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CHEMISTRY
ANSWER KEY & SOLUTION

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Answer Key

1. (C) 2. (B) 3. (C) 4. (A) 5. (B) 6. (A) 7. (B)

8. (C) 9. (A) 10. (D) 11. (A) 12. (B) 13. (A) 14. (D)

15. (D) 16. (B) 17. (C) 18. (D) 19. (A) 20. (A) 21. (B)

22. (B) 23. (B) 24. (C) 25. (D) 26. (A) 27. (B) 28. (A)

29. (C) 30. (A) 31. (C) 32. (A) 33. (D) 34. (C) 35. (A)

36. (D) 37. (D) 38. (D) 39. (C) 40. (D) 41. (A) 42. (B)

43. (B) 44. (A) 45. (C)

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1. Which of the following has maximum number of unpaired electrons ?
(A) Mg2+ (B) Ti3+ (C) Fe2+ (D) Cu2+
Sol. (C)
Electronic configureation of Fe2+ is

n=4
While Mg2+ has n = 0
Ti3+ has n = 0
Cu2+ has n = 1

2. During electrophilic substitution reaction of fullerene, the hybridisation of carbon atom

(A) remains sp2 in reactant as well as product (B) changes from sp3 to sp3
(C) change from sp3 to sp2 (D) cannot be determined
Sol. (B)
This problem includes concept of allotropic form of carbon (fullerene) and electrophilic substitution reaction of
fullerene.
When fullerene undergo electrophililic substitution, it undergo changes of hybridisation of carbon from sp2 to sp3.

3. Solids are attracted by magnetic field due to the presence of atoms, ions or molecules with unpaired electron, called
paramagnetic. Which among the following is paramagnetic ?
(A) Cl2O7 (B) Cl2O (C) ClO2 (D) Cl2O5
Sol. (C)
Molecules Total number of electrons Magnetic behaviour
Cl2O7 7 × 2 + 7 × 6 = 14 + 42 = 56 Diamagnetic
Cl2O 7 × 2 + 6 = 20 Diamagnetic
ClO2 7 × 1 + 6 × 2 = 19 Paramagnetic
Cl2O5 7 × 2 + 6 × 5 = 44 Diamagnetic

4. Count the total number of S––O bonds, which are having equal length in bisulphate ion ?
(A) 3 (B) 4 (C) 5 (D) 6
Sol. (A)
Structure of bisulphate ion is

All three bond lengths are equal.

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5. Which of the following statement(s) is/are incorrect about aspirin ?
P. Aspirin is analgesic Q. Aspirin is antipyretic
R. Aspirin is tranquilizer S. Aspirin doesn’t belong to narcotic analgesic
Choose the correct code out of the following
(A) Only P (B) R and S (C) P and R (D) Q and S
Sol. (B)
Aspirin is used to lower down the temperature so its is antipyretic it is also to cure the headache, so known as
analgesic.
But other two statements C and D are wrong.

6. What will be the product when phenol is treated with CO2 at 140-220° C ?
(A) o and p-salicylic acid (B) m and p-salicylic acid
(C) o and m-salicylic acid (D) Benzoic acid
Sol. (A)
Chemical reaction involved in given reaction is as follows

OH OH OH
COOH
CO 2
+

o-salicylic acid COOH

p-salicylic acid

7. Which of the following compound produces acetaldehyde on ozonolysis followed by acidic hydrolysis ?
CH3 C C CH3
P. Q.
H H
R. CH3CH2CH == CH2 S. CH3 C C CH3
Choose the correct choice out of the following
(A) P and R (B) P and Q (C) P, Q and R (D) Only P
Sol. (B)

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8. What is the intermediate involved in Reimer Teiemann reaction ?
(A) Carbocation (B) Carbanion (C) Carbene (D) None of these
Sol. (C)

9. What will be the product of the following reaction ?

(A) Propanol (B) Propanal (C) Acetaldehyde (D) None of these

Sol. (A)

10. Aspartame is one of the good artificial sweeteners whose use is limited to cold foods and soft drinks because
(A) It has very low boiling point (B) It gets dissociated at cooking temperature
(C) It is sweetener at low temperature only (D) It is insoluble at high temperature
Sol. (D)
Aspartame gets dissociated at cooking temperature.

