Maximum Marks: 70 Time allowed: One and a half hours (Candidates are allowed additional 15. minutes for only reading the paper.) ALL QUESTIONS ARE COMPULSORY The marks intended for questions are given in brackets CJ. Select the correct option for each of the following questions. 10. n. |. The number of faradays required to reduce 0.25 g of Nb(V) to the metal (atomic mass = 93) is: ‘A crystalline substance whose physical properties are independent of direction is called: (a) isotropic (b) anisotropic (e) isotopic (@) allotropic ty ‘The vapour pressure of CCl, at 25°C is 143 mm of Hg when 0.5 g of a non-volatile solute (mol. wt. = 65) is gi in 100 ml of CCly: The vapour pressure of the solution (density of CCly = 1.58 g cm”): ish (@) 141.93 mm (b) 94.39 mm (©) 199.34 mm (@ 143.99 mm 4 0.6 g of a solute is dissolved in 0.1 litre of a solvent which develops an osmotic pressure of 1.23 atm at am molecular weight of the solute is: 1 (@) 149.5 g mol? (b) 120.0 g mol? (©) 430.0 g mol’ (d) 174.8 g mot ty (@) 2.7 «10° (b) 2.7 «107 (013x107 (@) 7.8 x 10° Y ‘An element crystallises in a fec lattice with cell edge of 400 pm. The density of the element is 7 gem of atoms present in 280 g of this element will be: (@) 1.5 x 107 (b) 2.0 x 10°? (92.5 x 10% (a) 2.5 x 10% Which of the following is the correct statement regarding the stoichiometric defects? ty (a) When temperature increases, the number of defects decreases (b) Frenkel defect occurs when radius of cation is smaller {€) Schottky defect occurs when radius of cation is smaller (@) The density of crystals having Frenkel deféct is lesser than that of a pure perfect crystal ‘The relationship among osmotic pressures (11, 2, 3) ata definite temperature when 1 g of glucose (molar nas: 180), 1 g urea (molar mass = 60) and 1 g sucrose (molar mass = 342) are dissolved in 1 litre of wateris: i) (@) m > 12> 73 (b) xg > m1 >, () m2> m>m3 (a) a> mg>™ A solution of 0.640 g of azulene in 100.0 g of benzene boils at 80.23°C. The boiling point of benzene is 80.1003 K; is 2.53°C/molal. The molecular mass of azulene is: i (a) 99 (b) 108 © 118 (a) 125 The emf of the following cell V/A"? (0.01 M) | | Fe"? (0.02 M)/ Fe fi (Given E°qy*3q1 = -1.66 V and E°e'2/p~ = -0.44 V) () 1.84V (6) 1.23 V (91.39V (@) 1.65V The fraction of volume unoccupied by atoms in a fee and a bec unit cell are respectively: W (a) 0.32, 0.64 (b) 0.74, 0.28 (6) 0.64, 0.26 (d) 0.26, 0.32 Molybdenum (at. mass = 96 g mol”) crystallizes as bec crystal. If densi is 3, ehen the of molybdenum atom is (Nq = 6 x 107°): ity of erystal is 10.3 g/cm’, fl (@) 135.96 pm (b) 314 pm (©) 149.6 pm (@ 214.39 pm .12. 13. 14. 15. 16. 1. 18. 19. 20. a. 2, a 2, a 2, When molten LiCl is _ is electrolysed, lithium metal gets deposited at cathode. If current efficiency is 80% then how many grams of lithi : aay ithium are liberated when 1930 C of charge pass through the cell? (at. mass of Li = 7) a ooeanductivity of acon (90.112 (@) 0.224 (a) 180 $ cm? e “ity of a solution of an electrolyte ApBy is 180 $ cm? mol’. Its equivalent conductivity will be: [1] Ar 25°C, the wo (90S em? eq? (©) 60 Sem? eq" (a) 30 S cm? eq Fo pass ab peressure of pure Liquid’ (mol, mass = 40) is 100 tor, while tha of pure liquid is 40 tor (nt face 80). The vapour pressure at 25° ofa solution containing 20 g ofeach A and Bis a (a (6) 59.8 torr (©) 48 torr (a) 67 tor ass of non-volati i The mass