; R. K. MALIK'S raitramanovs,neorca son, non kar NEWTON CLASSES Enjoys unparalleled reputation for best results in terms of percentage selection www.newtonclasses.net ELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS] a amp, Wta = 27.0 g wil 27 gmequt,, (i) gm eq of Al= =3 Ans (..v.f. of Alin Al + 3c" Al= 3) 21 wt Gii) no. of gm atoms = no. of moles —— Ans ii) no, of atoms = no. of molesx Avogadro's no. 1 x6.023x 10" = 6.023 10" Ans Gv) no. of "required = 3no, of atoms deposited = 3 Avogadro's constant (v) no. of Fareday of electricity consumed = no. of gmeq = 3 Fareday Ans. (vi) W217 9 27 0.5% 16500 3 24%96500 BV = 6x96S00see = 6*96500see = 522000 _ teohrs3%6omn 3600 = 160 hr 49.8 min Ans (vii) gm eq of Clz produced = gm eq.of AL 33.6 lit Ans 2 np. Mass sigreases by 8 g ; 50 wt of Cr deposited = 8 g 5g = 35 x axt 96500 896500x3 S22 2269.23 see = 6.186 hr Ans .2 amp hr = 3600 sec (a) it w is the wt of silver deposited, then (umeg wt; 96500 7 Atwtof er Cr" #3C" > Cr gmegwt=: WHZLt Batt Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0661-2682623, 9635608812, 7546846949 NEWTONCLASSES.NETR. K. MALIK’S NEWTON CLASSES 108/ W= —41. 0.23600 = 0.8062 96500 Ans (b) no, of e” = no. of moles of ex Ny =no. of moles of Ax deposited xN, Ag +e Ag (1 mole of Ag is deposited by 1 moles of e') 0.806 108 (c) gm eq of Cu deposited = gm eq of Ag deposited Weu _ 0.806 57 108 6.02310" e° = 4.49x10"e Ans = Wen =0.237g Ans Q4:- Sol:- W=0.5 9; 96500 No.of eoulombs = 25% 76500 cotamb = 44,676 coulombs Q. _ 446.76 96300 96500 Vy 447.76 molar volume a 2 [For H3. eq. volume = —————] _ molar voue 96500 Oi Hassel 7! Gm eg. of Hz produced = «tevin Vit = 464s to alarvolume 0.0821 300 750 760% 2 = 0.0578 lit=57.8ml Ans = 4.64 10°x 0) Sol: H,0 —> H; —> N EL uno. NH; + HNO;——> NH,OH . Weight produced of NHJNOs per day = 5000 kg Sx10F 80 Moles of NH; & moles of HNOs. each should be 6.25% 10" moles/day NH; & HNO3 6.25 10° 6.2510" So moles of hydrogen atom = 3x moles of NHs + 1xmoles of HNOs 3%6.25 «108 + 1x6.25x 10" = 46.25% 10" Moles of NHiNOs produced per day Office.: 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2835608812, 7546845949, NEWTONCLASSES.NETELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS} 4x6.25x10" moles of H: produced = 9-2 10 2.5% 10" . moles of e-required per day = 2xmoles of Hi produced Sx 10" charge required per day = 25x 10'x96500 current per.day = 25%10°*96500 _ > 295.16 amp/day 4 243600 ave Q6: ‘Sok From Fareday’s second law Wan = Mew We. = 4.7625 g Ans, Also gm equivalent of substance deposited = no. of Fareday 0.15 = no. of fareday 153600 96500 O1S= 0.15%965 180 0.804 "Ans Qn Sol hy + 28:0 2F + 8,08 Milimole of = 2 milimoles of Sy 2xmilimole of ly = milimoles of $:0+ milimole of ly = 21:75%0.0851 _ 9 937 -nilimole of e emitted out = 0.9037%2=1,8074 Charge flown = 1.8074% 10 96500 t= 1.8074.