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1 s2.0 1359645496000845 Main
1 s2.0 1359645496000845 Main
1 s2.0 1359645496000845 Main
4375-4385,1996
Copyright 0 1996Acta Metallurgica Inc.
Pergamon Published by Elsevier Science Ltd
PII 81359-6454(96)00084-5 Printed in Great Britain. All rigbts reserved
1359-6454/96$15.00+ 0.00
D. HijMBERG
Weierstrass Institute for Applied Analysis and Stochastics, MohrenstraBe 39, D-101 17 Berlin, Germany
Abstract-We present a numerical algorithm for simulating the Jominy end-quench test and deriving
continuous cooling diagrams. The underlying mathematical model for the austenite-pearlite phase
transition is based on Scheil’s Additivity Rule and the Johnson-Mehl equation. For the formation of
martensite we compare the Koistinen-Marburger formula with a rate law, which takes into account the
irreversibility of this process. We carry out numerical simulations for the plain carbon steels C 1080 and
C 100 W 1. The results suggest that the austenite-pearlite phase change may be described decently by
the Additivity Rule, except for the incubation time. On the other hand, using a rate law to describe the
martensite formation is preferable to the Koistinen-Marburger formula, which leads to unphysical
oscillations of the cooling curves in simulated CCT-diagrams. Copyright 0 1996 Acta Metallurgica Inc.
Deviceforltdng and
piece
csnlrhg maIesl
t4co
1200
tom
E
em
i
b6w
400
200
3.5
0.02
3
2.5
1.5
0.005
loo 200 300 400 500 600 700 8cQ 0 109 200 300 400 500 600 700 800
T T
Fig. 4. The data functions a(T) and b(n for the carbon steel C 1080.
the course of the phase change than a rate law. Simple manipulations show that the solution is
Moreover, measurements by Hawbolt et al. [13] show given by:
that also in quantity the A-P transformation is
a(T) = ln(ln(O.01)) - In(ln(0.99)
described well by the additivity rule, except for the (6a)
incubation period where the pearlite fraction ln(tXr)) - ln(WN
predicted by the additivity rule shows only poor b(T) = -ln(O.Ol)t,(T)-“‘n. (6b)
coincidence with the measurements. It should be
noticed that equations of this type are also used for Figure 4 shows the behaviour of the coefficients
a(T) and b(T) in the temperature range (Mi, A.,) for
modeling fatigue effects, e.g. the Palmgren-Minor
the plain carbon steel C 1080. For temperatures
rule (cf. [6]).
A different approach to model a nucleation and below M,? the values are obtained by linear
extrapolation. Although it cannot be concluded from
growth process was chosen by Andreucci et al. [3].
the diagram, b also stays positive in the whole
Going back to the ideas of Johnson and Mehl they
derived an integral equation to describe the temperature range. Hence, in the following we
solidification of polymers in the non-isothermal case. assume a and b to be continuous functions on
[M/-, A,], bounded away from zero.
2.3. Identifying coefjicients from IT diagrams 2.4. An initial value problem for the A-P transform-
ation
Assuming that the generalized Johnson-Mehl
equation (2) appropriately describes the isothermal A simple way to exploit the additivity rule is to
evolution of the phase fractions we present a simple differentiate it formally with respect to time. Since we
method to obtain the data functions a(T) and b(T) obtain an inner derivative p, rearranging terms leads
from the IT diagrams. to the following initial value problem:
Since the bold-faced curves in these diagrams are
P(O) = PO (74
the “is0-fractions” p = 0.01 and p = 0.99, we
interpret these transformation curves as the ii(t) =fCt> P(t), TL (7b)
respective graphs of functions:
with
tE. Moreover, we have: prevents the formation of pearlite above the critical
temperature A,.
P(l) > 0, (10)
i.e. the irreversibility of the austenite-pearlite 2.5. The austenite-martensite phase change
transformation carries over to the model. Unfortu- While the additivity rule is a well investigated
nately, as Fig. 4 shows, the coefficient a, which was decent tool for describing the growth of pearlite,
equal to 4 in the original Johnson-Mehl equation and there seems to be no satisfactory model at hand for
assumed to be greater than 1 in [25] and [26], actually the martensitic transformation in steel.
takes values less than 1 if the temperature is in a range Usually, exponential growth laws like the
just below A,. In this case, we can prove the following: Koistinen and Marburger formula:
Proposition 1. Let T: [0, tE]+[M,, A,] be a continuous
m(r) = 1 - e-CM-W) (14)
function, such that
a(T(t)) < 1 for all 0 < t < tl are used (cf. [15], [17], [18], [22]).
