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_Bat
ch: Dat
e:

1. Accordi
ngt oBohr'
sModel
ofhy
drogenatom
(a)t
otalenergyoft
heel
ect
roni
squanti
zed

(
b)angul
armoment
um oft
heel
ect
roni
squant
izedandgi
venas

(
c)both(
a)and(
b)
(
d)noneoft
hese

2. Whi
choneamongt hefoll
owi ngstat
ement si
scorrect?
(
a)Anorbital
containi
nganel ectr
onhavingquantum number sn=2;
l=0;
m=0ands=+1/
2isspher
ical
.
(
b)ThefrequencyofX-raysislessthanthatofr
adio-wav es.
(
c)Al
lphotonshav esameener gy.
(
d)Asint
ensityofli
ghtincreases,i
tsfr
equencyalsoincreases.

3. Photoel
ect
ri
cemissionisobserv
edfrom asurf
aceforf
requenci
es1and2ofi
nci
dentradi
ati
ons(
1>
2)
.Ifthemaximum kineti
cenergyofphotoel
ect
ronsi
nt hetwocasesareintherat
ioof2:1,then
thr
eshold fr
equencyv 0i
sgiv
enby

(
a) (
b) (
c) (
d)

4. Corrector
derofr adi he1stor
usoft bi He+,
tofH, Li2+
,Be3+i
s
+ 2+ 3+
(a)H>He >Li >Be (b)Be3+>Li
2+
>He+>H
+ 3+ 2+ + 2+
(c)He >Be >Li >H (d)He >H>Li >Be3+

5. Therat
ioofr
adi
ioff
ir
stor
bit He+andLi
sofH, 2+
is
(a)1:2:3 (
b)6:3:2 (
c)1:
4:9 (
d)9:
4:1

6. Therati
oof(
E2–E1)t
o(E4–E3)f
ort
hehy
drogenat
om isappr
oxi
mat
elyequalt
o
(a)11 (
b)12 (c)15 (
d)10

7. Anel
ect
roni
saccel
erat
edt
hroughVv
olt
age.I
tsdeBr
ogl
i
ewav
elengt
his

(
a) (
b) (
c) (
d)al
loft
hese

8. Thecalcul
atedv
alueofmagnetcmomentof26Fe3+i
i s
(a)3.
89B.M (b)1.73B.
M (
c)4.
90B.
M (
d)5.
92B.
M

9. I
fanel
ect
ronhasspi
nquant
um numberof+ andamagnet
icquant
um numberof–1,i
tcannotbe

r
epresent
edinan
(
a)s-orbi
tal (
b)p-
orbi
tal (
c)d-
orbi
tal (
d)f
-or
bit
al

10. I
ftheK.
E.ofapar
ti
clei
sdoubl
ed,
itsdeBr
ogl
i
ewav
elengt
hbecomes

(
a)2t
imes (
b)4t
imes (
c) t
imes (
d) t
imes

11. Howmanyel
ect
ronswi
l
lhav
em (magnet
icquant
um number nFe3+i
)=0i on?
(
a)12 (b)13 (c)11 (
d)14

12. Ther
adi
usofsecondst
ati
onar
yor
biti
nBohr
’sat
om i
sR.Ther
adi
usoft
het
hir
dor
bitwi
l
lbe

(
a)3R (
b)9R (
c) R (
d)4R

13. Thewor kf
uncti
onforametalis4eV.Toemi taphot
o-el
ect
ronofzer
ovel
oci
tyf
rom t
hesur
faceoft
he
metal,t
hewavel
engthofi
nci
dentli
ghtshoul
dbe
(a)2700Å (b)1700Å (
c)5900Å (
d)3100Å

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14.Whi
choft
hef
oll
owi
ngsetofquant
um number
sbel
ongt
ohi
ghestener
gy?

