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NEBOSH IOG1 Element3
NEBOSH IOG1 Element3
NEBOSH IOG1 Element3
On completion of this element, delegates will be able to demonstrate an understanding of the unit
content through the application of knowledge to familiar and unfamiliar situations.
(3.1) Outline types of failure modes that may lead to loss of containment of hydrocarbons.
(3.2) Outline types of failure that may lead to loss of containment of hydrocarbons.
(3.4) Outline the hazards, risks and controls available for safe containment of hydrocarbons
offshore and onshore.
(3.5) Outline the fire hazards, risks and controls relating to hydrocarbons.
(3.6) Outline the hazards, risks and controls available for operating boilers and furnaces.
Forces on materials
Materials used in the construction of plant, equipment, pipelines, structures, etc. used in the oil and
gas industries, both onshore and offshore, will be subjected to various forces which will affect their
stability, strength and bonding with other materials.
Any force imposed on an item constructed from any material is resisted by its internal structure,
with the internal force equal to the opposite of the force applied.
Creep
Another failure mode affecting materials used in the construction of plant, equipment, etc. on oil
and gas installations is ‘creep’. This is a slow progression deformity in materials caused by elevated
temperatures combined with a constant load, or stress, applied close to the materials ‘elastic limit’
or stress point at which a material, if subjected to higher stress, will no longer return to its original
shape. Brittle materials tend to break at or shortly past their elastic limit, while ductile materials
deform at stress levels beyond their elastic limit.
The extent to which creep will affect a material will depend upon:
time
temperature.
Strictly speaking this is not a true failure mode, as failure will occur as either a brittle or ductile
failure depending upon the type and properties of the material involved, but must form part of the
testing and inspection programme for materials and plant or equipment exposed to extreme heat or
high pressures.
Creep should be considered during the initial design specifications of any plant, and can be
controlled by the shape of the components and the choice of materials, such as the use of chrome-
molybdenum steels which have low creep characteristics.
During process operations, stress can occur in either the process vessel itself, its assembled structure
or in associated pipework due to:
periodic fluctuations in operating pressure
temperature cycling
vibration
water hammer
periodic fluctuations of external loads.
Strain is the term used to compare the ability of a material to change length when subject to
compressive or tensile forces, and is the ratio of the extension over the original length.
𝐶ℎ𝑎𝑛𝑔𝑒 𝑖𝑛 𝑙𝑒𝑛𝑔𝑡ℎ
𝑆𝑡𝑟𝑎𝑖𝑛 =
𝑂𝑟𝑖𝑔𝑖𝑛𝑎𝑙 𝑙𝑒𝑛𝑔𝑡ℎ
When a material is distorted by the forces acting on it, it is now in a state of strain, where the strain
is the ratio of:
𝐷𝑒𝑓𝑙𝑒𝑐𝑡𝑖𝑜𝑛
𝐷𝑖𝑚𝑒𝑛𝑠𝑖𝑜𝑛 𝑜𝑓 𝑚𝑎𝑡𝑒𝑟𝑖𝑎𝑙
When higher stress loads are applied, the material’s deformation will remain and become a
permanent feature preventing the material from returning to its original size. When this occurs the
material is referred to as being plastically deformed.
Tensile strength is the maximum force required to cause a fracture, and when a material has been
stressed beyond its yield point, varying degrees of permanent deformity or extension will occur.
Therefore, knowing the tensile strength of any material during the design specification phase will be
a useful guide as to its mechanical properties, and therefore its yield point.
Failure will occur during the lifecycle of any process vessel, pipeline or structure if the endurance
limits of the materials used in its construction are exceeded.
During the design specification phase, values must be decided upon for the maximum allowable
stress that any material can safely withstand. This can be identified by applying a safety factor to the
material that it could be expected to withstand in standard test conditions. This would allow for any
discrepancies arising during design, the loading, the quality of materials, and the standard of
construction.
When selecting and specifying materials, designers must also take into account the suitability of the
fabrication process, such as welding of joints and connections, and the operating environment itself
(whether onshore or offshore).
Stress cracks is the term used to describe the form of attack in which cracks occur, and rapidly grow
and can lead to failures such as brittle fracture of the metal.
Stress corrosion cracking can be prevented through the careful selection of materials which are not
susceptible to specific corrosive environments, or to a lesser degree, by annealing after fabrication
welding.
Corrosive fatigue is the term applied to the premature failure of materials present in a corrosive
environment, and is caused by cyclic stress, which refers to the internal distribution of forces (a
stress) that changes over time in a repetitive fashion. This can occur in mildly corrosive
environments and can greatly decrease the fatigue life of a component. Unlike stress corrosion
cracking, corrosive fatigue can occur in any corrosive environment and is not dependent upon a
specific combination of a corrosive substance and susceptible metal.
Where cyclic stresses are likely to occur, designers must specify materials which have a high
resistance to corrosion during the design specification phase.
Thermal shock
Thermal shock is:
the effect of cracking resulting from rapid and extreme temperature changes causing a
material to expand and contract in a cyclic manner and eventually leading to fatigue failure.
At some point the stress will overcome the strength of the material, causing it to crack and
eventually fail if preventative measures are not in place, such as:
An example of the results of thermal shock could be the failure of a weld in a ductile material, due to
imposed stresses and strains, resulting in a brittle fracture occurring.
Brittle fracture
Brittle fractures will occur suddenly with no visual signs, such as in stress corrosion cracking, and
occurs when an excessive load is placed on a structure and the material is not able to slip:
Small cracks form and rapidly spread through the material so that a massive failure occurs. Failure
can also occur when the applied stresses are below the yield stress, and can also form part of the
sequence of other failure modes.
The speed of this failure often results in some of the released energy forming a sound. Brittle
fractures will have a characteristic ‘crack’ or loud bang.
Inherently brittle material – the atomic structure of some materials has difficulty in giving way
under stress conditions, resulting in brittle fracture failure, such as, cast iron, glass and ceramics.
plate thickness
residual stresses present after the fabrication process
the operating temperature.
In crude oil tanks, for example, the sea water will corrode the base plates and rim faster than other
parts of the storage tank structure. Pitting corrosion will be a significant feature of any corrosion
identified on the annular rim.
Corrosion can also occur from the tank settling into, or onto, the foundation, or from settlement of
the foundation itself, with the corrosion affecting joints and protective finishes due to the
movement.
Bacterial corrosion can also occur in storage tanks for hydrocarbon products, such as crude oil with
high sulphur content. This will be displayed as a deep pitting penetrating the bottom plates and the
rim, resulting in leaks occurring.
Where corrosion occurs this will result in mechanical failure of the rim and bottom plates, resulting
in a loss of containment.
To achieve this we must know and define the ‘safe operating envelope’ necessary to contain any
such reaction, with the designer specifying safety boundaries in terms of the upper and lower limits
and how violations of these limits and system failures will be detected and corrected should they
occur.
The designer may face constraints on the design which will allow for tolerances and recovery from
faults, providing there are suitable warning systems in place to indicate an overrun or failure is in
progress.
Modern oil and gas installations rely heavily on fault detection, alarm systems and instrumentation
systems to maintain safe operations within the defined safe operating envelope. Knowledge of these
limits during the designing of processes and mechanical systems together with effective
As oil and gas installations change with age, modifications, additions, etc. and are subject to
maintenance over their operational lifecycle, the limits of the safe operating envelope should be
maintained and remain a critical element of the process safety system.
Where a pressure component is loaded beyond its yield point by a mechanical (or static) force, such
as the internal pressure of a pipe, or the weight on a vessel, the yielding can continue until failure
occurs.
