NACE Corrosion Data Survey Metal Section 6th Ed Nace Publisher 1985

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I '
t
CORROSION
t
DATA S U R V E Y
Metals Section
i
Sixth E d i t i o n
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,
;
AN OFFICIAL
EE;
PUBLICATION
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Published by
National Association of Corrosion Engineers
1440 South Creek Drive
Houston, Texas 77084
Library of Congress Catalog Card Number: 84-62018
ISBN 0-915567-07-5
Neither the National Association of Corrosion Engineers, its officers, directors, nor members
thereof accept any responsibility for the use of the methods and materials discussed herein.
No authorization is implied concerning the use of patented or copyrighted material. The infor
mation is advisory only and the use of the materials and methods is solely at the risk of the
user.
Printed in the United States. All rights reserved. Reproduction of Contents in whole or part or
transfer into electronic or photographic storage without permission of copyright owner is ex
pressly forbidden.
r
e
'
Copyright 1985
National Association of Corrosion Engineers

PREFACE TO T H E SIXTH EDITION
A number of changes have been made in the Sixth Edition of this book to improve its accuracy and utility. Since the original edition
of the Corrosion Data Survey was published some thirty years ago, new or modified alloys have been introduced and a separate
survey on nonmetallic materials was published in 1975. An effort has been made in this edition to incorporate as much new data
(current to 1980) as possible and to revise and update the data on existing metallic materials wherever data could be obtained.
The earlier editions reported the highest corrosion rates for a given environment-alloy combination in cases where multiple
references were found for the same conditions. This was considered to be the best practice for earlier 'editions where many dupli
cate references were not found. However, where a large number of data are available, the highest reported corrosion rate may not be
representative of the expected performance of the environment-alloy combination, Consequently, the editor of this Sixth Edition
used his engineering judgment in reporting corrosion rates from conflicting data in the literature.
A number of alloys have evolved since the earlier editions were published. For example, alloy 20, alloy B, alloy C have been
replaced, mostly by alloy 20Cb3, alloy B-2, and alloy C-276 respectively. These newer alloys can have corrosion resistance that is dif
ferent from their predecessors. Whenever information was found on the new alloys, it was included In this edition. When no informa
tion was available on the newer alloys, the data on the older alloys were retained. No effort was made to verify the data carried over
from previous editions.
Some format changes have also been made. Most of the data from the short tables of previous editions have been incorporated
into the main tables. New categories of ferritic stainless steels (alloy 26-1 and 430) and austenitic stainless steels (20Cr-25N1-4.5Mo)
have been added. Since the corrosion rates of different copper base alloys were quite similar in most of the environments, these
were grouped into fewer alloy categories. Alloys G, G-3, 20, and 825 have been grouped together into a single family where previous
ly only data from alloy 20 and CN20 were included. A number of tables such as those for corrosion by waters, soils, atmospheric cor
rosion, low temperature corrosion, and stress corrosion cracking were eliminated since these were no longer considered adequate
to cover the topic areas of interest. Finally, the footnotes for corrosives have been deleted from the tables. References concerning
hazards of corrosives can be found at the end of the introduction.
It is believed that these changes improve and update the available information on corrosion of metals in various environments.
However, neither NACE nor the editor believethat corrosion performance of alloys can be specified on the basis of data presented
in this survey alone. Materials selection requires sound engineering judgment for each application. Additional information is re
quired for making the proper choice of materials.
D. L. Graver
Editor
INTRODUCTION
I n the development of new chemical processes, questions in ent ry represents the pa ge and line on which the data will be
variably arise concerning the choice of materials for certain found . Many synony ms tor t he corros ves i have been cross
equipment. However, since available corrosion information Is referenced in the index, although only one name will be given
scattered widely throughout the literature, these questions fre in the tables. If the corrosive of interest cannot be found in the
quently are difficult to answer. index, locate synonyms or another similar corrosive if possi
This survey summarizes both published and previously ble. If an alloy of interest is not among those listed, data for a
unpublished data in a group of tables for ready reference in

similar alloy may apply.
determining suitability of materials for possible use. These In read ng i the data table s, reference should be made to
tables should serve only as a guide, and it is to be expected

the temperature/concentration matrix shown on the fold-out
that in most cases additional information will be necessary. page. This illustrates the method by which concentration and
The tables have been checked against actual plant conditions

temperature are compared a gainst cor rosion rates. The
and a good correlation has been found. In cases of doubt, abscissa desi gnation "Percent Concentration in Water" d oes
representatives of metal and other material suppliers often

not necessarily mean "percent solution," but often pertains to
slurr es i or mixt ures above satura tion percenta ges. Data do not
can be helpful in supplying additional Information. Also, the
services of a corrosion engineer, to aid in precise interpreta

invariably conform to the actual boiling points of mixtures.
When reac tions at tempera tures abo ve boiling points are

tion of the data, combined with supplemental information will
noted it is assum ed that there is a pressure factor even though

be most beneficial. ·
th s i is not denoted in the matr ix.

Much of the da ta in this edition are taken from the Fourth
and Fifth Editions, although numerous new data points have
been add ed and man y data points from prev ou i s ed itions ha ve How the Data Are Posted
been changed or d e l e t ed . A li st of data sources and i ndividuals
Data taken from the literature are ad justed to fit the incre
who have helped review the data from previous editions ap
ments of the temperature/concentration matrix and therefore
pears at the end of this introduction. Many other individuals

cannot be considered exact. For example, a posting at the in
have contributed information and materials which was care
te rsection of the 40% co ncentration line and the 100 F (38 C)
fully considered. Their help was appreciated and is gratefully
temperature line actua lly represents a concentrat on i of 35 to
acknowledged.
45% and a temperature of 50 to 150 F (10 to 66 0).
No data are posted on zero concentration lines ; theref ore,
any posting on the shared line between data squares repre

How to Use the Survey sents 100% concentration, Postings on the 100% lines usually
refer to anhydrides but also may refer to some concentrations
Persons usin g the surv ey are remin ded that the data g iven in wh ch i a sma ll pe rcentage of wa e l r is p resent as may be he
t
are i
Ind cat ve i on y l and are not to be interpreted as absolut es case in eve ryday plant operat ons i . In some instances, special
w ith respect to specific app lications. The primary values of the arrays of data on an hydrides are posted. Data on mi xtures of
surve y are that it (1) identifies materials which are i

man fes tly unknown proportions are post ed on the 100% i
l ne . Thus, beer
unsuitable, (2) locates those which may have sa tisfactory per

is post ed as "100% beer."
formance and are candidates for further consideration, and (3) In this edition as in earlier editions, the relative impreci
gives limited information other than corrosion rates concern sion of the corrosives is acknowledged. Sometimes data are
ing performance which may be helpfu l. A list of relat ed NACE posted which are derived from exposures of materials to
pub lications a nd othe r related references ma y be found at the reagent grade corrosives. However, many of the data come
end of this introduction. from repor s t of actual operat ng i s ystems where reagent grade
Throughout this book , materials are arranged l

a on g the corrosives are rarely, if ever, encountered.
hori zontal a xis of each pa ge of tables. Corrosives are listed The following comments enlarge on the means used to
alphabetically along the vertical axis. The data representing present the data and emphasize the importance of many addi
average penetration per year are plotted on a matrix of variable tional factors in determining the corrosion resistance of a
temperatures and concentrations in water. A key to the matrix
material, since these cannot always be expressed in simple,
used in the tables, a key to the data points, footnotes to the
grap hic form. Consequently, IT S
I IMPORTANT THA T TH E
data tables , a nd a table ide ntify ing the metals and alloys are
FOLLOWING NUMBERED SECTIONS BE READ CAREFULLY.
located on the fold-out page immediately following this intro
duction for convenient reference. For comparison of penetra

1. Corrosives
tion rates, some typical rates are given in the Average Penetra
Although corrosives are listed alphabetically in the main
tion Rate per Year Compared to Weight Loss table also
tables, a series of other tables and graphs listed in the Table of
located on the fold-o ut pa ge. Penetration rates are not an un
Contents presents additional information on special topics
qualified indication of performance. Materials with low
. . and on certain generally encountered corrosives. Previous ex
penetration rates in a given corrosive may be unsuitable, or

perience has revealed that grouping corrosion rates by similar
failure may occur by some mode irrelevant to penetra tion. For compounds is helpful. When information on the particular cor
example, fish liver oil may be cataly zed by some copper a lloys, rosive under consideration is insufficient or lacking, there may
thus making copper unsuitable for this corrosive. Also, nickel, be others in the same general group which could be expected
which has a low corrosion rate in mercury, may stress crack. to react with materials in a similar manner.
Locating Data 2. Materials of Construction

To find data on a particular material in a particular cor Materials of construction available at reasonable cost
rosive, refer to the sub ect j index at the back of the boo k. and in a wide variety of forms have been selected for general
Locate the corrosive of interest. The number following the cor rosion rating. In special cases , other ma terials also are
plotted. Materials have been grouped under general classifica T he effect. of heat flux. on the corrosion rate must be
tion headings according to the major base metal. Within each recognized. Maintaining a liquid at a bulk temperature of 248 F
classification are a number of materials frequently considered (120 C). in a essel

v can produce no corrosion, whereas the
to have comparably similar corrosion resistances. For exam same temperature on the heating side of a metal surface may
ple: result in catastrophic corrosion,
Temperatures are plotted in degrees Fahrenheit from O t o
a. In carbon steels, carbon content up to 0.30% is not con 500 (-- 18 t0 260 Celsius) on the vertical axis of the matrix
sidered to alter appreciably the corrosion rate. shown on the fold-out page. This matrix makes up the data
tables throughout the book.
b. Silicon bronze, aluminum bronze, and tin bronze are con
sidered to have similar corrosion resistances in most 5. Corrosion Rates
media, but i
t i
s recognized they can differ markedly in An arbitrary set of corrosion rates has been established
specific environments. for this survey to meet the requirements of instrument, design,
and maintenance engineers. (See the Key to Data Points on
c. I n stainless steels, Types 302, 304, 304L, 321 and 347 are ex fold-out page.) The ideal rating (denoted in the tables by a s olid
pected to have similar corrosion resistance and are circle) has been assigned when corrosion is less than 2 mils
g rouped as 18Cr-8Ni austenitic stainless in the corrosion (50 ,um) per year. Many materials have t his property and may be
tables. used for some pieces of equipment, although they may be
ruled out for others because of other failings , such as con
d. In aluminum alloys, the following types are expected to tamination of product, brittleness, temperature limitations , or
have equivalent corrosion resistance: 1100, 3003, 3004, unavailability in suitable form,
5052, 6061, 6062, an d cast 4 3, 8214, 3 56, and 4 06. No alumi When this highest degree of corrosion cannot be in
num alloy containing over 1.0% copper should be con dicated, a secondary rating (an open circle) representing less
sidered to have corrosion resistance equal to these. than 20 mils (508 pm) per year corrosion rate is used. In the
development of this category, considerable difficulty has been
Thus where data on any of the above are shown in the data encountered due to the various methods of reporting corrosion
tables, other materials in the same group usually can be ex data. Materials reported as "recommended" or "completely
pected to perform in a like manner. resistant" may have corrosion rates less than 2 mils per year,
but without actual figures, they have been p laced in the sec
3. Concentration of Corrosives a nd category (20 mils per year) rather than th e ideal one. F or
Concentrations in all cases (except in certain solutions he

t ma ority
j n this category, the corrosion rates probably w
I ill
and gases, either desiccated or essentially so) are considered be below 5 mils per year. The rating of 20 mils per year in
to be water dilutions. of pure compounds. Although it is fully dicates those materials wh ch i orma y
ri ll wou d l be specified
understood that small quantities of contaminants may have a w here a corrosion allowance of 6 0 - 120 mils is added for pro
profound effect on corrosion rates, this factor is not ordinarily tection against possible mild corrosion.
taken into account In the tables, often because the specific A third classification (an open square) is provided to in
contaminants are not reported in the references from w hich dicate a co rr osion rate between 2 0 and 0
5 mils (508 and 1270
data are taken. In instances where a metal w as designated as um) per year, These materials can be used only in special
being unaffected by a chemical and no mention was made of cases where such a rate can be tolerated, but are not con
concentration or temperature, the tables show the metal as sidered ad eq uate for general plant construction.
satisfactory at the 100% line at room temperature. T his In T he fi nal rating (an X) is g iven where the corrosion rate is
dicates that the metal has a possible use and could be con probably too high (over 50 mils per yea) to merit considera
sidered. tion.
4. Temperature
Temperature may affect the corrosion rate through its et 6. Additional Factors Influencing
fect on oxygen solubility and availability. As temperature Corrosion Rates
rises, oxygen solubility in an aqueous solution decreases and There are many factors besides concentration and tem
at the boiling point most oxygen is removed. On the contrary, perature w hich influence corrosion rates and, while they are
the diffusion rate of oxygen increases with temperature. The often extremely important, it is impossible to list them all in a
corrosion rate may Increase w ith temperature to some maxi survey of this type. For example, velocity, aeration, heat flux,
mum and then decreases to some low value at the boiling the presence of oxidizing agents, and other chemical con
point. taminants can either increase or decrease the corrosion rate.
Temperature also may affect corrosion through its effect The effect of galvanic coupling is also Important in assessing
on pH, with Increasing temperature often resulting in decreas the useful life of a piece of equipment and should be con
ing pH. sidered.
Temperature also may affect corrosion rates through its Welding Is another factor which may influence service
effect on films. It may increase the solubility of protective cor life. Aside from intergranular corrosion, w hich is discussed
rosion products, as in the case of lead in hydrochloric acid. A below, there are instances where as-deposited weld metal is
change in temperature also may bring about changes in the attacked in preference to the base metal; conversely, there are
physical nature or the chemical composition of corrosion occasions when the weldment is more resistant. Additionally,
products which may make them considerably more or less pro localized stresses due to welding often make zones adjacent
tective. The behavior of zinc in water is an example. Another to welds susceptible to stress corrosion cracking. For these
effect of rising temperatures on films is caused by precipita reasons, selection of the correct welding material is as impor
tion of protective coatings on metallic surfaces, as in waters t ant as selection of the base material.
containing calcium sulfate and calcium carbonate. Many alloy systems show variations in corrosion resist
In solutions under pressure at temperatures above their ance as a result of being heated or cooled in a certain way. It is
normal boiling points, corrosion· rates may increase quite important that fabrication and heat treatment are such that an
rapidly w ith temperature, possibly because many of the fac alloy's corrosion resistance is not impaired if the fabricated
tors (such as diffusion, which normally acts to limit corrosion) part is intended for corrosive service. Generally the solution
are no longer controlling. The limiting effect of diffusion also annealed condition is preferred, but the manufacturer of the
can be overcome by rapid movement. alloy should be consulted for his recommendations.
ii
Corrosion Inhibitors, C. C. Nathan, Ed,, 1973. W. G. Ashbaugh, Union Carbide Corp., Texas City, Texas
Forms of Corrosion-Recognition and Prevention: NACE Hand Ronald E. Beese, American Can Co., Barrington, Illinois
book 1, C. P. Dillon, Ed., 1982. Karl J. Berggren, Buffalo Pumps Div., Buffalo, New York
Handbook of Corrosion Experiments. John RR. Boyd, The Clow Co., Coshocton, Ohio
High Temperature Corrosion (NACE Reference Book 6), Robert W . K . Boyd, Battelle Memorial Inst., Columbus, Ohio
A. Rapp, Ed., 1983. Marshall H. Brown, E. I. du Pont de Nemours & Co., Inc., Wil
High Temperature High Pressure Electro-Chemistry in Aque mington, Delaware
ous Solutions (NACE Reference Book 4), R. W. Staehle, F. H. Cocks, Tyco Laboratories, Waltham, Massachusetts
0. G. Jones, J. E. Slater, Eds. A. RR. Cook, International Lead/Zinc Research Org., New York,
Introduction to Oilfield Water Technology, A. G. Ostroff, 1979. New York
Localized Corrosion (NACE Reference Book 3), R. W. Staehle, Roy V. Comeaux, Essa Research & Eng., Baytown, Texas
B. F. Brown, J. Kruger, A. Agrawal, Eds., 1974. L. C. Covington, Titanium Metals Corp. of America, Hender
Process Industries Corrosion, 1975. son, Nevada
Stress Corrosion Cracking and Hydrogen Embrittlement of T. F. Degnan, E. I. du Pont de Nemours & Co., Inc., Wilmington,
Iron Base Alloys (NACE Reference Book 5), RR. W. Staehle, Delaware
J. Hochmann, R. D. MCright, J. E. Slater, Eds., 1977. Larry E. Drake, Stauffer Chemical Co., Dobbs Ferry, New York
Stress Corrosion Cracking Control Measures, B., F. Brown, G. B. Elder, Union Carbide Car/be, Inc., Ponce, Puerto Rico
1977. G. E. Galonian, General Electric Co., Schenectady, New York
The NACE Book of Standards. Paul J. Gegner, PPG Industries, Inc., Barberton, Ohio
The NACE Corrosion Engineer's Reference Book, RR. S. Treseder, L. w. Gleekman, Southfield, Michigan
Ed., 1980. Carl Hack, St. Joseph Lead Co., New York, New York
The Role of Bacteria in the Corrosion of Oil Field Equipment P. RR. Handt, Dow Chemical Co,, Midland, Michigan
(TPC-3), 1976. RR. L Jacobs, Getty Oil Co., Delaware City, Delaware
Russ W. Kirchner, Stellite Div,, Cabot Corp., Kokomo, Indiana
Dale W. Koch, Babcock & Wilcox Co., Akron, Ohio

Additional References J. B. Lawlar, Allied Chemical Corp., Camden, New J ersey
Bert Lofblad, Sandvik Steel, Inc., Fair Lawn, New Jersey
Handbook of Reactive Chemical Hazards, L. Bretherick, Ed., Anthony B. M isercola, Hooker Chemical Corp., Niagara Falls,
1984, Van Nostrand einhold Company, Inc., New York, New York
New York. B. Moniz, International Nickel Co. of Canada, Ltd., Toronto,
Dangerous Properties of Industrial Materials, 6th Edition, Ontario
N. I. Sax, 1984, Van Nostrand einhold Co,, Inc., New York, H. D. Rice, Huntington Alloy Products Div., The International
New York. Nickel Co., Inc., Huntington, West Virginia
Toxic and Hazardous Industrial Chemicals Safety Manual, Glenn Schiefelbein, Stainless Foundry & Eng. Co., Inc,, Mi!
1982, International Technical Information Institute, Tokyo, waukee, Wisconsin
Japan. C. C. Seastrom, E. I. du Pont de Nemours & Co., Inc., Wilming-
Materlal Safety Data Sheets, J. M. Nielsen, Ed,, 1980, Tech ton, Delaware .
nology Marketing Operation, General Electric Co., Sche R. • Skabo, Wyandotte Chemicals Corp., Wyandotte, Michigan
nectady, New York. L. S. Surtees, Kerr-McGee Corp., Oklahoma City, Oklahoma
The Merck Index - An Encyclopedia of Chemicals and Drugs, L. S. VanDelinder, Union Carbide Corp., South Charleston,
9th Edition, M. Windholz, Ed,, 1976, Merck & Co., Inc. West Virginia
J. M. A. VanderHorst, Consultant
Rita Wieland, Shell Development Co., Emeryville, California
Acknowledgments Louis Zadra, General American Transp. Corp., Sharon, Penn
sylvania
A. I. Zimmerer, Petro-Tex Chemical Co., Houston, Texas