( l=1,
a)n=2, m =0,
s=+ ( l=0,
b)n=3, m =0,
s=+

( l=0,
c)n=4, m =1,
s=+ ( l=1,
d)n=4, m =1,
s=+

15. It‘
0’i
sthet
hresholdwavel
engt
hforphot
oelectr
icemi
ssion,‘
’t
hewav el
engthofli
ghtf
all
i
ngonthe
surf
aceofamet aland‘
m’ i
sthemassoftheelectr
on,
thentheveloci
tyofej
ectedel
ectr
onisgi
venby

(
a) (
b) (
c) (
d)

16. AssumingRydber
g’sconst
ant( obe109670cm–1,t
RH)t helongestwav
elengt
hli
neintheLy
manser
ies
of thehydr
ogenspectr
um i
s
(a)1215.
8Å (b)1025.
8Å (c)972.
6Å (
d)949.
8Å

17. Theor
bit
aldi
agr
am i
nwhi
cht
heAuf
baupr
inci
plei
svi
olat
edi
s

(
a) (
b)

(
c) (
d)

18. Anel ectr

onispr
esenti
n sub-
shel
l.Thepossi
bleval
uesofazi
mut
halquant
um numberf
ort
his
elect
ronare
(a)0,1,2,3 (
b)1,2,3,
4 (c)3 (
d)4

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ITJEE At
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Answers

1. C 2. A 3. C 4. A 5. B 6. C 7. D

8. D 9. A 10. D 11. C 12. C 13. D 14. D

15. C 16. A 17. B 18. C

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1. Whichofthef ol
l
owingisnotcharact
erist
icofPlanck’
squantum theoryofradiat
ion
(A)Theabsorpti
onoremissionofenergytakesplaceconti
nuously
(B)Radi
ati
onisassociat
edwi t
henergy
(C)Radiat
ionenergyisnotemi t
tedorabsor bedconti
nuouslybutint hefor
m ofsmal lpacket
scal
l
ed
quanta
(D)Themagnitudeofenergyassoci
atedwi t
haquant um i
sproporti
onal t
othefrequency

2. Whi
choft
hef
oll
owi
ngi
sincor
rect
,whenanel
ect
ronj
umpsf
rom nthl
evel
to1stl
evel
inhy
drogenat
om?

(
A)Numberofspect
ral
li
nes=

(
B)Numberofspect
ral
li
nes=
(
C)I
fn=4,thenumberofspect
ral
li
nes=6
(
D)Numberofspect
ral
li
nes=

3. If i sthet
hreshol
dwavel
engt
hforphotoel
ect
ri
cemission, thewavel
engt
hofl
i
ghtf
all
i
ngont
he
sur
faceofametalandm,
themassofe–,
thenthevel
oci
tyofej ede–i
ect sgiv
enby

(
A) (
B)

(
C) (
D)None

4. Whi
choft hef
ollowi
ngpai
rofi
onshav
esamemagnet
icmoment
3+
(
A)Cr andCo+2 B)Fe+2andV+2
(
+3 +3
(
C)Fe andV D)Mn+2andCu+2
(

5. Agasabsorbsphot
onof300nm andre-emit
s2phot
ons,i
foneofithaswav
elengt
h450nm;t heot
her
has
(A)750nm (B)150nm (
C)900nm (D)none

6. Theuncer
tai
ntyintheposi
ti
onofaparti
clemovi
ngwi t
haveloci
ty
4x106cm/
4. secisequalt
oitsde−Br
ogli
e’swav
elengt
h.Theuncert
aint
yini
tsvel
oci
tyi
s,
( 5x105cm/
A)3. sec ( 5x106cm/
B)3. sec
(C)7x106cm/ sec (D)7x105cm/sec

7. I
fthetot
alener
gyofanelect
roni
nahydr
ogenatom i
nanexci
tedst
atei
s–3.
4eV,t
hent
hedeBrogl
ie
wavel
engt
hoftheel
ect
ronis
(
A)6.6×10–10m B)3×10–10m
( C)5×10–9m
( ( 3×10–12m
D)9.

