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Lesson 1 Thermodynamics
Lesson 1 Thermodynamics
MEAC 5502
Review Power and Industrial
Plant Engineering
Lecture 1:
Fundamentals of Power Plant:
a. Thermodynamics
b. Fluid Mechanics
➢ Temperature
- measure of intensity of heat. The degree of hotness or coldness
➢ Pressure
- it is the force applied per unit area
Absolute temperature
- the temperature measured from absolute zero.
Absolute zero
- the temperature at which the molecules stop moving.
Temperature Scale
• Celcius or Centigrade
• Fahrenheit
• Kelvin
• Rankine
Relation between temperature scales:
9
𝐹= 𝐶 + 32 𝑅 = 𝐹 + 460
5
5
𝐶= 𝐹 − 32 𝐾 = 𝐶 + 273
9
TEMPERATURE INTERVAL/CHANGE
– the difference between two temperature readings from the same
scale, and the change in temperature through which the body is heated.
Gage pressure
The pressure measured from the level of atmospheric pressure by
most pressure recording instrument like pressure gage and open-ended
manometer.
Note:
✓ Pgage = negative (-) when the pressure is vacuum.
✓ Perfect vacuum is -101.325.
Patm = 101.325 kPa
= 14.7 psi
= 1.032 kg/sq. cm
= 29.92 inHg
= 760 mmHg = 760 torr
= 1.013 bar
= 1 atm
Newton’s Second Law
States that the object will accelerate in the direction and directly
proportional to the unbalanced force acting on it.
𝐹 𝛼 𝑎𝑜
𝑎𝑜
𝐹=𝑚
𝑔𝑐
Where;
F = unbalance force
m = mass of the object
𝑎𝑜 =𝑔𝑜 =observed acceleration or local acceleration
= 9.81m/sec. square = 32.2 ft/sec. square
𝑘𝑔−𝑚 𝑙𝑏𝑚 −𝑓𝑡
𝑔�𝑐 = proportionality constant = 1 = 32.2
𝑁−𝑠2 𝑙𝑏𝑓 −𝑠2
Density and Specific Volume
The density is defined as mass per unit volume and the specific volume is
defined as volume per unit mass. Specific volume is the inverse of density.
Density:
𝑚
𝜌=
𝑉
Specific Weight
This defined as weight (force) of the thermodynamic substance per unit volume.
𝐹 𝑚𝑔𝑜 𝑔𝑜
𝛾= = =𝜌
𝑉 𝑣𝑔𝑐 𝑔𝑐
𝜌𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 𝛾𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒
𝑆𝐺 = =
𝜌𝑤𝑎𝑡𝑒𝑟 @ 4𝑜𝐶 𝛾𝑤𝑎𝑡𝑒𝑟 @ 4𝑜 𝐶
FORMS OF ENERGY
1. Potential Energy
The energy possessed by a body by virtue of its position.
𝑔𝑜
𝑃𝐸2 − 𝑃𝐸1 = 𝑚 𝑧 − 𝑧1
𝑔𝑐 2
𝑔𝑜
∆𝑃𝐸 = 𝑚 ∆𝑧
𝑔𝑐
2. Kinetic Energy
The energy possessed by a body by virtue of its motion.
1𝑚
𝐾𝐸2 − 𝐾𝐸1 = 𝑣2 2 − 𝑣1 2
2 𝑔𝑐
1𝑚
∆𝐾𝐸 = 𝑣2 2 − 𝑣1 2
2 𝑔𝑐
THERMODYNAMIC SYSTEM and SURROUNDINGS
Thermodynamics system or also known as control volume is defined
as a region in space that is under consideration, it also contains mass or
thermodynamic substance. It has the specific boundaries that separate it
from the external effects of the environment.
A system can be anything, for example, a piston, pump, blower,
turbine or compressor.
Wout Win
PE1 PE2 An open or steady-flow system
KE1 KE2 where mass and associated
min mout
energies, including heat and
U1 U2
work crosses the system
Wf1 Wf2 boundaries.
Qin Qout
2. Closed system (non-flow system) are able to exchange energy (heat and
work) across the system boundary not mass.
Wout Win
A closed or non-flow system, only
heat and work crosses the system
min = 0 mout = 0
boundaries.