Creep can lead to excessive deformation in turbine blades, and the rupturing of pressure systems,
and must be considered by designers during specification and load calculations when selecting
materials, such as chrome-molybdenum steels which have low creep characteristics.
Therefore, whilst design criteria will allow the calculation of the required thickness of materials, and
the stresses of the basic components due to the internal load and external pressures, the ultimate
determination of design loads will be left to the designer to quantify who must be competent,
experienced and must:
consider the use of materials which will avoid thermal shock and ensure that their strength is
sufficient to withstand it should this occur
ensure that the material has the appropriate thermal conductivity and heat capacity for the
operational and environmental conditions for its lifecycle.
Materials webpages from the UK’s Health and Safety Executive (HSE)
Web links
www.hse.gov.uk/offshore/materials.htm
Falling through the cracks video (YouTube) from the US Chemical Safety
Board (CSB)
www.youtube.com/watch?v=uo7H_ILs1qc
Weld failures
Welding is commonly used within the oil and gas industries during the fabrication of pressure vessel
shells, pipework systems and the installation of structures, including the attachment of non-pressure
components to a vessel wall, such as:
stiffening rings
lifting lugs
support clips for piping
internal trays.
Welded joints, as opposed to bolted joints, are also sometimes used for piping-to-vessel connections
to provide a leakproof connection.
The most widely used welding technique in fabrication process is arc welding.
Residual stresses can occur in the weld, and in the If the weld’s residual stress added to the
region adjacent to the weld, but due to the stress caused by an external load exceeds the
welding process are unavoidable. They are not, yield point of the material, a small degree of
however, considered dangerous when a static load plastic yielding will occur to redistribute the
is applied. stress.
To prevent the loss of ductility in heat affected This occurs in ductile materials, and one
zones, low-carbon non-hardenable steels are used important requirement for a good weld is high
as construction materials. ductility.
The residual stresses in heavier plates are usually removed by post-weld treatments. Cooling after
welding causes the weld to change dimensionally due to the temperature reduction and phase
change which may result in cracking in the weld, or the heat affected areas around the weld.
Therefore, the strength of a welded joint will be dependent upon the type of joint and the quality of
the welding, all of which is checked visually and by non-destructive testing.
Visual inspection will require a good light source, and will require the removal of surface coatings
such as paint, to allow the inspector to view the surface.
As visual inspection only allows for the external observation of the weld, or defect, it should not be
solely relied upon to confirm the integrity of joints, connections, etc.
Radiography
Involves the use of gamma or X-rays which are passed
through the material onto a strip of film.
Pressure testing
Involves subjecting a finished pressure system to a test
with the pressure at a value above the operating pressure,
usually 1.5 times.
Magnetic More sensitive than dye penetrant. Only suitable on ferrous metals.
particle
Can also detect sub-surface defects. Cannot detect defects at any
significant depth.
Eddy current Rapid detection of surface or sub- Cannot operate close to other free
surface flaws. surfaces – e.g. thin sheet.
Can measure depth of shallow flaws. Cannot detect deep defects.
Requires a power source.
Table 3.1: Summary of the advantages and disadvantages of different NDT techniques
(b) identify TWO NDT techniques that detect surface defects 2 marks
only
These systems will offer protection by activating emergency shutdown (ESD) systems such as:
pressure and temperature relief
flow parameter controls – flow rates, volumes in pipework, etc.
Collectively these systems are referred to as HIPS (High Integrity Protection Systems).
Where there is no independent mechanical system, instrumentation will be provided. This must be
of high integrity and have a high failure-to-safety built-in, be fault-tolerant and have redundant
systems capable of automatically taking over when the primary instrumentation fails.
When a fault or emergency situation, outside the normal safe operating envelope is detected, these
systems must be capable of operating quickly.
In a publication by the UK’s Health and Safety Executive (HSE), Loss of Containment Manual, it is
recommended that emergency shutdown (ESD) systems should have pressure transmitters, as
opposed to pressure switches in HIPS to achieve the fast response times when a situation outside
the normal operating envelope is detected.
These measures are supported by gas and fire detection and protection systems, which are designed
to protect the installation, plant, equipment from damage and personnel from injuries due to
exposure to gas and fire.
This will be achieved through monitoring of specific areas on the installation where fire is considered
a particular risk, such as in the event of an uncontrolled process, interaction of chemicals with air or
water, or through failure of containment systems in which a build-up of flammable gases will occur
and create an explosive atmosphere.
The fire and gas system must be capable of detecting such occurrences early in their development,
and alert process and control room personnel by setting of the ESD and associated visual and
audible alarms.
fire and gas detectors capable of detecting flame, smoke, temperature, rate of temperature rise
and installed throughout critical areas
feed monitoring information into control room displays, and ESD instrumentation / mechanical
systems to allow an automatic shutdown to occur when the detectors are activated.
Drilling systems
All operational functions and services related to drilling systems should be constantly monitored,
together with mechanical systems in place to control the drilling process. These may be located in
well-decks or drilling units.
Any such systems should also monitor and control water, steam and sludges for pressurisation and
lubrication, as well as the collection and transportation of oil and gas through the system to the
surface.
System monitors should be in place and linked into an ESD system to operate in the event of the
drilling control system failing.
Web links
Loss of Containment Manual from the UK’s Health and Safety Executive
(HSE)
www.hse.gov.uk/offshore/loss-of-containment-manual-2012.pdf
Example: Compressor
Motor
Gas flow to vessel
Control room
operating panel
It is possible that liquids may accumulate in the surge vessel and then enter the compressor –
therefore during abnormal operations liquid levels within the surge vessel can lead to catastrophic
compressor damage and failure.
To prevent this from occurring, the surge vessel is fitted with instrumentation to detect liquid
levels. The Distributed Control System (DCS) will under normal operating situations control the
operations of the surge vessel and compressor, sending by data to the control room. In abnormal
operating conditions, an independent (hardwired) detection and control system can activate an
emergency shutdown independent of the DCS.
The ESD system for the compressor would have three levels of instrumentation protection.
At 10% of the surge vessel’s capacity a high level alarm would operate in the control system
(controlled through the DCS).
At 50% of the surge vessel’s capacity, the detection system would communicate with the DCS
and initiate an emergency shutdown.
At 60% of the surge vessel’s capacity, the detection system (hardwired into the surge vessel)
would operate independently of the DCS and initiate an emergency shutdown.
All ESD systems should be independent of the normal production controls, so that in the event of a
failure affecting the DCS, emergency shutdown can still be performed independent of any system
failure. Likewise, control valves forming an integral part of an ESD should not be used for dual
purposes, such as for process operations and emergency shutdown.
All shutdown and blowdown valves should be designed to fail-to-safety. Blowdown refers to the
removal of liquid from a process vessel to reduce the likelihood of fires or explosions.
Shutdown valves forming part of the isolation for a pipeline and systems should always fail to a
closed position to prevent any uncontrolled release of contents.
Blowdown valves should on the other hand fail to an open position if their power supply or
control inputs are lost due to system failure.
If fail-to-safety does not form an integral part of any ESD system, the safety case or report will need
to be clear on the justification for any such exclusion.
Where by-pass systems are provided around shutdown valves, e.g. for maintenance purposes, these
will need to be locked closed, and the shutdown valve handwheels removed to prevent their
accidental opening. Any valves on hydraulic system return lines can cause failures, so should also be
locked open.
Levels of shutdown
The level of shutdown required as a response to an adverse situation will need to reflect the severity
of the situation. The following two tables set out the levels of shutdown response appropriate to
different levels of incident for offshore and onshore installations.