-.96.5 5 0.0242amp Ans 2+ um eq of Cr deposited = ym eq of Clp produced = no of faraday 6x 1x3600 _ 96500 No. of faraday passed = 224 ‘ er gm eq, of er deposited = —“" = 0.024 Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCR. K. MALIK’S NEWTON CLASSES gm eq of Cl; produced = 0.024 ¥ Egvolume Ans Qa Sol:- O2 in second cell has produced due to oxidation of oxygen present in water. 20° —30, +4e" At anode in 2" cell oxidation happen, so wt of anode won't change in 2" cell, In 2" cell Wa ._¥! WaAg(produced) So wt of cathode will ase by 0.772 g. In 1" cell 7) Again Cu™ will reducesat-cathode, so Wt of cathode will increase & at anode Cu will oxidise to form Cu™, so'wt of anode deceases. Also. Weu _WAg __16 Ecu EAg 2240 lO 935" 9 34 ech 2240 2 At cathode. 0.227 g Cu deposit. so wt will increases At anode, 0.227 g Cu oxidise. so wt of anode will deceases Q10:- Weu= Solr Wy. 100% 12x 3600(eg wt of water= =4024g =403¢ Ans 1= 1.30 amp t= 5 hr = 5x3600 sec H0—n, +40, 2H" + 2e° 3 Hy 20” —+0, +4e Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS} WH) = 2H. | _1.35%3600=0.244g Ans 96500 8 Molwt Wor = Zor. Lt = —S—x1.3%5%3600=1.942 Ans { egavtof 0. or Bon t= Feo ‘ + (somo 4 ) My X22.4 lit 22.4 lit = 2.7331it Ans VO = n022.4 lit = #29. 41it =1.358lit 32 Ans Qi: Sol:- Wiz = Z2.Q -(I) Zor.Q— (2) wow, _smeawtorH, mole wt 2x 96500 —2__ sy, -— 2 x 22400mt 96500%2 565002, Gmeg.wt0, 96500 Mol.wt0, xQ= MOM: BQ, 96500 x4 -_ 2 no, = 2 “ 96500x4 22400 96500x4 Qx2 22400 96500%2 * 96500%4 & Voz = no*22400 ml = Alq. Vy, +Vo, = 16,8~ -2-(112+56)=2 «168 965 965 = 268X965 «96 5coulomb 68 Ans Surface area = 800 cm? 1 = 0.2 amp for t= 3hr = 33600 sec Let times the thickness of Ag deposited, then it will happen on the one side of plate Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCR. K. MALIK’S NEWTON CLASSES Volume = At = 800xt cm* = 800 tem’ dAg= 10.47 glee mAg = dAg.VAg = 800tx 10.47 = 8376t A mAg=ZAgIt= —ALx3x3600x0.2 96500 : 108x108 2 7 12.087x2. 965 10 _ 12.087 2 8376 10 Thickness of Ag deposited in the vessel = 2.88 x 10% cm, Q14:- Sol:-1= 0.5 amp 1= 12 min & 20 see = 1260 + 20 = 740 sec Vix collected = 50 ml T=23°C =273 +23 = 296K 740mm P= 740 mm of Hg = 760mm 8376 © PV=nRT No. of moles of H evolved = 4/78 59107 0.0821 296 Charge transferred 0.5740 = 370 coulombs . Charge on single e = 1.6x 10°” coulomb. 370 ———, = 2.312510" 16x10" So no, of e” transferred = Also 2H" +2e°—> Hy moles of e'required to transfer = 2x moles of H evolved x2x107 2.3125x10" 4x10? 78x10" Ans 5 ame, t= 20 min = 20.60 = 1200 see i) Wey = #6u.lt 63.54 5 = —2.x0.5x1200—25_ x19 = 0.1975 9 96500 296500 2 0. 1975 =xN, = 1.87% 107 63.5 2) no, of Cu atoms deposit Qt6:- Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS| I mole of e’ has charge = 96500 coulomb Time = Ihr = 3600 sec Sol:- 1=3 amp Wt of water decompose = 18 g Wa. = Zuo-4 1g 96500%2 x3%t A see = 64333,33sec=17.89 hi 3500 7 see 3,33sec=17.8' hae 18= Qus:- Sol:- 50 ml of 0.1 M CuSO, Time = 12 minutes and | = 0.06 amp. No. of moles of O2 produced (1): 2Hy)O0 —> Cy + 4H" + de 10.0f faraday of charge vf. 1 «From reaction (1) Moles of H” produced = 4 xno. of moles of 2 produced = 4x 1.12% 10 = 4.48% 10% 8.96x10"°M. molesof