These equations all have in common that they do
then the following are valid:
not model the irreversibility of the austenite-marten-
lim p(t) = 0, (lla) site phase transition. Thus, in numerical simulations
r-0(+1 based on these models, owing to the release of latent
lim e(t) = co, (1 lb) heat, usually a decrease in the martensite fraction is
1-o(+) observed (cf. [15] and Section 4).
For the proof, we refer to [15]. The formation of martensite starts below the
In a nucleation and growth process the increase of critical temperature M, and the volume fraction of
the volume fraction of the new phase should be martensite only grows during non-isothermal stages
“small” during the incubation time, which is a of a cooling process. At this stage of the exposition,
contradiction to equation (11 b). Thus, Proposition 1 where we assume the temperature evolution to be
gives the mathematical reason why the additivity rule known a priori, one could argue that growth laws
does not work well for the early stages of the such as equation (14) are still valid, if only they are
transformation. As said before, this fact has also been modified by the logical statement that the volume
observed experimentally. fraction of martensite never decreases. For instance,
To overcome this difficulty, we adopt the following one could replace equation (14) with:
philosophy: We define an incubation time t,, which
m(t) = EC:; (1 - e-aMa-T(s))). (14’)
we keep fixed. Giving up the aim of predicting the
exact evolution kinetics during this incubation time, However, owing to the latent heat, the phase
we just gauge the processs by demanding that the transitions interact with the temperature evolution.
additivity rule shall hold, when the end of the Therefore, it is important to keep track of the actual
incubation time is reached. This leads to the transformation kinetics. Hence, we propose the
following model: following rate law for the growth of martensite:
?? Let T: [0, tE]+R be a given temperature
m(0) = 0, (W
evolution,
?? tle(O, tE) the fixed incubation time, then, ti(t) = (1 - m(t))G(T(t))H(-T!(t)). (15b)
depending on T,
?? p. is defined by:
Here, again H is the heaviside function. G shall be
bounded, positive and (Lipschitz-) continuous,
??
s
0
1
o r(T(5), PO) dr = ”
by the
satisfying G(x) = 0 for all x 3 h4,. Putting m(0) = 0,
we tacitly assume that we start with a temperature
T(0) > M,.
If during some stage of a heat treatment cycle
following initial value problem (IVP): either T > A4, or Tis increasing, i.e. T, 3 0, according
to equation (15b) we have k(t) = 0, whence no
P(0) = Par (13a) martensite is produced during this stage.
Moreover, since ti > 0, the irreversibility of the
o<t<tr martensite transformation is now incorporated in the
p(t),T)H(A, - T(t)) :t, < t < tE. model.
austenite in the case when both pearlite and exists a differentiable material function i? such that
martensite are present, i.e. 1 -p - m. the internal energy takes the form:
So we end up with the following initial value
problem for the phase transitions in eutectoid carbon e(x, t) = W, P, ml, (20)
steel: with the partial derivatives
(s dt aT
.f(t, P>m, T):= -
0 4T(5N7(Wj P, m) >
s 4
1
o W(t), PO)
dr= 1. 1 I, x> 6,
where 6 > 0 is a “small” parameter. Introducing the
(2) The ZVP [equations (16aHd)] has a unique further notation Aa(. -H6( - .), and using
(absolutely) continuous solution (p, m). equations (16a)--(d) we end up with the following
(3) PO< p(t) + m(t) < c~,,~,< 1 for all t < 10, 4. nonlinear parabolic problem (P,i) for phase
See [16] for the proof and the precise formulation transitions in eutectoid carbon steel:
of the necessary assumptions.
U%(T) F+ ,G”W~(T)(l -P - mNWM(Z)
2.7. Three-dimensional case
Let R c R-’be bounded with smooth boundary -V. (k(T)VT) = ~(WdTlp,, in ~2, (254
aa = :r and Q:=CI x (0, ts).
As mechanical effects are neglected in this paper, -k(T) g = y(T)(T - T,), in r x (0, tE), (25b)
using Fourier’s law of heat conduction, we get the
following balance of energy: T(,, 0) = A,, in R. (25c)
& Here, for almost all XE~, (p(x, .), m(x, .)) is the
p-+‘(kVT)=O, (19)
solution to the following (IVP):
where p is the mass density, e the specific internal p(x, 0) = po(T(x, .)), [cf. equation (12)] (25d)
energy and k the heat conductivity of the material
under consideration. m(x, 0) = 0, We)
In a spatial model the propagation of latent heat
pl(x, t) = (1 - p(x, t) - m(x, t))
released during the phase changes has to be
considered. Following [27], it is assumed that there f(t, p(x, t), m(x, t), T(x, .))&(A, - T(x, t)), (Xf)
4380 HOMBERG: A NUMERICAL SIMULATION OF THE JOMINY END-QUENCH TEST
r&(x, t) = (1 - p(x, t) - m(x, t)) doubtful, whether one would be able to obtain
enough measurements to include this dependency in
W(x, t))ffa(- Z(x, 0). Wg) numerical simulations.