Qin Qout
Wout = 0 Win = 0
Qin = 0 Qout = 0
Nonflow Process – a process that takes place in a closed system.
Example: compressor
Steady flow Process – a process that takes place in an open system in which
the quantity of matter within the system is constant.
Example: turbine
Mass flow rate going in the system = mass flow rate going out the system
𝑚𝑖𝑛 = 𝑚𝑜𝑢𝑡
m1 = 5 kg/s
m1 + m2 = 12 kg/s
m2 = 7 kg/s
The Continuity Equation
The continuity equation was derived from the law of conservation of mass.
𝑚1 = 𝑚2
𝜌1 𝑉1 = 𝜌2 𝑉2
𝜌1 𝐴1 𝑣1 = 𝜌2 𝐴2 𝑣2
For frictionless flow, t1 = t2
V = A1v1= A2v2
Where:
A = cross sectional area normal to the flow, sq. meter
v = average flow velocity, m/s
V = volume flow rate, cu. Meter/sec.
HEAT and ENTROPY:
Heat – a form of energy associated with the kinetic random motion of large
number of molecules.
Sensible heat – the heat needed to change the temperature of the body
without changing its phase.
𝑸𝒔 = 𝒎𝑪∆𝑻
Where:
Qs = sensible heat
m = mass
ΔT = change in temperature
C = specific heat
Cwater = 1.0 cal/gm C = 1 Btu/lb F = 4.186 kJ/kg K
Latent heat – the heat needed by the body to change its phase without changing
its temperature.
Latent heat of fusion – solid to liquid
Latent heat of vaporization – liquid to gas
𝑸𝑳 = ±𝒎𝑳
Where:
QL = heat needed
m = mass
L = latent heat (fusion/vaporization)
(+) = heat entering; substance melts
(-) = heat leaving; substance freezes
Note:
Latent heat of fusion of ice (Lf)
= 144 Btu/lb = 334 kJ/kg = 80 cal/gm
Latent heat of vaporization of boiling water (Lv)
= 970 Btu/lb = 2257 kJ/kg = 540 cal/gm
Entropy – the measure of randomness of the molecules of a substance.
- the measure of the amount of energy that is unavailable to do useful
work in a closed system undergoing a change of state.
2 PE2
KE2
H2
SECOND LAW OF THERMODYNAMICS
Heat cannot be transferred from cold body to hot body without an
input of work. It similarly states that heat cannot be converted 100% into
work.
The bottom line is that an engine must operate between a hot and
cold reservoir.
Also, is that energy has different levels of potential to do work, and
that energy cannot naturally move from realm of lower potential to a real of
higher potential.
CLAUSIUS STATEMENT
Clausius statement is based from the natural tendency of heat to
flow from high temperature region to low temperature region.
It states that the impossibility of a self-acting device to transfer heat
from a colder body to a hotter body without an aid of external work.
KELVIN-PLANK STATEMENT
A kelvin-plank statement is based on the concept of a thermal
efficiency. It states that a heat engine or similar device cannot be 100%.
It is impossible to construct a heat engine which operates in a
cycle and receives a given amount of heat from a high temperature body
and does an equal amount of work.
𝑅
𝐶𝑣 =
𝑘−1
𝐶𝑝
=𝑘
𝐶𝑣
𝑘𝑅
𝐶𝑝 =
𝑘−1
Where:
Cp = specific heat at constant pressure
Cv = specific heat constant volume
k = specific ratio
R = gas constant
GENERAL GAS LAWS
1. Boyle’s Law
If the temperature remained constant within a closed system, the
volume of the gas varies inversely with the pressure during the change of state.
1 𝑉2 𝑃1
𝑉𝛼 ; =
𝑃 𝑉1 𝑃2
2. Charles’ Law
If the pressure remained constant within a closed system, the volume
of the gas varies directly with the temperature during the change of state.
𝑉1 𝑇1
𝑉𝛼𝑇; =
𝑉2 𝑇2
3. Gay-Lussac Law
The pressure of an ideal gas if held at constant volume is directly
proportional to its temperature at any change of state.
𝑃1 𝑇1
𝑃𝛼𝑇; =
𝑃2 𝑇2
4. Combined Charles and Boyle’s Law
These laws state how one quantity varies with another if the third
quantity remained unchanged, but if the three quantities change
simultaneously, it necessary to combine these laws in order to determine the
final conditions of the gas.