The UK’s Health and Safety Executive (HSE) provides information on control systems, safety
instrumentation systems, safety integrity levels and emergency systems, as well as incident
investigation reports on their control systems webpage.
Web links
Control systems webpage from the UK’s Health and Safety Executive
(HSE)
www.hse.gov.uk/comah/sragtech/techmeascontsyst.htm
3 Fire or gas alarm Production may be affected depending upon the location, nature
activated and extent of the hazard. Equipment may be shut down or isolated
depending on which zone(s) is affected and the sensitivity of the
zone(s).
5 Manual initiation The inventory is to be vented and the platform abandoned. Subsea
of abandoning Isolation Valves (SSIVs) shut and all essential utilities shut down.
2 Process shutdown Involves the shutdown of all process systems and can be activated
automatically by monitoring equipment/ detectors. The aim is to
isolate all process equipment and limit the potential for an incident
escalating out of control.
The proposed bypass of an ESD system must be requested by a competent person justifying the
bypass. As part of the justification a risk assessment must be carried out prior to the bypass, as this
will identify any risk control measures required to safeguard both the personnel working on the
isolated ESD, and additional measures required to safeguard the installation in an emergency
situation.
The bypass should be controlled by a permit-to-work, signed off by a competent issuing authority,
and take place for the shortest possible period of time, where the bypass will need to continue past
the original completion date/time, the extension must be monitored and controlled and effectively
communicated during shift changeovers.
All ESD bypass systems must be subject to regular testing and inspection to ensure they operate
correctly when required, after an ESD has been returned to service its function must be fully tested
to ensure its functioning under operational conditions.
As with other maintenance and testing activities, the bypass must be documented in a bypass log
detailing:
bypass conditions – equipment involved, systems affected by the bypass
time and date of the bypass, plus cross-referencing into the approved permit-to-work
date and time of any assessment of the bypass
when the bypass was removed and reinstated into operations.
The number of bypasses taking place at any time must be controlled to ensure the overall safe
operation of the installation is not affected, and any emergency situations which may arise can still
be effectively dealt with by remaining ESD systems.
Exam question
The higher the safety integrity level, the more critical the safety system is. Examples of safety
systems include trip systems, high-integrity protective systems (HIPS), pressure relief systems and
blowdown systems.
Standard operating procedures for process operations should clearly identify which instrumentation
functions have been assigned safety critical elements, together with their assigned SIL. Trip settings
for any such instrumentation must be recorded in a trip register, together with procedures for proof
testing and the frequency between tests conducted by competent persons – review the Deepwater
Horizon incident in Element 1.1 for the importance of such testing.
Testing must prove the operational and performance standards for instrumentation continue to
meet the design and operational specifications, and must be documented to provide evidence of
such tests in the event of a serious incident.
The frequency of such testing will be influenced by the SIL rating, the higher the rating the more
frequent testing of the system will be required, and will involve breaking down processes to examine
sensors and logic/final end elements of the process.
The testing of sensors can be easily achieved through inhibiting their logic controls resulting in a
more frequent testing programme. However, the testing of logic and process end elements will
require a physical trip of the operating plant and equipment to occur, resulting in a shutdown, which
will result in a less frequent testing programme for these elements.
Again, just as valves forming part of an ESD should be independent of other elements, production
control functions must be separate from protective functions to ensure both do not fail in the event
of faults occurring.
There is also the risk that the pipeline from the process area to the flare may not be structurally
designed to handle the combined weight and pressure of liquid and gas, resulting in fracturing of the
pipeline at a joint, bend, etc.
Where liquid blowdown is to occur, this should be routed through a system designed to handle
liquids, and out into a suitable storage tank, pressurised sewer, or open pit if space allows.
Flaring
Gas flares are widely used throughout the oil and gas
industry, as well in chemical and petrochemical plants.
It has been known that during incidents, emergency venting has burnt off the total gas reserves of
an installation. Therefore, at oil and gas installations, as well as providing the facility to burn off
excess waste gas, a flare system will also provide a vital safety function in relieving overpressure
which may build-up during non-routine operations or process faults, thus protecting both process
plant and equipment, but also pipelines from failure and rupturing.
Where overpressurisation occurs, emergency relief valves will operate to automatically release
pressure – in some cases for both liquid and gas content – which will be routed through a ‘knock-
out’ drum and through large flare-header pipework systems to the flare stack to be burned off as
they vent through the stack.
Flaring activities can produce a range of by-products and adverse effects, such as:
noise
smoke
heat
light
radiation
various combustion and thermal decomposition products.
All of these can be eliminated, or minimised, through good initial design and operating practices.
Types of flare
The types of flare are determined by two factors.
Height of the flare-tip.
Mixing method.
For most flare types combustion of the waste or process gases occurs through a diffusion flame. Air
is diffused across the boundary of the fuel stream towards the centre of the fuel flow, which in turn
forms an envelope containing the combustible gas mixture around the core of fuel gas, and then
creates a stable glare at the flare tip.
In order to ensure the combustion process is efficient, and to minimise the generation of smoke, a
good supply of air must be present, as well as the correct mixture of air and gas.
The two constant features for any flare system will be its ability to operate reliably and to meet its
function as part of the overpressurisation relief system in the event of non-routine operations or
process failures.
Air-assisted flares
Use forced air for combustion and mixing, resulting in relatively smoke-free flaring.
The burner will have many small gas orifices, in a spider-shaped pattern arrayed inside at the top
of a steel cylinder, with the air for combustion provided by a fan in the bottom of the cylinder.
The fan speed can be altered to vary the amount of air for combustion.
Often used where there is no steam available to the flare, but not suitable for large flare types.
Non-assisted flares
These are simple types of flares and are not fitted with any steam or air mixing facility.
Limited to use on gas streams with low heat content, and a low ratio of hydrogen/carbon – this
will burn well without producing a large quantity of smoke.
Operate with less air to allow complete combustion, and have lower combustion temperatures.
Pressure-assisted flares
Utilise the vent steam pressure to assist with the mixing of combustible fuels at the flare burner
tip, where there is sufficient vent steam pressure this type can be used on flare tips which would
usually have utilised steam or air, and will result in a smokeless discharge.
Fitted with burner heads which will operate depending upon the amount of gas to be burnt.
Can also have the burner arrangement at ground level – if so the flare must be located in a
remote area away from process units and storage tanks, and with adequate space.
Monitoring flaring
Flaring activities should be monitored to ensure the integrity of the flare, and its emissions, which
will be achieved through the use of:
thermocouple sensors (usually sited within the flame to allow continuous monitoring)
ultra-violet flame sensors
remote flame sensors
flue analysers (monitor the condition of the fluid and gas mixtures in the stack).
Visual observation should also take place to ensure excessive smoking does not occur, and to carry
out remedial action where dirty flaring is avoidable.
Open drains carrying non-hazardous waste will generally return to an oil drain tank, and then onto
an injection unit to feed into downhole re-injection.
Open drain caissons are usually fitted with an extraction point to allow the removal of samples for
testing, as well as allow regular monitoring for cleanliness and oil or residue content.
Closed drains
Usually fed to high pressure and low pressure closed drainage drums. Once the liquid has been
drained from a vessel, the gas contained and released from the closed drain drums will be sent to a
flare, whilst the liquids are sent to a separator to be re-treated.
Liquids within a closed drain will commonly contain hydrocarbons, and as such can become a hazard.
Closed drain systems should not be connected into an open drain system. In a fire, gases would
flashover into the open system spreading the fire further into ‘safe’ area where additional ignition
and fuel sources could be present.
Sewage
Sewage should be collected by a sewage system and processed at a treatment plant involving the
maceration and chlorination of the waste.
