frequencies upto a maximum of
10,000 Hz, the maximum value of v upto which he can hear whistle is

(A) 15√2

ms
−1 15 C
(B) –
ms
−1

√2

(C) 15 ms
−1
(D) 30 ms
−1

73 1235434 A string is stretched between fixed points separated by 75.0 cm. It is observed to have resonant frequencies of
420 Hz and 315 Hz. There are no other resonant frequencies between these two. Then, the lowest resonant
frequency for this string is
A
(A) 105 Hz (B) 1.05 Hz
(C) 1050 Hz (D) 10.5 Hz
74 1235435 A sound absorber attenuates the sound level by 20 dB. The intensity decreases by a factor of

(A) 100 (B) 1000 A


(C) 10000 (D) 10
75 1235436 While measuring the speed of sound by performing a resonance column experiment, a student gets the first
resonance condition at a column length of 18 cm during winter. Repeating the same experiment during summer,
she measures the column length to be x cm for the second resonance. Then
B
(A) 18 > x (B) x > 54
(C) 54 > x > 36 (D) 36 > x > 18
76 1235437 A wave travelling along the x-axis is described by the equation y(x, t) = 0.005 cos(α x − βt). If the
wavelength and then α and β in appropriate units are

(A) α = 25.00π, β = π 0.08 2.0


(B) α = ,β = A
π π
π
0.04 1.0
(C) α = ,β =
(D) α = 12.50 π, β =
2.0
π π

77 1235438 A pipe of length 85 cm is closed from one end. Find the number of possible natural oscillations of air column in
the pipe whose frequencies lie below 1250 Hz. The velocity of sound in air is 340 m/s.

(A) 12 (B) 8 C
(C) 6 (D) 4
78 1235439 A train is moving on a straight track with speed 20 ms−1 . It is blowing its whistle at the frequency of 1000 Hz.
The percentage change in the frequency heard by a person standing near the track as the train passes him is (
speed of sound = 320 ms−1 ) close to:
D
(A) 18 % (B) 24 %
(C) 6 % (D) 12 %
79 1235440 A uniform string of length 20 m is suspended from a rigid support. A short wave pulse is introduced at its lowest
end. It starts moving up the string. The time taken to reach the supports is:
( take g = 10 ms−2 )

– – A
(A) 2√2s (B) √2s
(C) 2π√2s

(D) 2s
80 1235441 A pipe open at both ends has a fundamental frequency f in air. The pipe is dipped vertically in water so that half
of it is in water. The fundamental frequency of the air column is now:

(A) 2f (B) f B
f 3f
(C) (D)
2 4

81 1235442 A 20 cm long string, having a mass of 1.0 g, is fixed at both the ends. The tension in the string is 0.5 N. The string
is set into vibrations using can external vibrator of frequency 100 Hz. Find the separation (in cm) between the 5_5
successive nodes on the string.

82 1235443 A stationary source is emitting sound at a fixed frequency f0 , which is reflected by two cars approaching the
source. The difference between the frequencies of sound reflected from the cars in 1.2% of f0 . What is the
difference in the speeds of the cars( in km per hour) to the nearest integer?
The cars are moving at constant 6.5_7.5
speeds much smaller than the speed of sound which is 330 ms−1 .

83 1235444 π
When two progressive waves y1 = 4 sin(2x − 6t) and y2 = 3sin (2x − 6t − ) are superimposed, the
2 5_5
amplitude of the resultant wave is

84 1235445 π 2π
Four harmonic waves of equal frequencies and equal intensities I0 have phase angles 0, , and π . When
3 3 3_3
they are superposed, the intensity of the resulting wave is nI0 . The value of n is

85 1235446 A bat emits ultrasonic sound of frequency 1000 kHz in air. If the sound encounters a water surface, what is ratio
of the wavelengths of the reflected sound, to the refracted sound? Speed of sound in air is 340 ms−1 and in 0.21_0.25
water 1486 ms−1 .

86 1235447 If the kinetic energy of pulse travelling in a taut string is 3K × 10


−2
mJ then find the value of K. (Given

T = 10N and μ = 0.1kg/m.     


5_5

87 1235448 A stone dropped from the top of a tower of height 300 m high splashes into the water of a pond near the base of
the tower. When is the splash heard at the top given that the speed of sound in a is 340 ms−1 ? ( 8.5_8.9
g = 9.8 m s
−2
)

88 1235449 A steel wire has a length of 12.0 m and a mass of 2.10 kg. What should be the tension (in KN) in the wire so that
speed of a transverse wave on the wire equals the speed of sound in dry air at 20°C = 343 m s−1 .
20.3_20.7

89 1235450 A hospital uses an ultrasonic scanner to locate tumours in a tissue. What is the wavelength of sound (in mm) in 0.40
the tissue in which the speed of sound is 1.7 km s−1 ? The operating frequency of the scanner is 4.2 MHz.
_0.43
90 1235451 A source of sound with natural frequency n = 1.8 kHz moves uniformly along a straight line separated from a
stationary observer by a distance ℓ = 250 m. The velocity of the source is equal to η = 0.80 fraction of the
velocity of sound. Find the frequencey in kHz of sound received by the observer at the moment when the source 4.9_5.2
gets closest to him;

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