(38)
and the vector T, E R’“,N = (N, + l)(N: + 111,defined
r4 r2 by:
with
,6t
+---- 1 1
(a)
EE 2
7.2oa
6.400
5.6OC
4.8OC
T 4.OOC
3.2OC
2.4OC
1.6OC
0.8OC
log t
(b)
EE2
7.200
6.400 -
5.600 7
4.800 -
T 4.000 -
3.200 -
1.600
0.800
0
-0.500 -0.200 -0.100 -0.400 -0.700 1.ooo 1.300 1.600 l.!Wb 2.200 EEC
log t
Fig. 7. Numerical simulation of a CCT-diagram for the steel C 1080: (a) using the Koistinen-Marburger
formula, (b) using a rate law to describe the martensite fraction.
HOMBERG: A NUMERICAL SIMULATION OF THE JOMINY END-QUENCH TEST 4383
(b)
-
E Q Hardenability 80
E
.: 60
20
--I
0 8 16 24 32 40 0 8 16 24 32 40
Distance from quenched end (l/16 in. units) Distance from quenched end (1116 in. units)
Fig. 8. (a) Hardenability curve for the steel C 1080 (from [2]), (b) numerically calculated martensite
fraction plotted against the distance from the quenched end.
where C, Mn, Si are the volume fractions of carbon, Finally, the temperature thresholds A,, M: can be
manganese and silicon for the respective steel. The drawn from the respective IT diagram.
temperature-dependent correction values for k and
the data for specific heat c and density p have been
4. NUMERICAL SIMULATIONS
taken from tables in [lo].
For the latent heats we take the values from [14]: 4.1. Results for the steel C 1080
First, we applied our numerical scheme to the
L, = 17.0 ;, L, = 84.0 f. (43) eutectoid carbon steel C 1080 from [2] (see Fig. 2).
Figure 7 shows the CCT diagram. As expected, the
The heat transfer coefficient has been chosen as in curves are moved to later time and lower tempera-
[ll]: ture. The bucklings of the cooling curves between the
transformation lines indicate the release of latent heat
y(T) = -0.167 x lo4 + 0.108 x lo3 x T- 0.977 during the formation of pearlite. In Fig. 7(a), we used
the Koistinen-Marburger formula [cf. equation (14)]
x 10-l. T2sK. (4) to describe the evolution of the martensite fraction.
Instead of intersecting the dotted M, line only once,
u 700
0
.s 600
e
2 500
g
al 400
E
g 300
EE 2
1 \i --... \ -\‘--.
1.600 -
0.800 -
0~
-0.500 -0.200 -0.100 -0.400 -0.700 1.000 1.300 1.600 1.900 2.200 E@c
log I
Fig. 10. Numerical simulation of a CCT diagram for the steel C 100 W 1.
the cooling curves go up again. To prevent repeated martensite fraction is plotted against the distance
oscillations we even had to cut the latent heat Lp in from the quenched end. Obviously, pearlite also has
halves. a certain hardness, so one can only expect that both
To overcome this unphysical behaviour, we curves coincide for small distances from the quenched
replaced the Koistinen-Marburger formula with a end, which is almost the case.
rate law, which takes care of the irreversibility of the
phase change [cf. equations (15a) and (b)]. The 4.2. Results for the steel C 100 W I
resulting CCT curve is depicted in Fig. 7(b). Using In a second simulation, we applied our scheme to
the original value for L,, the cooling curves intersect the steel C 100 W 1 from [23]. Although this steel has
the A& line only once without performing unreason- a carbon content of 1.O%, during continuous cooling
able heating-up effects. it only performs the eutectoid transformation. Thus,
Finally, Fig. 8 shows the hardenability curve for C the application of our model is justified.
1080 side by side with a diagram in which the Figure 9 shows the IT diagram for this steel. The
70 l-
I
100 _.......................,.......
.............j. f_.__._ ..,..
60
80 . .._.._.
._........ I....._..........
,...f_.__. ..~ /.....................
o 60 __....................
.,.....
_..____j.____ .!-- F. i .,. .,...,.
.z
a
Y
I 40 _ ..~.................
/ ......I .., i .,...,.,.
E:
20 _....................
f .j ../
10 I A
0 10 20 30 40 50 60 0 1 2 3 4 5
Abstand von der abgcschrecktcn Stirnflltchc in mm Distance from quenched end (cm)
Fig. 11. Hardenability curve for the steel C 100 W 1 (from [23]), left; numerically calculated martensite
fraction plotted against the distance from the quenched end, right.
HOMBERG: A NUMERICAL SIMULATION OF THE JOMINY END-QUENCH TEST 4385