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Consumer Chemistry

WEEKLY LEARNING ACTIVITY SHEETS


Consumer Chemistry, Quarter 1, Week 1
PROPERTIES OF ORGANIC COMPOUNDS AND INORGANIC COMPOUNDS

Name:________________________________ Section: _________________

Most Essential Learning Competency (MELC)


Compare the properties of organic compounds and inorganic compounds

Learning Objectives:
The learners shall be able to:

1. Define organic and inorganic compounds


2. Differentiate organic from inorganic compounds
3. compare the properties of organic and inorganic compounds

Key Differences

● Organic compound is a class of chemical compounds in which one or more atoms of


carbon are covalently linked to atoms of other elements, most commonly hydrogen,
oxygen or nitrogen. On the other hand an inorganic compound is any compound that
lacks a carbon atom.
● Density of compound is usually based on the size of molecule against the size of atoms
in the molecule. Due to presence of more hydrogen atoms in organic compound,
organic compounds tend to be typically less dense than inorganic compounds. This is
because hydrogen is the lowest density atom among all atoms.
● Inorganic compounds are highly soluble in water. This is because they have ionic bonds
between molecules. Ionic bonds easily dissociate into positive and negative ions in
water. On the other hand, most organic compounds have covalent bonds between
molecules and hence are insoluble in water, though they are soluble in other organic
solvents.
● Organic compounds are formed as a result of actions of living organisms while inorganic
compounds are formed due to natural processes unrelated to any life form or as a result
of human experimentation in the laboratory.
● In most of the aqueous solutions, organic compounds are typically poor conductors of
electricity and heat. Inorganic compounds in aqueous solutions are good conductors of Pag
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electricity, this is because they have high ability to ionize and this makes them better
conductors.
● Inorganic compounds include salt, metals, silver, sulfur, pure diamond, substances made
from single elements and substances that do not contain carbon bonded to hydrogen.
On the other hand, examples of organic compounds include nucleic acids, sucrose,
enzymes, benzene, methane, fats and ethanol.
● Inorganic compounds have a faster overall rate of reaction than organic compounds.
Stable organic compounds are generally un-reactive due to presence of covalent bonds
that are difficult to break. On other hand, inorganic compounds have ionic bonds that
easily break; this makes them highly reactive, and will always react with whatever is
available

Activity 1. Organic and inorganic Concept Map

Objective: The learners shall be able to define organic and inorganic compounds.

What to do:

1. Based on the examples below, think of five words or phrases that you can associate
with an organic and inorganic compound.

Figure 1.

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2. Write your answer in a concept map as shown below.

organic inorganic

Figure 2. concept map in organic figure 3. Concept map in inorganic

Guide Question:

1. Using the words/Phrases in your concept map, define organic and inorganic

Activity 2: “Organic or Not”

Objective: Differentiate organic from inorganic compounds

What to do

I. For each statement below, write “O” if you think the statement relates to organic
compound or “I” if you think the statement relates to inorganic compound.

Write your answer on the line before the number.

____1. A chemical compounds in which one or more atoms of carbon are covalently linked to
atoms of other elements.

____ 2. Molecules associated with living organism.

____3. A compound that lacks carbon-hydrogen bonds


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_____4. Relatively low melting points and boiling points

_____5. High thermal stability, good electrical properties, and high modulus

_____6. “like dissolves like”

_____7. Dissolves in water

_____8. Most compounds are colorless

_____9. Show ionic bonding along with covalent bonding

_____10. Mainly show covalent bonding

II. In the table below decide if the compound is organic or inorganic.

Compound Organic Inorganic

CH3CH2OH

CaCO3

PbBr3

NaCl

C8H10N4O2

C4H10

CH4

CH3COOH

C3H8O

Al4C3

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Activity 3: Know My Differences and Similarities

Objective: The learners shall be able to compare the properties of organic and inorganic
compounds

What to do:

Using a Venn Diagram below, compare organic and inorganic compounds.

Organic Compound Inorganic compound

Diagram1.comparison between organic & inorganic compound

Guide Questions:

1. What are the properties of organic compound?


Usua Pag
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2. What are the properties of inorganic compound?

