Inspection Report Shore Quantity Report Ullage Report Time Sheet / Time Log Sample Report Quality Report

CLIENT : GERDAU ACOMINAS S.
A
RODOVIA MG 443 - KM 07 FAZENDA DO CADETE
OURO BRANCO - MG - BRAZIL. CNPJ: 17.227.422/0001-05
VESSEL : M/T"BOW CAROLINE"
VOYAGE NR. : 2022-04
PRODUCT : 212,230 METRIC TONS OF BENZENE AND MIXTURES HAVING 10% BENZENE OR
MORE
PORT OF LOADING : SANTOS, BRAZIL
PORT OF DISCHARGE : TERMINAL QUÍMICO DE ARATU S.A. - TEQUIMAR, ALEMOA
TERMINAL OF DISCHARGE : ROTTERDAM, THE NETHERLANDS
DATE : May 26th, 2022
REPORT : O/S OG&C 20023142/22
INDEX 7 PAGES
INSPECTION REPORT
SHORE QUANTITY REPORT
ULLAGE REPORT
TIME SHEET / TIME LOG
SAMPLE REPORT
QUALITY REPORT
gac.
This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.aspx. Attention is drawn to the limitation of
liability, identification and jurisdiction issues defined therein. Any holder of this document is advised that information contained hereon reflects the Company’s findings at the time of its
intervention only and within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to a transaction from
exercising all their rights and obligations under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and
offenders may be prosecuted to the fullest extent of the law.
Page 1 of 7
GERDAU ACOMINAS S.A

INSPECTION REPORT O/S OG&C 20023142/22

PRODUCT : 212,230 METRIC TONS OF BENZENE AND MIXTURES HAVING 10% BENZENE OR MORE
TERMINAL : TERMINAL QUÍMICO DE ARATU S.A. - TEQUIMAR, ALEMOA
CLEANLINESS REPORT OF SHORE TANKS
We hereby report that we have inspected on May 25nd, 2022 at 16:35 hours where accessible vessel's cargo tank(s) below,
respective pump, line and connecting lines of the above mentioned vessel before loading and found same empty, dry,
cleaned in our opinion based on visual inspection before loading and considering cleaning procedures used as previous
cargo informations received from the Master/Chief Officer, we formed the opinion that the designed cargo tanks were in
satisfactory clean conditions to receive a cargo of 212,230 metric tons of Benzene and Mixtures Having 10% Benzene or
More
Last Cargo 2nd Last Cargo 3rd Last Cargo Tank Capacity (m³) 98% Material / Coating Material
4P PETREPAR 150 GROUNDNUT OIL ACETONE 2.841,490 Stainless Stell
Santos, May 31th, 2022
gac.
This inspection was based on tank cleaning conditions in the date and time of inspection, not extending to the quality or tank coating guarantee that perhaps can change the characteristics of the cargo to be
stowed. This report does not exempt suppliers or terminals of its contractual obligations.
This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.aspx. Attention is drawn to the limitation of liability, indemnification
and jurisdiction issues defined therein.
Any holder of this document is advised that the information contained hereon is limited to visual examination of the safely and readily accessible portions of the consignment and reflects the Company’s findings at
the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all
their rights and obligations under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the
fullest extent of the law.
Page 2 of 7
GERDAU ACOMINAS S.A

SHORE QUANTITY REPORT O/S OG&C 20023142/22

PRODUCT : 212,230 METRIC TONS OF BENZENE AND MIXTURES HAVING 10% BENZENE OR MORE CERTIFICATE EXPIRATION
TERMINAL : TERMINAL QUÍMICO DE ARATU S.A. - TEQUIMAR, ALEMOA NUMBER DATE
PORT OF LOADING : SANTOS, BRAZIL TAPE 17/0468 22/01/2022
DATE : May 26th, 2022 THERMOMETER 7084/15 28/06/2022
SHORE FIGURESTABLE ANP