Treated sewage can then be mixed with sea water (for offshore installations) and untreated
‘domestic’ water (for onshore installations), for eventual discharge through a sewage caisson.
Food waste will also be macerated, and discharged through a sewage caisson. Offshore installations
may be permitted under national laws to discharge sewage directly into the sea.
Drain water will be passed through an interceptor unit which will usually heat up the contaminated
water, and inject treatment additives, before separating it into liquids, oils and sludges.
Separated oils will then be sent to a waste oil tank for storage, with solids dried and disposed of
safely and the water discharged into the sea when the oil content is low enough – 15 parts per
million (ppm) is stated in the International Convention for the Prevention of Pollution from ships
(MARPOL) from the International Maritime Organization (IMO).
An interceptor will consist of several layers of settling bays, which allow water to flow through each
bay whilst oil will stay on the top for collection in one area. The oil is then sucked out for safe
disposal.
Drain covers
Control room
operating
panel
Alarm
Oil level
Chamber 1 Chamber 2 Chamber 3 sensor
Shut off
to interceptor
Manual
isolation Manual
valve isolation valve
Automatic
isolation Outlet
valve stream
Offshore, an interceptor is often known as an oil/water separator, and will separate oil and water
before the latter is discharged into the sea. There are legal limits regarding the disposal of oil
contaminated water into the sea. A log of any such discharges must be kept, together with the
results of sampling conducted every 12 hours. Modern offshore installations will utilise a carousel
sampling system.
If too much oil accumulates in the separator, the excess oil will escape. Separators should be
installed with an automatic closure device and a high level alarm which will sound in a control room
to indicate maintenance is required.
Web links
All of the above can give rise to full-surface fires, which can be obstructed or un-obstructed.
Overfilling
Storage tanks can be overfilled due to:
Pressure relief valves will have an integral vent, which will open when a pre-set pressure is reached,
such as during tank emptying operations through pumping. In addition to pressure relief valves,
emergency valves will also be used to release any sudden rise in pressure beyond the normal limits
for the vent valves, for example, a fire in close proximity to a storage tank will result in the contents
heating and expanding.
Poor construction can also lead to deformation of the structure, as well as failure arising due to
settlement of foundations and/or tank bases.
Another common failure mode is due to faulty welding or the use of inappropriate steels during
manufacturing of the tank. Other structural issues will involve the shell thickness being inadequate
for the pressure or vacuum conditions, insufficient thickness to withstand repeated loading of the
contents or failure during, or due to lack of, hydraulic testing to prove the tank’s integrity.
Also the overpressurisation of tanks during refilling can cause expansion of the shell, resulting in the
weakening of seals. Likewise, the effects of vacuum when a tank is being emptied can also lead to
problems with the tank’s integrity, often resulting in inward bowing or warping of the shell, resulting
in damage to seals and joints.
As covered previously, corrosion to the annular rim at ground level, as well as damage resulting from
impacts on the shell’s surface coating, can cause the shell to weaken at the points of damage.
The tank will have a rim seal between the main shell and the floating roof, which will reduce vapour
evaporation and escape via the floating roof. The roof is supported by legs which hang down into the
liquid, so that when the liquid level is low, the roof will stand on the base of the tank, and a vapour
space will form between the liquid surface and the tank roof. The legs can be retractable to increase
the useable volume of the tank.
This type of tank will prevent the loss of fuel, by reducing the emissions of volatile organic
compounds (VOCs), but problems can arise due to the accumulation of snow and rain on the roof
which may result in the roof sinking. Where this occurs, water can be drained via flexible hoses from
a sump on the roof, usually passing through the tanks interior down into the base of the tank for
discharging through external control valves.
These tanks will have vents built into the fixed roof,
Floating deck to
together with inspection hatches. control vapours
Petrol
Consideration must also be given to the chemical and physical properties of the intended contents,
to ensure the contents and construction material are compatible and that failure will not occur due
to chemical attack.
As with all types of storage tanks, these should be protected from corrosion by suitable coatings, the
external surface of storage tanks intended to be sited underground at an onshore installation,
should be shot-blasted clean or chemically primed, and then coated with glass or synthetic fibre.
Supports must be designed to bear the weight of the tank, plus all the volume of the fluids contained
within the tank and taking into account the different specific gravities of the fuel contained, as well
as the additional weight from accumulated rainwater or snow.
Tank supports should also be designed to prevent corrosion from water accumulating within their
structures, and be designed to allow for the expansion and contraction of the tank due to
temperature changes.
Filling and emptying connections such as plug-on and unplug hoses, should be located in open air
and segregated from ignition sources. They should be no less than 2 m away from any building,
opening, trench, depression or drain, with spillages contained, during connection and disconnection
operations using flexible hoses, by a low sill or drained to a safe place.
The discharge end of the filling line should extend into the tank below the lowest anticipated level of
the liquid. This is to minimise aeration and the generation of static electricity. In order to maintain a
liquid seal, the discharge suction line should terminate above the bottom of the filling line.
Again the supports for pipework must be adequately designed, located and secured to support the
pipework’s configuration, as well as withstand anchorage and guide friction forces. Pipe supports in
the immediate vicinity of tanks will also require fire protection to a resistance of 2-hours.
Bunds should be designed and constructed to hold at least 110% of the tanks contents. Where bunds
may surround more than one storage tank, it should be designed to hold at least 110% of the largest
tanks capacity within the bund taking into account the space occupied by other tanks.
Where there is no hazard of pollution affecting the public, tank bunding to 75% of the tanks contents
may be permitted.
Where more than one tank is located within a bund, such as in a tank farm, immediate lower bunds
may be used to sub-divide tanks into groups.
This will allow containment of small spillages, and maximise the surface area of any spillage – this
will have an effect on the size of any fire occurring within a bund should the leak contents be ignited.
Bunds must be impervious to the liquid likely to be stored within the tanks, and designed to
withstand the full hydrostatic head (the vertical distance the liquid escaping from the tank will fall
Impact protection may also be required, such as crash barriers and bollards.
The bund’s height should consider the need to provide natural ventilation within the bund, as well as
escape for personnel and access to emergency personnel. Generally the height should not be more
than 1.5 m, or in the case of larger tanks up to 2 m. Where used, diversion walls and immediate
lower bunds should not exceed 0.5 m, unless ground conditions such as slopes require additional
height.
A bund’s floor should be made of concrete, or other material impervious and resistant to the liquids
stored within the tank, and provided with drainage (where necessary) to prevent minor spillages
accumulating near tanks. A suitable buried membrane may also be used, as can specially designed
systems using the water table to retain liquids not miscible with water.
No vegetation, other than short grass, combustible material, liquid containers or gas cylinders
should be stored in the bund, or within 1 m of the external wall of the bund.
Chlorate, or other oxidising substances, should not be used as weed killer within the storage area, as
this will introduce a fire hazard into the bund area.
Where surface water will be removed from a bund by an electrically driven pump, the equipment
must be of a type suitable to the zoning of the area – it must be intrinsically safe (see ‘selection of
safe equipment’ in Section 3.5).
Where a bund drain is used, the valve should be located outside the bund, with standard operating
procedures requiring the valve to remain closed, and preferably locked into the closed position,
except during cleaning operations.
Where surface water has been mixed with flammable liquids not miscible with water, this should be
routed through an interceptor to prevent the flammable liquids entering the drainage system.
The loss of hydrocarbon containment from storage tanks will also have a serious environmental
impact. Uncontrolled releases or leaks may enter surface water drainage systems, and cause
substantial water pollution outside the confines of the installation, as well as land contamination,
both of which can cause harm to our health if the contaminants enter the food chain.