3. What is/are the similarity/ies of organic and inorganic compound?

WEEKLY LEARNING ACTIVITY SHEETS


Consumer Chemistry, Quarter 1, Week 2
The Historical Development of Organic Chemistry

Most Essential Learning Competency (MELC)

Trace the historical development of organic chemistry

Historical timeline of the development of organic chemistry


● Georg Ernest Stahi (1660-1734) – the phlogiston theory ( set on fire) . Carbon was rich in
phlogiston because when it was heated with an oxide, the metal along with “fixed air
CO2 “ was formed
● Joseph Priestly (1733-1804) – the discoverer. Recognized the role of oxygen in the life
cycle.
● Antoine-Laurent Lavoisier (1743-1794)- Quantitative methods. Conservation of mass
● John Dalton (1766-1844) – atomic theory. He proposes the rule of Greatest Simplicity.
Which held that water was a binary compound of the formula of OH
● Jons Jacob Berzelius (1779-1848) electrochemical theory (dualism) He provided the
modern symbols of the elements and defined isomerism (equal parts). Isomers have the
same composition but not the same physical properties. Dualism held that organic
compounds, like inorganic ones, and electropositive and electronegative components.
● Friedrich Wohler (1800-1882)- Vitalism held that organic compounds( derived from
living or deceased organisms) were different from ammonium cyanate (inorganic)
countered this argument.
● Justus Liebig (1803-1873) –Radical Theory held that in organic chemistry radicals are
complex; in inorganic chemistry they are simple. He revolutionized chemical analysis so
that it could be conducted on small samples.
● J. B. Dumas (1800-1884) substitution theory. He chlorinates acetic acid
● August Wilhelm von Hofmann (1818-1892)- studies amines. A series of amines have
similar properties. Pag
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● Alexander Williamson (1824-1904) discovers a new route to ethers and defines the
water type.
● Edward Franklin (1825-1899) introduces the concept of valence. He also recognizes the
ability of N,P,As, and Sb to combine with 3 and 5 other elements.
● Friedrich August Kekule (1829-1896) establishes the tetravalence of carbon and he
structure of benzene
● Archibald Scott Couper (1831-1892) –uses lines to connect atoms
● Joseph Loschmidt ( 1821-1895) – Diagrammatical structural formulae of organic
chemistry
● Alexander Crum Brown (1838-1922) – atom connectivity and multiple bonds.
● Jacobus Henicus van’t Hoff (1852-1911) the arrangement of atoms in space. Carbon is
not only tetravalent but also tetrahedral
● Gilbert N. Lewis (1875-1946) Lewis dot formula
● Linus Pauling ( 1901-1994) –Quantum mechanics leads to resonance, hybridization,
molecular orbital theory and the nature of the chemical bond

Activity 1:” Name Me”

Objectives

1. Cite basic information contributed by early scientists in the development of organic


chemistry.
2. Appreciate the contributions of early scientists in the development of organic chemistry.

What to do:

Match Column A with B. Write only the letter of your answer


Column A Column B

1. Jons Jacob Berzelius a. The father of organic chemistry


2. Friedrich Wohler b. A physician by trade, first coined the term
3. Justus von Liebig “organic chemistry” in 1806.
4. Edward Franklin c. Produced the organic chemical urea
5. Robert Burns Woodward d. Discovered aldehydes and many more
6. August Kekule organic compounds
7. Joseph Priestly e. Visualized the ring structure of benzene in
8. Alexander Williamson 1865
9. Antoine-Laurent Lavoisier f. introduces the concept of valence
10. Archibald Scott Couper g. Recognized the role of oxygen in the life
cycle. Pag
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h. Known for his syntheses of complex organic


substances including cholesterol and Vit.
B12
i. developed for determination of elemental
composition
j. uses lines to connect atoms
k. Discovers a new route to ethers and
defines the water type.

First Summative assessment

Multiple Choices: choose the letter that corresponds to the correct answer.