SHORE TANK NR. 25052022 - 04:10 26/05/2022 - 01:17 16-1004
Reference Height (mm) OPEN CLOSE 13.240 OPEN CLOSE 13.408 OPEN CLOSE
Gauge, mm 2.621 117
Temp., ºC 21,00 21,50
Water, mm 0 0
Total Obs. Volume, Liters 249.155 11.036 238.119 0 0
Water, Liters 0 0 0
Roof, Liters 0 0 0 0 0 0 0 0 0
Line volume, Liters 1.022 1.022 0 0 0
G.O.V., Liters 250.177 12.058 238.119 0 0 0 0 0 0
V.C.F to Liters at 20ºC 0,99930 0,99890 0,00000 0,00000 0,00000 0,00000
G.S.V., Liters at 20ºC 250.002 12.045 237.957 0 0 0 0 0 0
S&W, % Volume
S&W, Volume Liters 0 0 0 0 0 0 0 0 0
N.S.V., Liters at 20ºC 0 0 0 0 0 0 0 0 0
Density at 20ºC (vac) 893,00 893,00
GROSS, Kilograms (vac) 223.252 10.756 212.496 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
GROSS, Metric Tons (vac) 223,252 10,756 212,496 0,000 0,000 0,000 0,000 0,000 0,000
0 0,000 0,000 0,000 0,000 0,000 0,000 0,000 0,000 0,000
W.C.F ( Vac to Air ) 1,00125 1,00125 0 0 0 0
GROSS, Kilograms (air) 222.973 10.743 212.230 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0
GROSS, Metric Tons (air) 222,973 10,743 212,230 0,000 0,000 0,000 0,000 0,000 0,000
0 0,000 0,000 0,000 0,000 0,000 0,000 0,000 0,000 0,000
W.C.F to Long Tons 0,9842065 0,9842065 0 0 0 0
GROSS, Long Tons 219,451 10,573 208,878 0,000 0,000 0,000 0,000 0,000 0,000
0 0,000 0,000 0,000 0,000 0,000 0,000 0,000 0,000 0,000
Factor to USBbls at 60ºF 0,159509 0,159509 0 0 0 0
GROSS, USBbls at 60ºF 1.567,32 75,51 1.491,81 0,00 0,00 0,00 0,00 0,00 0,00
0 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00 0,00
Factor to USGals at 60ºF 42 42
GROSS, USGals at 60ºF 65.827,44 3.171,42
62.656,02 0,00 0,00 0,00 0,00 0,00 0,00
0 0,00 0,00
0,00 0,00 0,00 0,00 0,00 0,00 0,00
Factor to Liters at 15ºC 0,9963 0,9963 0 0 0 0
GROSS, Liters at 15ºC 249.077 12.000
237.077 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0
Roof Weight
Remark: 1- Shore line empty before and after loading. Shore measurements according API 3.1.A
2- Tape and termomether/PET furnished by SGS
3- The densities reported herein are in Kg / m³ unit to follow the MPMSAPI 11, if necessary Kg / l divide the value by 1000.
gac.
Page 3 of 7
GERDAU ACOMINAS S.A

SHORE QUANTITY REPORT O/S OG&C 20023142/22

ANP TABLES
TCV - Total Calculated Volume 237.957

TOV - Total Observed Volume 238.119
WATER 0
ROOF Volume 0
LINE Volume 0
GOV -Gross Observed Volume 238.119
GSV - Gross Standard Volume 237.957
SW VOL 0
NSV - Net Standard Volume 0
GROSS, Kilograms (vac) 212.496
GROSS, Metric Tons (vac) 212,496
GROSS, Kilograms (air) 212.230
GROSS, Metric Tons (air) 212,230
GROSS, Long Tons 208,878
GROSS, USBbls at 60ºF 1.491,81
GROSS, USGals at 60ºF 62.656,02
GROSS, Liters at 15ºC 237.077
Note: Official Figures as per ANP Table by Law enforcement.
CONSIGNEE : RAIN CARBON GERMANY GMBH

Kekulestrasse 30,
D-44579 Castrop- Rauxel/Germany
Phone: 0049 2305 705-257,
mailto: DL-CAS-BTXTrading@raincarbon.com
NOTIFY : RUBIS Terminal B.V., Harbour No.:4 1 4 5

Welplaatweg 26 NL-3197 KS Rotterdam-Botlek
Phone: +31 10 2958175
mailto: planning.rotterdam@rubis-terminal.com
DESTINATION PORT : ROTTERDAM, THE NETHERLANDS
MELTING POINT: < 6°C

SHIPPED CLEAN ON BOARD
FREIGHT PAYABLE AS PER CHARTER PARTY'
SHIPPING NAME : BENZENE AND MIXTURES HAVING 10% BENZENE OR MORE ( I )
STOWAGE: 4P
NCM: 2710.99.00
gac.
This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.aspx. Attention is drawn to
the limitation of liability, identification and jurisdiction issues defined therein. Any holder of this document is advised that information contained hereon reflects the
Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this
document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any unauthorized alteration, forgery
or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.
Page 4 of 7
GERDAU ACOMINAS S.A