𝑃1 𝑉1 𝑃2 𝑉2
=
𝑇1 𝑇2
5. Daltons Law of Partial Pressure
The pressure exerted in a vessel by a mixture of gases is equal to the
sum of the pressures that each separate gas would exert if it alone occupied
the whole volume of the vessel.
𝑃 = 𝑃1 + 𝑃2 + 𝑃3 … … 𝑃𝑛
Where:
P = total pressure
P1, P2, P3, ……Pn = partial pressure of gases
Partial pressure – the pressure exerted by each gas.
6. Avogadro’s law
At equal volume, at the same temperature and pressure conditions,
the gases contain the same number of molecules.
𝑚1 𝑀1 𝑅1 𝑀1
= ; =
𝑚2 𝑀2 𝑅2 𝑀2
Where;
M1 and M2 = molecular weights
m1 and m2 = masses
R1 and R2 = gas constant
PROCESS
When a system undergoes any changes, it is to have undergone a
process.
CYCLIC PROCESS
- A process which gives the same states/conditions after the system undergoes
a series of process.
QUASI-STATIC
- A process in which system departs from equilibrium state only infinitesimally
at every instant.
THERMODYNAMIC PROCESS
1. Isometric or Isochoric or Isovolumic Process
- An internally reversible constant volume process of a working substance.
a. PV and T relation (V = C)
𝑃1 𝑃2
= ; 𝐶ℎ𝑎𝑟𝑙𝑒 ′ 𝑠 𝐿𝑎𝑤
𝑇1 𝑇2
b. PV and TS diagram
c. Non-flow Work
2
𝑊𝑜 = න 𝑃𝑑𝑉 = 0; 𝑤ℎ𝑒𝑟𝑒 𝑑𝑉 = 0 @ 𝑉 = 𝐶
1
∆𝑈 = 𝑚𝐶𝑣 ∆𝑇
f. Change in enthalpy
∆𝐻 = 𝑚𝐶𝑝 ∆𝑇
g. Heat transferred
𝑄 = ∆𝑈 + 𝑊𝑛 ; 𝑊𝑛 = 0 @ 𝑉 = 𝐶
𝑄 = ∆𝑈
h. Change in Entropy
𝑇2
∆𝑆 = 𝑚𝐶𝑣 𝑙𝑛
𝑇1
2. Isobaric Process
Isobaric process is an internally reversible constant pressure
process of a working substance.
c. Non-flow work
2
𝑊𝑛 = න 𝑃𝑑𝑉 = 𝑃 𝑉2 − 𝑉1
1
f. Change in enthalpy
∆𝐻 = 𝑚𝐶𝑝 ∆𝑇
g. Heat transferred
𝑄 = ∆𝑈 + 𝑊𝑛 = ∆𝑈 + 𝑃∆𝑉 = ∆𝐻
h. Change in entropy
𝑉2
∆𝑆 = 𝑚𝐶𝑝 𝑙𝑛
𝑉1
3. Isothermal Process
A reversible process occurring at constant temperature.