Cudeposited (. motesof SO, = motor Cu” removed from sol") Volume 0.06% 1260 _ 2.2410" a 5 = a8 10M, 2° 96500 350x107 50x10* Now HSO,’ a=" H’ + $0," ; Ka= 1.3210? oH + S04" =——=+ HOF; Ka= Initially 8.96x10°M 4.48x10°M 0 4.48% 10° M 0 4.42 10" (since Ka= 10° So reaction is assumed to 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONCR. K. MALIK’S NEWTON CLASSES constrat) Pt =—logH” ~log(4.48x10") = 25: ClOs + 1x0 —> ClOy + 2H" +2e i) To, produce 1 mole of ClOu', 3 mole of "are required + no, of Faraday for production of | mole of NaCiOy = 2F V, Woe, es Exo, eB VolH, 12.25 __VH, (i> Sol:- (i) In cell A: AgxSO, solution, so we have ions Ag’ & H’ for reduction at cathode Since Hg* has higher reduction potential, so it will reduce first At cathode Ag” +e” > Ag At anode, SO,” & O* ions are for oxidation since reduction potential of Sou” is higher, so 0* will oxidise first. So At anode: HO —+02 + 411" + 4e" Incell B: At cathode ; Cu?* + 2c’ —> Cu (again Cu?" has higher R.P. than H” so reduce first) At anode: Cu Cu’* + 2¢" (In presence of Cu electrode, we will oxidise as well as reduce first) \ War aaa Was Egwtg, EgwiAg Egwicu 16_ Wa 8 1087 W,, deposited =21.6g Ans Wo, deposited= 0.233 =6.35y 2 Ans 100 ml, M = 0.8 M CuSo, solution tinie = 30 min with current | = 5 amp 63.5f Wt of Cu deposited = ——42.x5x30x60 (W=Z.L.t) 96500 2.96 g Initially the wt of CuSO, in sol-" = 100 10" x0.8x 159.4 = 12.76 g Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS| 2 Wt of SO,” combined with 296 g of Cu = (23 es 3 4 wt of CuSO, demaining in the sole" = 12.76 - (2.96 +4.37)=5.31g Ans | amp. t =60 min = 60x60 sec Cull + 30,—c,Ho, +H,0 Meso Eq. wt of CutO, = MOM exwof CHO, , Wr deposited = 96500 13600 Bs ss = giogg00 20007129528 Q23:- Sol:- CsHsNO»———> CcHsNH> 20g (V.f=6) Current passed = 26.5 amp —hr It w is the oritical wt produced, then WHZlt 3 _93*26.5%36 6 F 6x965 96500 265% 3600 Actual wt produced = 12.76 g wtactually produced 155 _ mo 100 = 83.28% 3 Ans Current yield = Q24: Sol:- Wt of Cu deposited = 0.2964 g I= 0.5 am for & 30 min = 30x60 sec WHZLt => 0.2964 = SRE 69 53060 96500 Auwt 189) 64 = Aixt 189(gmeq tot Cu= miwt 2x965 2 965 4 = 63.565 ‘Ans Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCR. K. MALIK’S NEWTON CLASSES Ifwt of Cu deposited = I ky = 1000 g Then = W100 - Zu 0.00033 Cost of electricity = 0.25 Rs per Kwh. 3x10" coulomb: Int Kwh, E= 110° 3600 see = 3.6% 10°J sec Now, QV = _ E_ 36x10 Q ¥ 02 8x10" coulomb cost 0.25 rupees 8x10" colomb 0.2Siupees “18% 10" 0.25x3%10" _ 0.25 18x10" 3x10" =0,0416rupees = 4.16 paise Ans At anode: 2H,0—+ 0; + 4H" + 4e° ) No, of moles of H” present = Molarity x volume (in lit) 0! «50x10 = 5x10" No. of moles of ¢” required = 5x 10"? (From reaetion( 1)] ©. Change required = 5» 10°!" 