8. Thet
woel
ect
ronshav
ethef
oll
owi
ngsetsofquant
um number
s:
n l m s
x 3 2 −2 ½
y 3 0 0 ½
Whi
choft
hefoll
owingistr
ue?
(
A)xandyhavesameener gy (
B)xhasgr
eaterenergythany
(
C)xhasl
essenergythany (
D)xandyrepresentsameelect
ron

9. Oft
hef
oll
owi
ngquant
um st
atedesi
gnat
ionswhi
chi
s/ar
enotal
l
owedst
atef
oranel
ect
roni
nanat
om.

n 1 M
I 3 1 -
2
I
I 3 1 0
I
II 3 0 -
1
I
V 3 3 0
V 3 0 1/2

(
A)I
,I
I (
B)I
II
,I
V (
C)I
,I
II
,I
V,V (
D)I
,I
I,
II
I,
IV

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OneorMor
ethan

10. Theenergyofel ectroni nt hef irstBohror bitofH- at

om is-13.
6eV,t
henwhi
choft
hef
oll
owi
ng
+
stat
ement(s)i
s/arecorrectforHe
(A)Theenergyofelectr
oni nt hesecondBohror bitis-13.
6eV
(B)Theki
neticenergyofelect ronint hesecondor biti
s13. 6eV
(C)Thepotenti
alenergyofel ectronint hethir
dorbitis-12.1eV
(D)Thevel
ocityofelect
roni nt hesecondor bi
tis2.19×106ms-1

11. Whi
choft
hef
oll
owi
ngi
str
uef
ort
hedi
ff
erent
iat
ingel
ect
ronofscandi
um?

(
A)t
heor
bit
alangul
armoment
um i
s

(
B)spi
nangul
armoment
um i
s

(
C)spi
nmul
ti
pli
cit
yis2
(
D)or
bitangul
armoment
um i
s

12. Whenphotonsofener gy4.

25eVst ri
kesthesur f
aceofamet alA,theeject
edphot oel
ectronshav e
maxi
mum K. E.,KA eVanddeBr ogli
ewavelengt
h, .Themax imum K.E.ofphot
oelectr
onsl iber
ated
f
rom anot
hermet alBbyphot
onsofener gy4.2eVisKB =KA –1.5eV.I
fthedeBr ogl
iewav elengt
hof
t
hesephotoelectr
onsis thenwhichiscorr
ect
(
A)theworkf uncti
onofAis2.25eV (B)Theworkfunct
ionofBi s3.
7eV
(
C)KA=2.00eV (D)KB=2.75eV

Compr
ehensi
on

Asingleel
ectronor
bitar
oundastati
onar
ynucleusofchar
ge+ZewhereZi
sconst
ant
.Itr
equir
es47.
2eVt
o
exci
tetheelectr
onfr
om secondBohr’
sOrbi
ttothethi
rdBohr
’sOr
bit
.
13. ThevalueofZis--
(A)9 (
B)7 (
C)5 (D)2

14. Ener
gyrequi
redt
oexci
tet
heelect
ronf
rom t
hir
dtof
ourthor
bit-
-
(A)16.
5eV (
B)21.8eV (C)37.
5eV (
D)9.
4eV

15. Thewavel
engt
hofr
adi
ati
onr
equi
redtor
emoveelect
ronf
rom f
ir
stor
biti
s
(A)3.
653nm (
B)36.
53nm (
C)365.
3nm D)3653A0
(

16. Thepot
enti
alener
gyofel
ect
roni
nfi
rstor
biti
s
( 5x10–16J
A)- (B)- 5x10–15J
2. (
C)-
1.1x10–16J (
D)-
3.2x10–14J

17. Theki
neti
cenergyofel
ect
roni
nfi
rstor
biti
s--
(A)9x10–16J (
B)8.7x10–18J C)5x10–19J
( ( 5x10–17J
D)5.

FI
ITJEEPat
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r 2ndf
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na,
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0612-
3299798/99,
2205551/52
FI
ITJEE At
omi
cSt
r
Cl
i
uct
p
ure
CHEMI
STRY
CAS
Answer
s

1. A 2. D 3. C 4. A 5. C 6. A 7. A

8. B 9. C 10. ABCD 11. ACD 12. ABC 13. C 14. A

15. A 16. C 17. D

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3299798/99,
2205551/52