b. PV and TS diagram
c. Non-flow work
2
𝐶
𝑊𝑛 = න 𝑃𝑑𝑉 𝑤ℎ𝑒𝑟𝑒: 𝑃 =
1 𝑉
𝑉2 𝑉2
𝑊𝑛 = 𝑃1 𝑉1 𝑙𝑛 = 𝑚𝑅𝑇𝑙𝑛
𝑉1 𝑉1
∆𝑈 = 0
f. Change in enthalpy
∆𝐻 = 0
g. Heat transferred
𝑄 = ∆𝑈 + 𝑊𝑛
𝑄 = 𝑊𝑛 𝑓𝑜𝑟 ∆𝑈 = 0
h. Change in entropy
𝑉2
∆𝑆 = 𝑚𝑅 𝑙𝑛
𝑉1
4. Isentropic Process
Also known as the adiabatic process in which there is no heat that can be added
or removed in the system. The system is perfectly insulated from the environment. (Q=0)
a. PVT relation
𝑆 = 𝐶 𝑜𝑟 𝑃𝑉 𝑘 = 𝐶
𝑃1 𝑉1 𝑘 = 𝑃2 𝑉2 𝑘 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 − 𝑣𝑜𝑙𝑢𝑚𝑒
𝑘−1
𝑇1 𝑉2
= 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 − 𝑣𝑜𝑙𝑢𝑚𝑒
𝑇2 𝑉1
𝑘−1
𝑇1 𝑃1 𝑘
= 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 − 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒
𝑇2 𝑃2
b. PV and TS diagram
c. non-flow work
2
𝐶
𝑊𝑛 = න 𝑃𝑑𝑉 𝑤ℎ𝑒𝑟𝑒: 𝑃 =
1 𝑉𝑘
𝑃2 𝑉2 − 𝑃1 𝑉1 𝑚𝑅 𝑇2 − 𝑇1
𝑊𝑛 = =
1−𝑘 1−𝑘
d. Steady flow work
2
𝐶
𝑊𝑠 = − න 𝑉𝑑𝑃 𝑤ℎ𝑒𝑟𝑒: 𝑉 =
1 𝑃𝑘
𝑘 𝑃2 𝑉2 − 𝑃1 𝑉1 𝑘𝑚𝑅 𝑇2 − 𝑇1
𝑊𝑠 = =
1−𝑘 1−𝑘
𝑊𝑠 = 𝑘𝑊𝑛
e. Change in internal energy
∆𝑈 = 𝑚𝐶𝑣 ∆𝑇 = −𝑊𝑛
f. Change in enthalpy
∆𝐻 = 𝑚𝐶𝑝 ∆𝑇
h. Change in entropy
∆𝑆 = 0
5. Polytropic Process
A process that obey the thermodynamic relation 𝑃𝑉 𝑛 = 𝐶, where n is the
polytropic exponent and C is constant.
a. PVT relation
𝑃1 𝑉1 𝑛 = 𝑃2 𝑉2 𝑛 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒 − 𝑣𝑜𝑙𝑢𝑚𝑒
𝑛−1
𝑇1 𝑉2
= 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 − 𝑣𝑜𝑙𝑢𝑚𝑒
𝑇2 𝑉1
𝑛−1
𝑇1 𝑃1 𝑛
= 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 − 𝑝𝑟𝑒𝑠𝑠𝑢𝑟𝑒
𝑇2 𝑃2
b. PV and TS diagram
c. Non-flow work
2
𝐶
𝑊𝑛 = න 𝑃𝑑𝑉 𝑤ℎ𝑒𝑟𝑒: 𝑃 = 𝑛
1 𝑉
𝑃2 𝑉2 − 𝑃1 𝑉1 𝑚𝑅 𝑇2 − 𝑇1
𝑊𝑛 = =
1−𝑛 1−𝑛
d. Steady flow work
2
𝐶
𝑊𝑠 = − න 𝑉𝑑𝑃 𝑤ℎ𝑒𝑟𝑒: 𝑉 =
1 𝑃𝑛
𝑛 𝑃2 𝑉2 − 𝑃1 𝑉1 𝑛𝑚𝑅 𝑇2 − 𝑇1
𝑊𝑠 = =
1−𝑛 1−𝑛
𝑊𝑠 = 𝑛𝑊𝑛
e. Change in internal energy
∆𝑈 = 𝑚𝐶𝑣 ∆𝑇
f. Change in enthalpy
∆𝐻 = 𝑚𝐶𝑝 ∆𝑇
g. Heat transferred
𝑘−𝑛
𝑄 = m𝐶𝑛 ∆𝑇 where; 𝐶𝑛 = 𝐶𝑣
1−𝑛
h. Change in entropy
𝑇2
∆𝑆 = 𝑚𝐶𝑛 𝑙𝑛
𝑇1
GENERAL EQUATION FOR THERMODYNAMIC CURVES
The general equation of any process is
𝑃𝑉 𝑛 = 𝐶
If;
n = 0; isobaric process
n = 1; isothermal process
n = k; isentropic process
n = −∞ 𝑡𝑜 + ∞; polytropic process
n = ∞; isometric process
7. Vapor is the term given to a gaseous phase that is in contact with the liquid
phase.
ex. Steam
15. Critical point is a point that represents the pressure and temperature at
which liquid and vapor can coexist in equilibrium
-end-