Assistance of the following individuals in reviewing and
contributing data for previous editions is gratefully acknowl
edged:
t
l
L.
iv
7. Effect of Stress on Corrosion Rates Corrosion Catalog, Pacific Foundry co.
Two very important instances when stress and corrosion Corrosion Data Survey on Tantalum, M. Schussler, 1972, Fan
operating simultaneously will not cause increased general at steel, Inc., N. Chicago, Illinois.
Corrosion Guide, 2nd Edition, Eric Rabalt, 1968. Elsevier Pub

tack but will produce fracture are corrosion fatigue and stress
fishing Co., New York, New York.
corrosion cracking. While corrosion fatigue may occur in any
Corrosion Handbook, H. H. Uhlig, Wiley & Sons Publishing
corrosive medium, stress corrosion cracking requires a
Co., New York, New York.
specific combination of alloy and environment. Quite often the
Corrosion in Nuclear Applications, W. E . Berry, 1971, John
stress which causes stress corrosion cracking is due not only
Wiley, Inc., New York, New York.
to operating conditions but also to locked-in stress due to Corrosion Resistance of Metals and Alloys, 2nd Edition, F.
fabrication. Welding, in particular, often induces stresses suf L. LaQue and H. R. Copson, 1963, Reinhold Publishing Co.,
ficient to cause failure. For this reason, post fabrication heat New York, New York.
treatments often are specified. When stress cracking is in Dechema Werkstoff-Tabelle, Theodor Heussaller, Frankfurt,
West Germany.
dicated in the tables, the materials definitely should be stress
Duriron Catalog, Duriron Co.
relieved after fabrication, or a metal not susceptible to stress
Guide to Corrosion Resistance, J. P.- Polar, 1962, Climax
cracking should be selected. For stress relieving times and
Molybdenum Co., Div. Am. Metal Climax, Inc., New York,
temperatures, the manufacturer of the alloy should be con
New York.
sulted. Handbook of Chemistry and Physics, 47th Edition, Chemical
Generally, stressing metals at less than their elastic limit Rubber Co., Cleveland, Ohio.
does not markedly increase corrosion rates. Under some cir High Temperature Materials and Technology, I. E. Campbell
and E. M. Sherwood, Ed., 1967, Wiley & Sons, Inc., New
cumstances this may not be true. Occasionally alternating
York, New York.
stresses result in faster corrosion rates than static stress in
Industrial Engineering and Chemistry, American Chemical
one direction alone. Markedly different corrosion rates have
Society, Washington, D.C.
been experienced with certain metals when they were stressed
Interstate Commerce Commission Regulations.
after exposure in an environment rather than before. There
Korrosionstakellen Metallisher Werkstoffe.
also may be a differential in corrosion rates between that side
Lead, Lead Industries Association.
of a material under compressive stress and the one under ex Materials of Construction for the Chemical Process Industries,
tension. James A. Lee.
Materials Performance, National Association of Corrosion
8. lntergranular Corrosion Engineers, Houston, Texas.
lntergranular corrosion attacks grain boundaries of Meehanite Catalog, Meehanite Corp.
Metals and Alloys, Reinhold Publishing Co,, New York, New

materials and can be particularly aggressive when certain
York.
chemical solutions are in contact with austenitic stainless
Metals and Alloys Data Book, S. L. Hoyt.
steels which have precipitated carbides at grain boundaries
Metals Handbook, Vol. 1: Properties and Selection of Metals,
(sensitization). This precipitation is produced when the steel
8th Edition, Taylor Lyman, Ed., American Society for Metals,
has been subjected to temperatures between 800 and 1400 F
Metals Park, Ohio.
(426 and 760 C) and is often present adjacent to welded areas. Nickel and Nickel Alloys, International Nickel Co., New York,
Various methods have been developed to eliminate this un New York.
desirable condition. However, because intergranular corrosion Oil and Gas Journal, Petroleum Publishing Co.
is not produced by all corrosive media, special heat treatments Proceedings on Fundamental Aspects of Stress Corrosion
Cracking, RR. W. Staehle, A. J. Forty and D. VanRooyen, Eds.,

or specification of stabilized types of austenitic stainless
1969. NACE, Houston, Texas.
steels often are unnecessary.
Proceedings, 24, 25 and 26th NACE Conferences, NACE, Hous
Certain other metals and alloys are subject to inter
ton, Texas.
granular attack when exposed to specific media under some Proceedings, 1st International Congress on Metallic Corro
environmental conditions and others after an adverse heat sion, 1961, Butterworth's, London, England.
treatment. In such cases the manufacturer should be con Proceedings, 2nd International Congress on Metallic Corro
sulted for information relating to his product. sion, 1963, NACE, Houston, Texas.
Proceedings, 3rd International Congress on Metallic Corro
sion, 1966, Swets-Zeitlinger, Amsterdam, The Netherlands,

9. Corrosion Inhibitors
(English Edition).
Also not considered in this survey are the electrical tech
Proceedings, 4th International Congress on Metallic Corro
niques of cathodic and anodic protection, both of which have
sion, 1969, NACE, Houston, Texas.
benefits under some conditions. Those who are interested in
Rare Metals Handbook, 2nd Edition, C. A. Hampel, Ed., 1961.
investigating these techniques may get good advice from
Reinhold Publishing Co., New York, New York.
manufacturers and consultants in these fields. Resistance of Ti to Organic Acids, NACE T-5A-7b, July, 1972,
The technology of inhibition is well developed, but is not NACE, Houston, Texas.
considered in this book. Consult the reference list below for Silver in Industry, L. Addicks, A. Butts, J. M. Thomas.
sources of published information on inhibition. Underground Corrosion, Circular 579, Melvin Romanoff, 1957,
National Bureau of Standards, Washington, DC.
Zinc; Its Corrosion Resistance, C. I. Slunder and W. K. Boyd,
Sources of Data 1971, Zinc Development Association, London, England.
The majority of data for all editions of this book has been NACE References
collected from the following publications:
Atlas of Electrochemical Equilibria in Aqueous Solutions,
Atmospheric Corrosion of Metals, I. L. Rozenfeld, 1973, English Marcel Pourbaix, 1974.
Edition, NACE, Houston, Texas. Bibliography of Corrosion by Chlorine (TPC-4), 1976.
Book of Stainless Steels, E. E. Thum. Bibliography on Chemical Cleaning of Metals (TPC-6), 1960-
Chemical Engineering, McGraw-Hill Publishing Co., New York, 1974.
New York. Control of Pipeline Corrosion, A. W. Peabody, 1967.
Combating Corrosion in the Process Industries, Crane Co. Corrosion and Its Control: An Introduction to the Subject, J.
Corrosion Behavior of Major Architectural and Structural T. N. Atkinson and H. van Droffelaar, 1982.
Metals in Canadian Atmospheres, Summary of 2-Year Re Corrosion Control in Petroleum Production (TPC-5), 1979.
sults, E. V. Gibbons, Chairman Subcommittee C o n Atmos Corrosion Data Survey-Nonmetals Section, 1975.
pheric Corrosion Testing, 1959, ASTM, Philadelphia, Penn Corrosion Fatigue (NACE Reference Book 2), 0. F. Devereux,
sylvania. A. J. McEvily, R. W. Staehle, Eds., 1972.
iii
Keys to Data Tables
(Fold out)
Keys to D a t a T a b l e s
F (C)
500 (260)
20 40 60 80 100
Matrix Key
400 (204)
Throughout the data tables in
this book, data points represent
ing average penetration per year

300 (149)
(key below) are plotted on the
matrix enlarged here. The hor
izontal grid represents percent

200 (93)
concentration in water and the
vertical grid represents temper
ature. For more information on
100 (38) how to use this data survey,
consult the preceding introduc
tion.
20 40 60 80 100
0 ( - 1 8)
Percent Concentration in Water
Average Penetration Rate Per Year
7
Code Mils Inches mm
• < 2 0.002 50
0 < 20 0.020 508 Key to Data Points
□ { 20-50 0.020-0.050 508-1270
X > 50 0.050 1270
Footnotes for Data Squares
1. Pitting
2. Stress Corrosion Cracking

Key to Footnotes
3. Intergranular Attack
4. Crevice Attack
IDENTIFICATION AND NOMINAL ANALYSES
OF METALS AND ALLOYS
FERROUS ALLOYS Nominal Analysis (Percent)
Common Name or Type Chromlum Nickel Sicon ron GE Manganese spnorus $/fur
Stoel, Carbon, Milt <0.6 <2.25 bal <1.75
ron, Gray Cast 1.1-2.8 bal <3.80 0.15 0.10
ron, High Nickel Cast 14-32 bal
STEEL, Stainless, Martensitic and Fertic
AII Type!
405 11.5-14.5 <f
410 11.5-13.5 <I <1
STEEL, Stainless, Ferritlc
17C 17 0.5 1 bal 0.12 1 0.04 l 0.03
26-1 25-27 bal 0.005 Mo =0.75-1.5
Cus0.20
N =0.015
Cu +NI0.50
STEEL, Stainless, Austenitic
AISI Type
302 17.19 8-10 <1 bal <0.15 <2.0

304/304L! 18-20 8-12 <1 bal <0.08 <2.0
321 17.19 9-12 bal <2.0 TIC x 10
347 17.1g 913 bal C b + T a x 10
AISI Type
316/316L 16-19 10.14 <1 bal <0.1 <2.0 Mo=2-3
3177317L 18-20 11-15 <f bal <0.1 c2.0 Mom3-4
20-25-4.5 ..
,
904L 20 25 Mo4.5
ha! Cu=1.5
COPPER BASE ALLOYS Nominal Analysis (Percent
CDA Numb6 Naro 0ppor Zinc In Load erlc Iron Nickel 4gen
100-150 Electrolytic coppor 99.9
210 Gilding metal 95.0 5
220 Bronze, commercial 90.0 10
230 Brass, red 85.0 15
502-546 Bronze, phosphorus 91-99 1.-8 Also phosphorus
240 Brass, low leaded 80 20
260 Brass, cartridge 70 30
442445 Admiralty 70.73 28 1 Tr T Also Sb,P
268 Brass, yellow 64-68 32 T Te
270 Brass, yellow 63-68 32 Tr re
280 Muntz metal 59-63 37 Tr
464-467 Brass, naval 59-62 38 Te Te Tr Al <8
612 Brass, aluminum 92.8 Te
706 Cupro-nickel 88.5 1 0.05 1.3 911 Mn 1
710 Cupro-nickel 76.5 1 0.05 1.0 19-23 Mn T
715 Cupro-nickel 66.5 1 0.05 0.4-0.7 29-33 Mn e f
NICKEL BASE ALLOYS Nominal Analysis (Percent)
Designation Chromium Nickel Copper Molybdenum Manganese ton SiHcon Carbon Other
200 + 200L - 99. 5 0.05 0.25 0.15 0.05 0.06 Co trace
Monel 400 66 31.5 1.4 1.1
tncon6l 600 15.8 76 7.2 1.0
Ni.Cr-Fe-Mo Alloys
Incoloy 825 21.5 bal 2.0 3.0 1.0 29.0 0.05° 0.05 1.0 Tl
Hastelloy G/G-3 22.0 bal 2.0 7.0 19.5 1.0
19.21 30-34 bal Mo=2-3; C u = 3 - 4 ; Cb

20 Cb-3
ACI Tyout
Alloy 20 19-20 28-30 0.75 bal Mo =2; Cu3-4.5
CN 20 19-20 28-30 bat Mo 3; Cu=1.75
Hastelloy B 62 28 6.0
Hastelloy B-2 69 28 1.0
Hastelloy C 16 57 16 5 0.08 4W
16 57 16 5 0.01 4W
Haste[loy c-276
MISCELLANEOUS ALLOYS
Designation Purity and Alloying Elements Designation Purity and Alloying Elements
Alumninun Low copper, iron Silver 90% 4 Cu, Au, or Sn
Gotd +Ag, Ir, Pd, Pt, In Tantalum > 99.99 +
Platinum >99% + Ni, Os, Ru, Cu, Rh

Titanium +Pd, AI, Sn, or V
Lead >99.73% + Ag, Cu Zirconium +Ta, Mo, Mn, or Al
(9American Iron and Steel Institute (A1SI), Washington, DC.
Low carbon grade: C = 0.03 maximum.
6copper Development Association (CDA), New York, NY. See also The Corrosion o Copper, Tin, and Their Alloys, Henry Loldheiser, Wiley &
Sons, NY, NY, 1971.
Low carbon = 0,02 C, Type 201.
Aloy Casting instltute (ACI; now Steel Founders' Solety ot America), Des Plaines, IL.
Maximum
Section 1
M a i n Tables
8
The following tables contain the majority of data found in this volume. All data in this section pertain to the same
four alloy groups (iron base, copper base, nickel base, and other) and represent exposure to corrosives in the 0 to
500 F (-18 to 260 C) temperature range. The data are of the same kind and reliability and come from the same
sources as other data found in this volume.
The reader is advised to examine the following matrix upon which the tables in this section are based before
attempting to use the tables. A replica of this matrix appears on the adjacent fold-out page for ready reference
when reading the tables. A key to the data points (giving average penetration rates per year), a key to footnotes,
and a table of identifications and nominal analyses of metals and alloys are also located on the adjacent fold-out
page.
Consult the preceding introduction for further instructions on how to use this data survey.
F (C)
500 (260)
20 40 60 80 100
400 (204).
300 (149)
200 (93)
100 (38)
20 40 60 80 100
0 (-18)
Percent Concentration in. Water

IRON BASE COPPER ASE
COPPER
CORROSIVE CAST IRON STAINLESS SI£Et
&
STEEL BRAS5 Cu-Ni
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ACETALDEHYDE
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. ..
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N I C K E L B A S E O T H E R M E T A L S A N D A L L O Y S
Ni Ni-Cu Ni-Cr.Fe Gold

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Ni Cr.Fe -Mo A luring rm & Lead Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8-2 c-276 Platinum
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Ni Ni-Cu Ni-Cr-Fe Ni-Mo Ni-Cr-Mo Gold

Ni.Ce-Fe -Mo Aluminum & eod Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 B - 2 C-276 Platinum
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Ni-Cr-Fe-Mo Aluminum & lead Silver Tantalum Titanium Zirconium
99 66-32 76-1%-7 B-2 c-276 Platinum
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Ni Ni.Cu Ni-Cr-Fe Ni-Cr-Mo

Gold
Ni-Mo
Ni-Ce-Fe -Mo Aluminum lead Si/var Tantalum Titanium Zirconium
99 66-32 76-16-7 8 - 2 c-27%

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13 I 3
0
• •
m
I
o 0 �
0
• • • •
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X X
0 0
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1
IRON BASE
COPPER BASE
cc CORROSIVE CAST IRON STAINLESS STEEL COPPER

STEEL &
BRASS Cu-Ni
GRAY NICKEL 12 Cr 17 C 26-1 304 316 20-25-4.5 BRONZE
1 1 1 1 1 1 2 11 2 1
ANTIMONY
AN TRICHLORIDE
I x X. X NI X X. X X X X X x ¥ "y
0 0 0 X X .X x X x: .X X
A AINTIMONY
TAI TRIFLUORIDE
A AQUA REGIA
AIRACHADIC
A
ACID
AJ
ARSENIC ACID
PR
m
0
5l ¥ ¥ X X 0 0 0 0 0 0 x 0
ARSENIC
Al
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Al
ASCORBIC ACID
4
A ASPARTIC ACID
A AZOBENZENE
10
A
Cl
II
12
A
13
. .
A
Pl
I4
A
p
15
'
16 I
16
Ni Ni-C Ni-Cr.Fa% Ni-Mo Ni-Cr-Mo Gold
Ni-Cr-Fe Mo Aluminum & Load Sir Tantalum Titanium Zirconium

99 66-32 76-16-7 8-2 C-276 Platinum
1 1
I
• • • • • • • •
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2 2
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>
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10 I 0
I I
12 I2
13 I 3
I4 I4
I5 I 5
I6 I 6
17
IRON BASE
COPPER BASE

STEEL &
BRASS Cu-Ni
GRAY NICKEL 12 Cr 17 Cr 304 BRONZE
26 316 20-25-4.5
BARIUM I
I
CHLORATE
0 0 0 0
I
0 0 0 0 0 0
1 1 1 1 2 1 2 1 2
BARIUM
CHLORIDE
• • • • • • 0 0 0
2 0 0 X 0 c 0
• • • • • • • 0 0
BARIUM
CYANIDE
0
3 0
�
0
0 0 0
0 0 x X x X X X X X ¥ X X X
BARIUM
HYDROXIDE 0 0o 0 o 0 0
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4 0 0 0
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NITRATE
0 0 0 0 X ¥ x
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PEROXIDE
0 ¢
6 0 0 X 0 0 0 0 0 x ¥ X
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POLYSULFIDES
BARIUM
SULFATE
0
8 0 0 0 0 0 0 0
BARIUM
SULFIDE
91 , 0 0 0 0 0 0 x ¥ ¥
BENZALDEHYDE .
10 ]
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II
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0 0
• • • • • • • • • • • • • • •
12 #k 0 0 0
• • • • • • • • • • • • • • •
•
• • • •
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HEXACHLORIDE
13 X
BENZENE
X
SULFONIC ACID
x X .
0 0 0 0 0
14 x: X X ¥· 90 0 .X X X 9M
0 0
.
0 0
• 0 0 0 0 0 □ □ 0 0 0 0
BENZI DENE
15
BENZILIC ACID
I6 0
~l 0 0
'
18
NICKEL B A S E O T H E R M E T A L S A N D A L L O Y S
Ni Ni.C Ni-Ce-Fe Gold

Ni-Mo Ni-Cr-Mo
99 66-32 76-1%-7
Ni-Cr-Fe -Mo
8- 2 C-276
Aluminum
•
Platinum
Silver Tantalum Titanium Zirconium
• • • •
• • • • •
3 3
0
X XIX X XIX X X X X X
4
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19
IRON BASE
COPPER BASE
STEEL &
BRASS Cu-Ni
GRAY NICKEL 12 Cr 17 Cr 26 304 316 BRONZE
20-25-4.5
I I
TI I I I
I I I
I I I
TI I I I
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r ;
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0
0
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BENZOIC
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BENZOIN
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BENZOTRI
CHLORIDE
61 ¥
BENZOTRI-
FLUORIDE
BENZOYL
BENZOIC
ACID
8
l
l
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CHLORIDE
BENZOYL
PEROXIDE
10
BENZYL ACETATE
II
BENZYL
ALCOHOL
12
BENZYL AMINE
13
BENZYL
BENZOATE
14
BENZYL
BROMIDE
15
BENZYL
CHLORIDE
16 X x X
20
N Ni-Cu Ni-Cr.F% Gold

Ni-Mo Ni-Ce-Mo
Ni-Cr-Fe Mo Aluminum & eod Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8-2 C-276 Platinum
I I
I
I I
I
I
I I I
I
0 0 0 I
#
0
• • • • • • • 0 0 0
• • • • • 0
• • • • • • •
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0 0 0 0 0
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0 0 0 0
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ii ,-,-
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3
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4
4
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5
5
6
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7
8
8
9
9
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10
. I0
I
I
I2
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0
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13
I3
14
I4
15
I5
I6
I6
21
CORROSIVE CAST IRON STAINLESS S TE E L COPPER
STE EL &
BRASS C-Ni
BENZYL
DICHLORIDE
BENZYL PHENOL
BENZYL
SALICYLATE
3
1 1 2 1 2 1 2
BERRYLIUM
CHLORIDE
4i x X X X X X X X D D
BERRYLIUM
FLUORIDE
51 0 0 0 0 0
BERRYLIUM
SULFATE
0
6 0
0 0
BORIC ACID • • • •
X
• • • • • • • •
0
7 X
• • 0
• • • • • • •
BORNYL
ACETATE
BORNYL
CHLORIDE
BORNYL
FORMATE
10
1 1 1 1
BORON
TRICHLORIDE
II
BROMICACID
12 X .iox X X X X X X
BROMINE-DRY
3 « X X
BROMINE-WET
14
BROMINE
0
TRIFLUORIDE
15
BROMOBENZENE
16
22
Ni Ni-Cu Ni-Ce-f% Gold

Ni+Mo Ni-C-Mo
Ni-Cr-Fe -Mo Aluminum & leod Sir Tentlum fitaium Zirconium
99 66-32 76-16-7 8-2 C-276 Platinum
4
0
x. 'X x .X
X. DX ¥ X
• • • • ••• • • •
-·
5
0
6
• •
• ti •
• • •
7 • • • • • • • • • • • • •
• • • • • • • • • • • • • • • •
c
• • • • •
0
• • • • •
8 '
t
9
10 • I
I I
I2 I
X X ¥ x
I3 I
X X X X X
I4 I 4
• • • • •
• • • • • •
X X
•
I5 • • • • I 5
16 I 6
STEEL &
BRASS Cu-Ni
GRAY NICKEL 12 c, 17 Cr 26-1 304 316 20-25-4.5 BRONZE
BROMOCHLORO-
METHANE
1 1 1
BROMOCHLORO-
PROPANE
2
• • •
BROMOFORM
3 0
BROMOTOLUENE
BUTADIENE
BUTANE
BUTANEDIOLS
BUTANOL
8
4
BUTYL ACETATE
9
• •
BUTYLAMINE
10
BUTYL
BENZOATE
II
BUTYL
BUTYRATE
12
BUTYL
CHLORIDE
13 X X
X X
BUTYL
LACTATE
14
BUTYL
MERCAPTAN
0 0
15 0
BUTYL
METHACRYLATE
16
24
N I C K E L 8 A S E O T H E R M E T A L S A N D A L L O Y S
Ni Ni-Cu Ni-Cr-Fe Ni-Cr-Mo Gold

Ni-Mo
t.gr.fe-Mo Aluminum Silver Tantalum Titanium
99 66-32 76-16-7 8 - 2 c-276

•
Platinum
lod Zirconium
I I
2
2
3 3
4 4
5 5
6 6
7 7
8 8
• • • • •
9 9
• •
l
0
• • • • • •
10 I 0
I - I
2 I 2
3 I 3
14 I4
15 I 5
0
0 0
I6 I6
25
IRON BASE COPPER 8ASE
STEEL &
BRASS Cu-Ni
BUTYL PHENOLS
BUTYL STEARATE
BUTYRALDEHYDE
BUTYRIC ACID
0
□ 0
A o X 0
□ □ 0 o 0
BUTYRIC
ANHYDRIDE
-
5
BUTYROLACTONE
BUTYRYL
CHLORIDE
7 X X
10
II
12
I3
- .
I4
15
16
26
Ni Ni-C Ni-Cr-Fe Ni-Mo Ni-Cr+Mo Gold
Ni-Cr.f-Mo Aluminum & lead Silver Tantalum Titanium Zirconium