ULLAGE REPORT O/S OG&C 20023142/22

PRODUCT : 212,230 METRIC TONS OF BENZENE AND MIXTURES HAVING 10% BENZENE OR MORE CERTIFICATE EXPIRATION
TERMINAL : TERMINAL QUÍMICO DE ARATU S.A. - TEQUIMAR, ALEMOA NUMBER DATE
PORT OF LOADING : SANTOS, BRAZIL TAPE 2021010901-01KL Jan 09th, 2022
DATE : May 26th, 2022 THERMOMETER 2021010901-01KL Jan 09th, 2022
SHIP'S FIGURES AFTER LOADING - TABLE ANP

Vessel's Ullage Water Temp. T.O.V. O.B.Q. G.O.V. Water
VCF Factor G.S.V.
tank nº ( mm ) Inn (mm) ºC ( Liters ) ( Liters )
( Liters ) ( Liters )
Table ANP Lts at 20ºC
4P 9.730 NILL 22,30 1.146.252 1.146.252 0,99810 1.144.074
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
0 0,00000 0
TOTAL 1.146.252 0 0 1.146.252 1.144.074
FIELD COPY SIGNED BY VESSEL'S OFFICERS - These figures subject to check - Calculations in accordance with Loading Certificate
Remark: Vessel docked
All measurements were performed with vessel equipment. Certificates numbers and expiration dates reported above.
CONVERTION FACTORS: TABLE ANP R.O.B. without temperature DRAFT FWD AFT LIST
Kg (vac) to Kg (air) 1,00125 V.E.F. = 1,0000 ARRIVAL 9.20 9.20 0
MT (air) to LT 0,9842065 S&W DEPARTURE IN OP 0
Lts at 20ºC to USBbls at 60ºF 0,159509 S&W Volume 0 Sea condition Calm
USBbls at 60ºF to USGals at 60ºF 42 DENSITY Weather Sunny
Lts at 20ºC to Lts at 15ºC 0,9963 AT 20ºC
891,50 Kg/m³ 0,89150 Kg/l Wind Low
NET FIGURES Without V.E.F. With V.E.F.

Liters at 20ºC 1.144.074 1.144.074
Kilograms (vac) 1.019.942 1.019.942
Metric Tons (vac) 1.019,942 1.019,942
Kilograms (air) 1.018.669 1.018.669
Metric Tons (air) 1.018,669 1.018,669
Long Tons - Air 1.002,581 1.002,581
US Barrels at 60ºF 7.172,47 7.172,47
US Gallons at 60ºF 301.243,74 301.243,74
Liters at 15ºC 1.139.841 1.139.841
gac.
This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.aspx. Attention is drawn to the
limitation of liability, identification and jurisdiction issues defined therein. Any holder of this document is advised that information contained hereon reflects the Company’s findings at
the time of its intervention only and within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to a
transaction from exercising all their rights and obligations under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this
document is unlawful and offenders may be prosecuted to the fullest extent of the law.
Page 5 of 7
GERDAU ACOMINAS S.A

TIME SHEET / TIME LOG O/S OG&C 20023142/22

DATE : May 26th, 2022 SHORE LINE: LP 02 Last cargo:
DATE TIME REMARKS

May 23th, 2022 09:00 Vessel arrived at Santos roads
11:30 Pilot on board
12:18 First line ashore
12:42 Vessel berthed at Dow Guaruja
May 25th, 2022 09:12 Pilot on board

10:30 First line ashore
10:48 Vessel berthed at Alemoa III
11:30 Gangway
11:40 / 12:40 Key meeting
16:35 Ship tank inspected by visual and approved to loading
22:36 / 22:48 Hose Connection
22:48 / 22:58 Cargo and vapour return hose connection
16:35 / 23:59 Awaiting terminal to filling up shore line LP 02
May 26th, 2022 00:00 / 00:35 Awaiting terminal to filling up shore line LP 02
00:35 / 01:50 Filling up shore line LP12 from shore tank 16-1004
01:50 / 02:00 Sampling at shore manifold - visually approved
02:00 / 02:10 Samples at ship manifold - visually approved
02:10 Commenced loading
02:10 / 02:20 Filling up ship line untill pumpstack - visually approved
02:20 Commenced loading ship tank 4P
02:40 / 02:50 Sampling from first foot of ship tank - visually approved
08:15 Completed loading
08:20 Commenced blowing
08:20 / 09:15 Completed blowing
09:15 / 11:00 Pigging of shore line
11:00 / 11:05 Blowing shore hose and ship line
11:05 Completed loading
11:05 / 11:40 Awaiting for ship tanks stabilize
11:40 / 12:20 Measurements and calculations on board after loading
12:30 / 12:40 Cargo and vapour return hose disconnection
gac.
Page 6 of 7
GERDAU ACOMINAS S.A