1. Who is the father of organic Chemistry


a. Friedrich Wohler c. Jons Jacob Berzelius
b. August Kekule d. Justus von Liebig
2. Organic chemistry is the chemistry of
a. Halide compounds c. covalent compound
b. Metallic compound d. carbon compound
3. Vital biological molecules in living systems are largely
a. Organic compounds c. metallic compounds
b. Inorganic compounds d. inert elements
4. Which of the following is an important theory in organic chemistry
a. Atomic theory c. electronegativity
b. Ionic and covalent bonding d. all of these are important
5. What was the theory of a vital force?
a. The idea that organic matter is vital to our lives
b. The idea that the organic matter could only be formed by living organisms
c. The idea that carbon is vital in many reactions
d. The idea that there is a force that directs all reactions
6. All organic compounds are soluble in water
a. True c. depending on the number of carbons and branching
b. False d. depends of the temperature
7. Melting and boiling points of organic compounds are
a. Increase with the number of carbon atoms in the chain
b. decrease with the number of carbon atoms in the chain
c. increase with branching
d. determined by the bonding between the carbons and hydrogen Pag
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8. the volatility points of organic compounds are


a. increase with the number of carbon atom in the chain
b. decrease with the number of carbon atoms in the chain
c. increase with branching
d. determined by the bonding between the carbons and hydrogen
9. the viscosity points of organic compounds are
a. increase with the number of carbon atom in the chain
b. decrease with the number of carbon atoms in the chain
c. increase with branching
d. determined by the bonding between the carbons and hydrogen
10. What are the four major categories of organic compounds?
a. Acids, bases, nucleic acids and polysaccharides
b. Carbohydrates, lipids, nucleic acids, and proteins
c. Carbon, hydrogen, nitrogen and oxygen
d. Acids, carbon, proteins and lipids

WEEKLY LEARNING ACTIVITY SHEETS


Consumer Chemistry, Quarter 1, Week 3-4
IUPAC Nomenclature of Organic Compounds

Most Essential Learning Competency (MELC)

Describe the IUPAC nomenclature classification of organic compounds (functional groups,


aliphatic and aromatic compounds)

Learning Objectives
After completing this section, you should be able to
1. provide the correct IUPAC name for a given alkane structure.
2. draw the condensed structure of an alkane, given its IUPAC name.

Hydrocarbons
The simplest class of organic compounds is the hydrocarbons, which consist entirely of carbon
and hydrogen. The four major classes of hydrocarbons are the following:
1. alkanes which contain only carbon-hydrogen and carbon-carbon single bonds.
2. Alkenes which contain at least one carbon-carbon double bond (C=C) in their molecules.
3. Alkynes which contain at least one carbon-carbon triple bond (C≡C ) in their molecules. Pag
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4. Hydrocarbons which usually contain rings of six carbon atoms that can be drawn with
alternating single and double bonds. Alkanes are also saturated hydrocarbons, whereas
hydrocarbons that contain multiple bonds (alkenes, alkynes and aromatics) are
unsaturated.

The following table lists the IUPAC names assigned to simple continuous-chain alkanes
from C-1 to C-10. Common “ane” suffixes identifies these compounds as alkanes and are
prefixed depending on the number of carbon atoms in the chain, following standard
rules.

Number 1 2 3 4 5 6 7 8 9 10
of
carbons

Prefix Meth Eth Prop But Pent Hex Hept oct non Dec

Table 1. alkanes

Cyclic hydrocarbons Pag


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In a cyclic hydrocarbon, the ends of a hydrocarbon chain are connected to form a ring of
covalently bonded carbon atoms. Cyclic hydrocarbons are named by attaching the prefix
cyclo- to the name of alkane, the alkene, or the alkyne.

Table 2. Cycloalkanes

Alkyl groups
Acyclic alkanes can be described by the general formula C nH2n+2 (“n” is the number of
carbon). An alkyl group is formed by removing one hydrogen from the alkane chain and
is describe by the formula CnH2n+1. The removal of this hydrogen results in a stem change
from –ane to yl. Take a look at the following examples.

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example:

Naming alkyl halides


Halogen substituents are easily accommodated, using the names: fluoro (F-), chloro (Cl-),
bromo (Br-) and iodo (I-). These are inserted alphabetically into the name in the same
way as alkyl groups are included when naming complex alkanes.

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IUPAC (International Union of Pure and Applied Chemistry ) Rules for alkane
Nomenclature
1. find and name the longest continuous carbon chain.
2. Identify and name groups attached to this chain.
3. Number the chain consecutively, starting at the end nearest a substituent group.
4. Designate the location of each substituent group by an appropriate number and name.
5. Assemble the name, listing groups in alphabetical order.
6. The prefixes di, tri, tetra etc, used to designate several groups of the same kind, are not
considered when alphabetizing.