99 66-32 76-16-7 8-2 C-276 Platinum
2 2
3 3
4 4
• • • • • • •
X
• • 0
• • • • •
5 5
6 6
7 7
8 8
9 9
10 I 0
I - I
12 I 2
13 I 3
I4 I 4
15 I 5
I6 I 6
27
COPPER
&
STEEL BRASS Cu-Ni
20-25-4.5 BRONZE
GRAY NICKEL 12 c 17 Cr 26 304 316
1 2 1 2
CADMIUM
CHLORIDE 0 0
X Xx X X 0 0 0 0 X. DX 0
ll x X X x X X X
CADMIUM
SULFATE
0
• • • 0 0
2 0 0 0 0
• • •
0 0 0
CADMIUM
SULFIDE
3 ¥ ¥
CALCIUM
ACETATE 0 0 0 0
Ai % 0 0 0 0 # 0
�- -
--
# +# 'o
CALCIUM
ARSENATE .
5
CALCIUM
BENZOATE
CALCIUM
• • • • • • • • • •
BISULFITE X
• • • • • • • •
@
7 ¥ X X X ¥
• • • • • • • • • • □
CALCIUM
0
BROMIDE 0 0 0 0
0 0 0 0 0 0 0 0
8
CALCIUM
CARBIDE
x X
9
CALCIUM
CARBONATE
10 0 0 0 0
0 0
CALCIUM
CHLORATE 8 0 0 0 0 0 0 0
0 0 0 0 x X X X X X 0
1 it %k e 0 0 0 0 0 0 0 0 0
□ □
1 2 1 2
CALCIUM •
X X x X X X
CHLORIDE x 0 0 0 0 0 0 0
0 0 X
4 E
12 � 3#% 0 0 0 0 0 0 0 0 0 0 0 0
• • • • • 0
CALCIUM
CHROMATE 0 0
0 0 0
•
0 0
13 0
0 0 0 0
� •
. ..
CALCIUM
FLUORIDE
I4
CALCIUM
GLUCONATE
• •
15 • •
CALCIUM
HYDRIDE
16
28
Ni Ni-Cu Ni-Ce-Fe Gold

Ni-Mo Ni-Cr-Mo
99 66-32 76-16-7 8 - 2 c-276 Platinum
I
0 0 0 0
I
0 0 0
• •
0 0 0 0 X X
• •
2
• 2
• • • • • X
• • • •
• • •
• • • • • 0
• • • • • •
3
3
4
0 0 0 0 0 0
4
i 0 0 0 0 0 0 0 0
5
5
6
6
7
7
X X X le
X X X. X I «
•
8
8
0 0
# 0
u 0 0 0 0 0 0 0
□ 0
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9
9
X X
10
0
IC
0 0
• •
0
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I
0 0 0
I
0
1 0
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•
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• 0
•
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0 0
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• • 0
X
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13
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0 0 0 0
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14
I4
I5
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0 0
I6
I6
29
CORROSIVE CAST IRON STAINLESS STE El COPPER
&
STE EL 6RAS$ Cu-Ni
GRAY NICKEL 12 C 17 Cr 26-1 304 316 20-25-4.5

BRONZE
CALCIUM I
HYDROXIDE
0 0 0 0 0 0 0 0 0
I o 0 0 0 0
liit 0
I 1
CALCIUM
HYPOCHLORITE
2 X. X X X. IX ¥
□ x. X X. XI« X. OX 0
CALCIUM
LACTATE 0 0 0 0
• • 0 0 0
3 0 0 0 0
• • 0 0 0
CALCIUM
NAPHTHENATE
4
2 2 2 2
CALCIUM
NITRATE
0 0 0 0 0 0
5 0 0 0 0 0 0 0 0 0 0
CALCIUM
OXALATE 0 0 0 6 0
6 0 0 0 0 0 0 0 6 0 0 0
CALCIUM
OXIDE
7
CALCIUM
PERMANGANATE -
0 � 1 0 O 0 0 0 C 0 J
9.
8 0 0 0 0 0 0 # % 8 0 i 0 0 0
CALCIUM
, _
PHOSPHATE - -
0 0 0 0 0 0 0 0
9 0 I 0 0 0 0
CALCIUM
STEARATE
6 0 0 0 1 0 0 0 0
10 0 0 0 0 0 0 0 0 0 0
CALCIUM
i
SULFATE 1
• • • • • • • • • • • •
II • • • • • • • • • • • •
CALCIUM
SULFIDE -
0 0 0 0 0 0 0 0 0
12 0 0 0 5 6 0 0 0 0 X X
CALCIUM
'
SULFITE 0 0 0
0 0
• • •
13 0 0 & 0
• • • X X
CALCIUM
THIOCYANATE ,- ,-
0 0 0
I4 0 0 0
CAMPHENE
15
CAMPHOR
16
30
N I C K E L B A S E
O T H E R M E T A L S A N D A L L O Y S
Ni Ni-Cu Ni-Ce.F% Ni-Mo Ni-Cr+Mo Gold

Ni-Cr-Fe-Mo
Aluminum & ad Sir Tontolum Titanium Zirconium
99 66-32 76-16-7 B- 2 C-276 Platinum
I
0 0 0 0 I
• • • • • • • •
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1
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5
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• • • •
6
0 0 0 0 0
6
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7
7
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31
;
I R ON BASE COPPER BASE
COPPER
�
&
STEEL BRASS Cu-Ni
GRAY NICKEL 12 Cr 17 Cr 26-1 304 316 20-25-A.5 BRONZE
CAMPHORIC
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Ni Ni-Cu Ni-Cr-F% Ni-Mo Ni-Cr-Mo Gold

Ni.Cr-Fe -Mo Aluminur & lead Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8 - 2 c-27% Platinum
I
I
1 %
0
• •
t 0
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2
2
3 «4
4
4
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6 6
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• • • • • • •
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• • • • •
1
I2
• • • • •
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• • • • • •
I3 I3
4 I4
5 I5
6 I6
COPPER
&
STEEL 8RAS$ Cu-Ni
GRAY NICKEL 12 c, 17 Cr 26-1 304 20-25-45 BRONZE
CELLULOSE
METHYL
f[Hf[ tll++ldllld+llld
CELLULOSE
NITRATE
1 .2 1 2
CESIUM
CHLORIDE c 0 C
3l ? c 0
CESIUM
HYDROXIDE
4 a c
TY[A[fOHOl4]+
lllldllllhlllld
lld
+ld
ill}bl+lb}}}}d+
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PHENICOL
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CHLORIC ACID
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1 2 1 2
x X
CHLORINE
13 X X X X X X .X
CHLORINE
DIOXIDE
I4 0 0
CHLORINE
TRIR.UORIDE
15
CHLORACETAL
DEHYDE
34

Ni-Cr-Fe Mo Aluminum & ad Siver Tantalum Titanium Zirconium
99 66-32 76-16-7 B-2 c-276 Platinum
I
I
2
2
0 0
• 0
• • •
3
0 0
3
0
4
0 0 0 0
4
• 0 0 0
0 0 0
X
• X 0 0 0
5
5
6
6
7
7
X
8 X
8
0 0 O
• • •
0 0 0
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9 9
10
I0
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-
2 12
• • • •
X X X X X X X X • •
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• •
l
0 0
13 0 0 0 0 0
• 13
X 0 X X X X
• • • •
X X X K X X X X X
• • • • • • X
I4
I4
X X X 0 0 0
15 I5
16 I6
35
IRON BASE
COPPER BASE

STE EL &
BRASS Cu-Ni
GRAY NICKEL 12 Cc 17 Cr 26-l 304 31% BRONZE
20-25-4.5
1 1
CHLOROACETIC
X X
ACID(MONO)
l] o X X X X. /X 1. X ¥ X. IX X X X X. 'X X. DX X. X 8. DX X X
X. IX X. .X X. ¥
CHLORACETONE
2 X
CHLORACETYL
CHLORIDE
CHLOROALKYL
ETHERS
CHLOROAMINO
BENZOIC ACID
5 -
2 2
CHLOROANILINES
CHLOROBEN
ZALDEHYDE
7
1 2 1 2
CHLOROBENZENE
X
X X 0 0
8 0 X 0 X
CHLOROBENZO-
TRI FLUORIDES
CHLORODI
FLUOROETHANE
10
CHLORODIFLUO-
ROMETHANE
II
CHLOROETHYL
BENZENE
12
1. 2 1. 2
CHLOROFORM
13 x ¥
0
CHLOROHYDRIN
I4 '
CHLORONAPH
THALENE
15
CHLORONITRO-
BENZENE
16
36
Ni Ni-Cu Ni-Cr.F% Gold

Ni-Mo Ni-Cr+Mo
Ni-Cr-Fe ·Mo Aluminum & lead Silver Tantolum Titanium
99 66-32 76-16-7 Zirconium
8-2 c-276 Platinum
I
I
0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 • 0
• • •
X DX X X X X X X X X X X X X
• • •
3
• • • • • •
• • • • 0
• •
8
0 . 0
• •
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•
10
I
-
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12
'
13
• • • 0
• 0
•
f
• • • • • Xx
• 0
• • • 4
0 0 0
0
I4
0 0
0
•
0 0
•
'
'
16 I
t t l
•
37
COPPER
&
SI£EL 8RASS
C-Ni:
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Ni-Me
Ni-Cr-Fe -Mo Aluminum & lead Tantalum Titanium Zirconium
8 - 2 c-27% Platinum
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NI-Cr-Fe-Mo Aluminum & od Silver Tantalum Titanium
99 66-32 76-f&:; B- 2 c-276
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42
N I C K EL B A S E
Ni Ni-Cu Ni-Cr-f% Ni-Mo Ni-Ce-Mo Gold

Ni-Ce-Fe-Mo Aluminum & leod Silver Tantalum Titanium
99 66-32 76-16-7 Zirconium
8-2 c-276 Platinum
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IRON BASE
COPPER BASE

STEEL &
BRASS Cu-Ni
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44
Ni Ni-Cu Ni-Cr.f% Ni-Mo Ni-Cr-Mo Gold

NCe-Fe -Mo Aluminum & tod Siver Tantalum Titanium Zirconium
99 66-32 76-16-7 8-2 c-27% Platinum
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Ni Ni-Co Ni-Cr+Fe Ni-Mo Ni-Cr-Mo Gold

Ni-Ce-Fe -Mo Aluminum & lead Si/var Tantalum Titanium Zeconium
99 66-32 76-16-7 8-2 c-276 Platinum
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N I C K E L B A S E O T H E R M E T A L S A ND A L L O Y S
Ni Ni-Cu Ni-Ce-Fe Ni-Cr-Mo Gold

Ni-Mo
Ni-Cr-Fe -Mo lad $/vr Tantalum Titanium
99 66-32 76-16-7 8-2 C-276

Aluminum
•
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16
50
Ni Ni-Cu Ni-Cr-Fe Gold

Ni-Mo Ni-Cr-Mo
Ni-Cr-Fe -Mo Aluminum & lead Silver Tantalum Titanium
99 66-32 Zirconium
76-16-7 B-2 C-276 Platinum
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IRON BASE
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STEEL &
BRASS Cu-Ni
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52
N I C K E L B A S E

Ni-Mo Ni-Cr-Mo
Ni-Cr-Fe -Mo Aluminum & leod Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8-2 c-276 Pletum
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54
N I C K EL B A S E O T H E R M E T A L S A N D A L L O Y S
N Ni-Cu Ni-Ce-Fe Ni-Cr-Mo Gold

Ni-Mo
Ni.Cr-Fe-Mo Aluminum & lead Siver Tantalum Titanium Zcoium
99 66-32 76-16-7 8-2 C-276 Platinum
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IRON BASE
COPPER BASE

STEEL &
BRASS Cu-Ni
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MALONATE
15
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MERCAPTAN
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56
N I C K E L B A S E
Ni Ni-Cu Ni-Ce-Fu Gold

Ni-Mo Ni-Cr-Mo
Ni--Ce-Fe Mo Aluminum & lead Silver Tantalum Titanium Zirconium
99 66-32 76-16-7
8 - 2 c-276 Platinum
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IRON BASE
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STEEL &
BRASS Cu-Ni
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ETHYL NITRITE
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PELARGONITE
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PROPIONATE
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10
II
12
13
14
15
16
58
Ni Ni-Cu Ni-Ce-fe Ni-Mo Ni-Cr-Mo Gold

Ni-Cr-Fe -Mo Aluminum & lead Sir Tantalum Titanium Zirconium
99 66-32 76-16-7 B-2 c-276 Ptetimm
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IRON BASE
COPPER BASE
S1EEL &
BRASS Cu-Ni
GRAY NICKEL 12 c, 17 Cr 26 304 316 20-25-4.5 BRONZE
FATS, NATURAL
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60
Ni Ni-Cu Ni-Cr-Fu Ni-Mo Ni-Cr-Mo Gold

Ni--Cr-Fe -Mo Aluminum & od Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8-2 c-276 Platinom
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COPPER
&
STEEl BRASS Cu-Ni
26-1 316 20-25-4.5 BRONZE

GRAY NICKEL 12 Cr 17 Cr 304
FURFUAL
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Ni-Ce-Fe-Mo Aluminum lead
99 66-32 76-16%-7 B- 2 C-276
•
Platinum
Siver Tantalum Titanium Zirconium
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CORROSIVE CAST IRON
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Ni Ni-Co Ni-Cr.Fu Gold

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Aluminum & lead Silver Tantolum Titanium Zirconium
99 66-32 76-16-7 B - 2 c-276 Platinum
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99 66-32 76-16-7 8 - 2 c-27% Pletium
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Ni-Mo Ni-Cr-Mo I
Ni--Ce-Fe -Mo Aluminum & sod 5ver Tantalum Titanium Zirconium '
99 .66-32 76-16-7 8-2 C-276 Platinum
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S TE EL &
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HYDROXYCITRO-
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ACID
10
II
12
13
14
15
16
70
Ni Ni-C Gold
Ni-Cr-Fe Ni-Mo Ni-Cr-Mo
Ni.Cr-Fe -Mo Aluminum & eod Slvr Tantalum Titoni Zirconium
,, 66-32 76-16-7 B - 2 C-276 Platinum
I I
2 2
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4 4
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6 6
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8 8
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16 I6
71
COPPER
&
STEEL BRASS Cu-Ni
12 C 7 Cr 26-1 304 316 20-25-4.5 BRONZE

GRAY NICKEL
INDOLE
I
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16
I
I
72
. i
Ni Ni-Cu Ni-Cr-Fe Ni-Mo Gold

Ni-Cr-Mo
Ni--Cr-Fe -Mo Aluminum
99 66-32 76-16-7 8-2 c-276
•
Platinum
lead Silver Tantalum Titanium Zirconium
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73
COPPER
SEEL
•
BRONZE
BRASS Cu-Ni
GRAY NICKEL 12 Cr 17 C 26-1 304 316 20-25-4.5
ISOPHORONE
ISOPROPANOL
2
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Ni-Mo Ni-Cr-Mo
Ni-Cr.Fe-Mo
Aluminum & lad Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8 - 2 C-276 Platinum
I
I
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2
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75
ORROSIVE CAST IRON STAINLESS STEEL COPPER
&
STEEL 8RAS5 Cu-Ni
GRAY NICKEL 12 C 17 Cr 26-1 304 316 20-25-4.5 BRONZE
I I I I I I , I I I
ACTIC ACID I I I I I I I I I I
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ll o x ¥ t i#azsst #ssh • • •
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76
Ni Ni-Cu Ni-Cr-Fe Ni-Mo Ni-Cr-Mo

Gold
Ni-Ce-Fe-Mo Aluminum & lead Silvr Tantalum Titanium Zirconium
99 66-32 76-16-7 8 - 2 c-276 Platinum
t - I I I I I I I I
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77
IRON BASE
COPPER BASE
CORROSIVE CAST IRON STAINLESS STEEL co PPER

STEEL &
BRASS Cu-N;
GRAY NICKEL 12 Cr 17 Cr 304 BRO NZE
26 316 20-25-4.5
LEAD TRINITRO
RESORCINATE
1 2 1 2
LEVULINIC
ACID
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78

Ni-Mo Ni-Cr-Mo
Ni-Cr-Fe -Mo Aluminum leod Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 8- 2 C-276

•
Platinum
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I4 I4
I5 I5
I6 I6
79
COPPER
&
STEEL 8RAS$ Cu-Ni
17 Cr 304 316 20-25-4.5 BRONZE
GRAY NICKEL 12 Cr 26
1 1 1 2 1 2 1 2
MANGANESE
CHLORIDE
• • • •
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I
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4
2
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MERCURIC
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6 X X X X X X X X % X X X X X X
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= 0 0 X ox
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MERCURY
10
"MERSOL"
SULPHONIC
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II • • • • • • • $
• • • • • • • • •• • • • • • • • • • • • ••
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12
METALDEHYDE
13
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16
80
Ni Ni-Cu Ni-Cr-Fe Ni-Mo Ni-Cr-Mo Gold 0

Ni-Cr-Fe-Mo Aluminur & lead Silver Ta ntolum Titanium Zirconium
99 66-32 76-16-7 8- 2 c-27% Platinum
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81
:
,
•
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CORROSIVE cAr IRON STAINLESS SIEEL
s
SEE BRASS Cu-Ni
GRAY NICKEL 12 C 17 c, 26-1 304 31% 20-25-4.5 BRONZE
I I
METHYL ETHYL
I I
KETONE
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7
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;
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10
MILK
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MIXED ACIDS
H,SO, & HNO,
12
MOLASSES
13
MONOALLYL
PHTHAL ATE
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BUTENE
15 0 0
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82 .I
%
N I C K E L B A S E
Ni Ni-C Ni-Cr-Fe Gold

Ni-Mo Ni--Ce-Mo
Ni-Ce.Fe-Mo Aluminum & eod Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 B-2 c-276 Platinum
I
I
2
2
3
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3
0
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4
4
5
5
6
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13
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83
IRON BASE COPPER 8ASE
ORROSIVE CAST IRON STAINLESS STEEL COPPER
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Ni Ni-C Gold
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99 66-32 76-16-7 8-2 C-276 Platinum
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85
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Ni Ni-C Ni-Cr-F% Ni-Cr-Mo Gold

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99 66-32 76-16-7 B - 2 c-276
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Ni Ni-Cu Ni-Cr-F% Ni-Mo Ni-Ce+Mo Gold

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99 66-32 76-16-7 8-2 c - 2 7 6% Penn
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130
Ni Ni-C Ni-Cr-F% Ni-Cr+Mo Gold

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99 66-32 76-16-7 B- 2 C-276

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Ni Ni-Cu Ni-Cr-% Gold

Ni-Mo Ni-Cr+Mo
Ni.Cr-Fe-Mo Aluminum & ad Silver Tantalum Titanium Zirconium
99 66-32 76-16-7 B- 2 c-276 Platinum
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1
Ni Ni-C Ni-Cr-Fe Ni-Mo Ni-Ce+Mo Gold
Ni-Cr-Fe -Mo lead Slur Tantalum Titanium

•
Aluminum
Zirconium
99 66-32 76-16-7 8- 2 c-276 Platinum
• • . '
I
• • I
I • • I I
• • ,:
• • X
¢
2 I
0 ¥
t
- . I
[;
3
3
I
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(
i
i
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r
4 %
4
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• • X X
ll
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• • • • • • • • • • • • • • • • • • • ! «
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• • • • • • « ¥ X X
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,,
8
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l
,
j
fl:
t
I
4
I4
4
15
I 5
1:
,,
16
I6 fl
'
I
135
CORROSIVE
8RA5S C-Ni
l l 2 l l 2 l 2
ZINC CHLORIDE
X. DX. X X. X X 4 4 0o 0 p o t 4 d o d d.
2l x
• a le . H EE
• • • • • • •
ZINC
• • • • •
FLUOROSILICATE] 3 %
X .fix X
• • • • •
3\ 68 X. DX
• • • • • • •
ZINC
ll[+Ill}+++lll4
+bl[]lb++lb[+[+
]
j
HYDROSULfilf,]4
ZINC SULFATE
0
• • • •
5 0
• • • • • • •
10
[ 1 [l+l++
/+}+]}l}+4+]+ l]+ll+ll-+4l4+l}+]+Ill]}+4
4[+l+[44}L
12
4+
+4+l}+4l}+]I}+}44]'}[4
+}4]+l'}ll-I'll }}[]
[
+l
[
ill+}ill4l+]4++
]}'+}+l]+]l]'[+]4
[kl+l]
136