11. Bakelite with low degree of polymerisation is used in making glues, in varnishes and lacquers and bakelite with high
degree of polymerisation is widely used for making electric goods, fountain pen barrels, combs, etc. It is an example
of
(A) condensation polymerisation (B) addition polymerisation
(C) free radical polymerisation (D) None of these
Sol. (A)
Bakelite is a condensation polymer of phenol and formaldehyde

+ HCHO — Bakelite

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12. Which of the following reagent is used to convert glucose to gluconic acid ?
(A) H2SO4 (B) Br2/H2O (C) HNO3 (D) dil.HCL
Sol. (B)

Glucose gluconic acid.

Glucose on oxidation produces gluconic acid

13. Caprolactum may be obtained from

(A) hexane + cyclohexane (B) adipic acid + terphthalic acid
(C) adipic acid and hexamethylene diammine (D) cyclohexanone + hexamethylene diammine
Sol. (A)

Hence, cyclohexane produces caprolactum.

14. Product of following reaction is

(A) (B) (C) (D)

Sol. (D)

Formation of N-acylated product is due to presence of lone pair on nitrogen atom.

15. Which reagent will be used to complete below conversion ?

(A) KMnO4 (B) H2SO4 (C) P2O5 (D) CF3COOOH

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Sol. (D)
CF3COOOH peroxytrifluoroacetic acid which is used to convert aniline to nitro benzene.

16. What will be the product obtained when A reacts with heavy water,

Mg/ether D2 O
  A  ?

Choose the correct option regarding product

(A) (B) (C) (D)

Sol. (B)
Reaction sequence is as follows.

17. The AfF5 molecules is trigonal bipyramidal. The hybrid orbitals used by the As atoms for bonding are
(A) d x 2 y2 , dz2, s, px, py (B) dxy, s, px, py, pz

(C) s, px, py, pz, dz2 (D) d x 2 y2 , s, px, py

Sol. (C)
The trigonal bipyramid formation is a molecular geometry with one atom at the centre and 5 more atoms at the
corners of a triangular dipyramid. AsF5 has sp3d hybridization. In sp3d hybridization, it is dz2 orbitals which takes
part.

18. Which of the following pair is iso electronics ?

(A) CO2 and NO2 (B) BF3 and NH3 (C) NO3– and CCl4 (D) NO+ and SbH5
Sol. (D)
Species having same total number of valence electrons are isoelectronics with each other. Total valence electrons in
5  6 1
NO+ = = 10
2
Total valence electrons in SbH5 = 5 + 5 = 10

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19. Those polymers which get decomposed by the process of biodegradation are known as biodegradable polymer.
Among the folloiwng, the biodegradable polymer is
(A) Cellulose (B) polyethene (C) PVC (D) nylon 6
Sol. (A)
Cellulose in a biodegradale polymer which occurs in nature and degragate easily.

20. The shapes of NO3– and CO32– are

(A) triangular planar (B) tetrahedral and triangular planar respectively
(C) tetrahedral (D) angular and triangular planar respectively
Sol. (A) Structure of NO3– is

Hybridisation = sp2
Shape = triangular planar
Structure of CO32– is

Hybridisation = sp2
Shape = triangular planar

21. Compare the acidic strength of reaction product, B with respect to phenol, A and choose the correct order.
Chemical reaction is

(A) A > B (B) A < B (C) A = B (D) None of these

Sol. (B)

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22. What will be correct stereochemistry of product obtained on reaction of but-2-ene with OSO4 ?

(A) (B) (C) (D) None of these

Sol. (B)
OSO4 causes cis hydroxylation.

23. Product obtained on reaction 2-methyl cyclohexene with mCPBA followed by hydrolysis is

(A) (B) (C) (D)

Sol. (B)
mCPB causes formation of epoxide ring from less hindered side and ring opening will also occur from less hindered
side.

24. Which of the following is the product of Hafmann elimination of ?

CH2N+(CH3)2 OH

(A) CH2N(CH3 )2 (B) NH2 + (CH3)2N

(C) CH2 + (CH3)2NOH (D) + (CH3)4N OH

Sol. (C)
Chemical reaction occuring in given reaction is as follows.

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25. Which of the following will give positive carbylamine test ?
(A) N, N-diethyl aniline (B) N methyl propyl amine
(C) N, N-diethyl butyl amine (D) 2, 4-dimethyl aniline
Sol. (D)
Only primary amine undergoes positive carbylamine.