SAMPLE REPORT O/S OG&C 20023142/22

Before loading operation, samples were drawn from shore tank, sealed and distributed as follows:
1x½ liter for the consignee;
1x½ liter for analysis in our Laboratory (upper / middle / lower);
1x½ liter to be kept by us at your disposal for 06 (six) months (upper / middle / lower).
Before loading operation, one sample was drawn from shore manifold, sealed and distributed as follows:
1x½ liter to be kept by us at your disposal for 06 (six) months.
Before loading operation, one sample was drawn from ship manifold, sealed and distributed as follows:
On start loading operation, one sample was drawn from pumpstack, sealed and distributed as follows:
During loading operation, one sample of first-foot was drawn from ship tanks, sealed and distributed as follow:
gac.
This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.aspx. Attention is drawn to the limitation of liability,
identification and jurisdiction issues defined therein. Any holder of this document is advised that information contained hereon reflects the Company’s findings at the time of its intervention only and
within the limits of Client’s instructions, if any. The Company’s sole responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and
obligations under the transaction documents. Any unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the
fullest extent of the law.
Page 7 of 7
GERDAU ACOMINAS S.A

QUALITY REPORT O/S OG&C 20023142/22

Samples drawn from shore tanks before loading operation
METHODS 16-1004 16-1004 16-1004
Density at 20°C, g/cm3 ASTM D 4052 0,8930 0,9065

Benzene, wt.% ASTM D 6563 80,34 68,68
Sum of Benzene/Toluene and Xylene , wt.% ASTM D 6563 88,72 78,26
Toluene, wt.% ASTM D 6563 7,08 7,77
Xylene, wt.% ASTM D 6563 1,29 1,80
Nonaromatics, wt.% ASTM D 6563 0,91 0,83
Naphtalene content, wt.% ASTM D 6563 3,48 7,54
Sample date - 05/27/22 02/11/22
C.R.Q. Nr. 04425150

gac.
This document is issued by the Company under its General Conditions of Service accessible at http://www.sgs.com/en/Terms-and-Conditions.aspx. Attention is drawn to the limitation of liability,
indemnification and jurisdiction issues defined therein.
Any holder of this document is advised that information contained hereon reflects the Company’s findings at the time of its intervention only and within the limits of Client’s instructions, if any. The
Company’s sole responsibility is to its Client and this document does not exonerate parties to a transaction from exercising all their rights and obligations under the transaction documents. Any
unauthorized alteration, forgery or falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law.
The results shown in this test report specifically refer to the sample(s) tested as received unless otherwise stated. All tests have been performed using the latest revision of the methods
indicated, unless specifically marked otherwise on the report. Precision parameters apply in the determination of the above results. Users of the data shown on this report should refer to the latest
published revisions of ASTM D-3244; IP 367 and ISO 4259 and when utilising the test data to determine conformance with any specification or process requirement. This Test Report is issued
under the Company’s General Conditions of Service (copy available upon request or on the company website at www.sgs.com). This report shall not be reproduced except in full, without the written
approval of the laboratory.

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CLIENT : GERDAU ACOMINAS S.

GERDAU ACOMINAS S.A

INSPECTION REPORT O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

CLEANLINESS REPORT OF SHORE TANKS

4P PETREPAR 150 GROUNDNUT OIL ACETONE 2.841,490 Stainless Stell

Santos, May 31th, 2022

GERDAU ACOMINAS S.A

SHORE QUANTITY REPORT O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

SHORE FIGURESTABLE ANP

Santos, May 31th, 2022

GERDAU ACOMINAS S.A

SHORE QUANTITY REPORT O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

TCV - Total Calculated Volume 237.957

CONSIGNEE : RAIN CARBON GERMANY GMBH

NOTIFY : RUBIS Terminal B.V., Harbour No.:4 1 4 5

DESTINATION PORT : ROTTERDAM, THE NETHERLANDS

MELTING POINT: < 6°C

GERDAU ACOMINAS S.A

ULLAGE REPORT O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

SHIP'S FIGURES AFTER LOADING - TABLE ANP

NET FIGURES Without V.E.F. With V.E.F.

Santos, May 31th, 2022

GERDAU ACOMINAS S.A

TIME SHEET / TIME LOG O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

DATE TIME REMARKS

May 25th, 2022 09:12 Pilot on board

Santos, May 31th, 2022

GERDAU ACOMINAS S.A

SAMPLE REPORT O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

Santos, May 31th, 2022

GERDAU ACOMINAS S.A

QUALITY REPORT O/S OG&C 20023142/22

VESSEL : M/T"BOW CAROLINE"

METHODS 16-1004 16-1004 16-1004

Density at 20°C, g/cm3 ASTM D 4052 0,8930 0,9065

Santos, May 31th, 2022

C.R.Q. Nr. 04425150

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