Activity 1: “What is Your Name”

Objective
1. provide the correct IUPAC name for a given alkane structure.

What to do:
Write the correct IUPAC name of the following alkane structures.

2.

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3.

10 11. 12.
5

6.

7
13. 14. 15

9.

Activity 2: 2. “Draw Me”

Objective

draw the condensed structure of an alkane, given its IUPAC name.

What to do:

Given its name, draw the condensed structure of the following alkane

1. 1,1,3- trimethylpentane 6. ethylcyclopentane


2. 2-bromo-1-methylbutane 7. cyclopentane
3. Decane 8. bromomethane
4. 4-ethyl-3-methyloctane 9. 2-Bromo-3chlorohexane
5. 3-ethyl-1,1dimethylcyclohexane 10. 2-ethyl-2-fluoro-1-iodoheptane

Alkenes (general formula CnH2n) Pag


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Alkynes (CnH2n-2)

Naming alkenes and alkynes

1. Alkenes and alkynes are named by identifying the longest chain that
contains the double or triple bond.
2. The chain is numbered to minimize the numbers assigned to the double or
triple bond
3. The suffix of the compound is “ene” for an alkene or “yne” for an alkyne

The following structures are example of alkene

The following structures are example of alkyne

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Activity 3: alkene and alkyne

Objectives:
1. provide the correct IUPAC name for a given alkene and alkyne structure
2. draw the condensed structure of an alkene and alkyne, given its IUPAC name.

what to do:

I. Use systematic nomenclature to name the following structures.

2.

3.

4.
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5.
1.

6.

7.

8.

II. Given its name, draw the condensed structure of the following alkenes and alkynes
1. 3,3-dimethyl-butyne
2. 2,5-dimethyl-3-heptyne
3. 3-ethyl-5-methyl-1-hexyne
4. 2-methyl-2-pentene
5. 3,3-dimethyl-1-butene
6. 2,5,5-trimethyl-3-0ctene
7. 1-methyl-propene

ALCOHOL

An alcohol is an organic compound with a hydroxyl (OH) functional group on an aliphatic Pag
carbon atom. ROH is the general formula of alcohol where R is analkyl group. e
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Nomenclature of alcohols
● Alcohols with one to four carbon atoms are frequently called by common names,in
which the name of the alkyl group is followed by the word alcohol ( methyl alcohol,
ethyl alcohol, propyl alcohol and isopropyl alcohol)
● IUPAC rules for naming alcohols
Alcohol are named by changing the ending of the parent alkane to –ol
1. The longest continuous chain (LCC) of carbon atoms containing the OH group
is take as the parent compound- an alkane with the same number of carbon
atoms. The chain is numbered from the end nearest the OH group.
2. The number that indicates the position of the OH group is prefixed to the
name of the parent hydrocarbon,and the –e ending of the parent alkane is
replaced by the suffix –ol (in cyclic alcohols, the carbon atom bearing the OH
group is designated C1, but the 1 is not used in the name.) substituents are
named and numbered as in alkanes
3. If more than one OH group appears in the same molecule ( polydroxyl
alcohols), suffixes such as –diol and –triol ae used. In these cases, the –e
ending of the parent alkane is retained

Three Classification of alcohol


1. Primary (1) – the carbon atom wih the OH group attached to one carbon atom. Its
general formula is RCH2OH
2. Secondary (2) -the carbon atom wih the OH group attached to two carbon atom. Its
general formula is R2CHOH
3. Tertiary (3)- the carbon atom wih the OH group attached to three carbon atom. Its
general formula is R3COH

Example 1.

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Example 2.

⮚ The name is 6,8-dimethyl-3-decaol

Example 3

Activity 3: Alcohol

Objective:

1. identify the structural feature that classifies alcohols as primary, secondary, or tertiary.
2. identify the general structure for an alcohol
3. name alcohols with both common names and IUPAC names

What to do:
I. Name each of the alcohols shown below using IUPAC rules and classify it as primary,
secondary, or tertiary CH3CH2CH2OH
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1. CH3CH2CH2OH

2. (CH3)3COH
3.

4.

5.

II. Draw the structure for each compound


1. 2-heptanol
2. Cyclopropanol
3. 2,3,5-tri-ol octane
4. 3-methyl-1,3-di-olpentane
5. 3-methylhexanol

ALDEHYDES AND KETONES


Aldehydes and ketone are organic compounds which incorporate a carbonyl functional group
C=O. the carbon atom of this group has two remaining bonds that may be occupied by
hydrogen, alkyl or aryl substituents. If at least one of these substituents is hydrogen, the
compound is an aldehyde. Aldehyde is a compound containing a functional group with the
structure –CHO. If neither is hydrogen, the compound is a ketone. The functional group of
ketone is R2C=O or RCOR. With the general formula of CnH2nO

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Naming aldehydes
1. Aldehydes take their name from their parent alkane chains. The –e is removed from the
end and is replaced with –al.
2. The aldehyde functional group is given the # 1 numbering location and this number is
not included in the name.
3. For common name of aldehydes start with the common parent chain name and add the
suffix –aldehyde. Substituent positions are shown with Greek letters.
4. When the –CHO functional group is attached to a ring the suffix – carbaldehyde is
added, and the carbon attached to that group is C1.

Naming of ketones
1. Ketones take their name from their parent alkane chains. The ending –e is removed and
replaced with –one.
2. The common names for ketones are simply the substituents groups listed
alphabetically + ketone.
3. Some common ketones are known by generic names. Such as the fact that propanone is
commonly referred to as acetone

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Naming Aldehydes and Ketones in the Same Molecule


⮚ Molecules which contain both functional groups are named as “oxo” substituent. It is
not necessary to give the aldehyde functional group a location number, however, I is
usually necessary to give a location number to the ketone

Naming Dialdehydes and Diketones


⮚ For dialdehydes the location numbers both carbonyls are omitted because the aldehyde
functional groups are expected to occupy the ends of the parent chain. The ending –dial
is added to the end of the parent chain name.
⮚ For diketones both carbonyls require a location number. The ending –dione or -dial is
added to the end of the parent chain.

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Naming Cyclic Ketones and Diketones

⮚ In cyclic ketones the carbonyl group is assigned location position #1, and this number is
not included in the name, unless more than one carbonyl group is present. Remember
the prefix cyclo is included before the parent chain name to indicate that it is in a ring.
As with other ketones the –e ending is replaced with the –one to indicate the presence
of a ketone. With cycloalkanes which contain two ketones both carbonyls need to be
given a location numbers. Also an –e is not removed from the end, but the suffix –dione
is added.

Naming Carbonyls and Hydroxyls in the Same Molecule


⮚ The carbonyl is given the lowest possible location number and the appropriate
nomenclature suffix is included. In the case of alcohols the OH is named as a hydroxyl
substituent. However, the l in hydroxyl is generally removed.

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Activity 4. Aldehydes and Ketones

Objectives

1. provide the correct IUPAC name for a given aldehydes and ketone structure
2. draw the condensed structure of aldehydes and ketone

What to do
I. Name each of the aldehyde and ketone shown below using IUPAC rules

II. Give the structure corresponding to each name


1. Pentanal
2. 2-pentanone
3. 3-hydroxycyclopentanone
4. 3,4-pentanedione
5. 2,3-cyclohexanedione
6. 3-hydroxy-4-methlyl-2-butanone
7. 3-oxobutanal
8. Butanedial
9. 2-propanone
10. 2-bromo-5-methylcyclohexanone
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Carboxylic Acid
Carboxylic acids are named based on the number of carbons in the longest chain, including the
carbonyl group (-COOH). The –e ending is removed from the name of the parent chain and is
replaced –oic acid. Since a carboxylic acid group must always lie at the end of a carbon chain, it
is always given the # 1 location position in numbering and it is not necessary to include it in the
name.

Many carboxylic acids are called by the common names. These names were chosen by chemists
to usually describe a source of where the compound is found.

Naming Carbonyl Group Added to a Ring


⮚ When a carboxyl group is added to a ring the suffix –carboxylic acid is added to the
name of the cyclic compound. The ring carbon attached to the carboxyl group is given
the # 1 location number.