26. Magnetic momenf of K4[Fe(CN)5(H2O)] is

(A) 0 (B) 4.92 (C) 3.87 (D) 2.83
Sol. (A)
Let oxidation state of Fe in K3[Fe(CN)5(H2O)] is x
(+1) × 3 + x + 5 × (–1) + 0 = 0
+3+x–5=0
x = 5 – 3 = +2
Magnetic moment of Fe+ can be calculated

As  = n(n  2) BM
where n = number of unpaired electrons
electrons configuration of Fe2+ in [Fe(CN)5(H2O)] is
= [Ar] 3d6 4s° 4p°

n=0  =0

27. IUPAC name of [Cr(H2O)4Cl2]Cl is

(A) tetraaquadichlorochromate (B) tetraaquadichlorochromium (III) chloride
(C) tetraaquadichlorochromium (II) chloride (D) dichlorotetraaquachromium (III) chloride
Sol. (B)
Alphabetically ligand is written first with ending at ––O–– followed by metal ending at ium and then negative end
of coordination compound.
tetra aqua for — 4H2O
dichloro — for 2 Cl
chromium (III) — for Cr3+
chloride — for
IUPAC name = tetraaquadichlorochromium (III) chloride

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28. When benzene is heated with chlorine in the presence of sunlight, it forms
(A) BHC (B) cyclopropane (C) p-dichlorobenzene (D) None of these
Sol. (A)
If the benzene is heated wtih chloride in the presence of sunlight then hot benzene will also undergo an addition
reaction with chloride or bromine. The product we get is 1, 2, 3, 4, 5, 6-hexachlorocyclohexane.

29. The product formed when toluene is heated in light with Cl2 and in absence of halogen carrier is
(A) chlorobenzene (B) gammexane (C) benzotrichloride (D) DDT
Sol. (C)

30. In IF7 molecule, central atom has all the bonded electrons i.e., no lone pair is present on the central atom. Structure
of IF7 is
(A) pentagonal bipyramidal (B) octahedral
(C) square pyramidal (D) octahedral monpyramidal
Sol. (A)
Structure of IF7 is determined by using hybridisation as follows

V MC A 77
H  7
2 2
Hybridisation = sp3d3
Structure = Pentagonal bipyramidal

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31. On dissolving moderate amount of sodium metal in liquid NH3 at low temperature, which of the following does not
occur ?
(A) Na+ ions are formed in the solution
(B) Blue coloured solution is obtained
(C) Liquid NH3 becomes good conductor of electricity
(D) Liquid NH3 remains diamagnetic
Sol. (C)
On dissolving moderate amount of sodium metal in liquid NH3 at low temperature, that liquid NH3 becomes
paramagnetic due to presence of free electrons.

32. Most of the compounds of transition metals are coloured in solid state or solutions. The transition metals which
have either completely filled d-orbitals or completely empty d-orbitals are colourless. The colour of transition metal
is due to
(A) presence of unpaired d-electrons (B) small size
(C) metallic nature (D) all of these
Sol. (A)
Unpaired electrons undergo excitation from lower energy level to higher energy level, hence causes colour to
transition metal ions. Then, phenomenon is called d-d transition.

33. What amount of current will be required to evolve 20g of chlorine in 6 h from HCl solution ?
(A) 10 A (B) 15 A (C) 5 A (D) 2.45 A
Sol. (D)
According to Faradays’ first law, we know that
w = z.i.t

w wF 20  96500
i= = 
zt eq weigth  t 36.5  360  60

= 2.45 A

34. Which of the following is not the assumption of kinetic theory of gases ?
(A) The actual volume of the gaseous molecules is negligible as compared to the total volume of the gas
(B) Molecules are perfectly elastic
(C) The critical temperature is the measure of the kinetic energy of the molecule
(D) The effect of gravity on motion of molecules is negligible
Sol. (C)
Assumptions of kinetic theory of gases are
 The gas consists of very small particles known as molecules.
 These particles have the same mass.
 The number of molecules is so large that statistical treatment can be applied.
 These molecules are in constant, random and rapid motion.
 Except during collisions, the interactions among moleculars are negligible.
 The average kinetic energy of the gas particles depends only on the absolute temperature of the system
 It is not the critical temperature but temperature.

