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  • Note 9 May 2022

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    Mirza Nazifa
    19 views6 pages
    This document discusses non-degenerate perturbation theory. It introduces how the Hamiltonian and eigenstates are perturbed when a small perturbation is added. The key points are: - The unperturbed and perturbed energies and eigenfunctions are related through perturbation theory - The perturbed energy and eigenfunctions are expanded as a power series in terms of the perturbation strength - Terms up to first order give the first order correction to the energy and eigenfunction

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    This document discusses non-degenerate perturbation theory. It introduces how the Hamiltonian and eigenstates are perturbed when a small perturbation is added. The key points are: - The unperturbed and perturbed energies and eigenfunctions are related through perturbation theory - The perturbed energy and eigenfunctions are expanded as a power series in terms of the perturbation strength - Terms up to first order give the first order correction to the energy and eigenfunction

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pdf or txt
    19 views6 pages

    Note 9 May 2022

    Uploaded by

    Mirza Nazifa
    This document discusses non-degenerate perturbation theory. It introduces how the Hamiltonian and eigenstates are perturbed when a small perturbation is added. The key points are: - The unperturbed and perturbed energies and eigenfunctions are related through perturbation theory - The perturbed energy and eigenfunctions are expanded as a power series in terms of the perturbation strength - Terms up to first order give the first order correction to the energy and eigenfunction

    Copyright:

    © All Rights Reserved
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    of 6

    t i s is

    I Non Degenerate Perturbation Theory

    Degenerate some Energy butdifferent 4


    Et Degenerate
    t M
    Ei Degenerate
    Fj
    we have H4n
    É also 4514mi 8mn

    Forthis perturbationTheory
    Our Energy and State 4 are Perturbed Terganggo

    mTYaian
    H Hot at.ME
    En En t 2En t 2 En t
    our perturbed
    Eigenfunctions

    4h 4 t 24 any perturbed
    Your States
    Wavefunction
    Note y State
    eigenfunction
    Ho4 Eno 4 perturbed condition

    H 4 Enyo H4n En4n

    Hot 24 4924 t 2 Yu t

    E not 2 En I Ea't x

    4 24m 74 t

    G constant C I 1
    2 nilai

    4049 2 404 H 4,0 22C HoYu H Un


    t EnoUn't 2 Enoyn t En 4,0 t
    2 Enola En Yn t En 4 t

    I n't 2 4
    49 24 t
    44 La

    4
    ZerothORDER Isf ORDER
    1404,0 Enoyn HOYn t H 4 Enn t En 4
    2nd ORDER
    HOYn't H kn Eno 4 ten ti ten 4
    3rd ORDER 4th ORDER etc

    then for zeroth ORDER is Trivial

    But for the First ORDER

    H 14 H 14 Ei Yn En 1497
    multiplied by 481

    4414014n 4 H 14
    Eno 4 14n En 4,01497
    Please remember since
    Ho Ni Eileen's
    Thus
    Ui 4014 7 Eno 4 14
    Eno 4514n 7 4514 14,07
    Eno 4no I Un 7 t En Uno14h07
    finally Uno H 1457 En 4 14no

    usually 4 14 1

    En 4no 14 14h07

    QUESTION and Self Answer

    Asia
    n
    4 c
    1 in a Box

    1111
    particle

    Answer
    wegive
    pears.it tiff.r
    En 4514 14
    Vo
    En 249 Vol 4h07
    since Vo is a scalar we can use
    En Vo 4914407 Vo
    The Perturbed energy En Vo

    En 2491 H 1497
    but Vo Cx

    En 471 Cx 14ns
    C Uno x1 4h07

    C
    S sin
    Ht dx

    f fax t.tl nt
    0052
    En C
    dx
    dx
    t
    n
    x T1 cos 2

    1
    t Ex
    faa t.ca
    En Eno t 2 En t 2 Ent t

    En e En t En t Ea t

    Vo const En Vo

    Vo Cx En Ca

    How about En coming from

    2nd Order

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