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SAMPLE PAPER

CHEMISTRY
QUESTIONS

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1. The most acidic species among the following one is

(A) (B) (C) (D)

2. Determine the time required to 75% complete the first order reaction. If the reaction 20% complete in 10 min. Choose the
correct option.
(A) 0.233 min (B) 62.18 min. (C) 112.12 min. (D) 36.18 min.

Cl
COOH
3. IUPAC name of A is
A
(A) 3 methyl 2 chloro butanoic acid (B) 2 methyl 3 chloro butanoic acid
(C) 3 chloro 2 methyl butanoic acid (D) 2 chloro 3 carboxy, 2,3-dimethyl propane

4. Which of the following has linear geometry ?

(A) I3 (B) I 2 (C) H2O (D) SO2

5. Which of the following will undergo fastest elimination to give desired product ?

Cl Cl Cl

(A) (B) (C) (D)

Cl

6. Choose the process involved in the separation of ortho and para nitrophenol and the reason behind respectively
(A) steam distillation, metallic bonding (B) sublimation, Hydrogen bonding
(C) steam distillation, van der Waal's forces (D) steam distillation, Hydrogen bonding

7. If the mass of electron is 9.11 × 10–31 kg, Planck's constant is 6.626 × 10–34 J-s and uncertainty in position is 0.1 Å, then
uncertainty in velocity is
(A) 5.79 × 108 m/s (B) 5.79 × 105 m/s (C) 5.79 × 106 m/s (D) 5.79 × 107 m/s

8. If the bond forming entities are dissimilar with different electronegativity. The bond formed has partial ionic character as the
electron pair is attracted by more electronegativity. Such a bond is called polar covalent bond. Which of the following have
lowest degree of covalency ?
(A) NaCl (B) MgCl2 (C) AgCl (D) CsCl

O3 / NaOH Zn / CH3 COOH

9. CH  CH   X   Y , Y is

(A) CH2OH (B) CH3CH2OH (C) CH3COOH (D) CH3OH

CH2OH
10. An electron, a proton and an alpha particle have KE of 16 E, 4E and E respectively. What is the qualitative order of their
de-Broglie wavelengths ?
(A) e >  >  (A) = >e (C)  < e <  (D) <e 

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11. The another name of Nessler's reagent is ammonia kit is obtained by the reaction of KI with mercuric chloride and NaOH
solution. Which of the following is known as Nessler's reagent ?
(A) K2HgI4 (B) K2HgI4 + KOH (C) K2HgI4 + Hg (D) K2HgI4 + H2

12. Which one of the following is correct order ?

(A) –OH > –OR (order of –I effect)
(B) –CH3 > –CO3 > CCl3 (order of +I power)
(C) –F > –OH > –NH2 (order of – I effect)
(D) –NO –SO2R –SO3H–NO2 (set of meta directors)

13. Which of the following is not paramagnetic ?

(A) O 22  (B) B2 (C) N 2 (D) O2

14. Number of unpaired electrons of Ni in [Ni(CN)4]2– is

(A) 0 (B) 1 (C) 3 (D) 4

15. Vitamin B-12 also called cobalamin is a water soluble vitamin with a peyroline the normal functioning of the brain and nervous
system and for the formation of blood. Deficiency of vitamin B-12 causes
(A) scurvey (B) bery-bery (C) night blindness (D) None of these

16. Normality and molarity changes with temperature because they involve volumes. The normality of 0.3 M phosphoric acid,
H3PO4 is
(A) 0.9 (B) 0.1 (C) 0.3 (D) 0.6

17. Which of the following is incorrect regarding detergent ?

(A) Detergent is more better cleansing agent then soap.
(B) Detergent can be used in hard water also
(C) Detergent is soluble in water due to present of long hydrocarbon chain
(D) Detergent is insoluble in water due to presence of long hydrocarbon chain

18. Bond order of CO is equal to bond order of

(A) Be2 (B) O2+ (C) N2+ (D) N2

19. In a compound, atoms of element Y form CCP lattice and those of element X occupy 2/3rd of tetrahedral voids. The formula of
compound will be
(A) X3P4 (B) X4Y3 (C) X2Y3 (D) X2Y

20. What will be the product B in the following reaction ?

HBr aq KOH

H2 O2
 A  B

OH OH
(A) (B) OH (C) OH (D)

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21. Effective magnetic moment of Ce3+ ion is
(A) zero (B) 1.83 (C) 2.83 (D) 1.73

22. The solution which maintains its pH constant even upon addition of small amounts of acid or base, is called buffer solution.
which can act as a buffer ?
(A) NH4Cl + NH4OH
(B) CH3COOH + CH3COONa
(C) 40 mL of 0.1 M NaCN + 20 mL og 0.1 M HCN
(D) All of the above

23. What will be the product formed when acetone is treated with phenyl magnesium bromide followed by acidic hydrolysis ?