Naming carboxylic acids which contain other functional groups


⮚ Carboxyl group is given the lowest possible location number and the appropriate
nomenclature suffix is included. In the case of molecules containing carboxylic acid and
alcohol functional group the OH is named as a hydroxyl substituent. However, the l in
the hydroxyl is generally removed.

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⮚ In the case of molecules containing a carboxylic acid and aldehydes and/or ketones
functional groups the carbonyl is named as a “Oxo” substituent.

⮚ In the case of molecules containing a carboxylic acid an amine functional group the
amine is name “amino” substituent.

⮚ When carboxylic acids are included with an alkene the following order is allowed:
a. Location number of alkene, prefix name for the longest carbon chain and –oic acid
ending to indicate the presence of an alkene and carboxylic acid
b. Carboxylic acid has priority so it should get the lowest possible location number.
Also, remember that cis/trans or E/Z nomenclature for the alkene needs to be
included if necessary.

Naming dicarboxylic acids


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⮚ For dicarboxylic acids the location numbers for both carboxyl groups are omitted
because both functional groups are expected to occupy the ends of the parent chain.
The ending –dioic acid is added to the end of the parent chain

Activity 5. Carboxylic Acid

Objectives

1. provide the correct IUPAC name for a given Carboxylic Acid structure
2. draw the condensed structure of carboxylic acid

What to do
I. Name each of the carboxylic acid shown below using IUPAC rules. Select your
answer on the opposite side of the structure.

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II. Give the structure corresponding to each name


1. 3- methanoic acid
2. 3-chloropropanoic acid
3. 2-propenoic acid Pag
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4. 2-ethyl-6-iodo-3,3-dimethylheptanoic acid
5. 3-oxopentanoic acid
6. 3,4-dihydoxypentanoic acid
7. Ethanoic acid
8. 2-cyclohexene carboxylic acid
9. 2-bromo-2ethylbutanoic acid
10. Pentanedioic acid

Ester
⮚ Eaters are known for their distinctive odors and are commonly used for food aroma
and fragrances. The general formula of an ester is RCOOR. Esters are formed through
reactions between an acid and an alcohol with the elimination of water.
Naming of esters
1. Identify the oxygen that is part of continuous chain and bonded to carbon on both sides.
(on side of this oxygen there will be a carbonyl present but on the other side there
won’t be.)
2. Begin numbering the carbon chains on either side of the oxygen
3. Change the ending of the alkane on the same side as the carbonyl from –e to –oate
Example : CH3COOCH3 ( methyl ethanoate is the IUPAC name)

Activity 6. Ester

Objectives

1. provide the correct IUPAC name for a given Ester structure


2. draw the condensed structure of Ester

What to do
I. Name the following compounds:

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2.

II. draw structural formulas for following molecules:


1. Methyl butanoate
2. Ethyl-2-methylpropanoate
3. Ethyl-2,4-dimethylhexanoate

Amines and amides


⮚ An amine is derivative of ammonia in which one, two, or three hydrogen atoms are
replaced by hydrocarbon groups. Amines are classified as primary, secondary, or
tertiary by the number of hydrocarbon groups attached to the nitrogen atom. Amines
are named by naming the alkyl groups attached to the nitrogen atom, followed by the
suffix –amine

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⮚ Amide have a general structure in which a nitrogen atom is bonded to a carbonyl


carbon atom. In names for amides, the –ic acid of the common name or the –oic ending
of the IUPAC for the corresponding carboxylic acid is replaced by –amide

Activity 7. Amines and Amides

Objectives

1. provide the correct IUPAC name for a given amines and amides structure
2. draw the condensed structure of amines and amides

What to do
I. Name the following compounds:

1. 2

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4.

5.

II. Draw the structural formulas for the following molecules:


1. 2- methylpropanamide
2. N-ethyl-N-methylpentanamide
3. Trimethylamine
4. 1,4-diaminobutane
5. 2-pentanamine

Nitrile

⮚ Nitrile is an organic chemical that contains a cyano functional group C≡N. the general
chemical formula is RCN, where R is the organic compound
⮚ Name the parent alkane followed with the word –nitrile. The carbon in the nitrile is
given # 1 location position. It is not necessary to include the location number in the
name because it is assumed that the functional group will be on the end of the parent
chain.
⮚ When a nitrile is the highest priority functional group attached to a cycloalkane, the
name of the parent cycloalkane is followed by the word-carbonitrile. The ring carbon
attached to the nitrile is numbered C1 and the nitrile is not given a number in the name.