Ni-Mo Ni-Cr-Mo
Ni-Cr-Fe -Mo Aluminum
99 66-32 76-16-7 8 - 2 c-27%
•
Platinum
lad Silver Tantalum Titanium Zirconium
I
I
• •
•
X
2 X
#
0 0
0
• • ts# e • • • • • • • • • • • • • 0
• • • • • • • • • • • • • 0 L
• • • • • •
3
X
% • • 0 0 '
• • • 0
0
• • 0 0 x HEN
• • • • • • D D
• •
0
• • •
5
0O0
• • • • • • • • • • • • • •
0 00OXD
0
• • • • • • • • • • •
•
• •
6
I
f-
8
l
9 (
- �� . A
A
- I- -
••-I-- --
10
I
I -
I2
13
I4
I
I5 I
16
I
137
Section 2
Short T a b l e s
The following "short" tables contain data on additional materials not found in the main tables and are organized
separately to conserve space. Data in this section also represent exposure in the 0 to 500 F (-18 t0 260 C) cor
rosive temperature range, are of the same kind and reliability as other data found in this volume, and come from
the same sources.
Data are plotted in the same matrix used in the main tables (shown below). The reader is advised to examine
this matrix before attempting to use the talbes. A replica of the matrix also appears on the fold-out page im
mediately following the introduction for ready reference when reading the tables. A key to the data points (giving
average penetration rates per yean), a key to footnotes, and a table of identifications and nominal analyses of
metals and alloys are also located on the fold-out page.
Consult the introduction for further instructions on how to use this data survey.
F (C)
500 (260)
20 40 60 80 100
400 (204)
-
300 (149)
200 (93)
100 (38)
20 40 60 80 100
0 (-18)
Percent Concentration in Water

M I S C E LL A N E O U S M ET A L S ANO ALLOYS
CORROSIVE Steel Gray Aluminum
Cast
Iron
ALLYL BROMIDE
304 316 Ni-Cr-Fe-Mo Ni NI-Cu Ni-Gr.Fe Ni-Cr-Mo

ALUMINUM 99 66-32 76-16.7 €276
FLUOROSULFATE
0 0
•
2 0 • •
Copper Ni-Cu Ni-Mo Ni-C6-Mo
ALUMINUM
& 66-32 8-2 0276
Bronzo
OXALATE
3
Steel Gray 316 NLCrF8-Mo
ALUMINUM
Cast
Iron
STEARATE
4
Silicon 304 316 NC.Fe-Mo
AMMONIUM Cast
ron
ARSENATE
0
• •
0 0 0
5
•
Steel Siicon Copper NI Aluminum Load
AMMONIUM
Cast & 9
ron Bronzo
AZIDE
6
'
Stoel Gray Nickol Silicon
AMMONIUM Cast Cast Cast
Iron ron Iron
BENZOATE
7
Steel Gray Nickel 316 NIC&Fe-Mo
AMMONIUM Cast Cast
Iron Iron
BORATE
0 0 0 0
8
Silicon 316 Copper
AMMONIUM
Cast Aron
IODIDE
9
Silicon Aluminum
AMMONIUM
Cast Iron
LACTATE
. 4
· - f- .
□
10
140
MISCELLANEOUS M ET A L S AND ALLOYS
CORROSIVE Steel Aluminum
AMMONIUM
THIOGLYCOLATE
Steel Silicon Aluminum

ANTHRANILIC
Cast Iron
ACID
. -
2
304 316 NI NL.Cu NICI.F
ARSENIC PENTOXIDE
99 66-32 76.16.7
&
62% SULFURIC
x
• • ¥
3
Steel Gray Copper Aluminum Silver
ARSENIC DISULFIDE
Cast Iron
f
!
4
Stool Gray Copper Brass Silver
ARSENIC TRIOSULFIDE Cast fron
5
304 316
BEER
C - - h -
I- . .. l I- ·'-·
6
Ni Ni-Cu NiCrF8 Titanium Zirconium
BERYLIUM OXIDE 76-16.7
99 66-32
7
Steel Silicon 304 tu Ni-Gr-Fe·Mo N-GU
BISMUTH
Cast lron 66-32
SUBCARBONATE
0 0 0
8 0
Steel Silicon Ni-Cr-Fe-Mo

BISMUTH Cast Iron
NITRATE
9
Stoel Gray Ni Ni-Cu Lead
BROMOBENZYL
Cast Iron 99 66-32
CYANIDE
I I I
.
I l •
. -
. : t
I I
10
141
M I S C EL L A N E O U S M ET A L S AND ALLOYS
CORROSIVE 304 316 NL-Cr-Fe-Mo NI Ni-Cu Silvor
99 66-32
BROMOISOVALERYL
UREA
Steel SIiicon Gray 304 NI

BUTYL BENZOIC ACID Aluminum
Cast Iron Cast Iron
99
2
Steel SIiicon Gray Nickol
CALCIUM CYANAMIDE
Cast Iron Cast ron Cast Iron
3
Steel Gray Niel
CALCIUM CYANIDE Gold Platinum
Cast iron Cast Iron
4
304 316 NC-Fe-Mo Aluminum
CALCIUM
HYDROSULFIDE
0
5 • • •
Stool Gray d 316 NGr-F0-Mo Aluminum
CALCIUM PEROXIDE
Cast Iron
. -
0
6
Stool silicon Gray
CALCIUM
Cast iron Cast Iron
PHENOSULFATE
7
Silicon tray Nickel Ni-Cr-Fe-Mo Aluminum
CALCIUM PROPIONATE
Cast Iron Cast tron Cast Iron
8
Silicon NCr-Fe.Mo Ner-Mo
CALCIUM PYRIDINE
Cast Iron 0276
SULFONATE
9
Steel 304 to Copper Nickel
CEROUS CHLORIDE
1 1
2 2
10
142
M I S C E LL A N E O U S METALS AND A LL O Y S
CORROSIVE Stool Copper Aluminum Loa0 Silver
CEROUS FLUORIDE
Stoot Sitcon Load Siver

CEROUS SULFATE
Cast Iron
. . .
'
CHLOROBENZENE 60%
..
N N-Cu
68-32
Ni-Gt-Fe
76-16-7
N-Cr-Mo
C-276
CHLORAL40%
3
Stool 304 Copper Ni-Gt+MO Alumninum Load Silver
CHLOROBENZOYL
c276
CHLORIDE
A4
304 316
CHLOROPICRIN
5
Steel Silicon (fay
CINNAMIC ACID
Cast Iron Cast lron
6
Stoel Silicon 316 Aluminum Lead
COBALTOUS SULFATE
Cast Iron
-
•
,~~
•
7
Steel Silicon Gray Nickel Aluminurn
COPPER GLUCONATE
Cast Iron Cast Iron Cast iron
8
Steel Siicon Gray Nicket Aluminum
COPPER Cast iron Cast Iron Cast ron
NAPHTHENATE
9
Steel Sitton 316 Ni-Cr-Fe-Mo
Gray Nickel 304
CYANOHYDRIN
Cast ron Cast ron Cast iron
10
143
MISCELLANEOUS M E T A LS AND ALLOYS
CORROSIVE Steel silicon Gray Nickel 304 316 Ni-Cr-Fe·Mo NI
Cast Iron Cast Iron Cast Iron 99
DIBUTYL SEBACATE
304 316 Ni-Cu

DIBUTYL SULFATE 86-32
2
304 Tantalum Titanium 2Zirconlm
DICHLOROACETIC
ACID
3
Steel Silicon Gray Nickel
DIETHYLCARBONATE Cast Iron Cast Iron Cast Iron
4
stool Gray 304 316 NLG1-Fe.Mo Ni-Mo
DIISOBUTYL Cast iron 8-2
ALUMINUM CHLORIDE
5
304 316 NI Ni-Cu NL.Mo Aluminum
DIMETHYL 99 66-32 82
6
CHLORACETO
ACETAMIDE
- - · - - ·-
-- - - - - -- - --
•
6
Steel 304 316 Ni-Cr-Fe Aluminum Titanium
DIMETHYL (UNS) 76-16-7
H Y D R AZ I N E +
HYDRAZINE 50%-50%
7
Steel Silicon ray
DIMETHYL SULFATE Cast Iron Cast Iron
8
Silicon NI-Cu Ni-CF8-Mo
FERRIC Cast Iron 68-32
FERROCYANIDE
9 • •
Silicon Ni-Cr-Fe Ni-Mo Ni-Cr-Mo

FERROUS AMMONIUM Cast Iron 76-16-7 8-2 c-276
CITRATE
- -
---
0 0 0
Io
144
M I S C EL L A N E O U S M ET A L S AND A LL O Y S
CORROSIVE 304 316 NI-Cr-Fe+Mo Ni-Cr-Mo
Cc276
FERROUS IODIDE
0 2
• •
I
Steel Silicon Gray Nickol

GLYCEROL Cast Iron Cast Iron Cast Iron
MONOCHLORO
HYDRIN
. .
2
304 316 NICI-Fe.Mo Tantalum
GOLD CYANIDE
PLATING SOLUTION '
3
Silicon 316 Ni-Cr-Fe-Mo
IRON SULFAMATE Cast Iron
4
Steel $Ilion Gray Nickel
ISOBUTYLENE Cast Iron Casi Iron Cast fron
CHLOROHYDRIN
5
Stool Silcon NICrFe-Mo Aluminum
ISOBUTYIC
Cast Iron
ACID
6
Silcon Titanium
ISOPROPYL NITRATE
Cast Iron
7
304 316 NICrFe-Mo
LEAD FLUOSILICATE +
8.5% H,-Si-Fe +
6.9% Pb-Si-F,
8
Steel Silicon Gray Nickel Copper
LEAD NAPHTHENATE
9
Steal Silicon Gray Nickel 304 316 Ni-Cr-Fe-Mo
LEAD PATHALATE
10
145
M I S C EL L A N E O U S METALS AND ALLOYS
CORROSIVE Steel Silicon Gray Nickel
Cast iron Cast iron Cast Iron
LEAD SALICYLATE
Steel Silicon Gray 304 316 Ni-Cr-Fe-Mo NiMo

LEAD STEARATE Cast Iron
Cast Iron 8-2
2
Steel silicon Gray 304 316 Ni-Cr-Fe·Mo Ni·Mo
LEAD TETRA-ACETATE
Cast Iron Cast iron 8-2
3
Silicon 304 316 NL-Cr.Fe.Mo Ni-Cu Aluminum
LINALYL ACETATE
. Cast Iron 68-32
4
LITHIUM BENZOATE Cast iron Cast Iron Cast Iron
5
304 316 99 Ni-Cu Ni-Cr.Fe
LITHIUM BROMIDE
06-32
- c - j,-1-·
---�-
. . - . -- e- . •-�
6
LITHIUM SALICYLATE Cast Iron Cast iron Cast Iron
7
Steel Silicon Gray Nickel Titanium
MAGNESIUM Cast iron Cast Iron
Cast Iron
GLUCONATE
8
MAGNESIUM Cast Iron Cast Iron Cast Iron
GLYCEROPHOSPHATE
9
Steel Silicon Gray Nice
MAGNESIUM
Cast Iron Cast Iron Cast tran
HYPOPHOSPHITE
10
146
MISCELLANEOUS METALS A N D ALLOYS
CORROSIVE
Silicon 304 Aluminum
Cast lron
MAGNESIUM
PERCHLORATE
• •
I
Silicon
304 316 NiCrFe.Mo
MANGANESE Copper
Cast lron
CARBONATE
- .
0 O
e

MANGANESE
LINOLEATE
3
Stee Silicon
MANGANESE Gray Nickel 304 316 NiCrFe-Mo
C. I. C. I. C.1
NAPHTHENATE
4
304 316 NiC:-Fe.Mo
MERCURIC
ACETATE
5
Silicon 304 316 Ni-Cr-Fe.Mo
MERCURIC Ni-Cr-Fe Lead
Cast Iron
76-16.7
SULFATE
- - ..
4
I?
0 - - - - -
0 l? 0 0
6
Silicon Gray Nickel 304
METHACRYLIC ACID Steel 316
Cast Iron Cast Iron Cast Iron
7
METHYL ABIETATE 304 316 Ni-Cr-Fe-Mo
Cast Iron Cast ron Cast Iron
8
Steel Silicon tray Nickel 304 316
METHYL ACRYLATE Cast Iron
Cast Iron Cast Iron
Steel Silicon Gray Nickel Copper

METHYLAMYL
Cast ron Cast Iron Cast Iron
ACETATE
10
147
MISCELLANEOUS METALS A N D A LL O Y S
CORROSIVE Steel Silicon Gray Nickel
Cast iron Cast Iron

Cast Iron
METHYL LACTATE
Silicon 304 316 Ni-Cr-Fe-Mo Aluminum

Steel
METHYL Cast iron
METHACRYLATE
. .
2
Silicon Gray Copper
Steel
METHYL PROPIONATE Cast Iron Cast Iron
3
Silicon Gray Copper Aluminum Silver
Steel Ni-Cu
METHYL SALICYLATE Cast Iron Cast iron 66-32
4
Ni-Cr-Fe.Mo Aluminum
Steel 304
MON OM ETHYL
HYDRAZINE
5
Steel 304 316 NI-Cu Ni-C«Fe
NAPHTHENIC ACIDS 66-32 76.16.7
�c. . . e
'.
6
NI-Cu Aluminum
Silicon 304 316 NC&Fe·Mo
NICKEL ACETATE Cast Iron
66-32
7
Steel 304 Aluminum
316
NICOTINE
•
•
8
304 316 Ni-Cr-Fe·Mo Ni-Gr-Fe Ni-Cr-Mo
NITRIC ACID (25-35%) 76-16.7 C-276
+ 515 ppm CHLORIDES
9
Steel Gray Nickel Aluminum
NITROXYLENE Cast Iron Cast Iron
10
148
M I S C E L L A N E O U S METALS AND ALLOYS
CORROSIVE 304 Copper Ni-Cr-Fe

Gray
Steel
Cast iron 76-167
PENICILLIN
NUTRIENT
Silicon 316 Alurinurn

PERACETIC ACID Cast iron
- .
2
Siicon 316 Ni-Gr-Fe-Mo
PERMANGANIC ACID Cast Iron
3
Steel Siicon 304 Copper Brass Ni-Mo
PHENOL + Cast ron 8-2
3-5% SULFURIC ACID
4
Silicon N , 99 Alumninum
PHENYL GLYCINE Cast iron
4
I
i
5
Ii
Silicon Lead Titanium Zirconium
PHOSPHORUS Cast Iron
ii
TRI BROMIDE
t:
11
l
. .
... -
• - -· . .. . -- .. f;
f
.,
6
i,

POTASSIUM i
Cast iron Cast iron Cast Iron
I:
CITRATE "
g
POTASSIUM Stoel Si/icon Gray Nickel Silver
Cast Iron Cast iron Cast Iron i

GLUCONATE
� !
NICI-Fe-Mo Lead
POTASSIUM Steel Silicon 316
Cast iron
METABISULFITE

POTASSIUM
STANNATE
d 4
10
140
CORROSIVE
Silicon Ni-Cr-F8-Mo Aluminum
Steel
Cast Iron
RESORCINOL
0 I
Silicon Aluminum Titanium

Cast Iron
RICINOLEIC ACID
. .
2
Steel Silicon Aluminum Gold Silver
Cast Iron
SELENIC ACID
al '
304 316 NICI-Fe.Mo Titanium Zirconium
SELENOUS ACID
• • • • • •
4
• • • • • •
Silicon 304 Copper
Cast
Iron
SILICOTUNGSTIC
ACID
5
Silicon Ni-C&-Fe-Mo
Cast
Iron
SILVER
I
SULFATE I
6
304 316 Ni-Cr-Fe-Mo
SODIUM
BOROHYDRIDE
7 • • • • • • • • •
Steel Silicon 304 316 Ni-Cr-Fe-Mo Brass Aluminum
Cast
ron
SODIUM
CYANIMIDE
¥ ¥
8 9 • • •
Steel Gray Nickel
Cast Cast
Iron lron
SODIUM
GLUCONATE
304 316 Ni-Cr-Fe.Mo
SODIUM
HYPOPHOSPHATE
10
150
MISCELLANEOUS METALS A N D ALLOYS
CORROSIVE Steel Gray Nickel Ni-Cu

Cast Cast
ron Iron
SODIUM
HYPOPHOSPHITE
Steel Silicon 304 316 Ni-Cr-Fe-Mo Titanium
Cast
ron
I
SODIUM
OLEATE
2
0 0
l#
Steel 304 Aluminum Titanium
SODIUM
OXALATE
0
3 X
Steel 304 316 Alumninurn
SODIUM
PROPIONATE
4
316 NCt-Fe.Mo Copper Ni.Cu Aluminumn Lead Siver
304
SODIUM
PYROSULFITE
5
Steel Gray Nickel 304 316 NI-Cr.Fe-Mo
c Cast Iron
SODIUM
RESINATE
�. .
6
Steel 304 316 Aluminum
.,
3ODIUM
3TANNATE .,
'
.
7
Steel Gray
Cast
Iron
SODIUM
TETRASULFIDE
8
Stoel Gray Nicket
j
Cast Cast
Iron Iron ti
3ODIUM
TRICHLOROACETATE
9
316 Ni.Cr-Fe-Mo
STANNOUS
FLUORIDE
• • • • • •
• • • • •
10
151
CORROSIVE 304 Ni.Mo Aluminum

Ni-Cr-Fe-Mo
STREPTOMYCIN
Steel Gray Nickel
Cast Cast
Iron ron
STRONTIUM
CARBONATE
2
Steel 304 316 Ni Ni-Cu Ni-Cr.Fe Ni-Mo
l l
STRONTIUM
CHLORIDE
¥ x ¥ ¥ X X
3
Steel Gray 304 316 Copper Brass Aluminum Titanium
Cast
ron
SULFAMIC ACID
¥ X ¥
¥ X ¥
4
Gray Nickel Titanium Zirconium
Cast Cast
Iron
Iron
SULFANILIC
ACID
•
5
Gray 304 NICr-Fe.Mo Aluminurn
Steel
Cast
Iron
SULFONIC
ACIDS
0 0
X. DX X. .X 0 0 0 0 .X
6
Gray Nickel Nickol N-Cu Aluminum
Gast Cast
Iron ron
TERPINYL
ACETATE
7
Steel 316 Ni-Cr-Fe-Mo
Ni-Cr-MO Alumninum
c-276
THIOGLYCOLIC
ACID
•
• • • •
8
Nickel Ni-Cu Lead
Ni-Cr-Fe.Mo
THIOPHOSPHORYL
CHLORIDE
9
316 Ni-Cr-Fe.Mo
THIOUREA
10 •
•
152
MISCELLANEOUS METALS AND ALLOYS
CORROSIVE 304 316 Ni-Cr-Fe-Mo Nickel Ni-Cu Ni-Cr-Fe Ni-Cr-Mo
C276
ZINC
DI HYDROGEN
PHOSPHATE f
(fay Nickel
Steel
Cast Cast
Iron Iron
ZINC
NAPHTHENATE
2
. .
Aluminum Silver
ZINC
OXIDE
3
Steel Gray Nickel
Cast Cast
ron lron
ZINC
PHENOLSULFONATE
-� . .
"'
,. . . .
� 4 �L L .LL U..
10
154
M I S C EL L A N E O U S METALS AND ALLOYS
CORROSIVE 304 316 Aluminum
THORIUM
NITRATE
I •
•
Aluminum
Steel
TRIACETIN
. .
Steel Gray Nickel Copper Brass
Cast Cast
Iron ron
'RIALLYAMINE
3
Steel Gray Copper Brass
Cast
ron
RICHLOROETHANOL
MINE
4
Steel Gray Nickel Copper Brass
Cast Cast
Iron Iron
RIETHYL
PHOSPHATE
5
Steel Copper Aluminum
TUNGSTIC
. . . . . 1-
- - f- -
ACID
.
--
.
. -- . - -
.
+lh
6
Steel 316 Ni-Cr-Fe.Mo Aluminum
JNDECYLENIC
4CID
.
304 316 N-Cr-Fe-Mo
'
JRANIUM
I
HLORIDES
8
Aluminum Zirconium
VALERIC
ACID K
0 0
9
Steel Gray Nickel 304 316 Ni-Cr-Fe.Mo
Cast Cast
Iron Iron
ZINC
CYANIDE
0 0 0
Io
153
Section 3
H i g h Temperature
Tables
The following tables contain data representing exposure of materials to corrosives in the 660 t0 1560 F (350 t0
850 C) temperature range which could not easily be accommodated in the main tables. The data are of the same
kind and reliability and come from the same sources as other data found In this volume.
The reader is advised to examine the following matrix upon which the tables in this section are based (and
which differs from the matrix used in two preceding sections) betore attempting to use the tables. A replica of the
matrix appears at the bottom of each page in this section along with a key to data points (giving average penetra
tion rates per year), footnotes, and a table of average penetration rates per year compared to weight loss.
Consult the introduction for further instructions on how to use this data survey.
850 1560
20 40 60 80 100
750 1380
650 1200
550 1020
450 840
20 40 60 80 100
350 660
C F PERCENT CONCENTRATION IN WATER

M I S C E L L A N E O U S METALS AND ALLOYS
CORROSIVE
Silicon Cast Stainless Stainless
Ac1 20Cr30NI Nickel Ni-Cu NiCrFe
lron 302-347 316-317
ALIPHATIC DICAR
24
BOXYLIC ACID 1

