1) If a block of copper at 1 atm and temperature 298K is heated at constant volume

(may
be one can think of doing this by keeping the what will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation

2
)(Vm - b) = RT
wher
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
1) If a block of copper at 1 atm and temperature 298K is heated at constant volume
(may
be one can think of doing this by keeping the copper block tightly in a container
made
from a material which has very low thermal expansion coefficient) to 308K, what
will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1) If a block of copper at 1 atm and
temperature 298K is heated at constant volume (may
be one can think of doing this by keeping the copper block tightly in a container
made
from a material which has very low thermal expansion coefficient) to 308K, what
will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
(p + a / Vm
2
)(Vm - b) = RT
where a = 8 N m4 mol-2
and b = 3 x 10-5 m³ mol-
¹. R≈ 8.31 m³ Pa K-
¹ mol-
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
temperature measurements be in error at 100 °C1) If a block of copper at 1 atm and
temperature 298K is heated at constant volume (may
be one can think of doing this by keeping the copper block tightly in a container
made
from a material which has very low thermal expansion coefficient) to 308K, what
will be
the final pressure? Given the volumetric expansion coefficient of cooper as 4.95x
10- 5
K
-
1
and isothermal compressibility is 7x10- 12 Pa-1
.
2) Calculate the work in compressing quasi-statically, isothermally 32 gms of
oxygen at
298K from 1 atm to 1000 atms. Assume ideal gas behaviour.
Suppose the pressure on 32 g of copper is increased quasi-statically and
isothermally at
298K from 1 to 1000 atm, estimate the work done. Given the density of copper is
8960
kgm-
³ and isothermal compressibility of copper is 7.0x10-12 Pa-1
.
3) A constant volume gas thermometer of volume 1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
(p + a / Vm
2
)(Vm - b) = RT
where a = 8 N m4 mol-2
and b = 3 x 10-5 m³ mol-
¹. R≈ 8.31 m³ Pa K-
¹ mol-
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
temperature measurements be in error at 100 °C1x10- 3 m
3
contains 0.05 mol of a gas. It
is assumed that the gas obeys the perfect gas law, pVm = RT ; where Vm is the
volume
per 1 mol of gas ; but, in fact, its behavior is better described by the equation
(p + a / Vm
2
)(Vm - b) = RT
where a = 8 N m4 mol-2
and b = 3 x 10-5 m³ mol-
¹. R≈ 8.31 m³ Pa K-
¹ mol-
¹ is called the gas
constant. The thermometer is calibrated at the triple point of water. By how much
will
temperature measurements be in error at 100 °C
temperature measurements be in error at 100 °C