27

Solutions
solution of sodium chloride 69. Calculate the freezing point of the solution
G0/ An aqucous
freczes below
273 K. Explain the lowering when 31 g of ethylene glycol (C,H,O,) 1s
of water with the help of dissolved in 500 g of water.
in freezing point
a suitable diagram. (Delhi 2013C) (K,for water = 1.86 K kg mol ) (AI 2015)
osmosis and osmotic
61. Define the terms 70. A solution containing 15 g urea (molar mass
osmotic pressure of a solution
pressure. Is the 60 g mol ) per litre of solution in water
a colligative property? Explain. has the same osmotic pressure (isotonic) as a
(2/5, Delhi 2011) solution of glucose (molar mass = 180g mol)

List any four factors on which the colligative in water. Calculate the mass of glucose
62.
properties of a solution depend. present in one litre of its solution.
(2/5, AI 2011C) (3/5, AI 2014)

LAL (3 marks) 71. Define the following terms

(i) Osmotic pressure
63. Calculate the mass of ascorbic acid (Molar
(ii) Colligative properties (Foreign 2014)
mass = 176 g mol') to be dissolved in 75 g
of acetic acid, to lower its freezing point Some ethylene glycol, HOCH,CH,OH, is
72
by 1.5°C added to your car's cooling system along with
3.9 K kg mol) (2020) 5 kg of water. If the freezing point of
(K=
64. A 4% solution (w/w) of sucrose (M = 342 g mol) water-glycol solution is -15.0°C, what is the
boiling pointof the solution?
in water has a freezing point of 271.15 K.
(K, = 0.52 K kg mol and K, = 1.86 K kg
Calculate the freezing point of 5% glucose (M
mol for water)
= 180 g mol') in water. (Given : Freezing
point of pure water = 273.15 K) (Delhi 2014C)
(Delhi 2019) 73. 1.00 gofa non-electrolyte solute dissolved in
65. At 300 K, 30 g of glucose present in a litre 50 g of benzene lowered the freezing point
solution osmotic pressure ot of benzene by 0.400 The freezing point
of its has an

4.98 bar. If the osmotic pressure of a glucose depression constant of benzene is 5.12 K kg
solution is 1.52 bar at the same temperature, mol. Find the molar mass of the solute.
what would be its concentration?(AI 2019)
(AI 2013)
A 10% solution (by mass) ofsucrose in water
66. 74. A 5% solution (by mass) of cane-sugar in
has freezing point of 269.15 K. Calculate
water has freezing point of 271 K. Calculate
the freezing point of 10% glucose in water,
if freezing point of pure water is 273.15 K. the freezing point of 59% solution (by mass)
(Given: Molar mass of sucrose = 342 g mol, of glucose in water if the freezing point of
molar mass of glucose = 180 g mol") pure water is 273.15 K.
(Delhi 2017) [Molecular masses: Glucose CH,0,: 180 amu
Cane-sugar C,,H,,O : 342 amu|
6730 g of urea (M =
60 g mol'] is dissolvedin
(3/5, AI 2013C)
846 g of water. Calculate the vapour pressure
of water for this solution if vapour pressure A solution of glycerol (C,H,O,) in water
75
of pure water at 298 K is 23.8 mm Hg was prepared by dissolving some glycerol in
(3/5, AI 2017) 500 g of water. This solution has a
boiling
point of 100.42°C while pure water boils at
68, Calculate the boiling point elevation for a
solution prepared by adding 10 g of CaCl, to 100°C. What mass of
glycerol was dissolved
to make the solution?
200gofwater. (K, for water 0.52 Kkg mol", (K, for water = 0.512 K kg mol )
molar mass of CaCl, = 111 g mol")
(3/5, AI 2017C, Foreign 2014) (Delhi 2012, AI 2012)
 28 WEtECBSE

76. A solution containing 30 g of non-volatile 83. Define the foll

solute exactly in 90 g of water has a vapour van't Hoff factor-
pressure of 2.8 kPa at 298 K. Further 18 g
of water is added to this solution. The new
84. Define the folla
vapour pressure becomes 2.9 kPa at 298 K.
Abnormal mola
Calculate
i) the molecular mass of solute and S A (2 marks)
(11) vapour pressure of water at 298 K.
(Delhi2012C) 85. What is van't
values can it ha
Calculate the boiling point of a solution the solute mole
prepared by adding 15.00 g of NaClto 250.00g i) dissociatior
of water. (K, for water 0.512 K
=
kg mol
Molar mass of NaCl =58.44 g) 86. Assuming comp
(5/5, Delhi 2011)
the expected fr
78. A solution prepared by dissolving 8.95 mg prepared by dis
of a gene fragment in 35.0 mL of water salt, Na,SO,10
has an osmotic pressure of 0.335 torr at
25°C. Assuming the gene fragment is a (Kfor water = 1.8
Na = 23, S = 32
non-electrolyte, determine its molar mass.
(3/5, Delhi, AI 2011)
79. What would be the molar mass of a
87. A 1.00 mola
trichloroacetic a
compound if 6.21 g of it dissolved in 24.0 g
of chloroform to form a solution that has a
to its boiling po
boiling point of
boiling point of 68.04°C. The boiling point
van't Hoff factor
of pure chloroform is 61.7°C and the boiling
(K, for water = 0.
point elevation constant, K, for chloroform
is 3.63°C/m. (3/5, Delhi 2011)
88. What is van't H
80. The molecular masses of polymers are
value can it hav-
determined by osmotic pressure method and
not by measuring other colligative properties.
undergo dissocia
Give two reasons.
LAL 3 marks)
(3/5, AI 2011C)
89. A solution cont=
81Calculate boiling point of one molar
the mass 58.5 gm
1.06 g mL-l) of
aqueous solution (density It has an osmoti
KBr. [Given: K, for H,0 =0.52 Kkg mol, 27C. Calculate
atomic mass K 39, Br = 80] of NaCl in this s-
(3/5, AI 2011C) (Given: R =0.08

2.7 Abnormal Molar Masses

90. When 19.5 gof FF-
= 78 g mol) is d
VSA (1 mark)
the depression in f
82 Give reason for the following: be 1°C. Calculate t.
Elevation of boiling point of 1 M KCl F-CH,-COOH
solution is nearly double than that of 1 M Given: K,for wat-
sugar solution. (1/2, 2018)