96500 coulomb > 0,5*t=5* 10" 96500 me tn SIE 96500 0 96 ssec $10 Ans Q27:- Sol: V = 8.2% 10? lit= 8.2% 10" mL Rate of charge production = 1.5 10° coulomb per sec Density of water = Igm /ec Mass of water = vxd => 85x10 g = ———S x1 Sx 10*xt xO we pe BSHIOZ42 96500 A 18x1.5%10" 68710" hr = 7.03% 10" days = 1,925 10° years = 1.925 million years = 6.0710" sec Q28:- Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS| Sol:- Energy delivered per sec = 200 I/sec : ste E Charge delivered == ange delivered per see = > == At. cathode : Ni?” & HO ions are present, but Ni?" will reduce because it has higher reduction potential So at cathode: Ni** + 2e° —> Ni At anode: SO,” & H,0 are present to oxidise in the HO will oxidise first because of less reduce potential At anode : 2H,0 +0, + 4H" + 4e" (ii) no. of columbs passed = 0.05x40x60= 120 Ans (ii) Was = 2Nitt ~ 87329 = 0.0378 2x 96500 Ans (iv) moles of Ni present = 40x 107x0.125 = 5x 107 I © 296500 = 5x107°x2x 96500 965 0.05 0.05 (¥) wt produced at cathode = nNix At.wt. 5x 10"x $8.7 = 0.293 g yi 0.05% 1930s Wt produced at anode :~ Wo, = Smca.mof O, 96500 = 8, 19300%5 96500100 %0,05%19300 08g Wa _ Wow 1.307g __Wew Egwt,, Egmt 1 _63.5%1.3078 ‘2108 Now wt present initially = (moles of CuSOy. SH20). At wt cu to = x 635y = 2.545 2a95 8 e > 384g, Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCR. K. MALIK’S NEWTON CLASSES ". Amount of Cu remained in the sol-” = 2.545 g~ 0.384 g= 2.16 g wt of Cu/lit present now = 2 1000 =4.32g/lit Ans gai Sol:- Volume of H2 reacted at STP — 67.2 lit 22.4 lit Vek, = SmeaoFH, 96500 Win = Molwtof He vx 96500 z 296500 2x! 32x96 708 6st an 15x60 Ans WCu = Ze€u.Lt 63.5 = > x643.34x15%60 = 190.5 g Ans 296500 it x1x15%x60 Wt of Pd” deposited = 2.977 Woa = Zag tt 2.977 = SMES WPS 51 «3600 — 106.40 1x 96500 106.40%108 _ 2.977%965 Ans 3%3600 Q33:- Sol:- Wy = Zyl t= 2.Q 37.7 g= —M — x69500 3x 96500 9653%37.7 157 og 695 Ans Q34: Sol:- Total wt precipitated = 0.175 g % of Cu ppt = 72.8 % 28 Wr of cu ppt = 0.175x-——= = 0.1274 u ppt 100 8 Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS} % of Ni precipitated = 4.3% 43 2 Wt of Ni ppt = 0.175x—— = 7.5x10 Pp 100 8 % of Zn precipitated = 22.9% 22.9 Wt Zn precipitated ~ 0.175 x57 = 0.088 For Cu For Zn Wan = SmeeofZn 9 96500 1 Qan = 204%26500 119 94coulomb _ 0.1274 96500 Qeu= —3a 5 193.6colomb /I For Ni must riegol i @ total = QCu(l) + ON + On = 193.6 + 24,66 + 118,04 =336 coulomb Ans Q3 Sol:- WMg = ZMg.Q 24 5. 2Y 1x 10°g= x * 1B S500"? = 129508 0410" coutom ray required = QV = 8.04 10°x5 = 4.021 x107F In 1 Kwh = 1 103600 J = 3.6% 10°) no. of Kwh= 224*10 11 6 kwh Ans J, 941236004055 x1.2x3600_ 96500 Ans 96500 Wo, _ WAL ©, wo, 0403, eqwtO, eqwtAl 9 Now, 32 g of Opwill form 44 g of COr a 32 8= 0.3588 Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCR. K. MALIK’S NEWTON CLASSES 440.358 3p 8 70.4924 Ans > asta =2(4) la Cell constant = 0.728 cm! Ans Q38: Sol:- K = 1.342 mho m’' = specific conductance 70.5 ohm a= 1.86% 10m? 14 c ——mho 170.5 1 1 1 Also Kk = C{+] => 1342= x 1 a 170.5 1.86«10 1= 1.342% 170.5% 1.86% 10% 1=4,206x10?m Ans + Distance between two electrodes Q39: Sol:- Rx = 45 ohm & Ry = 100 ohm cet acg=t Rx Ry When equal volume of X & Y are mixed, then no of electrolyte per unit volume becomes half & so.conductivity