NATIONAL PUBLIC SCHOOL

HSR, BENGALURU
FIRST SEMESTER EXAMINATION 2021-22
CHEMISTRY-Answer Key

Class: 11 Max Marks: 35

No. of pages: 3 Time: 90 Minutes

SECTION-A
1. d) 1 m 1
2. c) 1 × 1023 molecules OR c) C6H12O6 1

3. b) 1s2 2s2 2p6 3s2 3p6 3d9 4s2 1

4. (d) The probability density of electrons for 2s orbital decreases uniformly 1

as distance from the nucleus increases.

5. (c) maximum Principal quantum number of any element of the period. 1

6. Ans: a 1
7. Ans: b 1
8. Ans: d 1
OR
Ans: d
9. Ans: a 1
10. Ans: d 1
11. a) Na < Mg > Al < Si 1
12. a) For transition elements, the 3d-orbitals are filled with electrons after 1
3p-orbitals and before 4s-orbitals.

13. c) A < C < B < D 1

OR
c) Chlorine has less negative electron gain enthalpy than fluorine.

14. a) Electronegativity 1

15. d) Both a) & b) 1

16. c) all the available atomic orbitals of equal energies 1

OR
c)Mostly in the region beyond the internuclear region

1
17. a) pz 1

18. a) O2– > O2 > O2+ 1

SECTION-B
19. Ans: M= dx mass% x 10/ 40 = 8.325M 2

20. 2

OR

21. 2
a) Ans: Half filled 2p configuration in N -higher stability
and 2p4 configuration -more inter electronic repulsions.
b) Ans: Mg+ attains Ne configuration after losing the second electron. But Na+
already has Ne configuration.
SECTION-C
22 i) Ans: Comp (II) -intermolecular H-bonding with water. 1
ii) Ans: PCl5 - 5bp, no lone pairs, sp3d hybridized
IF5 - 5bp, 1lp, sp3d2 hybridized

2
 2
23. I2 + NO3- NO2 + IO3- (pH<7) 3

Ans: I2 + 10NO3- + 8H+ → 2IO3- + 10NO2 +4H2O

Ans:

SECTION-D
24. i) 2

Ans: 3

ii) 1
a) H2C=O b) CH3F c) HC≡N
sp2 sp3 sp 3

OR
i)

ii) Ans: CH3CH2 CH2+< (CH3) 3CCH+2< CH3 CH+ CH2CH3< (CH3) 3 C +

Ans:

sp2, trigonal planar sp3, pyramidal

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