Whichever filling method is used, a primary hazard to avoid is overfilling. We’ve already discussed
the consequences resulting from overfilling (see Buncefield in Element 1.1), with the consequences
for the immediate and surrounding environment potentially catastrophic.
Therefore, the tank selected to be filled with a liquid must have sufficient capacity for the intended
contents, together with continued monitoring of the delivery to ensure overfilling does not occur, as
well as audible and visual high level alarms to warn of any dangerous situation. As previously
covered, adequate bunding should also be provided, supported by spillage kits and equipment
should overfilling occur and result in escape of the liquid into the bund.
Another important aspect is the correct marking of storage tanks to prevent dangerous situations,
such as uncontrolled chemical reactions between incompatible liquids from occurring.
Jet fires are usually fuelled by gas, two-phase flashing liquids and pure liquid releases.
Jet fires will present a significant risk to personnel, plant and equipment, particularly on offshore
installations as the high temperatures of burning liquids sprayed onto surfaces can lead to structural,
vessel and pipework failures all of which can cause an escalation of the situation.
The confinement conditions will also have a bearing on the jet fire – either confined or unconfined. A
release of crude oil, or of mixed fuels, will have different heat flux characteristics on contact with
heated surfaces, so in a confined space a jet fires temperatures will be carried through the structure
more readily than when unconfined, where prevailing weather conditions will affect the jet flame.
A confined jet flame will also produce smoke, thermal decomposition products and carbon
monoxide / carbon dioxide content.
If water is present in the fuel this can result in a more unstable jet flame, and in the case of an
unconfined jet fire, the flame may be extinguished before the fuel supply can be isolated, resulting in
the potential for an explosion to occur.
During the design phase of process plant and equipment, consideration must be given to the
potential length of any jet fire flames, to ensure no buildings or structures are placed in close
proximity and to ensure safety areas are maintained.
Pool fires are turbulent diffusing fires which burn above a horizontal pool of vaporising hydrocarbon
fuel. As opposed to a jet fire, a pool fire has little or no momentum.
Pool fires involving heavy hydrocarbons will produce large volumes of smoke, whilst pool fires
involving LNG will burn more cleanly.
Vapour clouds can be ignited by an ignition source of greater energy than the minimum ignition
energy of the vapour cloud, and can result in an explosion the effects of which may be:
overpressure
fire
explosion
flying debris as missiles.
The time period from the release of the fuel mixture in air through to ignition can range from a few
seconds, to tens of minutes. The amount of fuel involved can also vary, in the case of gas the amount
can vary from a few kilograms to up to several tons.
The pressure generated by an explosion’s combustion wave is dependent upon how fast the flame
propagates through the explosive mixture, and how easily the pressure can expand away from the
cloud (this is governed by confinement).
When an explosion of a fuel/air cloud is ignited by a spark, the flame will normally start out with a
velocity of between 3 to 4 m/s. If the cloud is uncontained and unobstructed then the flame is
unlikely to accelerate to velocities of more than 20 to 25 m/s, with the overpressure negligible.
Within a building, or other enclosed space, the temperature of the burning mixture will increase,
with the air/fuel mixture expanding by a factor of up to 8 or 9. This will have the effect of
accelerating the flame front to several hundred metres per second.
If the ignition source originates from a weak source, such as a hot surface or spark, the explosion will
initially start as a slow burning deflagration. Due to obstructing objects and confinement, the
deflagration can accelerate and become fast burning.
When a deflagration becomes sufficiently rapid, a sudden transition from deflagration to detonation
can occur.
If this transition between deflagration and detonation occurs, pressure loads of up to 50 bar can
occur locally, resulting in severe damage within the building, compartment, etc.
th
Refinery fire at Feyzin. 4 January 1966 webpage from the UK’s Health and
Safety Executive (HSE)
www.hse.gov.uk/comah/sragtech/casefeyzin66.htm
A large amount of volatile material is The plant oxidised cyclohexane which, when
released rapidly into the atmosphere to heated to 155oC at a pressure of 128 psi produced
form a vapour cloud and disperse. caprolactam – this was used in the manufacturing
If the vapour cloud comes into contact of nylon.
with an ignition source before it is In addition the site also stored large quantities of
diluted below its lower flammable limit, benzene, toluene, naphtha and gasoline.
a UVCE will occur.
The process consisted of six reactors in a series
Shock waves and thermal radiation from
containing a total of 120 tonnes of cyclohexane,
the explosion affecting both the site and
and a small amount of cyclohexanol. The sixth
surrounding area.
reactor in the series contained 94% cyclohexane.
The effects will be most pronounced
when explosions involve reactive gases The fifth reactor had developed a 6 foot crack, and
– such as ethylene – and least where was bypassed using a 20 inch diameter pipe fitted
unreactive gases are involved – such as between the 4th and 6th reactors.
natural gas. As each reactor was 14 inches below the preceding
one, a dog-leg was welded into this pipe (the pipe
was fabricated from material on-site, but not from
the same material as specified by the designers).
An expansion joint, in this case bellows, was
incorrectly installed and is thought to be the main
cause of the accident.
st
Flixborough (Nypro UK) Explosion 1 June 1974 webpage from the UK’s
Health and Safety Executive (HSE)
www.hse.gov.uk/comah/sragtech/caseflixboroug74.htm
location – siting hydrocarbon process plants away from residential areas to minimise the off-site
consequences if an explosion does occur
quantities stored – keep the amounts of volatile liquids, especially those stored under pressure,
and gases to the minimum
design and layout – include the installation of remote isolation and shut-off valves, provide as
much space around process vessels and containment vessels as is possible to achieve, route
pipelines, cables and services together where possible
buildings – well-ventilated but resistant to the entry of vapours, minimum number of occupants
when located near process plant and containment vessels, if required in close proximity to a
process unit/containment vessel consideration to providing blast protection must be made
emergency and safety measures – include the installation of leak monitoring and detection
devices, water sprinkler systems and automated alarm systems.
generated.
Crude oil can contain varying amounts of wax, which can accumulate within the pipeline, especially
under colder conditions.
Therefore, pipelines require regular inspection and cleaning to remove deposits which will affect the
flow of the product, together with adding additional weight to the pipeline.
Generally there are three types of pipeline.
Gathering pipelines – used for transporting oil and gas from wells to treatment and processing
plants.
Transportation pipelines – larger pipelines for transporting oil, gas and refined products cross-
country.
Distribution pipelines – consisting of smaller pipes for delivering oil to consumer outlets.
The pipeline will also be supported by field services, which will include instrumentation, data and
communications. Pumping stations and entry/recovery points for ‘pigs’ will also be provided. A
‘pig’ is a device used to carry out inspections or clean the inside of a pipeline – smart pigs will be
sent along the inside of pipelines to inspect and record internal conditions and remove wax
deposits.
Instrumentation positioned along points of the pipeline are known as remote terminal units
(RTUs), and will be connected to a central control room to allow the monitoring of flow rates,
pressure, temperature, etc.
There are many ways of monitoring pipelines, ranging from walking the pipeline to visually inspect it,
to satellite surveillance and location systems.
Pipelines health and safety from the UK’s Health and Safety Executive (HSE)
www.hse.gov.uk/pipelines/index.htm
P D
Drain valve D
The decommissioning of hydrocarbon process plant also has the extra safety issues associated with
the product itself, and its associated hazardous nature.
Before decommissioning can begin, a comprehensive plan should be developed with the starting
point being the plant shutdown, before isolation and cleaning ahead of dismantling/deconstruction
can take place.