of non-volatile solute having molecular mass = 40 which should be dissolved in $7 g octane to reduce its vapour pressure to 80% is: fet] 4728 05.08 (688 (5.98 Which will form maximum boiling azeotrope? a (@) Colle + CoHsCHs (b) HNO, + H,0) (c) CoHsOH + #20 (a) n-CoHyg + 2-CrHig If the ais Of CI” ion is 181 pm and the radius of Na* ion is 105 pm then the edge length of unit cell is: [1] (a) 286 pm (b) 76 pm (210 pm (@) 572 pm Aluminium crystallises in cep structure. Its metallic radius is 125 pm. The number of unit cells present in 1 cm? of aluminium wil be: a (a) 3.2 x 10° (b) 2.26 x 1072, (©) 1.8 x 10% (a) 2.89 x 1074 How many kilograms of ethylene glycol (molar mass = 62) should be added to 10 kg of water so that resulting solution freezes at -10°C (Ky= 1.86 K/molal)? a) (a) 4.2 kg (b) 2.1 kg (0) 2.6 kg (d) 3.3 kg Molar conductivities at infinite dilution of KCl, HCl and CHCQOK are 0.013, 0.038 and 0.009 Sm” mot’ respectively at 291 K. If conductivity of 0.001 M CH3COOH is 2.72 x 10™° Sm’, the degree of dissociation of acetic acid is: (1] (a) 0.05 (b) 0.08 (c) 0.034 (d) 0.69 The standard free energy change for the following reaction is -210 kJ/mol. Its standard cell potential will be: [1] (a) +1.09 V (b) +0.782 V (c) 40.394 V (d) +0.640 V How many unit cells are present in 5.0 g of crystal AB (formula mass of AB = 40) having rock salt type structure? (N4 = Avogadro's number) a Ny MA (4N4 @ Ma 4 10 40 The mass of glucose (molar mass = 180) that should be dissolved in 50 g of water in order to produce the same lowering of vapour pressure by dissolving 1 g of urea (molar mass = 60) in the same quantity of water is: [1] (6g 8g @ig 3g pound containing 1.82 g/1 has an osmotic pressure of 51.8 cm of mercury at 10°C. The Asolution of an organic comy ‘molecular weight of the organic compound is: rah (@) 62.04 (b) 65.8 (673 (70.2 If two substances A and B have P): Pj = 1: 2 and have mole fraction in solution 1 : 2, then mole fraction of A in vapours is: mM (3) 0.33 (0) 0.28 (052 (@)0.20 (i) The number of carbon atoms in a unit cell of diamond is: 22) a8 . (b) 6 (4 (12 (i) The coordination number of carbon in a unit cell of diamond is: 6 8 (4 (12 () The number of unit cells in hep unit cell 2 (4 6 (12 (17 (i) ABAB....... type of packing in crystals is called: (@) hep () fee (0 cep (ase (@ A-solution contains 92 g ethanol and 72 g water. The mole fraction of ethanol in solution is: 2) @) 0.38 (6) 0.66 (04 (0.33(ii) IFin an aqueous solution of a non-volatile solute, (a) vapour pressure of solution increases (©) osmotic pressure of solution increases ie specific conductivity of a soh aya to be 0.0058 ohm”? cm™ A) The molar conductivity ofthe soliton is (a) 289.5 ohm™ fm nol a (c) 241.66 ohm” cm? mol” i (i) The equivalent condyctivity of the solution is: (a) 106.78 chm” cm? (geq) : (©) 108.59 ohm™ em? (geq)~ 30, The standard electrode potentials of four elements A, B, the mole fraction of water is decreased, lution containing 5 g of anhydrous BaCl, (molar mass = t , then: (b) boiling point of solution decreases (4) no change in boiling point of solution 208) in 1000 mnt of 7 “ly Le) (©) 276.3 ohm”! cm? molt ! (a) 262.8 ohm em? mot” (b) 120.83 ohm” em? (geqy? (4) 105.43 ohm” em? (geqy? Cand D ate +1.06, +0.54, +1.36 and ~2.97 y respect (i) The most reactive element among A, B, C and D is: Wel, os (A (oD we by (i) The most powerful oxidising agent