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Bonding Agent Adhesion Sika Activator
Bonding Agent Adhesion Sika Activator
Bonding Agent Adhesion Sika Activator
PRODUCT NAME
SIKA ACTIVATOR
PRODUCT USE
Bonding agent containing solvent to promote adhesion.
SUPPLIER
Company: Sika Pty Ltd
Address:
55 Elizabeth Street
Wetherill Park
NSW, 2164
Australia
Telephone: +61 2 9725 1145
Emergency Tel:+61 2 9757 5634
Emergency Tel:+61 2 9757 5625 (A/H)
Fax: +61 2 9725 3330
Website: www.sika.com.au
Flammability
Toxicity
Body Contact
Reactivity
Chronic
RISK SAFETY
Highly flammable. • Keep away from sources of ignition. No smoking.
Irritating to eyes and skin. • Do not breathe gas/fumes/vapour/spray.
Very toxic to aquatic organisms, may cause • Avoid contact with skin.
long- term adverse effects in the aquatic
environment.
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 2 of 18
Section 2 - HAZARDS IDENTIFICATION
NAME CAS RN %
heptane 142-82-5 30-60
methylcyclohexane 108-87-2 30-60
naphtha petroleum, light, hydrotreated 64742-49-0. 10-30
ethanol 64-17-5 <10
other ingredients determined not to be hazardous 0-30
SWALLOWED
• If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help
avoid possible aspiration of vomitus.
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
• Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
• Seek medical advice.
• Avoid giving milk or oils.
• Avoid giving alcohol.
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 3 of 18
Section 4 - FIRST AID MEASURES
EYE
If this product comes in contact with the eyes:
• Wash out immediately with fresh running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
occasionally lifting the upper and lower lids.
• Seek medical attention without delay; if pain persists or recurs seek medical attention.
• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
If skin contact occurs:
• Immediately remove all contaminated clothing, including footwear.
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to
initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
• Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
• Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
• Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea,
intercostal retraction, obtundation) and given oxygen. Patients with inadequate tidal volumes or poor
arterial blood gases (pO2 50 mm Hg) should be intubated.
• Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of
myocardial injury has been reported; intravenous lines and cardiac monitors should be established in
obviously symptomatic patients. The lungs excrete inhaled solvents, so that hyperventilation improves
clearance.
• A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document
aspiration and detect the presence of pneumothorax.
• Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial
sensitisation to catecholamines. Inhaled cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the
preferred agents, with aminophylline a second choice.
• Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in
adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
EXTINGUISHING MEDIA
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.
• Water spray or fog - Large fires only.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• May be violently or explosively reactive.
• Wear breathing apparatus plus protective gloves in the event of a fire.
• Prevent, by any means available, spillage from entering drains or water course.
• Consider evacuation (or protect in place).
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 4 of 18
Section 5 - FIRE FIGHTING MEASURES
FIRE/EXPLOSION HAZARD
WARNING: In use may form flammable/ explosive vapour-air mixtures.
WARNING:
• Can become highly flammable in use.
• Avoid evaporation.
• Liquid and vapour are highly flammable.
• Severe fire hazard when exposed to heat, flame and/or oxidisers.
• Vapour may travel a considerable distance to source of ignition.
• Heating may cause expansion or decomposition leading to violent rupture of containers.
• On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic
material.
Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.
FIRE INCOMPATIBILITY
• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine
etc. as ignition may result.
HAZCHEM
•3YE
MINOR SPILLS
• Remove all ignition sources.
• Clean up all spills immediately.
• Avoid breathing vapours and contact with skin and eyes.
• Control personal contact with the substance, by using protective equipment.
• Contain and absorb small quantities with vermiculite or other absorbent material.
• Wipe up.
• Collect residues in a flammable waste container.
MAJOR SPILLS
• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• May be violently or explosively reactive.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or water course.
• Consider evacuation (or protect in place).
• No smoking, naked lights or ignition sources.
• Increase ventilation.
• Stop leak if safe to do so.
• Water spray or fog may be used to disperse /absorb vapour.
• Contain spill with sand, earth or vermiculite.
• Use only spark-free shovels and explosion proof equipment.
• Collect recoverable product into labelled containers for recycling.
• Absorb remaining product with sand, earth or vermiculite.