Similar to carrying out a HAZOP, or similar risk assessment process, before constructing,
commissioning and handing over a new process plant, the similar process should be followed to
identify the hazards associated with shutting down the plant, and setting procedures for the safety
of all persons present on the site, and involved in the shutdown, to ensure a safe transition from
operational status to isolation and disconnection from surrounding process plant, equipment and
pipelines – care must be taken to ensure this will not have an adverse impact on safety equipment
and systems.
Following shutdown and isolation, the next step is the decontamination of the plant.
Internal and external areas of structures, plant and equipment are likely to have been exposed to
contaminants, so will also require decontamination to:
remove contaminants and reduce occupational health risks to persons carrying out the
decommissioning of the plant
salvage equipment and maintain its usability as far as possible
clean up and restore the site environmentally.
Decontamination will usually involve the use of water, compressed air, and for heavy contamination
steam, caustic and detergents may also be required – again with the risks to the health of those
involved in decontamination evaluated in a risk assessment, referencing into technical information
from suppliers/manufacturers of the cleaning agents used.
The next phase of decommissioning is dismantling. This is carried out in phases and may require the
dismantling of some elements of the structure, process vessel, etc. before decontamination can take
place, with further dismantling and/or breaking up taking place once decontamination is complete.
Where plant and equipment is to be re-used it may require the application of a protective coating or
packaging, before transportation into storage or to another location.
Where practicable the preferred option is to recycle any components, supports, pipelines, etc. which
are suitable for continued use, after decontamination and refurbishment. If not possible, then
disposal will involve scrapping or disposing of the materials in a landfill site.
Decommissioning – offshore
Issues to be considered during planning
Decommissioning an offshore installation should be considered a process rather than a simple
deconstruction activity for the following reasons.
The nature of the working environment, which can change suddenly and dramatically and have a
serious impact on planned activities.
The technical nature of decontaminating and dismantling a structure where the surrounding
area is constantly shifting and moving.
Not all alterations, modifications, etc. may have been included in drawings and plans for the
installation.
The safe draining and removal of hydrocarbons, and other potentially hazardous substances and
materials stored on the installation.
Storage for materials, equipment and accommodation for personnel.
Safe isolation and disconnection from any well-head, undersea pipeline, etc.
Emergency response and assistance from the mainland in the event of a serious incident.
Full site details must be acquired, including all safety case information to allow a full determination
of the hazards, and development of appropriate procedures to safely secure and isolate any existing
oil and gas wells.
Adequate finance will need to be in place, as the decommissioning agent will need to know the costs
associated with plugging the well, abandoning equipment in place, etc.
Only contractors who have a proven track record and experience in securing existing oil and gas
wells should be selected to carry out such tasks.
removal of the deck support structures, including accommodation blocks and other facilities
removal of the drilling deck and plant
removal of plant and structures associated with the storage and transportation of oil and gas
brought to the surface.
The size and configuration of all of the above will differ from platform to platform, and will require a
survey to identify hazards to the health and safety of personnel carrying out the decommissioning.
This will require making a decision on how to safely remove and dispose of the platform and
associated structures, etc. Possible options include:
As with onshore installations, disposal will be based on future requirements for any re-useable
components and the cost of transporting components to shore for breaking up to allow recycling of
re-usable materials or eventual disposal at a suitable landfill facility.
The jacket structure (the structure supporting the platform from the seabed) poses a different set of
challenges and problems. How much of it can safely be left in place? This will have been in place for
years, possibly decades, and will have developed and support its own marine eco-system, but if left
in place will pose a hazard to marine transport.
The decommissioning agent will need to make a determination, in consultation with national marine
agencies/bodies as to the pros and cons of:
leaving the structure in place to continue to provide an established marine eco-system and, if
close to shore, marine recreation (e.g. scuba diving) and the need to provide effective maritime
warning and navigation beacons to mark the location
dismantling the structure from the surface to the seabed with the risks associated with working
at depth.
Due to the size of such structures, especially those on the seabed, it may be more economical to
abandon in place, following consultation with the relevant national or international marine agencies.
To reduce emissions associated with providing electrical power on a platform, electricity may be
supplied via cables laid on the seabed from an onshore facility. Again the environmental, technical
and safety challenges of their removal need to be considered. It is more common to disconnect the
power cables and to leave them in place, as opposed to dragging them up from the seabed and the
damage this can cause to aquatic flora and fauna. For both of these, the decommissioning work will
take place along the full length of the pipeline/cable, not just at the onshore and offshore
connections.
For seabeds, unless abandoning in place represents a major operational loss, it is more common to
leave seabed structures in place for the same reasons discussed above.
The amount of time the platform has been in place, and the nature of the operations and debris
likely to have been disposed of from the platform, will determine the nature and duration of any
seabed clean-up and removal operations.
The decommissioning, dismantling and disposal of these must be considered and planned at the
same time as the activities taking place offshore.
The decommissioning should follow the steps outlined for onshore facilities.
Planning should also include the likelihood of any contaminants penetrating the ground to reach the
water table. To prevent this identification of a decontamination area with an impervious hard
standing, bund and drainage/interceptor arrangements should be in place, with all decontamination
operations covered by a permit-to-work, risk assessments and safe systems of work.
To safeguard the health of personnel carrying out decontamination activities, health surveillance,
appropriate personal protective equipment and welfare facilities must also be provided.
Air quality/pollution
Environmental monitoring of the air quality during dismantling and decontamination activities will
need to be scheduled for the duration of the project. Air quality issues can arise in connection with:
venting and opening up process vessels, storage tanks, etc. to atmosphere or during
purging/inerting operations
cutting and burning operations using oxy-acetylene cutting equipment, or cold cutting using high
pressure water jets
spraying of detergent and other cleaning agents onto structures for decontamination in place
prior to dismantling and removal
the accidental release of asbestos, PCBs (polychlorinated biphenyls), hydrocarbons, etc. during
their removal.
Prior to decommissioning commencing, a full survey of the structure, plant, etc. should be carried
out to identify any potential health hazards, determine the route of exposure and likely health
effects and develop preventative measures to avoid or minimise exposure to any hazards by
personnel involved in such tasks.
Noise
Noise will be generated due to the use of plant and equipment during cutting, grinding, lifting, etc.
operations.
As with air quality, regular checks on the noise levels personnel will be exposed to in different areas
will need to be carried out by competent persons.
Consideration must also be given to the navigational hazard decommissioning operations may pose,
which may require the setting up an exclusion zone for maritime transport.
Where sub-surface/seabed structures are left in place, navigational charts will need to be updated
so that drag nets from fishing vessels do not snag on such structures.
Wherever possible, seabed structures should be abandoned in place to prevent harm to marine eco-
systems from dismantling, dragging, explosives, etc.
when more than one contractor is working on the platform at the same time
when responding to process failures, such as hydrocarbon leaks, whilst other processes and
activities are going on
where there is overlap between the platform and support vessel operations
when simultaneous maintenance operations are being carried out on the same plant/area by
different teams or contractors.
Fire is a chemical reaction involving rapid oxidation (burning) of a fuel. Three things must be present
at the same time in order to produce fire.
Fuel – any combustible material - solid, liquid or gas.
Oxygen – sufficient oxygen must be present in the atmosphere surrounding the fuel for fire to
burn.
Heat/ignition – sufficient heat energy must be applied to raise the fuel to its ignition
temperature.
The combination of these three elements is frequently referred to as the ‘fire triangle’.
The important thing to remember is that if any one of these three things can be removed there will
be no fire or the fire will be extinguished.
Liquids
Solids
Examples: gasoline,
Examples: coal, timber,
kerosene, turpentine,
paper, plastics.
alcohol, paints.