among A, B, Cand D is: @c (b)D (OA (B 31. Number of constituent particles in a unit cell of se, bee and fcc are respectively: @)1,2,6 () 1, 2, (0) 4, 2,1 (@) 2, 6,8 1) (i) Coordination number of sce, bee and fee is respectively: (@)2,4,6 ()4,8, 12 (06, 12,8 @1,2,4 32 () Ina face centred cubic lattice, unit cell is shared equally by how many unit cells? ; @2 4 6 8 2) (i) Metal deficiency defects are shown by: (@) alkali metals (b) non-metals (0 alkaline earth metals (d) transition metas 33. The vapour pressure of Pure benzene and toluene at 25°C are 100 mm and 50 mm tespectively. They are mixed j equimolar ratio, i { The total vapour pressure of solution is: (2) 50mm (b) 25 mm (075 mm (@) 100 mm (2) The mole fraction of toluene in vapour phase in Contact with solution at equilibrium is: (0.75 (6) 0.33 (00.67 (@) 0.20 $4.” (i Relative lowering of vapour pressure i highest for 0.1 M aqueous solution of i (2) urea (6) glucose (0 Mgcl, (a) Mgso, (Vapour pressure of water at 293 K is 17.595 Tim Hg. When 25 g of glucose is dissolved i450 8 of water, the Vapour pressure of the solution will be (@) 18.66 mm (6) 19.02 mm (0 21.94 mm (@) 17.44 mm 35. (i) The equilibrium constant for the following general reaction is 10°, what i the value of E° for the cell at 298K: Oe" ed — 2x2" (ag) + 37% oy (@)+1.05 (b) 40.2985 (0 ~0.0985 v (@~0.2955 v | In electrolysis of a oxytungsten complex fon using 1.10 A for 40 : a Ge ot Whatis the charge on tungsten in vee material?" Produes 0.838 g of tungsten (mole @) 6 (b)2 + @4 @. 36. (i) For a spontaneous Reaction, AG, K- and E°cey will be Tespectively: a (a) -ve, > 1, sve (b) 4ve, > 1, ve (©) -ve, <1, -ve @ ji (@) The charge required for the eduction ot 1 mole of MnO,” to Minds is; wee ve @1F WSF (O3F nt ge 37.) The cubic unit cel of Al (molar mass = 27 g mol) ie cubic unit cell is: Smol"') hasan edge length of 405 Pm. Its density is 2.7 gem”. TH (@) primitive (©) body centred (i Ina face centred cubic unit cell, edge length is; (a) 2r & 3 r ee (d) face centred (dy *3. a a 4a Gold erystallises in fec lattice, Its density is 1 -3 eneas ot 7 9. omic mass is 197 gmol”*, (2] (i) The edge length of unit cell of old ae eqn) and seo aes __ 407 pm (b) 189 pm (© 204 pm (4) 302 pm (i) The approximate number of unit cells present in 1 g of gold is: (013.06 x10 tb) 1.56 x 107 (0 3.84 x 1077 (a) 7.64 x 107° (2) (@ An azeotropic solution of two liquids has a boiling point higher than either of the two when it: (a) shows a negative deviation from Raoult’s law _(b) shows a positive deviation from Raoult’s law (@) shows no deviation from Raoult’s law (a) is saturated (i) 0.6 g of a solute is dissolved in 0.1 litre of a solvent which develops an osmotic pressure of 1.23 atm at 27°C. The molecular weight of solute is: (a) 149.5 g mol (b) 120.0 g mol” (€) 60.0 g mol” (d) 180.0 g mol” () Ifliquids A and B form an ideal solution then: {a) entropy of mixing becomes zero (b) free energy of mixing becomes zero (©) enthalpy and entropy of mixing becomes zero _(d) enthalpy of mixing becomes zero (i) Which of the following pairs of liquid mixtures shows negative deviation from Raoult’s law? (@) Toluene and benzene (b) Acetone and chloroform (© Acetone and carbondisulphide (d) Chloroform and ethanol (i) The function of salt bridge is to: {@) eliminate liquid junction potential where the ions are present in large excess at the junction (b) increase