Grsy Cast lron Mt Steet AC 20C3ONT Copper Brass 70-80 Bea 59.93 Nickel Ni-Cu
ron 302-347 316-317
ALUMINUM
2
Aluminum Silicon
NiCrfe Tantalum Titanium Columtium Fosterite Fe00,0, Magnesia Molybdenum Tungsten
Oxide Car bide
Zircon
Nickel NiCrfe Platinum
AMMONIA
Ni.Mo NiC«Mo
AMMONIUM
CHLORIDE
4
Stainless
NiCrfe Platinum Titanium
302-347
BARIUM CHLORIDE
""
AVERAGE PENETRATION PER YEAR

850 1560
20 40 60 80 100
inch AVERAGE PENETRATION RATE/YR COMPARED TO WEIGHT LOSS
Cod 4 le
7%a%
750 1380
• < 2 0.002 50.8 cos m t hm"le lb/ft,/V'
cps r t e % +
0 < 20 0.020 508.0 A L U M I N U M LEAD
20 0.020 508.0

•
<3.79
650 1200
□
<138 <0.0284
• <15.25 <576 <0.A178
I 50 0.050 270.0 0 <7,90 <380 <0.284

0 <31.50 <$760 <1.478
x 379945 1380-31450 0.284-0.71 1.178-21.945

50 0.050 1270.0 □ □ 315.393.75 5760-14,400
550 1020
X 2945.5 2>450 >0.71 X 2>393.75 >14,400 2.945
SOME CONVERSION FACTORS
COPPER, N I C K E L I R O N TANTALUM
Stet: mpy + lb//1x 24.5
ipy 696 density = mdd

450 840
g/m/dx0.0144 + density =ipy
• <IL.9 <43$ <0.0896
• <23.06 <843 <0.172
0 <119.0 <43$0 <0.896

f micron 0,0397 mt 0 <230.6 <8430 <1.2
rt per million = 0.001 g/liter

20 40 60 80 100 □ 19.0297.5 4350-10875 0.896-2.24
□ 230.6-576.5 8430-21,075 1.724.3
350 660 Normal 1 g equiv. liter (wt)

X >297.5 >10875 4.
>124 X >576.5 >21,075
C PERCENT CONCENTRATION IN WATER
156
M I S C E L L A N E O U S M E T A LS A N D A L L O Y S
CORROSIVE
Nickel Cast Silicon Cast Stainless
Gray Cast lron Mild Steel ACI 200-30NI Copper Bras 70.80 Brass 59-93 Nickel Ni-Cu
ron lron 302-347
BIPHENYL
NIC«Fe NiMo Gold Platinum Zirconium
Stainless Stainless
Mild Steel NiCrFe Tantalum Titanium Zirconium Columbium Molybdenum
302-347
Tungsten
405-410
BISMUTH
2
Stainless Stainless -
Gray Cast Iron Mitd Steel Copper Brass 70-80 Brass 59-93 Nickel Ni-Cu Lead Tantalum
302-347 316-317
CADMIUM
3 '
Titanium Molybdenum
le
3
Stainless Stainless
Mild Steel AC1 20Cr30Ni
302-347 316-317
CALCIUM
4
Stainless Stainless
Copper NiCrFe Platinum Tantalum Zirconium
302-347 316-317
CARBON DIOXIDE
h3
Nickel NiCrFe Aluminum

CALCIUM CHLORIDE
I ,
1 . No water FOOTNOTES FOR DATA SQUARES
2. No air, oxygen
1 3 . May pit 27. > 538 C = nitriding
3. Low a i r , oxygen
1 4 . May stress crack 28. Over I 000 C
4. Pits 1 5 . Transgranular attack
5. Stress cracks 1 6 . Vapor 20. Agitated 29. 8 ps
6. Stress corrosion 1 7 . Aerated 2 1 . 7 pH 30. Oxide
7. Discolors 1 8 . Catalyzes 22. < 7 pH 3 I . When wet

8. Crevice attack 1 9 . Static 23. > 7pH 32. Weight gain
9. I n t e r g r a o u l a r attack
24. 25 to 100C 33. 1 2 5 psi
10. No chlorides
2 5 . Graphitizes
1 1 , May discolor
1 2 . May catalyze 26. Embrittles
157
M I S C E L L A N E O U S METALS AND A L L O Y S
CORROSIVE
Nickel Cast Silicon Cat Stainless Stainless
Grey Cast Iron Copper
lron AC1 20Cr3ONT Best 70-80 Bras 59-93 Nickel Ni-Cu
ron 302-347 316-317
L
1 I
o
CARBON
MONOXIDE 1
NiCrFe NiMo NiCrMo Aluminum Platinum
no 4
Stainless
NiMo NiCr-Mo Gotd Platimmn
302-347
CARBON
f 1 l
f
TETRACHLORIDE
2
Stainless Stainless
Mild Steel Brass 70-80 Nickel Ni-Cu NICrFe NiMo
302-347 NiCrMo Platinum Magnesium
316-317
CHLORINE
X 0 0 0
3
Stainless
NiC-Fe NiCrMo
302-347
CHLORINE + STEAM
4
Stainless Stainless
Mid Steel Copper Gotd Silver
Platinum Tantalum Titanium Zirconium
302-347 316-317 Columbium
CESIUM
819 ,,,
- 2 c 3
r '
31 2
Hafnium Molybdenum Tungsten Vanadium
2 87 2 r he '
'
Stainless
Mitt Steel
302-347
COPPER SULFIDE
850 1560 AVERAGE PENETRATION PER YEAR

20 40 60 80 100
ic AVERAGE PENETRATION RATE/YR COMPARED TO WEIGHT L0g
Coed ii Meo
7%%%
750 1380
• < 2 0.002 50.8 cos r t he n/ 0os rt4my "..,,,,.,. /
0 < 20 0.020 508.0 A L U M I N U M

LE A 0
650 1200 20 0.0270 508.0

□ • <3.79 <138 <0.084
• <15.75 <$76 <0.1178
I 50 0.050 270.0 0 <31.90 <1380 <0.284

0 <3150 <$160 <1.178
X > 50 0.050 1270.0 □ 37.9.945.5 1380-34$0 0.2840.7

□ 315/393.75 $760-14,400 1,178-2.945
550 1020
X >945.5 >3450 0. 7 1 X >393.75 >14,400 >2945
C O P P £ RH , N I C K E L + I R O N TANTALUM
Steel: rpy I/Ty+x2A.5
ipyx696 density + d4
450 840
gm{de0.0144 density ipy
• <4L.9 <43$ <0.096
• <23.06 <84.35 <0.172
< 1 1 9. (
micron 0,0397 mil 0 <4350 <0.896 0 <230.6 <8430 <1.72
20 Pets per million 0.09l g/liter

350 660
4 60 80 100
□ 1 1 9. 0 2 9 7 5$ 43$01087$ 0896.21.24
□ 230.6576.5 8430-21,075 1.724.3
N o r a l ! g e q u i v. liter (wt
x 297.5 >10875 >2.24 x 576.5 >21,075 4.J
158
M I S C EL L A N E O U S METALS A N D ALLOYS
CORROSIVE
Ni-Cu Ni«Fe NIM Silver
FATTY ACIDS
Nickel Ni Cu NiCrFe NiCr Mo Gold Platinum

FLUORINE
•
2
Stainless
Platinum Silver
302-347
FORMALDEHYDE
3
• • •
. . . . .
3
Nickel Tantalum Titanium Beryllium Molybdenum Rhenium Tungsten
GALLIUM
9
4
Stainless Stainless
Stainless
AC1 20Cr3ONi
302-347 316-317 405-410
GLASS
1. No water FOOTNOTES FOR DATA SQUARES
32. With steam

2. No a i r , oxygen 1 3 . May pit 24. No sulfur
3. Low air, oxygen 1 4 . May stress crack 2 5 . With sulfur 33. As catalyst
4. Pits 1 5 . Transgranular attack 34. No solder

26. No hydrogen sulfide
5. Stress cracks 1 6 . Vapor 20. Agitated
6. Stress corrosion 1 7 . Aerated 21. 7 pH 27. No quartz
7. Discolors 1 8 . Catalyzes 22. < 7 pH 28. Embrittled by O, or N

8. Crevice attack 1 9 . Static 2 3 . > 7 pH
29. No nitrogen
9. I n t e r g r a n u l a r attack
30. Liquid or vapor
10. No chlorides
3 1 . Decarburizing
1 1 . May discolor
1 2 . May catalyze
159
CORROSIVE
Nickel Cast Stainless Stain/s
Gray Cast iron Mitt Steel ACI 20Cr30Ni Copper Bas 70-80 Br59-93 Cupronickel NiCrFe
hron 302-347 316-317
HYDROGEN
I
Niece NiMo NiCrMo Aluminum Ptstinm Siver Tantalum
'
Stainless
Mild Steel
302-347
Ac 20col Nickel NL.Cu NiCrFe NiMo Nieto Gotd Platinum Silver
HYDROGEN
CHLORIDE
2
Stainless
Ni-Cu Aluminum Sifve
316-317
HYDPOGEN
CHLORIDE
+STEAM + AI
3
Steinle4s Stainless
302-347 405.-410
HYDROGEN + .S
0
4
Stainless
Mild Steel Copper Nickel Ni-Cu NiCrFe Aluminum Magnesium
302-347
HYDROGEN FLUORIDE
•
•
•
5
Mitt Steel NiCrFe Platinum Rhodium
HYDROGEN SULFIDE
AVERAGE PENETRATION PER YEAR

850 1560
20 40 60 BO 100
le AVERAGE PENETRATION RATE/YR COMPARED TO WEIGHT LOSS
Coe
•• 7%6 •
750 1380
0.002
ng col ,.,...,.. _.,,..
• ] '
la'i [ 3 0bs rt4y
""''"'
0 < 20 0.020 508.0 ALUMINUM LEAD
0.020 508.0
650 1200
□ [ • <3.79 <13S <0.02&4
• <15.7$ <576 <0.1178
50 0.050 270.0 0 <37.90 <1380 <0.284

0 <31.50 <760 <178
550 1020
x > so 0.050 1270.0 □ 379.9454 1380-3450 0.2840.71
□ 31.$-3931.7$ $760-14,400 1,178.2945
X 945.$ >3450 >0.7l X >393.7$ >14,400 2.945

C 0 P P R , N I C K E L 1 I R O N TANTALUM
Sieet: mopy b/ft/y1x 24.$
pyx6«density m
450 840
tr{40.0144 + density ipy
• <L,9 <45 <00896
• <23.06 <84 <0.172
4119.0 <43$0
micron 0.0393 «l 0 <0.896 0 <230.6 <430 <1.
Pets per million 0.00lg/liter 19027$

20 40 60 100 □ 43$0-10875 0.8962.24
□
230.6-576.$ 8431021,075 1.72-4.
350 660 Normal l g equiv, Aitr [wt)
x >297.$ > 1087$ 22.24 X >576.5 >2,0$ 4.3
160
CORROSIVE
Stainless
Gray Cart lron Mild Steel NiCrfe Nido NC-Mo Platinum Silver Titanium
316-317
HYDROGEN IODIDE ,,
.
.
+ I0DINE + WATER
1
Aluminum Siticon
Magnesia Zwcon Feo 0, 0, Fosterite
Oxide Carbide
IRON, MOLTEN
1535C
2
Nickel Cs»st Stainless Stainless Stainless
ifd Steel Copper Beas 70-80 Bes 59-93 Nickel
Gray Cast ron Ni-Cu
ron 302-347 316-317 405-410
LEAD
3
Alumnimun
Nice NiCrMo Tutalumn Titanium Zirconium Columbium Foo Cr,0, Fosterite Magnesia Molybdenurn
0ide
'
I '
' '
' '
I I
Silicon
Tungsten Zircon
Carbide

34. Annealed
2. No air, oxygen 13. May pit
27. Embrittle, 35. No cold work
3. Low air, oxygen 1 4 , May stress crack
4.Pits 15. Transgranular attack 28. May carburize 36. Brittle 41. Weight lost
5. Stress cracks 16. Vapor 20. Agitated 29. < 0.04%P +S, 37. Impervious
6. Stress corrosion 1 7 . Aerated 21. 7 pH <0.35 38. No silica 42. Loses ductility
7. Discolors 1 8 . Catalyzes 22. < 7 pH
30. < Re 22 39. Hydrogen purges j> 150
3 1 . 1500 psi 40. Weight gained /vol/o
9. Intergranular attack 24. + 7% H,S, 2000 psig
1 0 . No chlorides 25. <7% H,S, 500 psig 32. < 60,000 psi UYS 43. Anhydrous, 100%
1 1 . May discolor 26. + Steam 33. Low HS 44. 50 hours

1 2 . May catalyze
161
CORROSIVE
Silicon Cat Stainless Stainless
Mid Steel
froin 302-347
Ac1 20col Copper Brass 70-80 Bess 59-93 Nicket Ni-Cu NiCrFe
316-317
5 8 9
9
LI T H I U M N
c c
1 "
NiMo Aluminum Lead lstimum Silver Tantalumn Titanium Zirconium Hafnium Molybdenum Tungsten
f 2
' c
30c
'
, ,
'
c 2 c c
Vanadium
Sificon Cast Stainless Stainless

Mid Steel AC 20Cr30NT Copper Brass 70-80 Bras 69-93 Nickel
ron 302.347 Ni-Cu NiCr Fe
316-317
MAGNESIUM
Aluminum Silicon
Aluminum Lead Tantalum Titanium Fe0cr, o, Fosterite Magnesia Zircon
Oxide Carbide
ltsoic
Stainless Stainless
Gray Cast Iron Mitd Steel Nickel Ni-Cu Tantalum Molybdenum
302-347 405-410
MERCURY
9 9
3
Stainless Stainless
Mitd Steel Ni Cu NiCrFe
302.-347 316-317
N A P H TH E N I C ACIDS
4
850 1560 AVERAGE PENETRATION PER YEA

20 40 60 80 100
Loch ., fl
To%w
co
AVERAGE PENETRATION RATE/YR COMPARED TO WEIGHT L09
750 1380
• < 2 0.002 50.8 cos hat 4 l

b /f,1/y,
cos rte'ye 4 /
0 < 20 0.020 508.0 ALUMINUM LEAD
650 1200 20 0.020 508.0 <3.79

□ ( •
<138 <0.0284
• <15.75 <576 <0.1178
50 0.050 270.0 0 <3790 <1380 <0.284

0 <3LSO <51760 <1.1T8
x > 50 0.050 270.0 □ 317.9945.$ 1380-3450 0.2840.7l

□ 31.5-393.75 $760-14,400 1.178-2.945
550 1020
¥ >945.5$ >450 0.7l X >393.75 >14,400 2.945
C O P P E R , N I C K L r R O N TANTALUM
Steel: mpy + l//yx 24.5
pyx696 detsity = mad

450 840
g/ml4 x 0. 0 44 +density ipy • <IL.9 <43 <0.0896
• <23.06 <84 <0.72
<119.0
l micron = 0.03937 ail 0 <43$0 <9.896
0 <230.6 <8430 <1.12
P s per million = 0.0Ol g/liter 190297.5

20
350 660
40 60 80 100
□ 435010875 0.8962.24
□ 230.6576.5 8430-21,075 1.724.3
Normal1 g equiv. liter {wt)
X 2>297.5 > 10875 2>2.24 X >576.5 21,05 24.
C P£HCENT CONCENTATON IN WATER
162
CORROSIVE
Mitd St
eel Nickel Ni-Cu NICrF%
PHENOL
NiMo NiCrMo Gold Platinum
PHOSGENE
2
Stainless Stainless
Nickel NiCrFe Tutatum Titanium Columnbium Molybdenum
302-347 316-317
POTASSIUM
1 I 4 o IC C
2
'
8 31
3 -
Silicon Cast
NMo Molybdenum
Iron
POTASSIUM
[88C
CARBONATE
Mid Steel lutinum Titanium Tungsten
POTASSIUM
1
CYANIDE
(i) 5
Stainless Stainless
Copper Nickef Ni.Cu Platinum Sidver
302-347 316-317
POTASSIUM
1
"
35 3
HYDROXIDE
2
6
NiCrFe NifeC NiMo NiCrMo
POTASSIUM
NITRATE
1 . No water FOOTNOTES FOR DATA SOUAES

35. Mass transfer
2. No air, oxygen 1 3 . May pit

27. Stressed 36. No sulfur
3. Low air, oxygen 14. May stress crack
28. Flowing 37. Phase boundary
4. Pits 15. Transgranular attack
29. 32-38 ppm oxygen
5. Str ess cracks 1 6 . Vapor 20. Agitated 38. Vacuum
6. Stress corrosion 17. Aerated 2 1 . 7 pH 30. Decarburization 39. 4200 psi
7. Discolors 1 8 . Catalyzes 22. < 7 pH 3 1 . <50 ppm oxygen 40. 1 5 psig

32. < 1 0 ppm oxygen 41. Type 347
9. Intergranular attack 24, Lithium chloride

33. 15 fps 42. Low carbon
10. No chlorides 25. < 100 ppm oxygen
34. Stress relieved 43. Low velocity
1 1 . M a y discolor , Em brittled by oxygen
12. M a y catalyze
163
CORROSIVE
Stainless Stainless
Gray Cast lron Mild Steel
Copper Nickel Ni-Cu NiCrFe Aluminum
302-347 316.317 Gold tatinumn
POTASSIUM PEROXIDE
Tantalum Titanium Molybdenum

Nickel NiCrfe
lron 302-347 316-317
POTASSIUM
THIOSULFATE
2
Stainless Stainless
Nickel NiCrFe
302-347 316-317
POTASSIUM TITANIUM
FLUORIDE
3
Stainless Stainless Stainless
Gray Cast Iron Mid Steef ACI 20Cr30Ni Copper Brass 59-93 Nicket Ni-Cu NiCrFe
302-347 316-317 405-410
SODIUM
2 2 2
0M
4
Aluminum Silicon
Silver Tantalum Titanium Zirconium Fe0 c,0, Columbium Fosterite Magnesia
Oxide Vanadiumn
Carbide
Zircon
Nickel NiCrFe Platinum Sitver Molybdenum

SODIUM ACETATE

0 40 60 00 100
le AVERAGE PENETRATION RATE/YR COMPARED TYO WEIGHT LDgS
of 4. ee6et
7%a
750 1380
• < 2 0.002 50.8 Cos m/tatty

L
1y cos wa [ he ,.m'IYt
0 < 20 0.020 508.0 ALUMINUM LEAD
650 1200 20 0.020 508.0

D • <3.79 <138 <0.0284
• <15.75 <576 <0.1178
I 50 0.050 270.0 0 <7,90 <1380 <0.284

0 <31.S0 <5760 <t.178
x > 50 0.050 1270.0 D 37.9.94$.5 1380-1450 0.284-0.71 D 31,$.393.75 $760-14,400 1.178-2.945

550 1020
X 245.5 >3450 >-0.71 X >-193.75 >14,400 2945
COPPER,NICKEL o t l R O N TANTALUM
Steel: mpy = I [ f t 24.5
pyx696density md
450 840
g/mtd 0.0144 % density ipy • <11.9 <43s <0.0896

• <23.06 <84 <0.172
< 1 1 9. 0
I micron 0.031937 a 0 <4350 <0.896 0 <230.6 <8430 <1.72
60 es per million 0.00 /lite

20 4 80 100 D 119.0297.$ 435010875 0.8962.24
D 230.6-576.5 84310-21,075 1.24.3
350 660
Normal}gqui, liter (wt)
29 5 > 10875 >224 X >576.5 24.3
>21,075
C F PERCENT CONCENTRATION IN WAYE

'
164
CORROSIVE
Gotd Platinum Tantalurn
SODIUM BISULFATE
Stainless Stainless
Mild Steel NiCfe Platinum Tantalum ridiuarn Molybdenunn heniun
302-347 316-317
SODIUM CARBONATE
. . 4
2
Stainless
NiCFe Platinum Silver Titanium
316-317
SODIUM CHLORIDE
3
Stai
nless Stainless
Gry Cast lron Mitd See ACI 20Cr30Ni Ni-Cu CrFe platinum Tantalum Titanium
302-347 316-317
SODIUM CYANIDE
4
Stainless
ACI 20Cr 30Ni Nickel Ni-Cu NiCefe NiMo NiC-Mo Gold Pttinumn Siver
Mitd Steel
302-347
SODIUM HEX AMETA
PHOSPHATE
Tantalum Titanium Beryllium Molybdenum Tungsten Vanadium
Nickel Cast Stainless

Gray Cast rot Mitd Stael AC 20Cr30Ni]. Copper Cuponickel Ni
ckel
Ni-Cu NCFe NiCrMo
ron 302-347
SODIUM HYDROXIDE
4 I I I
I I
' ' ' '
l if t # t s
Aluin4n lgtinun Tstlurn Tieniurn Molybdenurr Tngten Vanadium

.
2 . N o air, oxygen 1 3 . May pit 27. 1 0 ppm oxygen
3. Low air, oxygen 1 4 . May stress crack 28. Decarburizes