Gases
Examples: natural gas,
LPG, hydrogen, acetylene.
naked flames
external sparks
internal sparking
static electricity
hot surfaces
chemical reactions.
Classification of fire
In the UK fires are classified in accordance with BS EN 2 Classification of fires as follows (this is in line
with EU and International classification, but the US have a different system).
Electrical
a source of ignition – casings of electrical appliances would be a class a fire.
shop.bsigroup.com/ProductDetail/?pid=000000000030124873
A block of wood will require a hotter heat source (greater ignition energy) for combustion to occur
than will be required to ignite petrol. This is because when heated, combustible materials give off
flammable gases and vapours, which if the temperature is high enough and a sufficient level of
oxygen is present, ignition of these gases and vapours will occur resulting in a fire. Therefore, if the
petrol is already producing vapours it will be easier to ignite than the block of wood.
All materials will burn if sufficient heat is present to cause the molecules to break down and give off
flammable vapour. Once the vapour or gas is released it is this which ignites resulting in more heat
being released and therefore resulting in more reactions and the fire has begun.
The longer the fire burns the more the material will decompose, resulting in less material to react
and ultimately the fire to run out of material to propagate, causing it to die out.
Fuel Smoke
Oxygen
Heat
Ignition
heat
The decomposition of the material during a fire is referred to as pyrolysis. The smoke which is
produced during a fire contains the unburnt products of pyrolysis, including the vapours given off.
Growth
Induction
Time
Prior to the fire reaching the fully developed stage, there is a period of time where there is a risk of
flashover occurring.
This occurs due to the layering of hot gases beneath a ceiling, and the oxygen concentration in the
air being less than normal. At this time, as the concentration of gaseous fuel rises sharply, if air
enters it will mix with the fuel layer and, given the presence of heat and flame, a flashover will occur.
Fully developed
This is the stage where the reactions are not as rapid as the growth stage, but the fire continues
to burn violently consuming all the available oxygen and fuel sources.
This stage is characterised by large flames and very high temperatures, in excess of 300oC.
At this stage the fire is controlled not by the fuel sources present to burn, but by the amount of
oxygen on which it can feed.
Decay
At this stage, the fire has consumed all the available fuel and will eventually die down and
extinguish – this can be due to the intervention of on-site emergency teams or local emergency
services, or naturally due to the lack of oxygen and fuel to support the combustion stage.
As the structure of solids is based on tightly formed particles, it will require substantial heat sources
to be applied for a fire to be initiated.
Liquids
Liquids will readily supply fuel to a fire due to their ability to release vapour.
Liquids such as petrol, paraffin, white spirit, thinners, varnish and paints
present a significant fire risk.
Other chemicals, such as twin-pack adhesives, acetone and toluene also release 3
vapours, and due to their lower flashpoint present a greater risk.
Aerosol containers contain a flammable liquid, which is pressurized to a level so that it changes to a
gas. Therefore, these containers present a significant risk if they come into direct contact with a heat
source.
Gases
Common throughout workplaces and include natural gas and liquefiable
petroleum gas (LPG).
The most common type of flammable gas used in workplaces is LPG. These are
stored in pressurized cylinders and include butane and propane.
2
Also dissolved acetylene and oxygen mixtures are used in welding operations.
As with the vapours given off by flammable liquids, gases present a significant risk of fire and they
also pose a significant explosion risk.
Gases do not always pose a risk when in containers. Gases can be produced by chemical reactions,
processes, decomposition of waste oil, contaminated water etc.
Therefore, recognizing how the supply of oxygen can be increased or decreased is vital in
considering control factors.
Ventilation and air handling systems can provide an enhanced supply of oxygen, as can the presence
of oxygen cylinders used in welding, medical use in hospitals, etc.
As with gases, chemical reactions can also produce oxygen. Particular chemicals such as sodium
chlorate (pesticides), hydrogen peroxide (water treatment).
Oxidizers give off highly exothermic reactions which in contact with other
substances, particularly flammable substances.
Fire initiators
As we’ve seen previously, for a fire to start there has to be sufficient heat from an initiator or
ignition source.
About dangerous substances – Liquids webpage from the UK’s Health and
Safety Executive (HSE)
www.hse.gov.uk/fireandexplosion/about.htm#liquids
Web links
Fire prevention
Effective plant and process control design during the initial design phases.
Structural fire protection of buildings and support structures for process plant, equipment and
pipelines.
Segregating the storage of flammable liquids and gases away from ignition sources.
Use of inert gases to purge process vessels and storage tanks prior to maintenance work, or by
providing an inert blanket over flammable liquids in storage.
Controlling the quantities of flammable liquids and gases stored at the installation, either in
external storage vessels or in suitable storage arrangements within buildings which are designed
and provided with suitable ventilation and detection/alarm systems.
Minimising the likely ignition sources in process and storage areas through the use of intrinsically
safe equipment.
Use of monitoring and detection equipment for detecting vapours accidentally released from
storage or process vessel, before they reach the lower/upper explosive limits, which will trigger
an alarm and shutdown of a process unit, pump, etc.
Control
The avoidance of, or minimizing the potential for, an explosive atmosphere is a critical element of
eliminating the risk, or mitigating the consequences, of an explosion.
Oil and gas installation operators must consider the substitution of flammable substances with inert
materials, or minimizing the concentrations of the flammable substances, so as to avoid their
explosive range.
Where combustible liquids are concerned, the aim should be to reduce the concentration of any
mist formed to below the lower explosive limit. This in turn should ensure it is sufficiently below its
flashpoint and thus prevent an explosion.
With appropriate dispersal, these materials can prevent the formation of an explosive atmosphere.
This is known as inerting.
It follows that the materials used in the construction of containment vessels, etc. should be non-
combustible themselves.
Leak detection systems should be fitted, with particular attention paid to:
joints
piping
areas that may be subject to impact
areas that may be subject to hazardous interactions with other substances.
Mitigation
The best means of containing a primary explosion is to ensure that the process equipment is suitably
constructed to withstand one.
The pressure generated by a dust explosion is usually within the range of 5 - 12 bars. To design plant
to the same standards as pressurised vessels is likely to be cost prohibitive, therefore designers look
to design-in explosion venting.
Explosion venting
This is one of the most effective measures for relieving pressure, however it is often difficult to size
the vent correctly to ensure that sufficient pressure relief is available as the vent must allow
sufficient outflow of the burnt fuel and air to relieve the pressure being generated by the heat of the
explosion.
There are a wide variety of designs which are dependent upon the processes being carried out, such
as:
Dust explosion
The following hazards caused by venting will need to be Fire
controlled or minimized.
Therefore, consideration must be given to the location of explosion relief panel or venting during the
design stage of process units, vessels, etc.
Explosion suppression
Where explosion venting is not Suppressor
practicable, the next option is explosion Nozzle
Pressure rise
suppression.
detector
Any suppression unit will be: Ignition
permanently pressurised
fitted with a large diameter discharge
orifice
fitted with a valve which will work at a Pressure
high enough speed to discharge the wave Flame
suppressant (often achieved via a
small detonation charge).
Fire, explosion and risk assessment webpages from the UK’s Health and
Safety Executive (HSE)
www.hse.gov.uk/offshore/assessment.htm
Many fuels present on oil and gas installations are capable of accumulating and retaining charges
during high flow-rates, with this accumulated static electrical charge eventually released. If the
discharge energy is of sufficient potential it can result in the ignition of a fuel/air mixture. The
potential of any charge to ignite a flammable fuel/air mixture will be dependent upon the
flammability limits of any such mixture.
mixing
pouring
pumping
filtering
agitating liquids.