in final solution will be Cy = = 0.016 mho Ans 2 45/2 100 ) L.x153.7 = 0.295 mbo m',= 2.95% 10" mho em! 520 Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS} *1000 =115mhocm? Ans Sol:- K = 0.0227 mho cm"' = 2.7% 10" mho cm volts I= 2xr=2. «0.01 om=2x 107 em a= mrl=25%3.14x10%em? =K=c( hee) ay 2.7107 253.14 x10" 2x10" C= 1.059 10" mho 1= CV = 1,059x10"x2=2.1310% amp Ans Q42:- Sot:- 4°C,H,COONa = 83mhoem?, “NaCl = 127 mhocm? =C AHCI = 426mhocm? 4°C\H,COOH = A°C,H,COONa + 2% ye, 2 ect 83 4426-127 =382mhocm* Ans 73.52 a 96500 x £2 457<10"'cm/see 10 distance in 2hr = V,, t= V,.x2x3500see =4.57x10" x7200=3.29em Ans Atcone —"0.0128N of CH,COOH 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONCR. K. MALIK’S NEWTON CLASSES Acucooy =14mhocmeg" + 2¢,,coon = 39 mhoem? eg CH;COOH == CH:COO” + HY 0.0128 M 0 0 0.0128(1-a) 0.0.128.4 0.01280 “Ka = 0.01280)" © G.58x10" «0.0128 0.012802) 0.0128(1-3.58x10") _ B.58x10" x0.0128)" _ 0.0128% (3.58107)? ~~ 0,0128x0.996 0.996 Ka=1.647x107 Ans 45 Sol:- Specific conductance of AgCl = 1.828% 1 K ge) = 1.82610 mhoem™ Aggy =138.26 mhoom? AgCl === Ag'(aqs)_ + Cl(aqs) For S be the solubility of AgCl Ksp = [Ag’] [CI]=S.S=S? +S will be the mole / lit ions present in the solution, Also since Ag’ & CI’ have 1 unit charge as it. So mole / lit will be equal to eq / lit +. X eg of ions present in 1 lit of sol-” 1000ml x /-Axge)= Sp. conductance * volume containing 1 ¢q = 1.826% 10781008 Xx Also AgCl is spairingly soluble in water. s0 Anger ® A nge, (C= V dilution doesn’t effect much). 526 x 10* 1826010" 2138.26 326 x10 138.26 +. Solubility in g/lit= 1.32 10%% 143.5 =189x107 g/ lit Ans =1.32x10°M. =0.58« 10 mhocm™ Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS} 2° ¢ =330mhocm*; 2”, =198mhocm? Let H20 dissociates to give x mole / lit of | H’ & OH ions. The same amont of H" & OH" will be present as eg / li So, H* = x eq/lit & OH" = x eq/lit ‘ 7 1000 Volume contain I eg of H* or OH = ——ml x eg conductance of water = sp. conductance x volume contain ! eg of ions = 0.58% 107 x 0% x Since dissociation of HO doesn't change by taking less on more amount of water. $0 Ayo =Aior Ait Aig = 350 + 198 = 548 1000 0.58 107 x——— = $48 x 5.8%10" 548 Cu 63.5g =1mole For deposition of 1 mole of Cu, 2 mole of e's are required no. of e's = 12,044% 10" Q3:Ans: (¢) We Rea QCFist law) % = “A, (2nd law :E, & E, areeg.wt.) Q4: Ans: (b) gmeg.wt 96500“? 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONCR. K. MALIK’S NEWTON CLASSES WwW Q =—9_ =) = Q = 96500 cou Gmequt 7565007! “79 96500 coulomb QS: Ans: (b) W=2-Q =>%=mx 10" Q7: Ans (b) WZ. Q 96500 Q8: Ans (d) w = Sed 9.196500 96500 = noof faraday = Bs =I 7 Spy 7 Bmee wt gmegq wt=31.7 Q9: Ans (b) o.1og = Smet %0.5x193 0 gmeq wt= 108 g QUO: Ans (c) pi is increased, so OH" cone-" increases at anode Also, At anode, oxidation will happen & CI’ will oxidise first than the OH” ion cl In } CT will oxidise because it has less reduction potential on, Atcathode in H’, K’~»H" will reduce because it has high reductiog