4. Pits 15. Transgranular attack
5. Stress cracks 16. Vapor 20. Agitated 2 9 . > 400 C
6. Stress corrosion 1 7 . Aerated 21. 7 pH 30. No ammonia salts
7. Discolors 1 8 . Catalyzes 22. < 7 pH 3 1 . With fluorides
8. Crevice attack 19. Static 2 3 . > 7 pH 3 2 , Hydrogen embrittles
9. I n te rg ra nula r attack 24. Low carbon 33. If stressed
1 0 . No chlorides 2 5 . Flowing 34. Mass transfer > 500€

1 1 . M a y discolor
1 2 . May catalyze 26. < 1 0 0 ppm oxygen 35. 30 ft/min
165
CORROSIVE
Stainless Stainless
it Steel Copper Nickel Ni-Cu Gold Platinum Silver
302-347 405-410
4 5
$ODIUM NITRATE
I
Gold Pttinurn Silver Tantalur Titanium Zirconium Molybdenum Palladium Tungsten

$ODIUM PERCHLORATE
Silver Titanium
SODIUM PEROXIDE
3
Stainless Stainless
Mitd Steel NiCrFe Tantalum Zirconium Beryllium Columnbium
302-347 316-317
SODIUM P O TA SS IUM
1 p o
3 l
E
'
4
Stainless Stainless
Gey Cant lron Mid St
eel AI 20Cr3ON; NiCrfe Platinum
302-347 316-317
SODIUM S I LI C A TE S
l oa dc 1
,
I c 0 c
" " '
AC1 20Cr30Ni NiCrFe Gold Platinum Siver Titanium Zirconium
SODIUM SULFATE
c c
'
6
Stainless
lutirum ntalum
316-317
SODIUM SULFIDE
9 c

0 40 60 80 100
Ced ., lm
7%%
.e AVERAGE PENETRATION ATE/YR COMPARED TO WEIGHT LOSS
750 1380
cps
• < 2 0.002 50.8 me'4 he+ / cos tasty he m4
0 < 20 0.020 508.0 A L U M I N U M LEAD
650 1200 20 0.020 508.0

D • <3.79 <138 <0.0284
• <15.5 <S76 <0.1178
l 50 0.050 270.0 0 <7,90 <138 <0.284

0 <3.50 <5760 <1.178
X > 50 0.050 1270.U D 317.99435.5 1380-340 0.2840.71

D 391.5-393.75 5760-14,400 1.178-2.945
550 1020
X 945.5 >3450 -0.71 X >3193.75 >14,400 >2.945
COPPER, N I C K E L IRON
Steel: rpy 1 { 0 x 24.5 TANTALUM
ipyx696 density ma
450 840
gm/d00144+density ipy • <11,9 <43$ <0.0896

• <23.06 <843 <0.172
< 1 1 9. 0
l micro 0,03931 mil 0 <43$0 <0.896
0 <230.6 <8430 <1.12
Puts per million + 0.001 gtet 19.0297.5

20 40 60 0 100 D 43$010875 0.896-2.24 D 230.6576.5 8430-21,075 1.724.3
350 660
Normal = l g eqoi. liter (wt)
X >29.5 > 10875 >2.24 X >576.5 >21,075 4J
C F PERCENT CONCENTRATION IN WATER
166
M I S C E L L A N E O U S METALS A N D A L L O Y S
CORROSIVE
Nickel Cast Stainless Stainless Stainless
Gray Cast ton Mtd Steet Nickel Ni-Cu NiCrfe NiFeCr
AC 20Cr3ONi
fron 302-347 316-317 405-410
4 '
S TE A M 0
NiMo NiCrMo Aluminum Gold Platinum Siver Tantalum Zirconium Molybdenumn Tungsten
'
. .
Nickel Platinum Zirconium Molybdenum
STRONTIUM N I T R A TE
+ TETRAHYDRATE
2
Silicon Cast Saintess Staintes
Gry Cast iron AC 20Cr30Ni Nickel Ni-Cu NiCrfe NiCrMo Aluminum Platinum
Iron 302-347 316-317
SULFUR
'
h
Tantalumn Molybdenum
3
Stainless Stainless
Gay Cast iron Mitd Steel ACI 20Ce30Ni Nickel Ni-Cu NiCrFe NiMo Aluminurn Gold
302-347 316-317
SULFUR DIOXIDE
c c
' I!
• •
•
16
• •
•
•
••
•
4
-
Platinum Titanium lridiurn Molybdenum Rhodium Tungsten
• • c •
' ' '
• • •
• • •
1 . •
• • • .

34. 125 mpy, 1204 C
27. Flowing, no pressure
3. Low air, oxygen 14. May stress crack
4,Pits 1 5 . Transgranular attack

28. 4400 psig 35. H, evolved > 1127 €
5. Stress cracks 1 6 . Vapor 20. Agitated 29. 5000 psig 36. 198 C, < 200 psig
6. Stress corrosion 1 7 , Aerated 21. 7 pH

30. May sensitize > 1400 37. Weight gain
7. Discolors 1 8 . Catalyzes 22. < 7 pH
psi 38. Embnttles 39. No sulfur
3 I. May embrittle
9. I n t e r g r a n u l a r attack 24. Explosive 40. May explode if wet
1 0 . No chlorides 25. No pressure 32. 268 mpy, 1 2 04 C
under pressure
1 1 . May discolor 26. + Ve diu .,~ 33. 8-mil pits, 1095 C
1 2 . M a y catalyze . 'a n a c u m pentoxide 41. Low carbon
167
M I S C E L L A N E O U S M E T A L S A N D A L L O Y S
CORROSIVE
Nickel Cast Stainless Stainless
Mitd Steel Nickel
hron AC1 20Cr30NI NiCrFe NiCrMo Aluminum
302-347 316-317
SULFUR TRIOXIDE
Gray Cast iron Tantalum Tinium Colmbium Molybdenum Tungsten

TIN
Mitd Steel Nickel Ni-Cu NCr Fe
URANIUM FLUORIDE
3
Stainless Stainless
AC1 20Ce30Ni Nice NirFe NiFeCr NiMo NiCo
302-347 316-317
VANADIUM PENTOXIDE
K a .
9 I9
¥
I
I
14 14 4 14
f
25 2
2!
z .21
4
Stainless
AC 20C-30NI Ni-Cu Platinum
302-347
VINYL CHLORIDE
•
•
5
Nickel Cast Stainless Stainless
Gray Cast ron Mild Steet Ac zocroul Copper Nickel NiCrFe Aluminum Gold
fron 302-347 316-317
WATER GAS
If
32
Platinum

20 40 60 80 100
ad .. id
7%%w
id
AVERAGE PENETRATION RATE/YR COMPARED TO WEIGHT L0g
750 1380
• < 2 0.002 50.8 cos mt ha / cps rt1 a

•
0 < 20 0.020 508.0 A L U M ! U M
LEAD
650 1200 20 0.020 508.0

□ • <3.79 <138 <0.0284
• <IS.75 <S76 <0,1178
I 50 0.050 270.0 0 <37.90 <1380 <0.284

0 <31.50 <5160 <1.78
x >
1270.0 17.9.945.5
50 0.050 □ 1380-345$0 0.284.0.71
□ 31.5.-3193.75 $760-14,400 1.178-2.945
550 1020
¥ 945.5 >-31450 0.7 x >393.75 >14,400 >2.945
C O P P E R , N I C K E L « l R 0
Steet: spy =/ft/yx 24.5 T A N T A L U M
+pyx 696 density = ma

450 840
g/m/dx00144 + density = ipy • < I L. 9 <435 <0.0896
• <23.06 <843 <0.172
0 <119.0 <430 <0.896

l micron + 0,03937 % 0 <230.6 <8430 <1.72
Pats per mi[ion 0.004 g/liter

20
350 660
40 60 80 100
□ 19.021975 4350-10875 0.896-2.24
□
230.6-576.5 8430-21,075 L.724.3
Normal+ I g eqvie. liter (wt)
x >-297.5 10875 2.24 x 576.5 2,05 4.3
168
M I S C E L L A N E O U S M E T A L S A N D A LL O Y S
CORROSIVE
Ausninu
Mitd Steel Nickel Ni-Cu NC±Fe Tantalum funiurn
Oxide
Fe0 c,o, Coturmbium Fosterite Magnesia
ZINC
Silicon
olbden fugten Zircon
Carbide
1 . No water FOOTNOTES FOR DATA SQUARES

27. W i t h sodium sulfate 32. Stellte
3. Low a i r , oxygen 14,May stress crack
28. Stress relieve pressure 33. Diffuses into
4.Pits 1 5 . Transgranular attack
vessels
5. Stress cracks 1 6 . Vapor 20. Agitated
6. Stress corrosion 1 7 . Aerated 21. 7 pH 29. Except deoxidized
7. Discolors 18. Catalyzes 22. < 7 pH CDA HO

30. In sulfur reducing
9. I n t e r g r a n u l a r attack 24, Mass transfer
atm.
10. No chlorides 25. Variable
1 1 . May discolor
3 1 . No sulfur
26. With sodium
1 2 . May catalyze
169
.
---
·-
Section 4
Graphs
f
References and Comments for Figure 1
The data points in Figure I are labeled with the reference finery Steels,' Tetsu To Hagane, 1960, Vol. 46, No. 10, pp. 1349-52.
26. Moore, K. L., and Bird, D. B., 'How to Reduce Hydrogen Plant
numbers of their sources as listed below. The letter symbols
Corrosion,'' Hydrocarbon Processing, 1965, Vol. 44, No. 5, pp. 179--
in the figure refer to the comments following the references.
84.
27. Union Oil Company of California, private communication to API
REFERENCES: Subcommittee on Corrosion, 1976.
I. Shell Oil Company. private communication to API Subcommittee on 28. Amoco Oil Company, private communication to API Subcommittee
Corrosion. on Corrosion, 1976
2. Timkin Roller Bearing Company, private communication to AP! Sub 29. Standard Oil Company of California, private communication to API
committee on Corrosion. Subcommittee on Corrosion, 1976,
3. Naumann. F. K.. Influence of Alloy Additions to Steel upon Resis 30. Exxon Corporation, private communication to API Subcommittee on
tance to Hydrogen Under High Pressure." Technische Mireilungen Krupp. Corrosion, 1976.
1938, Vol. I. No. 12. pp. 223-34. 31. Shell Oil Company, private communication to APT Subcommittee on
4. Inglis, N. P.. and Andrews. W.. ''The Effect on Various Steels of Corrosion, 1976.
Hydrogen at High Pressure and Temperature.' Journal of the Iron and 32. Cities Service Company, private communication to API Subcommittee
Steel Institute, 1933. Vol. 128. No. 2. pp. 383--97. on Corrosion, 1976.
5. Cox,J. L., ·What Steel to Use at High Pressures and Temperatures.' 33. Gulf Oil Corporation, private communication to API Subcommittee
Chemical & Metallurgical Engineering. 1933, Vol. 40, pp. 405-9. on Corrosion, 1976.
6. Sarjant. R. J.. and Middleham. T. H., ''Steels for Autoclaves,' World 34. Koch Refining Company, private communication to AP! Subcom
Power Conference, Chemical Engineering Congress Transactions. Lon mittee on Corrosion, 1980
don. June 1936. Vol. I, pp. 6 6 -- 1 1 0 .
7. Standard Oil Company of California. private communication to API
Subcommittee on Corrosion.
8. E. I d u Pont de Nemours & Company. private communication to APL COMMENTS:
Subcommittee on Corrosion,
A. A section made of A I06 pipe was found to be attacked to 27 percent
9. Ammoniawerk Merseberg, private communication to API Subcom of its thickness after 5745 hours. Other pieces of pipe in the same line
mittee on Corrosion. 1938. were unaffected.
JO. Hercules Powder Company. private communication to AP! Subcom B. The attack was concentrated in the overheated section of a hot bent
mittee on Corrosion.
steel elbow. The unheated straight portions of the elbow were not attacked.
I. Zapffe.C. A . . ' Boiler Embrittlement,"Transactions of the American C. In a series of 29 steel samples, 12 were attacked while 7 were not.
f Mechanical Engineers,
Society o 1944. Vol. 66. pp. 81-126. D. After 2 years' exposure, five out of six pieces of carbon steel pipe
12. The M. W. Kellogg Company, private communication to API Sub were attacked. One piece of pipe was unaffected.
committee on Corrosion.
E. Attack was concentrated in the weld and heat-affected sections of A
13, Gcrman operating experience. private communication to AP Sub 106 pipe. Metal on either side of this zone was unaffected.
committee on Corrosion, 1946,
F. After H years' service, attack was found in the hot bend section of A
14. Vanadium Corporation of America, private communication to APL 106 pipe. Unheated straight sections were not affected.
Subcommittee on Corrosion. G. After 2 years' service, all parts of carbon steel pipe, including weld
15. Imperial Chemical Industries. Billingham. England, private commu and heat-affected zones, were satisfactory.
nication to API Subcommittee on Corrosion, H. After 4 years' service, weld and heat-affected zones of A 106 pipe
16. Evans, T. C.. "Hydrogen Attack on Carbon Steels.Mechanical showed cracks.
Engineering. 1948. Vol. 70, pp. 4 1 4 - 1 6 , J. After 3 I years' service, a forging of 0.3C- I .3Cr-0.25Mo steel showed
17. Norweg Hydroelectric, Oslo, Norway. private communication to API cracks 0.007 inch (0.2 millimeter) deep.
Subcommittee on Corrosion. K. Pipes of l.25Cr-0.25Mo steel.
I8. Union Oil Company of California, private communication to APL L. After 4 years' service, a forging of 0,3€-1.3Cr-0.25Mo steel was
Subcommittee on Corrosion. 1980. unaffected.
19. Ciuffreda. A. R . , and Rowland. W. D.. Hydrogen Attack of Steel M. After 4 years' service, a forging of 0.2C-1.2Cr-0 .35Mo steel showed
in Reformer Service.' API Proceedings, Volume 37, pp. 1 1 6 - 2 8 . Amer cra cks 0.032 inch ( 0.8 m ill imeter) deep.
ican Petroleum Institute. Washington, D.C.. 1957 N. After 7 years' service, a forging of 0.3C-1.52Cr-0.50Mo steel showed
20. API Refinery Corrosion Committee Survey, 1957. cracks 0.050 inch ( 1 . 3 millimeters) deep.
21. Air Products. Incorporated. private communication to API Subcom P. After 30 years' serv ice, a for ing
g of 0.30C-0.74Cr-0.43Ni steel was
mittee on Corrosion. March, 1960. una ffected .
22. Gardner. G. D.. and Donovan, J, T.. 'Corrosion and Erosion in the Q. After 15 years in ammonia service, a pipe of 0. 15 C-2 2 . 5 Cr-1 00Mo
.
Synthetic Fuels Demonstration Plants." Transactions of the American So steel showed no hydrogen cracks but was nitrided to a depth of 0.012 inch
ciety o
f Mechanical Engineers, 1953, Vol. 75, pp. 525--33 (0.3 millimeter).
23. Amoco Oil Company, private communication to API Subcommittee R. Sta nless steel
i cl adding on 0.5Mo teel.
s No nown h d
k y rog en attack .
on Corrosion, 1960. S. After 8 years, carbon steel cracked.
24. Comings. E. W.. High Pressure Technology, McGraw-Hill. New York. T. Afte r I8 years, carbon steel did not show hydrogen attack.
1956. U. After 450 days· exposure, l .25Cr-0.5Mo valve body was not damaged
25. Hasegawa. M., and Fujinaga. S., "Attack of Hydrogen on Oil Re by hydrogen.
172
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ROGEN SULFIDE and PHOSPHORIC ACID
Hydrogen Sulfide vs Low Cr Steels Phosphoric Acid vs Type 3 1 6 Steel
c
220
180
140
100
60
40 80 120
PERCENT PHOSPHORIC ACID

600 900 1000 1100 200
Temperature, F
lsocorrosion of Type 316 steel in furnace grade phosphoric acid
Predicted long-term corrosion rates [mpy) of low chromium steels as under mildly agitated conditions. Mils per year averages: 1 = 0 1o 1.
a function of temperature and hydrogen sulfide pressure. 2 = 1 t 0 10.3= 1 0 t 0 5 0 . 4 = 5 0 . 5 = Boiling point curve.
Carbon Steels vs 3000 ppm Hydrogen Sulfide in 5% S o d i u m Chloride
30
cr
a
�
40%
c
25
P
•
:,:
,oo ...�
20
Applied Stresses
Expressed as % of Yield Deformation
"
Day Approximate correlation of

Week
Month
hardness, time to failure, and
o.
',}}
'.,
++z, applied stress for carbon steels
Tire to Failure, Hours

(3000 ppm HS in 5% NaCn).
175
CAUSTIC SODA SERVICE GRAPH
AREA "c
ff
125
APPLICATION OF NICKEL ALLOYS TO BE C O N S I D E R E D IN THIS AREA
M e.
NICKEL ALLOY TRIM FOR VALVES
Oh
I N AREAS B" &C"
100
200
180
� 75
~
0r
....
160 (
.

«t
or
A
C.
::E
....
l
140
50
f l
AREA "A"
fM
:i
CARBON STEEL
MM .
NO STRESS R E LI E F NECESSARY 25
i
Me
L
•
0
I
fl
1
l
l a
1 1
0 1
10 20 30 40 50
1 »
C O N C E N T R A TI O N NAOH, % BY WE I G H T
176
I
CODE FOR MIXED ACIDS GRAPH
Materials in shaded zones have reported corrosion rates of <20 mpy
ZONE1 ZONE2 ZONE 3 ZONE4 ZONE 5
20Cr 30Ni 18Cr 8Ni 20Cr 30Ni 18Cr 8Ni 18Cr 8Ni
Gold 20Cr 30Ni Gold 20Cr 30Ni 20Cr 30Ni
Lead Cast Iron Platinum Gold Aluminum
Platinum Gold Silicon Iron Platinum Gold
Silicon Iron Lead Tantalum Silicon iron Platinum
Steel Platinum Tantalum Silicon Iron
Tantalum Silicon Iron Tantalum
Tantalum
100% H0
100% HNO3
CORROSION RESISTANCE OF MATERIALS TO MIXED ACIDS
AT ROOM TEMPERATURE
177
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a
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f--
400
200
ff
0oi 100
1ff
0
2000 3000 4000
CARBON MONOXIDE PARTIAL PRESSURE, L B S /S Q . IN.
178
CODE FOR CARBON MONOXIDE GRAPH
Materials in shaded zones have reported corrosion rate <20 mpy
ZONE 1 ZONE 4
5Cr 0 . 5 M o steel 12Cr, Types 4 0 5 , 4 1 0
12Cr, Types 4 0 5 , 4 10 17Cr, Type 430
17Cr, Type 430

18Cr 8Ni, Types 321, 3471
18 Cr 8Ni , Types 321, 347

25Cr, 20Ni, Type 310
25 Cr 20Ni, Type 310

27Cr, Type 446
5Mn Bronze 5Mn Bronze
Carbon Steel
ZONE 2
ZONE 5
12Cr Steel, Type 405, 4 1 0
5Cr 0.5Mo
17Cr Steel, Type 430
27Cr Steel, Type 446 12Cr, Types 4 0 5 , 4 1 0
17Cr, Type 430

18Cr 8Ni, Types 321, 347
25Cr 20Ni Steel, Type 310

18Cr 8Ni, Types 321, 347
5% Manganese Bronze 25Cr 20Ni, Type 310
27Cr, Type 446
ZONE 3 5Mn Bronze
18 Cr 8Ni, Types 321, 347

Carbon Steel
25Cr 20Ni, Type 310
27Cr, Type 446
5Mn Bronze
I. Low pressure end only.
2. (Ref: Technical Oil Mission-Reel 87, Bag 3979, Item 1 1 5 , Pages 1846, 1860)
179
C
240r----------r--------.--------,-------� 116
h
t
%
•
j
I!
J
l
200
93
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2
,_
160
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c
u
•
z
Ah
,_
120
49
ij 3
!
¥
8$j ar
4//44
80 27
- 18
10 20 30 40
CONCENTRATION HCI%
180
CODE FOR HYDROCHLORIC ACID GRAPH
Materials in shaded zones have reported corrosion rates of <20 mpy.
ZONE 1 ZONE 3
20Cr 30Ni' 62Ni 28Mo°
2
66Ni 32Cu Molybdenum
62Ni 28Mo Platinum
2
Copper Silver
Nickel? Tantalum
Platinum Zirconium
Silicon bronze
Silicon cast iron'
Silver ZONE4
Tantalum 66Ni 32Cu?·°
Titanium 62Ni 28Mo°
Tungsten Platinum
Zirconium Silver
Tantalum
Tungsten
ZONE 2
Zirconium
62Ni 32Cu
Molybdenum
Platinum
ZONE 5
Silicon bronze
62Ni 28Mo°
Silicon cast iron'

Platinum
Silver
Silver
Tantalum
Tantalum
1. <2% at 25 C
Zirconium
Zirconium 2. No air
3. No FeC
4. < 1 0 % a t 2 5 C
5. No chlorine
404
C
l '
!
( [Ph}h}pl 4 E
I
B O I LI N G POINT
! '
225
%sty
$ , , 8 ;
7
g
<
>
»
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...
•
Lu
0¢
2
,_
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u
a.
4
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A
,_ 150
- 66
I·
'
125
I
I
100
-38
75
10 20 30 40 50 60 70 80
CONCENTRATION HF,%
182
CODE FOR HYDROFLUORIC ACID GRAPH
Materials in shaded zone have reported corrosion rate of <20 mpy
ZONE 1 ZONE 5
20Cr 30 Ni 70Cu 30Ni'

ZONE3
1
25Cr 20Ni Steel 66Ni 32Cu
20Cr 30Ni
70Cu 30Ni 54Ni 15Cr 16Mo

70Cu 30 N i '
66Ni 32Cu' Gold

54Ni 15Cr 16Mo
54Ni 15Cr 16Mo Lead'

66Ni 32Cu'
Copper' Platinum
Copper'
Gold Silver
Gold
1
Lead
Lead'
Nickel'
Platinum ZONE 6
Nickel cast iron

Silver 66Ni 32Cu'
Platinum
54Ni 15Cr 1 6 M o
Silver
Gold
ZONE4
Platinum
ZONE 2 70Cu 30Ni'
Silver
1
20Cr 30Ni 66Ni 32Cu
70Cu 30Ni' 54Ni 15Cr 16Mo
1
54Ni 15Cr 16Mo Copper ZONE 7
66Ni 32Cu Gold 66Ni 32Cu
Copper' Lead' 54Ni 15Cr 16Mo
Gold Platinum Carbon steel
Lead' Silver Gold
Nickel' Platinum
Platinum Silver
Silver I. No air
183
}st[
0 O h}
300
f f] lll
fl
AVOID HASTELLOY B AND D IN+
THIS R A N G E AT B O I LI N G POINT
B O I LI N G POINT
100
100
20 40 60
PERCENT CONCENTRATION IN WATER
184
CODE FOR SULFURIC ACID GRAPH
Materials in shaded zones have reported corrosion rate <20 mpy

ZONE 1
ZONE 6
20Cr 30Ni
62Ni 2 8 M o . °
1
66Ni 32Cu
Gold
62Ni 28Mo
Platinum
Type 3 1 6 °
Silicon iron
Al bronze 10%1
ZONE 3
ZONE 4
Tantalum
Copper
20Cr 30Ni°
20Cr 30Ni
ZONE7
Gold 1
66Ni 32Cu
62Ni 28Mo
Gold
Lead
62Ni 28Mo
Type 3 1 6 °
Platinum
Molybdenum
Gold
Gold
Silicon iron
Nickel cast iron
Lead
Lead°
Tantalum
Platinum
Molybdenum
Nickel cast iron
Silver
Platinum
Platinum ZONE 8
Tantalum
Silicon iron
Silicon iron 20Cr 30Ni
Zirconium
Tantalum 18Cr 8Ni
Steel
Zirconium 54Ni 15Cr 16Mo

Tantalum
ZONE 2
Gold
Zirconium°
20Cr 30Ni°
Platinum
66Ni 32Cu ZONE 5

Steel
Silicon cast iron
62Ni 28Mo
20Cr 30Ni
Silver
Type 3 1 6 ° ZONE 9
62Ni 28Mo
Tantalum
AI bronze 10%' 20Cr 30Ni
Gold
Zirconium
Copper' 18Cr 8Ni
Lead
Gold Gold
Platinum
1. No air
2. < 1 0 % aerated
Lead Platinum
3.<75 ¢
Silicon iron
4. <20% at 2 5 C
Molybdenum 5. <25% aerated at 25 C Tantalum

6. <96% concentration ZONE 10
Nickel cast iron° 7. > 80% concentration
8. <80% aerated
Gold
9. <75C, <96%
Platinum
10. 20 to 50 mpy 185
Platinum
SUBJECT INDEX
A hydroxide, 6-14
hydride (see pentane)
nitrate, 6-15
laureate, 14-1
Acetaldehyde, 2-1 oxalate, 138-3
mercaptan, 14-2
Acetamide, 22 potassium sulfate, 6-16
nitrate, 14-3
Acetanalide, 2-3 stearate, 138-4
phenols, 14.4
Acetic acid sulfate, 8-1
prorionate, 14-5
aerated, 2-4 Amino valerate, 14-6
non-aerated, 2-5 anthraquinone, 8-2 Aniline, 14-7
vapor, 2-6 benzene, 8-3 Aniline hydrochloride, 14-8
Acetic anhydride, 2-7 benzene sulfonic acid, 8-4 Anisole, 14-9
Acetic ester (see ethyl acetate) benzoic acid, 8-5 Anthracene, 14.10
Acetoacetic acid, 28 ethane (see ethyl amine) Anthracene chloride, 14-11
Acetone, 2-9 ethanol (see triethylamine) Anihranlic acid, 139-2
Acetone cyanohydrin, 2-10 " + carbon dioxide, 8-7 Anthraquinone, 14-12
Acetonitrile, 2-11 " + hydrogen sulfide, 8-8 Antraquinone disulfonic acids, 14-13
Acetoparatoluidine, 2-12 " +CO, + H,S,89 Antichlor (see sodium thiosulfate)
Acetophenetidine, 2-13 gaiicyciic acid, 8-12 Antimony
Acetophenone, 2-14 phenols, 8-10 pentachloride, 14-14
Acetotoluidine, 2-15 pyridine, 8-11 pentafluoride, 14.15
Acetyl acetone, 2-16 toluene (see benzyl amine) sulfate, 14-16
Acetyl chloride, 4-1 Ammonia (anhydrous), 8-13 trichloride, 16.-1

1
Acetylene, 4-2
Ammonium trifluoride, 16-2
t
Acetylene dichloride
acetate, 8-14 Aqua regia, 16-3
(see dichloroethylene)
arsenate, 138-5 Arachadic acid, 16.-4
. I
"
Acetylene tetrachloride, 4-3 azide, 138-6 Aragonite (see calcium carbonate)

I
Acetylenogen (see calcium carbide) benzoate, 13-7

Arsenic
i
Acetyl formic acid (see pyruvic acid) bicarbonate, 8-15

acid, 16-5
Acetyl oxide (see acetic anhydride) bifluoride, 8-16 disulfide, 139-4 4
Acetylpropionic acid (see levulinic acid) biphosphate, 10-1 pentoxide & 62% sulfuric, 139-3
Acety! salicyclic acid, 4-4 bisulfite, 10-2 trichloride, 16-6
2-Acetyl thiophene, 4-5 borate, 138-8 triosulfide, 139.5
Aconitil acid, 4-6 bromide, 10-3 trioxide, 16-7
Acridine, 4-7 carbamate, 10.4 Ascorbic acid, 16-8
Acrolein, 4-8 carbonate, 10-5 Aspartic acid, 16-9
Acrylaldehyde (see acrolein) chloride, 10-6 Aziridine (see ethylene imine)
Acrylic acid, 4-9 citrate, 10-7 Azobenzene, 16-10
Acrylonitrile, 4-10 dichromate, 10-8
Adipic acid, 4-11 fluoride, 10-9
Aldehyde (see acetaldehyde) fluorosilicate, 10-10

B
Aliphatic alcohol sulfonates, 4-12 formate, 10-11
Aikane (see dodecyl benzene) hydroxide, 10-12 Barium

Alkane sulfonic acid, 4-13 iodide, 138-8 chlorate, 18-1
Alkylaryl sulfonates, 4-14 lactate, 138-9 chloride, 18-2
Alkyl boranes, 4-15 molybdate, 10-13 cyanide, 18-3
Alkyl phenol, 4-16 nitrate, 10-14 hydroxide, 18-4
Alky/naphthalene sulfonic acid, 6-1
oxalate, 10-15 nitrate, 18-5
Ally! alcohol, 6-2
perchlorate, 10-16
peroxide, 18-6
Ally! aldehyde (see acrolein) persulfate, 12-1
polysulfides, 18-7
Allyl amine, 6-3 phosphate, 12-2
sulfate, 18-8
Ally! bromide, 138-1 picrate, 12-3
sulfide, 18-9
Ally! chloride, 6-4 polysulfide, 12-4
Beer, 139-6
Allylidene diacetate, 6-5 salicylate, 12-5
Benzaldehyde, 18-10
Ally! sulfide, 6-6 sulfamate, 12-6
Benzamide, 18-11
Alpha hydroxy toluene (see benzy sulfate, 12-7
Benzathrone (see benzyl benzoate)
alcohol) sulfide, 12-8
Benzene, 18-12
Alphapentyl cinnamaldehyde (see amyl sulfite, 12-9 Benzene hexachloride, 18-13
cinnamic aldehyde) thiocyanate, 12-10 Benzene sulfonic acid, 18-14
Aluminum thioglycolate, 139.1
Benzidene, 18-15
acetate, 6-7 thiosulfate, 12-11 Benzilic acid, 18-16
chlorate, 6-8 tungstate, 12-12
Benzoic acid, 20-1
chloride, 6-9 Amyl Benzoic anhydride, 20-2
diformate, 6-10 acetate, 12-13 Benzoin, 20-3
ethylate, 6-11 alcohol, 12-14
Benzonitrile, 20-4
fluoride, 6-12 chloride, 12-15
Benzophenone, 20-5
fluorosilicate, 6-13, 138-2 cinnamic-aldehyde, 12-16
Benzotrichloride, 20-6
187
Benzotrifluorlde, 20-7
bromide, 28-8 Chloracetone, 36-2
Benzoyl benzoic acid, 20-8 carbide, 28-9 Chloracetyl chloride, 36-3
Benzoy! chloride, 20-9

carbonate, 28-10 Chloroalkyl ethers, 36-4
Benzoyl peroxide, 20-10 chlorate, 28-11 Chloroamino benzoic acid, 36-5

Benzyl chloride, 28-12 Chlciroanllines, 36-6
acetate, 20-11 chromate, 28-13 Chlorobenzaldehyde, 36-7
alcohol, 20-12 cyanamide, 140-3 Chlorobenzene, 36-8

amine, 20-13 cyanide, 140-4 Chlorobenzene 60%, chloral 40%, 141-3
benzoate, 20-14
fluoride, 28-14 Chlorobenzotrifluorides, 36-9
bromide, 20-15
gluconate, 28-15 Chlorobenzoyl chloride, 141.4
chloride, 20-16
hydride, 28-16 Chlorodifluoroethane, 36-10
dichloride, 22-1
hydrosulfide, 140-5
Chlorodifluoromethane, 36-11
phenol, 22-2
hydroxide, 30-1 ChloroethyI benzene, 36-12
salicylate, 22-3
hypochlorite, 30-2 Chloroform, 36- 1 3
Berrylium chloride, 22-4

lactate, 30-3 Chlorohydrin, 36-14
Berrylium fluoride, 22-5

naphthenate, 30-4 Chloronaphthalene, 36-15
Berrylium oxide, 139.-7

nitrate, 30-5 Chloronitrobenzene, 36-16
Berryllum sulfate, 22-6

oxalate, 30-6 Chlorophenohydroxy acetic acid, 38-1
Betamethylacrolein (see crotonaldehyde)

oxide, 30.-7 Chlorophenols, 38-2
Betamethacrylic acid (see crotonic acid)

permanganate, 30.-8 Chloropicrin, 38-3, 141-5
Bismuth subcarbonate, 139-8 Chloroprene, 38-4

peroxide, 140-6
Bismuth nitrate, 139-9

phenosulfate, 140.7 Chloroquine, 38-5
Boric acid, 22-7

phosphate, 30-9 Chlorosilanes, 38-6
Bornyl acetate, 22-8

propionate, 140.-8 Chlorosulfonic acid, 38.7
Bory! chloride, 22.-9

pyridine sulfonate, 140.9 Chlorotoluene sulfonic acid, 38-8
Bornyl formate, 22-10

stearat e, 30-10 Chlorotoluidines, 38.9
Borom trichloride, 22-11

sulfate, 30-11 Chlorotrifluoroethylene (CTFE), 38-10
Bromic acid, 22-12

sulfide, 30-12 Chlorotrifluoromethane, 38-11
Bromine--dry, 22-13 sulfite, 30-13 Chloroxylenol, 38-12
Bromine--wet, 22-14 thiocyanate, 30-14 Cholesterol, 38-13
Bromine trifluoride, 22-15

Camphene, 30-15 Chromic
Bromobenzene, 22-16
Camphor, 30-16 acid, 38-14
Bromobenzyl cyanide, 139-10
Camphoric acid, 32-1 chloride, 38-15
Bromochloromethane, 24-1 fluoride, 38-16
Capric acid, 32-2
Bromochloropropane, 24-2 hydroxide, 40-1
Caproaldehyde, 32-3
Bromoform, 24-3
Capsicin, 32-4 nitrate, 40-2
Bromoisovaleryl urea, 140.1 phosphate, 40-3

Carbazole, 32-5
Bromotoluene, 24-4 sulfate, 40-4
Carbitol (see diethylene g lycol)
Butadiene, 24.-5
Carbon disulfide, 32-6 Chromiurn potassium sulfate, 40-5
Butane, 24-6
Carbon fluorides, 32-7 Chromyl chloride, 40-6
Butanediols, 24-7
Carbonic acid - carbon dioxide, 32-8 Cinnamic acid, 141-6
Butanol, 24.-8
Carbon Cinnamic alcohol, 40-7
Butyl monoxide, 32-9 Cinnamic aldehyde, 40-8

acetate, 24.-9
tetrabromide, 32-10 Citric acid, 40-9
amine, 24-10
tetrachloride, 32-11 Coal gas, 40-10
benzoate, 24-11
Carnallite, 32-12 Cobalt acetate, 40-11
benzoic acid, 140-2 Carotene, 32-13 Cobaltous linoleate, 40-12
butyrate, 24-12 Casein, 32-14 Cobaltous sulfate, 141-7
chloride, 24-13 Cellulose Codeine sulfate, 40-13
lactate, 24-14 acetate, 32-15 Cod liver oil, 40-14
mercaptan, 24-15 acetate butyrate, 32-16 Coniferin, 40-15
methacrylate, 24-16 methyl ether, 34-1 Copal, 40-16
phenols, 26-1 nitrate, 34-2 Copper acetate, 42-1
stearate, 26-2
Cerous chloride, 140-10 Copper ammonium acetate, 42-2
Butyraldehyde, 26-3
Cerous fluoride, 141-1 Copper carbonate, 42-3
Butyrlc acid, 26-4
Cerous sulfate, 141-2 Copper gluconate, 141-8
Butyrlc anhydride, 26-5
Cesium chloride, 34-3 Copper naphthenate, 141-9
Butyrolactone, 26.-6
Cesium hydroxide, 34-4 Copper nitrate, 42-4
Butyryl chloride, 26-7

Cetyl alcohol, 34-5 Copper sulfate, 42-5
Chaulmoogric acid, 34-6 Copper Sulfate & 5% H,$0,, 42-6
Chloral, 34-7 Creosote, 42-7
C Chloramines, 34-8 Cre~sol, 42-8
Chloramphenicol, 34-9 Crotonaldehyde, 42-9
Cadmium chloride, 28-1 Chloranil, 34-10 Crotonic acid, 42-10
Cadmium sulfate, 28-2 Chlordane, 34.11 Cumaldehyde, 42-11
Cadmium sulfide, 28-3 Chloric acid, 34-12 Cumene, 42-12
Calcium Chlorine, 34-13 Cumene hydroperoxide, 42-13
acetate, 28-4 Chlorine dioxide, 34-14 Cupric chloride, 42-14
arsenate, 28-5 Chlorine trifluoride, 34-15 Cupric cyanide, 42-15
benzoate, 28-6 Chloracetaidehyde, 34-16 Cuprous chloride, 42-16
bisulfite, 28-7 Chloracetic acid (mono), 36-1 Cyanamide, 44-1
188
Cyanoacetic acid, 44-2 Dioctyl phthalate, 50-12 chloride, 60-7
Cyanogen, 44-3 Dioxane, 50-13 iodide, 143-1
Cyanogen chloride, 44-4 Dioxidine, 50-14 sulfate, 60-8
Cyanohydrin, 141-10 Dipentene, 50-15 Fluoboric acid, 60-9
Cyanuric chloride, 44-5 Dipenyl, 50-16 Fluorine gas, 60-10
Cyclohexane, 44-6 Diphenylamine, 52-1 Fluorine liquid, 60-11
Cyclohexanol, 44-7 Diphenyleng oxice (dibenzofuran), 52-2 Fluosilicic acid, 60-12

Cyclohexanone, 44-8 Dipenyl oxide, 52-3 Formaldehyde, 60-13
Cyclohexene, 44-9 Diphenyl propane, 52-4 Formanide, 60-14
Cyclohexylamine, 44-10 Dodecyl benzene, 52-5 Formic acid, 60-15
Cyclopentane, 44-11
Furfural, 60-16
Cyclopentadiene, 44-12
Furfural alcohol, 62-1
Cyclopolyolefins, 44-13
E
Epichlorohydrin, 54-1
D
Ethane, 54-2
G
Ethanol, 54.3
Dextrose, 46-1
Ethyl
Gallic acid, 64-1
Diacetone alcohol, 46-2
acetate, 54-4
Diallyl phthalate, 46-3 Gelatin, 64-2
acetoacetate (see acetoacetic ester)
Diamyl ether, 46-4 Gluconic acid, 64-3
acgtoacetate, 54-5
Dibenzo furan (see diphenylene oxice) Glutanic acid, 64-4
acrylate, 54-6
Dibenzyl, 46-5 Glycerol, 64.-5
alcohol (see ethanol)
Dibenzyl ether, 46-6 Glycerol + NaCl, 64-6
amine, 54-7
Dibutyl Glycerolmonochlorohydrin, 143-2
benzene, 54.8
Glycerophosphoric acid, 64-7
amines, 46-7
benzoate, 54-9
Glycidol, 64-8
ether, 46-8
bromide, 54-10
Glyoxylic acid, 64.9
phthalate, 46-9
butyrate, 54-11
Gold cyanide plating solution, 143-3
sebacate, 142-1
chloride anhydrous, 54-.12
Guanidine nitrate, 64-10
sulfate, 142-2
chloride moist, 54-13
thiourea, 46-10
formate, 56-13
Dichloroacetic acid, 142-3
malonate, 56-15
Dichlorobenzene, 46.11
mercaptan, 56-16
Dichlorobutate, 46-12 H
nitrite, 58-1
Dichlorobutene, 46-13
pelargonite, 58-2
Dichlorodifluoromethane, 46-14 Heptachlor, 66-1
propionate, 58-3
DDT, 46-15 Heptaldehyde, 66-2
silicate, 58.4
Dichloroethylene, 46-16 Heptane, 66-3
stearate, 58-5
Hexachlorobutadiene, 66-4
Dichloroethylether, 48-1
valerate, 58-6
Hexachloroethane, 66-5
Dichlorohydrin, 48-2
Ethylene, 54-14
Hexachloropentadiene, 66-6
Dichlorophenol, 48.-3
Ethylene
Hexaethyltetraphosphate, 66-7
Dichloropropene, 48-4
chlorohydrin, 54-15
Hexafluoroxylene, 66-8
Dichlorotetrafluoroethane, 48-5
cycnohydrin, 54-16
Hexamethylene diammonium adipate,
Dieldrin, 48-6
diamene, 56-1
66-9
Diethanolamine, 48-7
diamene hydrochlorine, 56-2 J
Hexamethylene tetramine, 66-10

Diethanolamine + HS, 48-8 !
dibromide, 56-3
Hexane, 66-11
Diethanolamine + HS + CO,, 48-9
dichloride, 56-4
Hexanetriol, 66-12
Diethylamine, 48-10
dichloride & steam, 56.-5
Hexanol, 66-13
Diethyl aniline dimethyl aniline, 48-11
glycol, 56-6
Hexylene glycol, 66-14
Diethylcarbonate, 142-4
glycol dibutyl ether, 56-7
Hydrazine, 66.15
Diethylene glycol, 48-12
glycol monobutyl ether, 56-8
Hydroabietyl alcohol, 66-16
Diethylene triamine, 48-13
glycol monomethylacetate ether, 56-9
Hydrobromic acid, 68-1
Diethylether, 48-14
glycol monoethylether, 56-10 Hydrocarbon fluorides, 68-2
Diethylphthalate, 48-15
imine, 56-11
Hydrochloric acid (aerated), 68-3
Difluoroethane, 48-16
oxide, 56-12 Hydrochloric acid (not aerated), 68-4
I
Diglycolic acid, 50-1

