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Las - Consumer Chem. WK 1-4
Las - Consumer Chem. WK 1-4
Learning Objectives:
The learners shall be able to:
Key Differences
electricity, this is because they have high ability to ionize and this makes them better
conductors.
● Inorganic compounds include salt, metals, silver, sulfur, pure diamond, substances made
from single elements and substances that do not contain carbon bonded to hydrogen.
On the other hand, examples of organic compounds include nucleic acids, sucrose,
enzymes, benzene, methane, fats and ethanol.
● Inorganic compounds have a faster overall rate of reaction than organic compounds.
Stable organic compounds are generally un-reactive due to presence of covalent bonds
that are difficult to break. On other hand, inorganic compounds have ionic bonds that
easily break; this makes them highly reactive, and will always react with whatever is
available
Objective: The learners shall be able to define organic and inorganic compounds.
What to do:
1. Based on the examples below, think of five words or phrases that you can associate
with an organic and inorganic compound.
Figure 1.
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organic inorganic
Guide Question:
1. Using the words/Phrases in your concept map, define organic and inorganic
What to do
I. For each statement below, write “O” if you think the statement relates to organic
compound or “I” if you think the statement relates to inorganic compound.
____1. A chemical compounds in which one or more atoms of carbon are covalently linked to
atoms of other elements.
_____5. High thermal stability, good electrical properties, and high modulus
CH3CH2OH
CaCO3
PbBr3
NaCl
C8H10N4O2
C4H10
CH4
CH3COOH
C3H8O
Al4C3
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Objective: The learners shall be able to compare the properties of organic and inorganic
compounds
What to do:
Guide Questions:
● Alexander Williamson (1824-1904) discovers a new route to ethers and defines the
water type.
● Edward Franklin (1825-1899) introduces the concept of valence. He also recognizes the
ability of N,P,As, and Sb to combine with 3 and 5 other elements.
● Friedrich August Kekule (1829-1896) establishes the tetravalence of carbon and he
structure of benzene
● Archibald Scott Couper (1831-1892) –uses lines to connect atoms
● Joseph Loschmidt ( 1821-1895) – Diagrammatical structural formulae of organic
chemistry
● Alexander Crum Brown (1838-1922) – atom connectivity and multiple bonds.
● Jacobus Henicus van’t Hoff (1852-1911) the arrangement of atoms in space. Carbon is
not only tetravalent but also tetrahedral
● Gilbert N. Lewis (1875-1946) Lewis dot formula
● Linus Pauling ( 1901-1994) –Quantum mechanics leads to resonance, hybridization,
molecular orbital theory and the nature of the chemical bond
Objectives
What to do:
Multiple Choices: choose the letter that corresponds to the correct answer.
Learning Objectives
After completing this section, you should be able to
1. provide the correct IUPAC name for a given alkane structure.
2. draw the condensed structure of an alkane, given its IUPAC name.
Hydrocarbons
The simplest class of organic compounds is the hydrocarbons, which consist entirely of carbon
and hydrogen. The four major classes of hydrocarbons are the following:
1. alkanes which contain only carbon-hydrogen and carbon-carbon single bonds.
2. Alkenes which contain at least one carbon-carbon double bond (C=C) in their molecules.
3. Alkynes which contain at least one carbon-carbon triple bond (C≡C ) in their molecules. Pag
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4. Hydrocarbons which usually contain rings of six carbon atoms that can be drawn with
alternating single and double bonds. Alkanes are also saturated hydrocarbons, whereas
hydrocarbons that contain multiple bonds (alkenes, alkynes and aromatics) are
unsaturated.
The following table lists the IUPAC names assigned to simple continuous-chain alkanes
from C-1 to C-10. Common “ane” suffixes identifies these compounds as alkanes and are
prefixed depending on the number of carbon atoms in the chain, following standard
rules.
Number 1 2 3 4 5 6 7 8 9 10
of
carbons
Prefix Meth Eth Prop But Pent Hex Hept oct non Dec
Table 1. alkanes
In a cyclic hydrocarbon, the ends of a hydrocarbon chain are connected to form a ring of
covalently bonded carbon atoms. Cyclic hydrocarbons are named by attaching the prefix
cyclo- to the name of alkane, the alkene, or the alkyne.
Table 2. Cycloalkanes
Alkyl groups
Acyclic alkanes can be described by the general formula C nH2n+2 (“n” is the number of
carbon). An alkyl group is formed by removing one hydrogen from the alkane chain and
is describe by the formula CnH2n+1. The removal of this hydrogen results in a stem change
from –ane to yl. Take a look at the following examples.
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example:
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IUPAC (International Union of Pure and Applied Chemistry ) Rules for alkane
Nomenclature
1. find and name the longest continuous carbon chain.
2. Identify and name groups attached to this chain.
3. Number the chain consecutively, starting at the end nearest a substituent group.
4. Designate the location of each substituent group by an appropriate number and name.
5. Assemble the name, listing groups in alphabetical order.
6. The prefixes di, tri, tetra etc, used to designate several groups of the same kind, are not
considered when alphabetizing.
Objective
1. provide the correct IUPAC name for a given alkane structure.
What to do:
Write the correct IUPAC name of the following alkane structures.
2.
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3.
10 11. 12.
5
6.
7
13. 14. 15
9.
Objective
What to do:
Given its name, draw the condensed structure of the following alkane
Alkynes (CnH2n-2)
1. Alkenes and alkynes are named by identifying the longest chain that
contains the double or triple bond.
2. The chain is numbered to minimize the numbers assigned to the double or
triple bond
3. The suffix of the compound is “ene” for an alkene or “yne” for an alkyne
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Objectives:
1. provide the correct IUPAC name for a given alkene and alkyne structure
2. draw the condensed structure of an alkene and alkyne, given its IUPAC name.
what to do:
2.
3.
4.
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5.
1.
6.
7.
8.
II. Given its name, draw the condensed structure of the following alkenes and alkynes
1. 3,3-dimethyl-butyne
2. 2,5-dimethyl-3-heptyne
3. 3-ethyl-5-methyl-1-hexyne
4. 2-methyl-2-pentene
5. 3,3-dimethyl-1-butene
6. 2,5,5-trimethyl-3-0ctene
7. 1-methyl-propene
ALCOHOL
An alcohol is an organic compound with a hydroxyl (OH) functional group on an aliphatic Pag
carbon atom. ROH is the general formula of alcohol where R is analkyl group. e
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Nomenclature of alcohols
● Alcohols with one to four carbon atoms are frequently called by common names,in
which the name of the alkyl group is followed by the word alcohol ( methyl alcohol,
ethyl alcohol, propyl alcohol and isopropyl alcohol)
● IUPAC rules for naming alcohols
Alcohol are named by changing the ending of the parent alkane to –ol
1. The longest continuous chain (LCC) of carbon atoms containing the OH group
is take as the parent compound- an alkane with the same number of carbon
atoms. The chain is numbered from the end nearest the OH group.
2. The number that indicates the position of the OH group is prefixed to the
name of the parent hydrocarbon,and the –e ending of the parent alkane is
replaced by the suffix –ol (in cyclic alcohols, the carbon atom bearing the OH
group is designated C1, but the 1 is not used in the name.) substituents are
named and numbered as in alkanes
3. If more than one OH group appears in the same molecule ( polydroxyl
alcohols), suffixes such as –diol and –triol ae used. In these cases, the –e
ending of the parent alkane is retained
Example 1.
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Example 2.
Example 3
Activity 3: Alcohol
Objective:
1. identify the structural feature that classifies alcohols as primary, secondary, or tertiary.
2. identify the general structure for an alcohol
3. name alcohols with both common names and IUPAC names
What to do:
I. Name each of the alcohols shown below using IUPAC rules and classify it as primary,
secondary, or tertiary CH3CH2CH2OH
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1. CH3CH2CH2OH
2. (CH3)3COH
3.
4.
5.
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Naming aldehydes
1. Aldehydes take their name from their parent alkane chains. The –e is removed from the
end and is replaced with –al.
2. The aldehyde functional group is given the # 1 numbering location and this number is
not included in the name.
3. For common name of aldehydes start with the common parent chain name and add the
suffix –aldehyde. Substituent positions are shown with Greek letters.
4. When the –CHO functional group is attached to a ring the suffix – carbaldehyde is
added, and the carbon attached to that group is C1.
Naming of ketones
1. Ketones take their name from their parent alkane chains. The ending –e is removed and
replaced with –one.
2. The common names for ketones are simply the substituents groups listed
alphabetically + ketone.
3. Some common ketones are known by generic names. Such as the fact that propanone is
commonly referred to as acetone
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⮚ In cyclic ketones the carbonyl group is assigned location position #1, and this number is
not included in the name, unless more than one carbonyl group is present. Remember
the prefix cyclo is included before the parent chain name to indicate that it is in a ring.
As with other ketones the –e ending is replaced with the –one to indicate the presence
of a ketone. With cycloalkanes which contain two ketones both carbonyls need to be
given a location numbers. Also an –e is not removed from the end, but the suffix –dione
is added.
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Objectives
1. provide the correct IUPAC name for a given aldehydes and ketone structure
2. draw the condensed structure of aldehydes and ketone
What to do
I. Name each of the aldehyde and ketone shown below using IUPAC rules
Carboxylic Acid
Carboxylic acids are named based on the number of carbons in the longest chain, including the
carbonyl group (-COOH). The –e ending is removed from the name of the parent chain and is
replaced –oic acid. Since a carboxylic acid group must always lie at the end of a carbon chain, it
is always given the # 1 location position in numbering and it is not necessary to include it in the
name.
Many carboxylic acids are called by the common names. These names were chosen by chemists
to usually describe a source of where the compound is found.
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⮚ In the case of molecules containing a carboxylic acid and aldehydes and/or ketones
functional groups the carbonyl is named as a “Oxo” substituent.
⮚ In the case of molecules containing a carboxylic acid an amine functional group the
amine is name “amino” substituent.
⮚ When carboxylic acids are included with an alkene the following order is allowed:
a. Location number of alkene, prefix name for the longest carbon chain and –oic acid
ending to indicate the presence of an alkene and carboxylic acid
b. Carboxylic acid has priority so it should get the lowest possible location number.
Also, remember that cis/trans or E/Z nomenclature for the alkene needs to be
included if necessary.
⮚ For dicarboxylic acids the location numbers for both carboxyl groups are omitted
because both functional groups are expected to occupy the ends of the parent chain.
The ending –dioic acid is added to the end of the parent chain
Objectives
1. provide the correct IUPAC name for a given Carboxylic Acid structure
2. draw the condensed structure of carboxylic acid
What to do
I. Name each of the carboxylic acid shown below using IUPAC rules. Select your
answer on the opposite side of the structure.
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4. 2-ethyl-6-iodo-3,3-dimethylheptanoic acid
5. 3-oxopentanoic acid
6. 3,4-dihydoxypentanoic acid
7. Ethanoic acid
8. 2-cyclohexene carboxylic acid
9. 2-bromo-2ethylbutanoic acid
10. Pentanedioic acid
Ester
⮚ Eaters are known for their distinctive odors and are commonly used for food aroma
and fragrances. The general formula of an ester is RCOOR. Esters are formed through
reactions between an acid and an alcohol with the elimination of water.
Naming of esters
1. Identify the oxygen that is part of continuous chain and bonded to carbon on both sides.
(on side of this oxygen there will be a carbonyl present but on the other side there
won’t be.)
2. Begin numbering the carbon chains on either side of the oxygen
3. Change the ending of the alkane on the same side as the carbonyl from –e to –oate
Example : CH3COOCH3 ( methyl ethanoate is the IUPAC name)
Activity 6. Ester
Objectives
What to do
I. Name the following compounds:
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2.
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Objectives
1. provide the correct IUPAC name for a given amines and amides structure
2. draw the condensed structure of amines and amides
What to do
I. Name the following compounds:
1. 2
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4.
5.
Nitrile
⮚ Nitrile is an organic chemical that contains a cyano functional group C≡N. the general
chemical formula is RCN, where R is the organic compound
⮚ Name the parent alkane followed with the word –nitrile. The carbon in the nitrile is
given # 1 location position. It is not necessary to include the location number in the
name because it is assumed that the functional group will be on the end of the parent
chain.
⮚ When a nitrile is the highest priority functional group attached to a cycloalkane, the
name of the parent cycloalkane is followed by the word-carbonitrile. The ring carbon
attached to the nitrile is numbered C1 and the nitrile is not given a number in the name.
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Activity 8. Nitrile e
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Objectives
What to do
I. Draw the structural formula of the following compounds:
1. 2-chlorobutane nitrile
2. Pentane nitrile
3. Cyclohexanecarbonitrile
4. 2,3-dimethylheptanenitrile
5. Benzenecarbonitrile
Second summative
Multiple Choices: Choose the letter of the correct answer. Write your answer in
your notebook.
16. Carboxylic acids combined with alcohols in high temperature will form a(n)
a. Ester b. alcohol c. amide d. amide
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17. Which of the following groups can be classified as carbonyls? e
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