L !

{1\ Ttll t-Hl t NA AR If 1,irv l

Jt «;{' ()D H ' II ti Cl .2 0
IC 1rn 10 B.

~I ~PJP·hM1 b Gf\9 C11"' Qffit71 "

Ci1 3Hr O {coo)3 - 7

+l'lo 2' {3 0 { co_o )3 2 - t 1-1 3 0 t

( Ka !:__)
'2 7 l Ti 1b-r j [ c 1 µ-,i O(coo );-;-: J I i(.Q .J. • I, 7 " I0
-r

[ C31-f rO ( C00 ) 3 -J

.,, I o-r :: 1, 1
1, 1 :,e ,o-•

1.1 O, 1 x mll"lo I l X +-j :: (

t'~ -- - - -- - - - - --
0, 1 j f(l m O /

~ I ---------

= Ort x mmol
o ,. 1 ( roo -") m-t1 o / ----- - - ---- - -
--- -----
--------
. - - - f_t_ 1 -:- 6, 1 X ll'1 r('l0 /
ro - <5,/.xmmol --- - --------

8 S - c,, I~ -;<. = CJ, I ,<

-----
_.i_ r -:: 0 1 /7~ f "' -r Or
= D1 ~7_x________
_ _ X
· --:: ~8r~- - - - - - - - - - - - - - - - - - -
-- ____o,u_----- ----
- _ _--=------3. 11 , B_ __
- - - ---- -- -
_ ___:_7- +_y -= _ roO ______ _
J-= too-Jtr -=1 9 r
-- - - - -

--- -- - -- -
-------

--------

---- ---- -- - --
 -------------
Q o,~P'I:
Ac~ Cl ( ru:p = f,77 · tf'~ )_
( t19 ( Nf-/3 )2] t { f- F " r, 7 . 10 l )

N H ; 00 1'11 I · 0, f M
OIf Q n!1 o : ma cf<J A 9 C..J _ _ _ _ ------- -- --- --- -

A3 x A.9 t t x-
CA , t j : [,-: J
A 9t T :ZN # 3 ....,
ll ; A !um i,- _ bo h wli A .9 t hat il /Ol)ifO{i A 9 fi tr1 Pmb e n+u l{ r-ompte ~ r NH ]
[ x. J [ A.9 ( N +-I 3 ) 2J t-

- - -- -
t- r p • [ Aj t J[ .,cj : [ A3t j -= ic, P

[ xj
~f = [ A-9 { Nt-l3 )z] +-= [A q (1'J+f3 ) 2J + [ x-J
[ A9t J{ r-JH 3)1- l<L p (N H_ 3) 2

l< r = [ c J c)(-J
1op(N H_3)z
------------- ----
~1 -: [ ,C J l

fcip ( N+i 3r1

[,c..] -= ~ K-t- ~sp (Nt-h)-i

[ er- J = 1, 7 . 101 . 1,r=t _10- 10 (o,t /vi r,

0 IO 300 9' /O•J
; V 0,3009 . ro-V -= o,r , ,o- z M

_ m G rS''i ,&J[ f =_9,, . ,0-1 mol - 1oorl1 { · _111 , r ..3,/4,o/ 21 , r . 10 ' 2 =- t; , 219ro m
l oco rn / -4
CD G f bS 01 -t fr -- pb ro £q_1 .2- _ , o,~ 1/0_!_ t _ _
0
<1 ) -t ____ f :_

p1:, .1t -t .2rho ._ p b Q J(t ) + 4 H-t-rr6- f 0

= - 1 ,4» vot + ·
PbiOH s1 t- fb-2t t :iH ,o p_brs) 1" S0-4 2
- r pb0.1 + 4H t

@ potentia l tQd.OH

f 0 redof'f ::, f 0
pb , 01 / pbt t ro11 • f 0 fb 2 ! /!_6!!,1
= ( -0 ,H - (- f1 <1rs-) vo t l-
= 1, 10s vo,t-

2.

-c 0,029b /0,9 ~ :: t,t o r v-o H·

f 09 K ::: I I / o~r \fl! /f- -

01():J.96

1< = 1, r; 72 o_K _ 10 n; ·
- - -- - - - - -

---- - - - ------------

--- - - -- ----

- - - - - ·- --- --- -