Therefore, during fuel loading/unloading activities effective bonding and earthing systems must be
in place. These will reduce the discharge by allowing continuity through the fuelling system’s
connections, as will conducting materials in the vessel and pipework’s structures.
In some cases additives can be added to fuels to prevent, or dissipate, any build-up of static
electrical charges.
Lightning
Lightning is a natural form of static electricity. A large amount of electrical energy is dissipated in a
short period of time in a limited space with varying degrees of damage. The vast majority of lightning
strikes exceed 3 000 amps.
Before a lightning strike the electrical potential between the cloud and the earth could be as much
as 1 000 000 watts per metre of strike. Therefore oil and gas facilities must be protected against
lightning strikes, with the measures employed based upon:
the lightning strike risk
the number of people likely to be affected
the location of the structure and the nearness of other tall structures
the type of construction, including materials used
the contents of the structure or premises including any flammable substances, floating roofs on
storage vessels, etc.
the explosion prone parts of any process should be kept as high as possible (on a building this
should be at roof level, to minimize the risk of building collapse)
where any hazardous part of the plant is located within a building, the area should be reinforced
and protected from the rest of the area by a blast wall
escape routes and other emergency response planning must take into account the explosive
nature.
The classification of hazardous areas into zones is based on the assessment of two factors:
Zone 0 An explosive atmosphere consisting of a mixture with air of flammable substances in the
form of gas, vapour, or mist is present continuously or for long periods or frequently.
Note: in general these conditions, when they occur, arise inside containers, pipes and
vessels.
Zone 1 A place in which an explosive atmosphere consisting of a mixture with air of flammable
substances in the form of gas, vapour or mist is likely to occur in normal operation
occasionally.
Note: this zone can include, among others, areas in the immediate vicinity of:
a Zone 0 area
feed openings
Zone 2 A place in which an explosive atmosphere consisting of a mixture with air of flammable
substances in the form of gas, vapour or mist is not likely to occur in normal operation
but, if it does occur, will persist for a short period only.
Note: This zone can include, amongst others, places surrounding Zones 0 or 1.
Type of Ex
Definition Zone(s) Examples
equipment code
Electrical and control systems webpages from the UK’s Health and Safety
Executive (HSE)
www.hse.gov.uk/offshore/controlsystems.htm
Furnaces
Furnaces are used in oil refineries to directly heat crude oil. By reaching its boiling point fractional
distillation occurs separating the various petroleum products, such as LPG, petrol, kerosene, diesel
oil, fuel oil and asphalt.
The crude oil is heated in a direct-fired furnace, and then fed into a vertical distillation column at just
above atmospheric pressure and close to 400oC. This results in all but the heaviest fractions flashing
into a vapour.
Steam boilers
In a steam boiler, fuel is ignited to produce a flame, which in turn heats water to above its boiling
point, instead of placing the flame directly under the boiler’s water storage, most modern boilers
now have superheating elements which will concentrate the space in which steam is generated to
give increased energy.
Steam boilers operate on the principle of convection – steam collects at the top of the boiler to pre-
heat water flowing into the boiler via inlet tubes, which ensures cold water does not enter the
boiler, thus keeping a high internal temperature.
Closed and open system boilers can also come in two different configurations.
Fire tube boilers – consist of an outer shell – referred to as the fire tube – with tubes of water
inside. Heated gases pass through the core of the fire tube to heat water in the internal water
tubes, which in turn generates steam.
Steam out Hot gasses
Boiler
Furnace Smokestack
Water tube boilers – consists of vertical tubes above the heat source. Water enters the vertical
tube and is heated until steam is produced, which then passes out through the top of the tube.
Hot gasses
Steam out
Water pipes
Furnace
Smokestack
Water in
Before operation of a boiler operators must ensure all valves and switches are operating correctly,
as well as visually inspecting all pipe fittings and valves to ensure they are clear of blockages and
remain open during use. A low-water cut-off valve should be installed within the system to ensure
water is maintained at operating levels, with regular tests carried out to ensure the low-water cut-
off valve functions correctly.
Boilers are fitted with safety valves to prevent the pressure rising above pre-set safe operational
limits, and the standard pressure valves fail to operate. It follows that safety valves should be
inspected, tested and maintained regularly to ensure their operation if overpressurisation takes
place.
Therefore, constant monitoring of temperature and pressure must take place to ensure the process
remains within safe design parameters, and overpressurisation safety measures installed onto
furnaces and distillation columns to prevent fire and explosion occurring.
Boilers
Loss of pilot gas supply – for the boiler to perform its function a pilot light will need to be
continually maintained to light the boiler fuel. The pilot flame is lit by an ignition transformer,
with the pilot light in turn igniting the main heating flame. For boilers using liquid fuel, the pilot
light is fuelled via an atomizer.
If the pilot flame is extinguished, e.g. due to a disruption in the fuel supply or over-pressure from
the main gas supply, the fuel supply to the pilot light will still enter the unit, resulting in a
potential build-up of flammable and/or explosive gases. This can result in a boiler explosion. To
prevent this flame detectors are used to ensure that the pilot light flame can be ‘seen’ at all
times whilst the boiler is in operation, and an alarm raised if the pilot light is extinguished.
Low tube flow – the flow of either hot water or heated air through the boiler tubes must be
maintained at all times so that both temperature and pressure in the boiler are maintained
within safe operational limits.
If tube flow is interrupted, or reduced, heat exchange will become inefficient, resulting in
temperature and pressure rises which could result in a boiler explosion.
Control of tube metal temperature (TMT) – this is essential to ensure excessive stresses are not
placed on boiler tubes during increased periods of demand.
Tube temperature monitoring of the boiler furnace walls, generating tubes, super-heater tubes
and re-heater tubes can minimise problems such as leaks, breaks and blockages in pressurised
areas of the boiler from occurring, as well as detecting heat-transfer reduction due to scale
build-up.
TMT is measured during operating cycles by thermocouples welded into the tube walls.
Boiler explosions are similar to BLEVEs, as steam will require 1 600 times more space than water and
will expand in seconds. So a sudden release in pressure from a structural failure, loss of water, etc.
will result in the steam being released under high pressure.
Firebox explosions occur after a flame-out has taken place and the firebox is hot. In gas-fuelled /
gas-ignition boiler systems the pilot light could be extinguished due to a disruption in fuel, with the
fuel vapours exploding in the firebox. This is likely to cause damage to the pressurised tubes inside
the boiler shell, resulting in structural failing and release of pressurised steam. This in turn is likely to
lead to a steam explosion.
Overfiring is the term given to an overlarge heating flame, and is caused by either too much fuel
being supplied, or poor flame adjustment, and can lead to flame impingement. This occurs where
the flame used to heat the water within the boiler comes into contact with the boiler’s surfaces and
components, such as heating coils or pipework which will cause erosion and corrosion, cracking and
failure of the materials.
Poor water management, together with the lack of / incorrect water treatment can also increase the
problems of flame impingement. This can occur through the accumulation of sediment, and other
contaminants, inside tubes which can result in localised heating on the inside of tubes whilst flames
impinge on the outside surfaces of the tubes.
Web links
Furnace/boilers webpages from the UK’s Health and Safety Executive (HSE)
www.hse.gov.uk/comah/sragtech/systems7.htm
Information sourced from the Health and Safety Executive and Government
Departments has been reproduced and/or adapted under the terms of the
open government license for public sector information version 2.0, as
presented by the National Archives at:
www.nationalarchives.gov.uk/doc/open-government-licence/version/2
Whilst every effort has been made to ensure the currency and accuracy of the
information contained within Astutis Ltd bears no liability for any omissions or
errors, or any concepts and interpretations advanced by the authors.