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Activity 8. Nitrile e
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Objectives

1. draw the condensed structure of Nitrile

What to do
I. Draw the structural formula of the following compounds:
1. 2-chlorobutane nitrile
2. Pentane nitrile
3. Cyclohexanecarbonitrile
4. 2,3-dimethylheptanenitrile
5. Benzenecarbonitrile

Second summative

Multiple Choices: Choose the letter of the correct answer. Write your answer in
your notebook.

1. Which are polyunsaturated compounds?


a. Compounds with two or more double bonds
b. Compounds with less carbon atoms than normal
c. Compounds which lack hydrogen
d. Compounds with several missing oxygen atoms
2. In organic chemistry, the reactions of many molecules are dependent upon the
functional group. The functional group can also affect physical properties. What
characteristic of carboxylic acid gives the molecule a much higher boiling point than
many other molecules of similar molecular weight?
a. Catalysis b. hydrogen bonding c. inertness d. periodicity
3. Many of the series compounds that constitute the field of organic chemistry contain the
same functional group. The group in question is “C=O” which is essentially a double
bonded carbon to oxygen bond with two side groups attached to the carbon atom.
What is the name of this functional group?
a. Carbonyl group c. ether group
b. Ester group d. alkyl group

4. Which of the following functional groups do not have a carbonyl group?


a. Amides b. Aldehydes c. Amines d. Ester
5. What is the IUPAC name of a given compound? Pag
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a. Hexane 1,2,5-tricarbonitrile c. Hexane 1,3,6-tricarbonitrile


b. Butane 1,2,4-tricarbonitrile d. butane 1,3,4-tricarbonitrile

6. The IUPAC name of this compound is


a. 4-ethyl-3methyl-trans-3-heptene c. 4-ethyl-3-methyl-cis-3-heptene
b. 5-ethyl-6-methyl-trans-5-heptene d. 5-ethyl-6-methyl-cis-5-heptene
7. IUPAC name of CH3COOH is
a. Acetic acid b. formic acid c. methanoic acid d. ethanoic acid
8. If the alkane contains 24 hydrogen atoms, how many carbon atoms does it have?
a. 11 b. 12 c. 22 24
9. Choose the one that is not a class of organic compound?
a. Amides c. carbonyl compound
b. Electro compounds d. nitro compound
10. Which compound is a secondary alcohol?
a. Butan-1-ol c. butan-2-ol
b. isobutyl alcohol d. 2-methylpropan-2-ol
11. Which class of compounds shows H-bonding even more than in alcohols?
a. Phenols b. carboxylic acid c. ethers d. aldehydes
12. Name the ester formed when methanol is reacted with butanoic acid
a. Methyl propanoate c. butyl methanoate
b. Methyl butanoate d. butyl ethanoate
13. Which of the following acids is an organic compound?
a. Hydrochloric b. sulfuric c. ethanoic d. nitric
14. The correct sample of IUPAC name of the compound is
a. 2-methyl 2-(1 methylethoxy) propane c. 1-isopropoxy-1,1-dimethylethane
b. T-butyl isopropyl ether d. 2-(1,1-dimethylethox) propane
15. What functional group is HC=O?
a. Carbonyl aldehyde c. carbonyl ketone
b. Carboxylic d. ester

16. Carboxylic acids combined with alcohols in high temperature will form a(n)
a. Ester b. alcohol c. amide d. amide
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17. Which of the following groups can be classified as carbonyls? e
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a. Aldehydes b. esters c. ketones d. aldehydes and ketones


18. Which of the following is not a primary amine?
a. N-methylethaneamine c. 3-hexanamine
b. Cyclopentanamine d. 1-butanamine
19. What is the amino group’s structure?
a. –COOH b. –NH2 c. –OH d. CHO
20. What is the basis for classifying amines as primary, secondary, or tertiary?
a. The number of carbon atoms bonded directly to the nitrogen atom
b. The number of carbon atoms bonded to a carbon bearing nitrogen
c. The number of nitrogen atoms present
d. The number of hydrogen atoms present

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