pot. :. KOH remain in sol-", so pH increases QI1: Ans (4) Using Cu electrode, at anode: Cu —+ Cu” + 2€" ‘So-same amount of Cu will 0 into the sol-” as the amount of Cu deposited at cathode. Q12: Ans (d) 5101 1 =965amp G’ per sec = 1 = 10" lo _ 10" no of "passing per sec = 12 = 10 peer 16x10" 1.6 Q14: Ans (c) Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS} Ag’ te-——>Ag 107.9 gm=1 mole 1 mole deposition will require | mole of e” QUS: Ans (c) WeZit q.wtof tin 96500 118.7 10 x96500 1187x36 n= Ss 965x 22.2 Q46: Ans (b) 1 Kwh = 1x10" J/s «3600 = 3.6% 105) Q in (Shr) = 8x 3600 15 = 4.32 10° coulomb: E = QV =4.32x 10x 110 = 4.752% 10" J 3.6% 10° H cost 5 pa 3 3.6x10° 22g x2x53600 *10*3600 2Ans 5x4.752x107 36x10" = 66 paise £4,752 10", Q17: Ans (a) | faraday will deposit eg. wt of each metal For Ag”. €q. w 18-1082 For Au", eq. wt= 384 _59.59 For Cr’, eq. wt= 2 14 Q18: Ans (c) 1 1 0.02 ; 7 moles of Ag= 7 %0.2x0.1=——= gm eg of Ag” because v.f= |) meq of A It = 1 265002107 smeq oF AB * 96500 e107 SLLGmin - 59 minutes Q19: Ans (¢) (1) 2H:$0, —+ 1810, +H (2) 2H,0 —> 2H: +O, Office.: 606 , 6" Floor, Hariom Tower, Circular Road, Ranchi-1, Ph. 0861-2662623, 9636608812, 7546846949, NEWTONCLASSES.NETR. K. MALIK’S NEWTON CLASSES 2.35 lit Volume of H; librated from reac~" (2) = 22.35 lit 47 lit Volume of Hz evolved from reac-" (1) = total volume evolved — volume of H; liberated from reac-" (2) =9.72-4.7 = $8.02 lit Now for reaction (1) €q of Hz evolved from reac-" (1) = gm eq of H2S;0x produced 2% ~ Gmeq.of H,S.0, produced. 1: 0.448 = gm eq of HiS:0x produced, Q20: Ans (d) ‘gm eg of H2 evolved = gm eg of evolved Vo, Vo; cgvoll, eg.VolO, 224, 4 it @ VO; = 5.7 Jit Q21: Ans (a) 10'* xt=96500 col. (change on | mole of ¢') t= 26500 9.6510" see 10" Q22: Ans (a) 18/ pea x3nt 96500 ae 96500 2sec St =18hr Q23: Ans (a) At Pt cathode Ag’ will reduce first Ag’ +e ——> Ag. but at Ag anode, the same amount of Ag will oxidise to produce to Ag". Ag— > Agi +e So the amount of Ag” in solution doesn’t change effectively Q24: Ans (a) For alkali metal & alkaline certain metal fused salt electrolysis is the way to get metal. Q25: Ans (d) Ag” has higher reduction potential than H” so it will reduce first so H» can’t produce similarly NOy will oxidise first because it has lower reduction potential. Q26: Ans (a) Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCELECTROLYSIS & ELECTROLYTIC CONDUCTANCE [R C MUKHERJEE SOLUTIONS|___21 pH won’t change if H,0 will reduce & H20 doesn’t oxidise.’ Which will happen increase of AgNO. : Ans (c) Ans (d) . K=C (Y) Specific conductance = conductance xcell constant : Ans (a) 4g = %1000 A,, ‘will be lowest if N is maximum : Ans (d) Ay = S100 “ON For 1 eq present in lee _ Kx1000 _ = "1000 Also for bec, Y= Vy =1-.C=K : Ans (b) }: Ans (d) 1 ForN/). Normality = — orig. Nommality = For | eg-", 10 lit of sol-" require V=10 lit= 10.000 mi : Ans Axes = Acicoone + Artes ~ Acn,coon = 91 +426-391 =126mhocm’ Ans N +1000 = 1000 => 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONC