R. K. MALIK'S JEE (MAIN & ADV.), MEDICAL + BOARD, NDA, IX & X NEWTON CLASSES Enjoys unparalleled reputation for best results in terms of percentage selection www.newtonclasses.net CHEMICAL EQUIVALENCE [R C MUKHERJEE SOLUTIONS] In FeCh, Iron is in Fe” state. Atwt _ 56 ee Q2: Sol:- Eq. wt of oxide = eq. wt of metal + eg. wt of oxygen 2+8=20 [Since eq, wt of compound = (e9.wt of cation + eq. wt. of anion Q3: Sol:- From law of gram equivalence For Oxides gm €q. of cation = gm eq. of anion g meq. of metal = gm eq. of oxygen =i275_1 8 4 Also for chloride ‘gm eq. of metal = gm eq. of halogen Al 37 40 eqwiof balogen eq, wt of halogen = 404271 Q4- Sol:-In first oxide ‘gm eg. of oxygen = gm eq. of Arsenic 100-" S52) 65.2 ( 8 eq.wtof Arsenic ~. eq. wt of Arsenic 15 g Ans In 2™ oxide gm eg of oxygen = gm eq, of Arsenic aS 15.7 ° ‘equwtof arsenic 75.7x8 29. = 49g a 9. wiof Arsenie= —S77==249g “a8 Metal oxide + Ha —> Metal From law of chemical equivalence. gm eq, of metal oxide = gm eq. of Hz 306 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.; 0651-2662623, 9835608812, 7548845949 NEWTONCLASSES.NETR. K. MALIK’S NEWTON CLASSES 180833 eq. of oxide 11200 Metal nitrate—> Metal chloride 2g 2.66 gm From principle of chemical equivalence ‘gm equivalent of metal = gm équivalent of chloride 2g 2.66g eq.wtof metal eq. wtMetal chloride {2m _/ __2.66g eq.wtof Metal eq. wt of Metal +eq, wt of chlorine 2g _ 2.66 E E+355 (Let eq. wt of Metal = E) (2.66.2) B= 235.5 3.782 = 107.55 g Ans Ql4:- Sol:- BaCl, ——+ BaSO, 2gm 225g gm eq. of BaCl, = gm eq. of BaSO,, 2g 2.258 eq.wtof BaCl, eq.wtof BaSO, If E is the equivalent weight of Ba, then 2 _ 225 E+355 E+48 2.25E+2.25x35.5=2E+96 > SBI S 6g Se Ans Qis:- Sol:- Metal chloride cuntains 47.23% of Metal + +, 100 gm of Metal chloride contain (100 ~ 47.23) gm of chlorine In any compound, from principle of gm equivalent; gm equivalent of cation = gm eq. of anion.CHEMICAL EQUIVALENCE [R C MUKHERJEE SOLUTIONS] 47.23g _ 52.77g eq.wiofM 35.58 eq.wtof M = 4223%35:5 91 979 $2.77 M+ compound —»N Tm 088 g From principle of chemical equivalence gm ~eq of M= gm eq of N Ig __(0.88g eqwiofM eg.wtofN eq. wt of N = 0.88xeq. wt ofM = 0.883 1.77 = 27.96 g Ans Qi6: Sol:- 0.5 lit of 0.01 M Cu (II) Sol-" moles of Cu(II) =0.5x0.01= 5x10" ©. moles of Cu (II) = moles of CuSQy.5H:0 = 5% 10" weightof CuSO,.5H,O 18x5+96+63.5 Wr of CuS0..5H,0 = 1.248 ¢ Ans = 5x10" +5 “1 +6 SO; +HCIO;—> HCI + $0,” Note v=? 169. gm (only one oxidised state possible for SO2 because s has only- atNTP v.f=6 2, 0, 2, 4, 6 oxide state possible) V.f=2 From principle of chemical equivalence gm eq. of SO» = gn eq. of HCIOs VSO, _ 16.9. 4, % VSO, =13.44lit Ans Qi8; Sol:- -2 +7 +6 +4 HyS + KMnOs—>K;SO,+ MnO; wt? 632g vf=8 vf=3 From principle of chemical equivalence gm eq, of H2S = gm eq of KMnO, “wt _ 6.32 TY Wt= 0.511 gm Ans 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONC6 R. K. MALIK’S NEWTON CLASSES Q19:- Sol:~ CsHig Os + KOH —> complete neutralisation lem 0.768 viel Let n is the no. of ionisable hydrogen in it gm eq. of CoH Os — gin eg, of KOH 9.763 | stancy factor of C,HyO, =n) + 0.768146 n= se Ans Q20:- sid SoR.A 0 45 2 SZn+ V2.0; —> Séno + 2V° “Reduced So0A Vf=2 Vf=10 Wtin 1 gm-equivalent of R.A = eq. wt of Zn vi =32.7 gm Wein 1 gm equivalent of 0.4 = eq, wt of Vs _ Molwt vi +80 an 47 +6 (1) KMn0, —> Mn"! (2)K2Cr:0; — 21 V.f=5 V.F=6 47 +5 1 +5 “1 (3)KMn0,—+Mno, | (4)KIO;—>r | (5) KCI0; —>-cr Vt=3 Vi=6 V.f=6 Eq, wt. ineach case = Molsttof compound valancy factor Calculating for each one- (1) eq. wt=31.6g (2) eq. wt= 49. gm (3) eq. wt= 52.67 gm (4) eq. wt = 35.67 g (5) eq. wt = 92.67 g + KCIOs, KMnOy, KIOy, K:Cr0;, KMnOg <0) <@ <@ <@) Office.; 606 , 6” Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0861-2662623, 2895608612, 7546845949, NEWTONCCHEMICAL EQUIVALENCE |R C MUKHERJEE SOLUTIONS] Q22:- Sol:- HyPO, + OH —>H,POy + #20 w.f=1) eg. wtof Hypo, ~ Mobwtof H,PO, VE H,PO, + 20H’ —> HPO,” + 2H,0 Mol.wtof H VA HPO, + 30H’ —+PO,* +3H,0 (vf=3) eq, wt of HsPO.= .¢9, wt of HPO.= Mol.wtof HPO. Bene nal 3 23:- Sol (a) SO» + 2H:S = 38 + 2H,0 (v.f= 4) equwtofso, = MolwrofSO; _ 64 4 4: (b) 580) + 2KMnO, + 2H:0 = K,S05 + 2MnSO, + 2H:S0. (v.f=2) cq, wt of 0, ~ Molto SO, :. no, of equivalent = no. of moles xv. = 1x6 =6 Ans 06 , 6 Floor, Hariom Tower, Circular Road, Ranchi-1, Ph.: 0651-2662623, 9836508812, 7546846949 NEWTONC