the cell potential at the positive electrode () decrease the cell potential at the negative electrode (d) eliminate the impurities present in the electrolyte (i For the redox reaction: 2n(s) + Cu*? (0.1 M) —>+ Zn"? (1 M) + Cu(s) taking place in a cell, E’ey) = 1.10 V, Ecey for the cell will be: (a) 1.80V (b)1.07V (0) 0.82V (a) 2.14V (i) In preparing a salt bridge, we use KCI with agar-agar because: (a) the hydration power of K* and CI” ions are the same (b) the sizes of the K* and CI” ions are almost equal (6 the equivalent conductances of K* and CI" ions are nearly the same at infinite dilution (d) the electropositive character of K and electronegative character of Cl are comparable (i) The conductivity of 0.2 M solution of KCI at 298 K is 0.0248 S cm”. The molar conductivity of 0.2 M solution (2) (2) [2] of KCl is: (@)248 Sem? mol? (b) 124S em® mol (0 169 S cm” mol (a) 150 $ cm? mol” {) Cubic close-packing of equal-sized spheres is described by: (2) (@) AB AB AB .. (B)ABACAC BC vrsunes (6) ABC ACB ABC (a) ABC ABC (ii) In an NaCl crystal structure: (@) 6 comers are shared (b) 12 edges are shared (04 corners are shared (d) 2 edges and 6 corners are shared (2) (i) In both Schottky and Frenkel defects: (a) stoichiometry is maintained but electrical neutrality is not maintained (b) stoichiometry is not maintained but electric neutrality is maintained (c) both stoichiometry and electric neutrality are maintained (d) both stoichiometry and electric neutrality are not maintained (ii) A metal crystallises in a fee structure. If the edge length of its unit cell is ‘a’, the closest approach between two atoms in metallic crystal will be: @s (oy V2a (2a (@) 22a v2 {18 g glucose (Cgl/120¢) is added to 178.2 g of water. The vapour pressure of water for this aqueous solution at 100°C is: (2] (a) 7.6 torr (i) A solution containing 10 g per dm” of urea (molecular mas: solute, The molar mass of the non-volatile solute in g mol’ is: (@) 300 (b) 350 (©) 250 (@ 200 (b) 76.0 torr (©) 752.40 torr (a) 759.0 torr 30) is isotonic with 5% solution of a non-volatileThe questions given below consist of an Assertion and Reason. Use the following key to choose the appropriate, (a) Assertion is false but Reason is true. in (b) Assertion is true but Reason is false. {c) Both Assertion and Reason are true but Reason is not the correct explanation of the Assertion. (@) Both Assertion and Reason are true and Reason is the correct explanation of the Assertion. 46. Assertion When an atom crystallises either in fec or hep arrangement, density of the solid both the arrangements. : “emails Sn Reason Both foc and hep have same value of limiting packing fractions. 47. Assertion _ Ratio of atoms in unit cell of simple cubic, bec and fec is 1: 2: 4. q Reason _ Packing fraction is minimum in simple cubic system. 48. Assertion _; Addition of non-volatile solute to a volatile solvent increases the boiling point. Reason Addition of non-volatile solute results in lowering of vapour pressure. 48, Assertion; When a solution of non-volatile solute in water is cooled slightly below its freezing temper some ice separates out and then freezing stops Reason Separation of ice increases the molality of the left over solution. 50, Assertion; The electrode potential of standard hydrogen electrode is zero only at 0°. Reason Standard hydrogen electrode is a standard reference electrode. =a