Date

UmAnG
Page

Rull
Subt(ycle t d HEA tenelenelne-eltaine
CH2
NH
2-methy ylo heManayne

2 Amines

CH-NHLH
N-meths_Methalauine
rine3

N-Fthy W-mehyl ethanaine

CHH
Sensul amine
 Date O5/o7/12
Page
umAnG5

Arune Lownenname IUPA Nane

CH,-LH,-NH, Etylurine Fthanamnhe

H, -H,-H-NH -pgylaruine Prapan--apuine

CHg-(H-UH Ispepylassine Pnaban-1-4uine
NH

H--CHH Ehylnehulanine N-methulmehunaik

CH-N-H unthylaine NN-0imetylmeha

(
nauine

GH-N-H,14 w,N-DieHyltutyla NNDiehylhutun-t

-mine amine

NA,-1M-CH=(H losine nop-2-en Faie

N4-(4 -NH Hxamthylene Prep Henane-LL-
dioine hiaine
NH
niline lint on Benzyan-
-aune
 Date 0 / 0 2
UnAns5
Page

3-Tm benzarie

utWe runes

CH

U7esmey- Pynapnidal
Bend angle less han lo128
emeTMio aunes
lgnpnd
emeim muy be_degined a8
hauing same mellan fAImula_ but
athargaeent
hauing difenent_2 uututalieui
Knaun_as
THS pepeniy

Ohain e
Pehiien
Mtuous
H,-(H,-1H H H - H
 Date

UmAnG
Page

chain meism 2

CH-H -CH -NH

3-1ethulutnauine

2 -dimethul Pslunamine
b)PeHhion_iamLLm
LHH (H, -(H,-(H,- NH
Pentunune_
LH-H-H,(H-(Hz
NH
fentun-1- aine
j H- (H-(H-(4-(Hz
Pentn-3-auine
CH3
CH(4-(HH
3-Methy hutun-3auine
 Date

RANS
Page

Metomerin -Fundisnal issmexun

Ex Hs
w ,2 Arin

WP

LH-CH,-CH-H NH-(H2
N Metyl_butanarune

D CH- -H - H
NN-Dime Hyl bopanaine
 Date
Page
uInAnG

-Reduction
Pdditien Hydncn
Metals tn/Hu
Sn/H
Fe/H

GX Nitzebenzene to niline NH
No +6CHJ n/HC

PNitzebtehane fo ehunaune

CH-CH,-H,-o é U7 CH,H,-A-N

CGAETf Nitile to runes

BBengeni~zik fo AJtPiNE-_Bnzyl arine

LEN H-NH
10HJ
Sn/H

XPneyhane itile to Orepunan

 Date
Page

CH-H-GtEN Snfrt
G H-CH,-(H,-NH

EHGHmann do bncik_dgrdaisN Headicn

LO Jeation

CoNH, to NH
Armide runs

Reagont:
Sile_praut Ko +2KBY tFH

C-(oNH t b r t fKoH
r KH

Co
 (Dao HLL
LumAne Page

Physical tnpeiutieS
Poiling Point
Thebeling peint
laines dehends upn Ayerequn bendin
Out dalLehd and annes
lalushel hae highet kelng hslt de
fo mall uze aygen_afsm uhid
mNe elltionegatie than rittepun

wste ut 1° ad acunes
haing ÁigNet_heiling _pint_
hauripg
htn _ 3 b e z a u s e 1o
aplity t am_-bnding
uAilP

bending

Anmutic VS Aliphat anine

CH- NH

kaug les bali

AHnT than allphat ne

to i u
tyersgenbgnding eaHiy
 Date
uImAnS
Page.

NSHC: Slupil al8 dehends upen

hylzbgenBNUing_due

due to hylregn
hnaiy

he boHC trength in amAne8 due

iN eN hauxing lone pain _eltin

ThRt i avalluhle kon cdenaton
i d e t o fI induutive eHe._

Exaple Out 2and3 arinds

3 amineg a mau
Doi then auines_duLe_fo tT
induutive etet

In ras Þhaye

due tot naluLhve let

 Date

UmAnS Page.

asict ty n 24 pho
xden aidty
2'aines 2 Tnine8}arunes 2NH

CHe)-/on
H-
133
i2Benzene to anli
4bylasuneAeuution

This neaton_wth J prinaly

auine ALy
 Date
Page

CHHN CH,-,-H
Carhlyarne Teet (t e (axblyanint eyve)
0bsduahio Feul Sm eling
Reagont ALohoictoH
CHC CChlsro-
foam)
fnaluthisceyanide CNE)|
NCMaus o-odinale

CH-CH-H, t CHC_t3HoH(ale

#Reation aAh wÜrgus aud

CaOuimaty aliphaticamines Neuut with

NAuud to otM dlihatn
dizniyn At3_hidh being ytabdle
PaNg+H
R-NHtHoNO R-OHN tHJ
h2y halde_2Nad uHh HoNo (waN
and Au fo_pelue_6p.c

CH NHP
Hono
Par 5 , (7HF tttt*
 Date
Page

Caueylaihe R
lCHH-NH, +(HJ t 3Ho

buimny AinesHCaud_eHh the

allehAi
ChNenefeaM i0 the_reene
KOR give_alkyl iLynide This athdyl
eatien RHON_p4th6
-ai

t CHU t 3HoH
Pnde
 (DatoI6F/22
LImAng Page

O diihioguih 1 2 3 Arines
TetHinsbeng's Tet
Hinsheng's Reagent engene &uphonyl leide (tso c
Primalty_Aines SUondaty unes TOtiay ruhs

NH-CH3 +HK S-NCH), +H No Aeaufin

N-Mel bengene NN Dime#yl benzene Due to ahsene _

ulphoine-anine Sulbhenarine hydsgn atom
CColuukle in waten Cinseuhle in cunkenl

Nete: NgO-a-daushengene Huhongp chlotide

Heplaued hy p- tulenesulphonul Chlwide

This aelutien Cp-foulene kulhengl chlaide) j the

sezuatict _imay, SeuANdAiy aug tetiay

EElednapilic Substitten Aeutien ines

NH
Aniine
 UimAnGage

2Anilne0 P_directing antl tivaig piou

d
t an aiuating g7u_due to #he_hesene
ne_kun eleutnen_cn utTEAN_ dnaiA

Omigaicn
NH
H t 367
3HBr
Cwhte_ PPe
24LTribnerme ilne_

Reautien Aniline uith (S

NH- NH--(
+ CH CooH
CH t
R-CH

t HB

t HOH CH CH(00H
 h_de anines behaue a nucdeaphilest
AMLACdeApNles_e HR Shie tare k haudng jone
pojn 6 eleelren on csution
18111
hy anline d pat UndOlgg_ Euede- Luatt
neaution?
MUAe to salt (omatien_ah alunisitra chloride
uiduhih u ud aa_tatalyt
Lhag and hete altsa3 a tteny deuhivih
u _utha neashA_
ZeittenL0 The diplaz D

HOL MI/OU hline to Sufhaiy

add
Sulphepation H, lo4 neplenent -Hby
SO2H
NH CHSO
NH
Ciliuigdliegn
(H-HS4 whate

Culphan audl