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35. A solid is made of two elements P and Q. Atoms P are in ccp arrangement and atoms Q occupy all the octahedral
voids and half o the tetrahedral voids, then the simplest formula of the compound is
(A) PO2 (B) P2Q (C) PQ (D) P2Q2
Sol. (A)
Four atoms P contributes to one unit cell from ccp arrangement and 4 atoms Q from the all octahedral voids and
4 atoms Q from the half of the tetrahedral void contributes one unit cell.
So, formula of solid is P4Q8 so, the simplest formula of the solid is PQ2.

total volume of sphere

36. The space occupied in different packing is called packing fraction. Packing fraction =
volume of the unit cell

Fraction of total volume occupied by atoms in a simple cubic unit cell is

 3 2 
(A) (B) (C) (D)
2 8 6 6
Sol. (D)
In simple cubic arrangement, number of atoms = 1
a = 2r

Volume occupied by one atom

Packing fraction =
Volume of unit cell

4 3 4 3
r r
3 3 
= 
a 2 (2r) 3 6

37. 50 mL each of 1 M CH3COOH and 0.50 M NaOH are mixed (Ka for CH3COOH = 1.8 × 10–5). The pH of the mixture is
(A) 6.27 (B) 2.67 (C) 1.67 (D) 4.74
Sol. (D)
As we know, number of millimoles = molarity × volume in ml
 For 50 ml CH3COOH millimoles = 1M × 50 ml = 50 m moles
For 50 ml NaOH millimoles = 0.5 M × 50 ml = 25 m moles
Thus from the following equation,
CH3COOH + NaOH  CH3COONa + H2O
50 m mol 25 m mol 0
5 m mol 0 25 m mol

[salt]
pH = pKa + log
[acid]

25
= log(1.8 × 10–5) + log
25
pH = 4.74

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38. Chlorobenzene reacts with chlorine in the presence of Anhyd. FeCl3 gives ortho and para dichlorobenzene. Which
of the following order is correct regarding dipole moment of o, m and p dichloro benzene ?
(A) o > p > m (B) p > o > m (C) m > o > p (D) o > m > p
Sol. (D)

39. A compound obtained by the hydrolysis of the substance A, on reduction forms 2-hexanol. Hence the substance
A is
(A) 3, 3-dichlorohexane (B) 2, 3-dichlorohexane (C) 2, 2-dichlorohexane (D) 1, 1-dichlorohexane
Sol. (C)

40. A metal is said to be diamagnetic if it does not have any unpaired electron. Among the following, which one is
diamagnetic ?
(A) Co2+ (B) Cu2+ (C) Mn2+ (D) Sc3+

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Sol. (D)
Metal ion Electronic configuration
3+
Sc [Ar] 4d0
Mn 2+ [Ar] 4d5
Co2+ [Ar] 4d7
Cu2+ [Ar] 4d9
Sc3+ has no unpaired electron, hence it is diamagnetic.

41. Metals are generally hard, opaque, shiny and good conductor of heat and electricity. Which of the following
elements has highest density ?
(A) Os (B) Ir (C) Fe (D) Ru
Sol. (A)
Osmium (Z = 76) has maximum density among all elements. Osmium is a hard, brittle, bluish-white transition metal in
the plantinum family and is the densest naturally occuring element, with a density of 22.59 g/cm3.

42. Propyl nitrile may be converted into butyl amine by using reduction. Which of the following reagent can do this ?
(A) Sn/HCl (B) LiAlH4 (C) conc. HCl (D) All of these
Sol. (B)
LiAlH4
CH3CH2 –– C  N   CH3 CH2 –– CH2 –– NH2
Propyl nitrile Butyl amine
This reaction is known as Mendius reaction.

43. Arrange these substrate in case of dehydration.

H
OH OH OH OH
(I) (II) (III) (IV)

(A) I < II < III < IV (B) III < IV < II < I (C) I < II < IV < III (D) II < III < IV < I
Sol. (B)
Greater the stability of product formed greater is its ease of dehydration.

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44. A common nitrate test is known as brown ring test. An organic compound which give possible brown ring test and
chiral is

(A) (B) (C) (D)

Sol. (A)

Due to presence of NH2 group, it show positive brown ring test. It is chiral also due to presence of chiral centre
shown by #. Where carbon atom is attached to four different groups.

45. Which of the following will undergo fastest SN1 reaction ?

(A) (B) (C) (D)

Sol. (C)
Greater the stability of carbocation greater will be reactivity of substrate towards SN1 reaction.

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