OH
OH OCH3

(A) (B) (C) OH (D)

24. Which of the following has highest 2nd ionisation energy ?

(A) O (B) N (C) C (D) B

25. Which of the following reaction is not a redox reaction ?

1
(A) CaCO3  CaO + CO2 (B) Na + H2O  NaOH + H2
2

1
(C) MnCl3  MnCl2 + Cl2 (D) O2 + 2H2  2H2O
2

26. Phenol is heated with phthalic anhydride in presence of conc. H2SO4. The product gives pink colour with alkali. The product
is
(A) phenol phthalein (B) bakelite (C) salicylic acid (D) fluorescein

27. Which of the following is a lanthanide ?

(A) Curium (B) Californium (C) Erbium (D) Amercium

28. Electron gain enthalpy increases across the period and decreases down the group. Which of the following order of electron
gain enthalpy is correct ?
(A) F < Cl < Br < I (B) F < Cl > Br > I (C) I > Br > F < Cl (D) I < Cl < Br > F

29. When two or more species have same structures are called isostructural species. SF4 is isostructural with
(A) TeF4 (B) CH4 (C) SnCl4 (D) XeOF4

30. In which if the following pairs of both the complenes show optical isomerism ?
(A) cis –[Cr(C2O4)2Cl2]3– , cis –[Co(NH3)4Cl] (B) [PtCl(dien)]Cl, [NoCl2Br2]2–
(C) [Co(NO3)3 (NH3)3] , cis–[Pt(en)2]Cl2] (D) [Co(en)3]Cl3, cis –[Co(en)2Cl2]Cl

31. When a compound has M–C bond called organometallic compound. Which of the following is not an organometallic
compound ?
(A) Tristriphenyl phosphine rhodium chloride (B) Ziesse's salt
(C) Ferrocene (D) Sodium cyanide

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32. XeF6 is colourless crystalline solid. It undergoes hydrolysis in water. The final product obtained is an explosive solid. This
explosive solid will be
(A) XeO3 (B) XeO (C) XeO2 (D) Xe

33. When a substance or element easily reduced, it is said to be oxidising agent. Which of the following represent correct order
of oxidising power ?
(A) F2 < Cl2 < Br2 < I2 (B) I2 < F2 < Cl2 < Br2 (C) Br2 < I2 < F2 < Cl2 (D) I2 < Br2 < Cl2 < F2

34. The number of spectral lines that can be possible when electrons in 7th shell in different hydrogen atoms return to the second
shell is
(A) 12 (B) 15 (C) 14 (D) 10

35. Which of the following compound is not a sandwich compound ?

I. Ferrocene II. Uranocene III. Nickelocene IV. Dibenzene chromium
(A) I, II and III (B) I, II and IV (C) All of these (D) None of these

36. Principal quantum number defines the principal shell in which electron is revolving around the nucleus and Azimuthal
quantum number described the name of the subshell and the shape of orbitals. The values of principal and Azimuthal
quantum number for 23rd electron present in iron atom are
(A) 3 and 2 (B) 3 and 1 (C) 4 and 1 (D) 4 and 0

37. [Co(NH3)4(NO2)2] Cl exhibits

(A) ionisation isomerism, geometrical isomerism and optical isomerism
(B) linkage isomerism, geometrical isomerism and optical isomerism
(C) linkage isomerism, ionisation isomerism and optical isomerism
(D) linkage isomerism, ionisation isomerism and geometrical isomerism

38. A compound A is obtained by reaction between first member of 1st group element and lightest element of periodic table, then
correct statement about compound A is
(A) A is acidic in nature
(B) A is basic in nature
(C) A is amphoteric in nature
(D) A turns blue litmus paper red

39. Select correct statements and choose the correct code out of the following.
I. CH2 – C – CH3 angle in (CH3)2 C=CH2 is smaller and the CH3 – C = CH2 angle is larger than trigonal 120°.
II. O–I–F angle is less than 90° (89°) in IOF4–.
III. In SeOCl2, Cl–Se–Cl angle is less than the Cl–Se–O angle.
IV. POCl3 is tetrahedral with a double bond between P and O, there is no lone pair on central atom.
(A) I and II are correct (B) II and III are correct
(C) I, II and III are correct (D) All are correct

40. Potasium superoxide is the inorganic compound with the formula KO2. It is a yellow solid that decomposes in moist air. It is
a rare example of a stable salt of the superoxide ion. Which of the following statement is incorrect regarding potassium
superoxide ?
(A) Oxidation state of oxygen in KO2 is –1/2
(B) Oxidation state of potassium is +1
(C) It is used in preparation of breathing mask
(D) It is a reducing agent

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41. Van-Arkel method of purification of metals involves converting the metals to a
(A) volatile stable compound (B) non-volatile stable compound
(C) volatile unstable compound (D) None of these

42. Werner's theory was the first successful theory, which explained the properties of complexes. According to Werner's theory
the primary and secondary valence of [Co Cl3(NH3)3] Cl3 is
(A) 3 and 3 respectively (B) 6 and 6 respectively (C) 3 and 6 respectively (D) 6 and 3 respectively

44. Boron on reaction with CO2 and H2O produces boron hydride as a major constituent the other byproduct produced in these
reactions are
(A) H2O and C (B) H2 and CO2 (C) H2 and C (D) H2O and CO2

43. Element A burns in nitrogen to give an ionic compound B. Compound B reacts with water to given C and D. A solution of C
becomes 'Milky' on bubbling carbon dioxide. The element A is
(A) Na (B) Mg (C) Ca (D) Be

45. The product of the following reaction

OH

Br2 / Fe
  ? is .....
CHO

OH OH OH OH
Br Br
(A) (B) (C) (D)
Br CHO CHO CHO CHO
Br

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