Ethylidene chloride, 56-14
Hydrocyanic acid, 68-5
Diglycolic acid dibutylester, 50-2
Hydrofluoric acid (aerated), 68-6
Dihydroxy dipenyl sulfone, 50-3
I
Hydrofluoric acid (not aerated), 68-7
Diisobutyl aluminum chloride, 142-5
F Hydrogen, 68-8
Diisobutyl carbinol, 50-4
Hydrogen
Diisobutyl kentone, 50-5
Fats, natural, 60-1 chloride (anhydrous), 68-9
Dimethyl amine, 50-6
Ferric fluoride (anhydrous), 68-10
Dimethyl chloraceto acetamide, 142-6
chloride, 60-2 peroxide, 68-11
Dimethyl ether, 50-7
ferrocyanide, 1429 sulfide (anhydrous), 68-12
Dimethyl formandide, 50.8
hydroxide, 60-3 sulfide, 68-13
Dimethyl hexane, 50-9
nitrate, 60-4 Hydroiotic acid, 68-14
Dimethyl (uns) hydrazine + hydrazine
sulfate, 60-5 Hydroquinone, 68-15
50%-50%, 142-7
Ferrous Hydroxyacetic acid, 68-16
Dimethyl hydrazine unsymmetrical, 50-10
ammonium citrate, 142-10 Hydroxycitronella, 70-1
Dimethyl sulfate, 142-8
ammonium sulfate, 60-6 Hypochlorous acid, 70-2
Dinitrochtorobenzene, 50-11
189
M Naphthylamine + sulfonic acid, 86-8
Nickel
Indole, 72-1
Magnesium
acetate, 146-7
Iodine, 72-2
gluconate, 144-8
ammonium sulfate, 86-9
Idoform, 72-3
glycerophosphate, 144-9 chloride, 86-10
Iron potassium sulfate, 72-4

hypophosphite, 144-10 nitrate, 86-11 j
Iron sulfamate, 143-4
perchlorate, 145-1 sulfate, 86-12
lsoamyl, 72-5
Manganese Nicote ne, 146-8
lsoamyl butyrate, 72-6
carbonate, 145-2 Nitric acid, 86-13
lsoborneal acetate, 72-7 chloride, 80-1
25-35% + 515 ppm chlorides, 146-9
lsoborneal ester, 72-8 dioxide, 80-2 red fuming, 86-14
lsobutyl linoleate, 145-3

white fuming, 86-15
acetate, 72-9
naphthenate, 145-4
Nitric + hydrofluoric acid, 86-16
chloride, 72-10
sulfate, 80-3 Nitroanilines, 88-1
glycol, 72-11
Mannitol, 80-4
Nitroben zene, 88-2
oxide, 72-12
Mercaptains, 80-5
Nitrodiphenyl ether, 88-3
isolvalerate, 72-13
Mercuric
Nitroethane, 88-4
phosphate, 72-14
acetate, 145-5
Nitrofluorobenzene, 88-5
lsobutylene chlorohydrin, 143-5
chloride, 80.6
Nitrogen tetroxide + <0.1% water, 88-6
lsobutyric acid, 143-6
cyanide, 80.7
Nitrogen tetroxide + > 10% water, 88-7
IsochotyI chloride, 72-15
iodine, 80-8
Nitroglycerine, 88-8
Isododecane, 72-16
nitrate, 80-9
Nitroisopropyl benzenes, 88-9
lsophorone, 76-1
sulfate, 145-5
Nitromethane, 88-10
lsopropanol, 76-2
sulfate, 145-6
Nitrophenols, 88-11
lsopropanyl acetate, 76-3
Mercury, 80-10
Nitro propane, 88-12
Isopropyl acetate, 76-4
Mersol sulfon ic acid, 80-11
N itrosy l chloride, 88-13
lsopropyl 2 chloroethyl sulfite, 76.5
Mesityl oxide, 80-12 N itrosu l furic acid, 88-14
lsopropyl chloride, 76-6
Metaldehyde, 80-13 N itroto l uen e s, 88-15
lsopropyl amine, 76.7
Methacrylic acid, 145-7 Nitrous acid, 88-16
lsopropyl nitrate, 143-7
Methallyl amine, 80-14 Nitrous oxide, 90-1
Isovaleric acid, 76.8
Methallyl chloride, 80-15 Nitroxylene, 146-10
Methane, 80-16
Methyl
L abietate, 145-8
0
acrylate, 145-9
Lactic acid, 74-1 amyl acetate, 145-10

Octyl acetate, 92-1
Laurie acid, 74-2 ethyl ketone, 82-1
Octyl alcohols, 92-2
Lauryl alcohol, 74-3 ethyl oleate, 82-2
Octyl chloride, 92-3
Lead formate, 82-3
Oleic acid, 92-4

acetate, 74.4 iodide, 82-4
O rthoto l uidine, 92-5
arsenate, 74.5 isobutyl carbinol, 82-5
Oxalic acid, 92-6

bromide, 74-6 isobutyl kentone, 82-6
carbonate, 74.7 isovalerate, 82-7
chloride, 74-8 lactate, 146-1 p

chromate, 74.9 methacrylate, 146-2
dioxide, 74-10 pentadiene, 82-8

Palamitic acid, 94-1
fluosilicate + 8.5% H,-Si-Fe + 6.9% propionate, 146-3
Paraformaldehyde, 94-2
Pb-Si-F, 143-8 salicylate, 146.4
Paraldehyde, 94-3
linoleate, 74-11 sulfuric acid, 82-9
Parathion, 94-4
naphthenate, 143-9 valerate, 82-10

Penicillin nutrient, 147-1
nitrate, 74-12 MIlk, 82-11

Pentachloroethane, 94-5
oxide, 74-13 Mixed acids, H,SO, & HNO, 82-12

Pentachloroethylene, 94-6
pathalate, 143-10 Molasses, 82-13

Pentachlorophenol, 94.7
salicylate, 144-1 M onoa ll y l phthalate, 8 2-14

Pentaerythritol, 94.8
stearate, 144-2 Monochlorobutene, 82-15

Pentane, 94.9
sulfate, 74-14 Monoethanolamine, 82-16

Peracetic acid, 147-2
Monomethyl hydrazine, 146-5

sulfide, 74-15
Perchloric acid, 94-10
Mononitrotolvene, 84-1
tetra-acetate, 144-3
Perchloroethylene, 94.11
trinitroresorcinate, 74-16 Morpholine, 84-2

Perchloryl fluoride, 94-12
Levulinic acid, 78-2
Permanganic acid, 147-3
Linalyl acetate, 144-4

Persulfuric acid, 94-13
Linseed oil, 78-3 N Phenethyl alcohol, 94-14

Lithiu m
Phenol, 94-15
benzoate, 144-5 Naptha, 86-1
Phenol + 3-5% sulfuric acid, 147.4
bromide, 144-6 N a p h t h a l e n e, 86-2

Phenol-2-4 disulfonic acid, 94-16
carbonate, 78.-4 N aphthalene chloride, 86.3
Phenol sulfonic acid, 96-1
chloride, 78-5 Naphthalene sulfonic acid, 86-4

Phenyl
hydroxide, 78-6 N a p hthalene acid, 86-5
acetic acid, 96-2
hypochlorite, 78-7 Naphthals, 86.6

glycine, 147.-5
salicylate, 144-7 Naphthenic acids, 145-5
hydra zine, 96-3
sulfate, 78-8 Naphthenic acids, 145.6
hydrazine hydrochloride, 96.4
Naphthoquinoline. 86-7
Lithapone, 78-9
mercuric acetate, 96.5
190
Phosgene, 96-6 1,3 Propanediol, 104-6 bromide, 114-9
Phosphating solutions, 96-7 Propionaldehyde, 104-7 bromile, 114-10
Phosphoric acid, 96-8 Propionic acid, 104-8 carbonate, 114-11
Phosphoric acid (aerated), 96-9 N-Propyl acetate, 104-9 chlorate, 1 1 4- 1 2
Phosphoric acid vapors, 96-10 N-Propyl alcohol, 104-10 chloride, 114-13
Phosphoric anhydride, 96-11 Propylene, 104-11 chlorite, 1 1 4- 1 4
Phosphorous, 96-12 Propylene dichloride, 104-12 chromate, 114-15
Phosphorous oxychloride, 96-13 Propylene oxide, 104-13 citrate, 114-16
Phosphorous pentachloride, 96-14 N.-Propyl nitrate, 104-14 cyanate, 116.1
Phosphorous tribromide, 147-5 Pyridine, 104-15 cyanide, 116-2
Phosphorous tribromlde, 147-6 Pyridine + carboxylic acid + cyanimide, 148-8
Phosphorous trichloride, 96-15 dimethylamide, 104-16 diphenyl sulfate, 116-3
Phthatic acid, 96-16 Pyridine sulfonic acid, 106-1 disilicate, 116-4
Phthalic anhydride, 98-1 Pyrogallic acid, 106-2 dithionite, 116-5
Phthalic anhydride + maleic Pyroligneous acid, 106-3 dodecyl benzene sulfonate, 1 1 6-6
anhydride, 98-2 Pyruvic acid, 106-4 ethylate, 116-7
Picric acid, 98-3 ethylenediamine tetracetate, 116-8
Piperonal, 98-4 ferricyanide, 116-9
Polybutadiene, 98-5 Q fluoride, 116-10
Polychlorinated polyphenols, 98-6 fluoracetate, 116-11
Polyethylene, 98-7 fluorophosphate, 116-12

1
Quinaldic acid, 108-1
Polyethylene terephthalate, 98.-8 Quinine, 108-2 fluorosilicate, 116-13
Polyglycerol, 98-9 Quinine bisulfate, 108-3 flrmaldehyde sulfoxylate, 116-14
Polyisobutylenes, 98-10 Quinine hydrochloride, 108-4 formate, 116-15
Polyisoprene, 98.11 Quinine sulfate, 108-5 gluconate, 148-9
Polymethyl methacrylate, 98-12 Quinine tartrate, 108-6 glutamate, 116-16
Polypropylene, 98-13 Quinizarin, 108.-7 hydrosulfide, 118-1
Polystyrene, 98-14 Quinoline, 108-8 hydroxide, 118-2
Potassium Quinone, 108-9 hypochlorite, 118-3
acetate, 98-15 hypophosphate, 148-10
bicarbonate, 98-16 hypophosphite, 149-1
bifluoride, 100-1 R iodide, 118-4
bisulfate, 100-2 metaphosphate, 118-5
bisulfite, 100-3 Resorcinol, 148-1 metasilicate, 118-6
bitartrate, 100-4 Ricinoleic acid, 148-2 methylate, 118-7
bormide, 100-5 ongalite, 110-1 nitrate, 118-8
carbonate, 100-6 Rosin, 110-2 nitrite, 118-9
chlorate, 100-7 oleate, 149-2
chloride, 100-8 oxalate, 149-3
chromate, 100-9 pentachlorophenate, 118-10

s !
citrate, 147-7 perborate, 118-11
cyanate, 100-10 percarbonate, 118-12

Saccarin solutions, 112-1
cyanide, 100-11 perchlorate, 118-13
Salicyclic acid, 112-2
dichromate, 100-12 peroxide, 118-14 i
Selenic acid, 148-3
ferricyanide, 100-13 persulfate, 118-15 Ir
Selenous acid, 148-4 . , ,
ferrocyanide, 100-14 phenolate, 118-16

Silicon tetrachloride, 112-3 I
i
fluoride, 100-15 phosphate, 120-1

Silicotungstic acid, 148-5
formate, 100-16 phosphate (tribasic), 120-2
Silver
gluconate, 147-8 plumbite, 120-3
bromide, 112-4
hydroxide, 102-1 propionate, 149-4
chloride, 112-5
hypochlorite, 102-2 polysulfides, 120-4
cyanide, 1126
iodate, 102-3 pyrosulfite, 149-5
nitrate, 112.7
iodide, 102-4 resinate, 149-6
sulfate, 148-6
metabisulfite, 147-9 salicylate, 120-5
Soap, 112-8
metasilicate, 102-5 sesquisilicates, 120-6
Sodium
nitrate, 102-6 silicates, 120-7
acetate, 112-9
nitrite, 102-7 stannate, 120-8, 149-7
alkylaaryl sulonates, 112-10
oxalate, 102-8 sulfate, 120-9
aluminate, 112-11
perchlorate, 102-9 sulfide, 120-10
aluminum fluoride, 112-12
permanganate, 102-10 sulfite, 120-11
aluminum sulfate, 112-13
peroxide, 102-11 tartrate, 120-12
arsenate, 112-14
persulfate, 102-12 tetrasulfide, 149-8
arsenite, 112-15 I
phosphate, 102-13 trichloroacetate, 149-9

benzoate, 112-16
phosphate + hydrogen sulfide, 102-14 thiocyanate, 120-13
bicarbonate, 114-1
silicate, 102-15 thioglycolate, 120-14
bichromate, 114-2
i
stannate, 147-10 thiosulfate, 120-15

bifluoride, 114-3
sulfate, 102-16 valerate, 120-16
bisulfate, 114-4
sulfide, 104-1 Sorbitol, 122-1
bisulfide, 114-5
sulfite, 104-2 Sorbase, 122-2
bisulfite, 114-6
thiocyanate, 104-3 Stand oil, 122-3
bitartrate, 114-7
Propane, 104-4 Stannic ammonium chloride, 122-4
borohydride, 148-7
1,2 Propanediol, 104-5 Stannic chloride, 122-5
bromate, 114-8
191
Stannous fluoride, 149-10 Thioamyl alcohol, 126-10 u
Stannovs bisultate, 122-6 Thioglycolic acid, 150-8
Stannovs chloride, 122-7 Thionyl chloride, 126-11 Undecylenic, 151-7
Steam, 122-8 Thiophosphory! chloride, 150-9 Uranium chlorides, 151.8

Steam, geothermal (aerated), 122-9 Thiorea, 150-10 Uranium hexafluoride, 132-1
Steam, geothermal (airfree), 122-10 Thiorium nitrate, 151-1 Uranyl carbonate, 132-2
Stearic acid, 122-11 Tin, 126-12 Uranyl fluoride, 132-3
Streptomycin, 150-1 Tin ammonium chloride, 126-13 Uranyl nitrate, 132-4
Strontium carbonate, 150-2 Titanium sulfate, 126-14 Uranyl sulfate, 132-5
Strontium chloride, 122-12, 150-3 Titanium tetrachloride, 126-15 Urea, 132-6
Strontium nitrate, 122-13 Tolvene, 126-16 Uric acid, 132-7
Styrene, 122-14 Tolvene sulfanyl chloride, 128-1
Succinic acid, 122-15 Toluquinone, 128-2
Sugar, 122-16 Tolylaldehyde, 128-3

V
Sulfate black liquor, 124-1 Toxaphene, 128-4
Sulfate green liquor, 124-2 Toxaphene & sulfur, 128-5

Valeric acid, 151-9
Sulfate liquor with 10% sulfur dioxide, Triacetin, 151-2
Vegetable oils, 134-1
124-3 Triallylamine, 151-3
Vinyl acetate, 134.-2
Sulfamic acid, 150-4 Trbromoethy/benzene, 128-6
Vinyl benzene, 134-3
Sulfalinic acid, 150-5 Tributyl amine, 128-7
Vinyl chloride, 134-4
Sulfonated oil, 124.4 Tributyl phosphate, 128-8
Sulfonic acid, 150-6 Trichloro acetic acid, 128-9
Sulfur, 124-5 Trichlorobenzene, 128-10
aerated, 124-6 Trichloroethane, 128-11 X

chloride, 124-7 Trichloroethanolamine, 151.4
containing oils, 124-8 Trichloroethylene, 128-12 Xylene, 134-5
dioxide, 124-9 Trichloroethylene condensate, 128-13 Xylidine, 134-6
dioxide 2-5%, plus H,0, 124-10 Trichloromonofluoroethane, 128-14
trioxide, 124-15 Trichloropropane, 128-15

y
Sulfuric acid, aerated, 124-11 Trichlorotrifluoroethane, 128-16
Sulfuric acid, fuming, 124-12 Tricresyl phosphate, 130-1
Sulfuric acid, no air (static), 124-13 Triethanolamine, 130-2

Yeast, 134-7
Sulfurous acid, 124-14 TriethyI phosphate, 1515
Sulfury! chloride, 124-16 Triethylamine, 130.3 3
Triethylene glycol, 130-4 z

Triethylamine tetramine, 130-5
Trifluoro acetic acid, 130-6 Zinc

T
Tri-is0butyl aluminum chloride, 130-7 carbonate, 136-1
Tall oil, 126-1 Tri-isopropanol amine, 130.-8 chloride, 136-2
Tri-methyl benzene, 130-9 cyanide, 151-10

Tannic acid, 126-2
Tri-isopropyl benzyl chloride, 130-10 dihydrogen phosphate, 152-1
Tartaric acid, 126-3
Trimethyl amine, 130-11 fluorosilicate, 136-3
Terpenes, 126-4
Trimethyl pentanes, 130-12 hydrosulfite, 136.4
Terpin ol, 126-5
Trimethy! phosphite, 130-13 naphthenate, 152-2
Te rpinyl acetate, 150-7
Triphenyl phosphite, 130-14 oxide, 152-3
Tetrabethylene pentamine, 126-6 t.
Tungstic acid, 151-6 phenolsulfonate, 152-4

Tetrafluorethylene, 126-7
Tetrahydronaphalene, 126-8 Turpentine, 130-15 sulfate, 136-5
Tetraphophoric acid, 126-9
192

NACE Corrosion Data Survey Metal Section 6th Ed Nace Publisher 1985

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NACE Corrosion Data Survey Metal Section 6th Ed Nace Publisher 1985

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National Association of Corrosion Engineers

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Library of Congress Catalog Card Number: 84-62018

National Association of Corrosion Engineers

from previous editions.

hazards of corrosives can be found at the end of the introduction.

quired for making the proper choice of materials.

unpublished data in a group of tables for ready reference in

tables should serve only as a guide, and it is to be expected

The tables have been checked against actual plant conditions

representatives of metal and other material suppliers often

services of a corrosion engineer, to aid in precise interpreta­

When reac tions at tempera tures abo ve boiling points are

noted it is assum ed that there is a pressure factor even though

th s i is not denoted in the matr ix.

and Fifth Editions, although numerous new data points have

pears at the end of this introduction. Many other individuals

No data are posted on zero concentration lines ; theref ore,

any posting on the shared line between data squares repre­

refer to anhydrides but also may refer to some concentrations

surve y are that it (1) identifies materials which are i

unsuitable, (2) locates those which may have sa tisfactory per­

Throughout this book , materials are arranged l

duction for convenient reference. For comparison of penetra­

penetration rates in a given corrosive may be unsuitable, or

Locating Data 2. Materials of Construction

classification are a number of materials frequently considered (120 C). in a essel

ple: result in catastrophic corrosion,

Temperatures are plotted in degrees Fahrenheit from O t o

tables throughout the book.

b. Silicon bronze, aluminum bronze, and tin bronze are con­

sidered to have similar corrosion resistances in most 5. Corrosion Rates

and maintenance engineers. (See the Key to Data Points on

tables. used for some pieces of equipment, although they may be

ruled out for others because of other failings , such as con­

development of this category, considerable difficulty has been

Concentrations in all cases (except in certain solutions he

fect on oxygen solubility and availability. As temperature Corrosion Rates

point. taminants can either increase or decrease the corrosion rate.

ing pH. sidered.

High Temperature High Pressure Electro-Chemistry in Aque­ mington, Delaware

Introduction to Oilfield Water Technology, A. G. Ostroff, 1979. New York

Process Industries Corrosion, 1975. son, Nevada

1977. G. E. Galonian, General Electric Co., Schenectady, New York

Russ W. Kirchner, Stellite Div,, Cabot Corp., Kokomo, Indiana

Dale W. Koch, Babcock & Wilcox Co., Akron, Ohio

Bert Lofblad, Sandvik Steel, Inc., Fair Lawn, New Jersey

Dangerous Properties of Industrial Materials, 6th Edition, Ontario

New York. Nickel Co., Inc., Huntington, West Virginia

1982, International Technical Information Institute, Tokyo, waukee, Wisconsin

Japan. C. C. Seastrom, E. I. du Pont de Nemours & Co., Inc., Wilming-

nectady, New York. L. S. Surtees, Kerr-McGee Corp., Oklahoma City, Oklahoma

Rita Wieland, Shell Development Co., Emeryville, California

Acknowledgments Louis Zadra, General American Transp. Corp., Sharon, Penn­

A. I. Zimmerer, Petro-Tex Chemical Co., Houston, Texas

contributing data for previous editions is gratefully acknowl­

Corrosion Guide, 2nd Edition, Eric Rabalt, 1968. Elsevier Pub­

tension. James A. Lee.

Materials Performance, National Association of Corrosion

8. lntergranular Corrosion Engineers, Houston, Texas.

lntergranular corrosion attacks grain boundaries of Meehanite Catalog, Meehanite Corp.

Metals and Alloys, Reinhold Publishing Co,, New York, New

services of a corrosion engineer, to aid in precise interpreta

any posting on the shared line between data squares repre

unsuitable, (2) locates those which may have sa tisfactory per

duction for convenient reference. For comparison of penetra

b. Silicon bronze, aluminum bronze, and tin bronze are con

ruled out for others because of other failings , such as con

High Temperature High Pressure Electro-Chemistry in Aque mington, Delaware

Acknowledgments Louis Zadra, General American Transp. Corp., Sharon, Penn

contributing data for previous editions is gratefully acknowl

Corrosion Guide, 2nd Edition, Eric Rabalt, 1968. Elsevier Pub

this book, data points represent

matrix enlarged here. The hor

vertical grid represents temper

consult the preceding introduc