k1 ≔ 0.1 k2 ≔ 0.01 k3 ≔ 0.09 k4 ≔ 0.

009
 k1 ≔ 0.1 k2 ≔ 0.01 k3 ≔ 0.09 k4 ≔ 0.009

d
―― y ＝ -k1 ⋅ y + k2 ⋅ z f ⎛⎝x , y , z , w⎞⎠ ≔ -k1 ⋅ y + k2 ⋅ z
dx

d
―― z ＝ -⎛⎝k2 + k3⎞⎠ ⋅ z + k1 ⋅ y + k4 ⋅ w g ⎛⎝x , y , z , w⎞⎠ ≔ -⎛⎝k2 + k3⎞⎠ ⋅ z + k1 ⋅ y + k4 ⋅ w
dx

d
―― w ＝ k3 ⋅ z - k4 ⋅ w p ⎛⎝x , y , z , w⎞⎠ ≔ k3 ⋅ z - k4 ⋅ w
dx

⎡“ k ” “ x” “ y” “z” “w” ⎤
⎢ 0 0 1 0 0 ⎥
⎢ ⎥
⎢ 1 5 0.61463047 0.3041607 0.08120883 ⎥
⎢ 2 10 0.38708794 0.3789391 0.23397296 ⎥
⎢ 3 15 0.24963188 0.36154799 0.38882013 ⎥
⎢ 4 20 0.16474399 0.31430622 0.52094979 ⎥
S_Ec_D ⎛⎝f , g , p , 0 , 1 , 0 , 0 , 50 , 5⎞⎠ = ⎢ ⎥
⎢ 5 25 0.11123969 0.26369857 0.62506174 ⎥
⎢ 6 30 0.07689958 0.21956917 0.70353124 ⎥
⎢ 7 35 0.05451459 0.18440641 0.761079 ⎥
⎢ ⎥
8 40 0.03973331 0.15772929 0.8025374
⎢ ⎥
⎢ 9 45 0.02987054 0.13808313 0.83204633 ⎥
⎢⎣ 10 50 0.02323498 0.12389041 0.8528746 ⎥⎦ Ca ＝ 0.02323498

nf ≔ rows ⎛⎝S_Ec_D ⎛⎝f , g , p , 0 , 1 , 0 , 0 , 50 , 5⎞⎠⎞⎠ = 12 Cb ＝ 0.12389041

k ≔ 1 ‥ ⎛⎝nf - 1⎞⎠ Cc ＝ 0.8528746

⟨⟨1⟩⟩ ⟨⟨2⟩⟩
x ≔ S_Ec_D ⎛⎝f , g , p , 0 , 1 , 0 , 0 , 50 , 5⎞⎠ y ≔ S_Ec_D ⎛⎝f , g , p , 0 , 1 , 0 , 0 , 50 , 5⎞⎠
⟨⟨3⟩⟩ ⟨⟨4⟩⟩
z ≔ S_Ec_D ⎛⎝f , g , p , 0 , 1 , 0 , 0 , 50 , 5⎞⎠ w ≔ S_Ec_D ⎛⎝f , g , p , 0 , 1 , 0 , 0 , 50 , 5⎞⎠

0.9

0.8

0.7

0.6
y
k

0.5

0.4 z
k
0.3

0.2 w
k
0.1

0
0 5 10 15 20 25 30 35 40 45 50

x
k

mol mol mol

Ca ＝ 0.02323498 ―― Cb ＝ 0.12389041 ―― Cc ＝ 0.8528746 ――
l l l
 mol mol mol
Ca ＝ 0.02323498 ―― Cb ＝ 0.12389041 ―― Cc ＝ 0.8528746 ――
l l l

b) Cb max
xo ≔ 0 yo ≔ 1 zo ≔ 0 wo ≔ 0 xf ≔ 16 h ≔ 1.6

⎡“ k ” “ x” “ y” “z” “w” ⎤
⎢ 0 0 1 0 0 ⎥
⎢ ⎥
⎢ 1 1.6 0.85323672 0.13644458 0.0103187 ⎥
⎢ 2 3.2 0.72987567 0.23310217 0.03702216 ⎥
⎢ 3 4.8 0.6259411 0.29918478 0.07487412 ⎥
⎢ 4 6.4 0.53816587 0.34194932 0.11988481 ⎥
S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠ = ⎢ ⎥
⎢ 5 8 0.46386096 0.36709585 0.16904318 ⎥
⎢ 6 9.6 0.40080947 0.37908647 0.22010405 ⎥
⎢ 7 11.2 0.3471805 0.38140039 0.27141911 ⎥
⎢ ⎥
8 12.8 0.30145916 0.37673781 0.32180303
⎢ ⎥
⎢ 9 14.4 0.26238961 0.36718279 0.3704276 ⎥
⎢⎣ 10 16 0.22892869 0.35433316 0.41673815 ⎥⎦

nf ≔ rows ⎛⎝S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠⎞⎠ = 12

k ≔ 1 ‥ ⎛⎝nf - 1⎞⎠
⟨⟨1⟩⟩ ⟨⟨2⟩⟩
x ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠ y ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠
⟨⟨3⟩⟩ ⟨⟨4⟩⟩
z ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠ w ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠

0.4

0.36

0.32

0.28

0.24

0.2

0.16 z
k
0.12

0.08

0.04

0
0 1.5 3 4.5 6 7.5 9 10.5 12 13.5 15 16.5

x
k

xo ≔ 9.6 yo ≔ 0.40080947 zo ≔ 0.37908647 wo ≔ 0.22010405

xf - xo
xf ≔ 11.95 h ≔ ――― = 0.235
10
 xf - xo
xf ≔ 11.95 h ≔ ――― = 0.235
10

⎡“ k ” “ x” “ y” “z” “w” ⎤
⎢ 0 9.6 0.40080947 0.37908647 0.22010405 ⎥
⎢ ⎥
⎢ 1 9.835 0.39238178 0.37996039 0.22765782 ⎥
⎢ 2 10.07 0.38415164 0.38063637 0.23521199 ⎥
⎢ 3 10.305 0.37611399 0.38112353 0.24276246 ⎥
⎢ 4 10.54 0.36826395 0.38143068 0.25030536 ⎥
S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠ = ⎢ ⎥
⎢ 5 10.775 0.36059674 0.38156626 0.25783699 ⎥
⎢ 6 11.01 0.35310774 0.38153843 0.26535382 ⎥
⎢ 7 11.245 0.34579243 0.38135503 0.27285253 ⎥
⎢ ⎥
8 11.48 0.33864642 0.38102362 0.28032995
⎢ ⎥
⎢ 9 11.715 0.33166546 0.38055147 0.28778306 ⎥
⎢⎣ 10 11.95 0.32484537 0.37994559 0.29520903 ⎥⎦

nf ≔ rows ⎛⎝S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠⎞⎠ = 12

k ≔ 1 ‥ ⎛⎝nf - 1⎞⎠
⟨⟨1⟩⟩ ⟨⟨2⟩⟩
x ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠ y ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠
⟨⟨3⟩⟩ ⟨⟨4⟩⟩
z ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠ w ≔ S_Ec_D ⎛⎝f , g , p , xo , yo , zo , wo , xf , h⎞⎠

z
k

t ≔ 10.775 min
0.3818
mol
0.38155 Cbm ≔ 0.38156626 ――
l
0.3813

0.38105

0.3808

0.38055

0.3803

0.38005

0.3798

0.37955

0.3793

0.37905

9.55 9.8 10.05 10.3 10.55 10.8 11.05 11.3 11.55 11.8 12.05

x
k