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 5 of 18
Section 6 - ACCIDENTAL RELEASE MEASURES
evacuation half
direction downwind
distance
wind isolation down wind distance
direction distance
half
evacuation downwind
INITIAL direction
ISOLATION distance
ZONE
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal to
the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of vapour
concentration may exist resulting in nearly all unprotected persons becoming incapacitated and unable to take
protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to life-
threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from a
small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 127 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 6 of 18
Section 7 - HANDLING AND STORAGE
SUITABLE CONTAINER
• Packing as supplied by manufacturer.
• Plastic containers may only be used if approved for flammable liquid.
• Check that containers are clearly labelled and free from leaks.
• For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where
a can is to be used as an inner package, the can must have a screwed enclosure.
• For materials with a viscosity of at least 2680 cSt. (23 deg. C)
• For manufactured product having a viscosity of at least 250 cSt. (23 deg. C)
• Manufactured product that requires stirring before use and having a viscosity of at least 20 cSt (25 deg.
C): (i) Removable head packaging; (ii) Cans with friction closures and (iii) low pressure tubes and
cartridges may be used.
• Where combination packages are used, and the inner packages are of glass, there must be sufficient inert
cushioning material in contact with inner and outer packages
• In addition, where inner packagings are glass and contain liquids of packing group I there must be
sufficient inert absorbent to absorb any spillage, unless the outer packaging is a close fitting moulded
plastic box and the substances are not incompatible with the plastic.
STORAGE INCOMPATIBILITY
• Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
• Store in original containers in approved flame-proof area.
• No smoking, naked lights, heat or ignition sources.
• DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
• Keep containers securely sealed.
• Store away from incompatible materials in a cool, dry well ventilated area.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storage and handling recommendations contained within this MSDS.
_____________________________________________________
+ X X X X +
_____________________________________________________
+: May be stored together
O: May be stored together with specific preventions
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 7 of 18
Section 7 - HANDLING AND STORAGE
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m³ STEL ppm STEL mg/m³ Notes
___________ ___________ _______ _______ _______ _______ _______
Australia Exposure heptane (Heptane (n- 400 1640 500 2050
Standards Heptane))
Australia Exposure methylcyclohexane 400 1610
Standards (Methylcyclohexane)
Australia Exposure naphtha petroleum, 900 (see
Standards light, hydrotreated Chapter 16)
(Petrol (gasoline))
Australia Exposure ethanol (Ethyl 1000 1880
Standards alcohol)
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit for safety
considerations even though the relevant toxicological data indicated that irreversible health effects or
impairment of escape existed only at higher concentrations.
MATERIAL DATA
HEPTANE:
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
for heptane (all isomers)
The TLV-TWA is protective against narcotic and irritant effects which are greater than those of pentane or
n-hexane but less than those of octane. The TLV-TWA applies to all isomers.
Inhalation by humans of 1000 ppm for 6 minutes produced slight dizziness. Higher concentrations for
shorter periods produce marked vertigo, incoordination and hilarity. Signs of central nervous system
depression occur in the absence of mucous membrane irritation. Brief exposures to high levels (5000 ppm for 4
minutes) produce nausea, loss of appetite and a "gasoline-like" taste in the mouth that persists for many
hours after exposure ceases.
SIKA ACTIVATOR:
Not available
METHYLCYCLOHEXANE:
For methylcyclohexane:
High concentrations produce narcosis in animals. The TLV-TWA is based on analogy with heptane, a substance
exhibiting similar toxicology, and is thought to be protective against irritation. Prolonged exposure by
monkeys to 370 ppm failed to produce adverse health effects.
Odour Safety Factor (OSF)
OSF=0.63 (METHYLCYCLOHEXANE).
The TLV-TWA is protective against ocular and upper respiratory tract irritation and is recommended for
bulk handling of gasoline based on calculations of hydrocarbon content of gasoline vapour. A STEL is
recommended to prevent mucous membrane and ocular irritation and prevention of acute depression of the
central nervous system. Because of the wide variation in molecular weights of its components, the conversion
of ppm to mg/m3 is approximate. Sweden recommends hexane type limits of 100 ppm and heptane and octane type
limits of 300 ppm. Germany does not assign a value because of the widely differing compositions and resultant
differences in toxic properties.
Odour Safety Factor (OSF)
OSF=0.042 (gasoline).
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA)
(CEL = Chemwatch Exposure Limit).
ETHANOL:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or
throat. Historically occupational exposure standards for these irritants have been based on observation of
workers' responses to various airborne concentrations. Present day expectations require that nearly every
individual should be protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effect-
levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach,
typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals,
has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure
limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine
to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on
intensive odour, local irritation, and elimination half-life. However this system is being replaced to be
consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this
is more closely allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
• cause inflammation
• cause increased susceptibility to other irritants and infectious agents
• lead to permanent injury or dysfunction
• permit greater absorption of hazardous substances and
• acclimate the worker to the irritant warning properties of these substances thus increasing the risk of
overexposure.
For ethanol:
Odour Threshold Value: 49-716 ppm (detection), 101 ppm (recognition)
Eye and respiratory tract irritation do not appear to occur at exposure levels of less than 5000 ppm and
the TLV-TWA is thought to provide an adequate margin of safety against such effects. Experiments in man show
that inhalation of 1000 ppm caused slight symptoms of poisoning and 5000 ppm caused strong stupor and morbid
sleepiness. Subjects exposed to 5000 ppm to 10000 ppm experienced smarting of the eyes and nose and coughing.
Symptoms disappeared within minutes. Inhalation also causes local irritating effects to the eyes and upper
respiratory tract, headaches, sensation of heat intraocular tension, stupor, fatigue and a need to sleep. At
15000 ppm there was continuous lachrymation and coughing.
PERSONAL PROTECTION
EYE
• Safety glasses with side shields.
• Chemical goggles.
• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 9 of 18
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
written policy document, describing the wearing of lens or restrictions on use, should be created for each
workplace or task. This should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in
their removal and suitable equipment should be readily available. In the event of chemical exposure, begin
eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the
first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national
equivalent].
HANDS/FEET
• Wear chemical protective gloves, e.g. PVC.
• Wear safety footwear or safety gumboots, e.g. Rubber.
OTHER
• Overalls.
• PVC Apron.
• PVC protective suit may be required if exposure severe.
• Eyewash unit.
• Ensure there is ready access to a safety shower.
RESPIRATOR
•Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national
equivalent)
Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and
the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and
inside the mask) may also be important.
Required minimum Maximum gas/vapour Half- face Respirator Full- Face Respirator
protection factor concentration present
in air p.p.m. (by
volume)
up to 10 1000 A- AUS / Class1 -
up to 50 1000 - A- AUS / Class 1
up to 50 5000 Airline * -
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 10 of 18
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
up to 100 5000 - A- 2
up to 100 10000 - A- 3
100+ Airline**
The local concentration of material, quantity and conditions of use determine the type of personal protective
equipment required. For further information consult site specific CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-
designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove
or dilute an air contaminant if designed properly. The design of a ventilation system must match the
particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation
system may be required. Ventilation equipment should be explosion-resistant.
APPEARANCE
Clear slightly yellowish highly flammable liquid with a hydrocarbon
odour; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 11 of 18
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the individual.
Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce
gastrointestinal discomfort and may be harmful if swallowed. Ingestion may result in nausea, pain and
vomiting. Vomit entering the lungs by aspiration may cause potentially lethal chemical pneumonitis.
EYE
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or
prolonged exposure to irritants may produce conjunctivitis.
SKIN
Skin contact with the material may damage the health of the individual; systemic effects may result
following absorption.
The material may accentuate any pre-existing dermatitis condition.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury
with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage
is suitably protected.
INHALED
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal
handling, may be damaging to the health of the individual.
SIKA ACTIVATOR:
None assigned. Refer to individual constituents.
HEPTANE:
TOXICITY IRRITATION
Inhalation (human) TCLo:1000 ppm/6m Nil Reported
METHYLCYCLOHEXANE:
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 12 of 18
Section 11 - TOXICOLOGICAL INFORMATION
TOXICITY IRRITATION
Oral (mouse) LD50:2250 mg/kg Nil Reported
Inhalation (mouse) LC50:41500 mg/m³/2h
Intravenous (mouse) LD50:234 mg/kg
Lifetime exposure of rodents to gasoline produces carcinogenicity although the relevance to humans has been
questioned. Gasoline induces kidney cancer in male rats as a consequence of accumulation of the alpha2-
microglobulin protein in hyaline droplets in the male (but not female) rat kidney. Such abnormal accumulation
represents lysosomal overload and leads to chronic renal tubular cell degeneration, accumulation of cell
debris, mineralisation of renal medullary tubules and necrosis. A sustained regenerative proliferation occurs
in epithelial cells with subsequent neoplastic transformation with continued exposure. The alpha2-
microglobulin is produced under the influence of hormonal controls in male rats but not in females and, more
importantly, not in humans.
ETHANOL:
TOXICITY IRRITATION
Oral (rat) LD50:7060 mg/kg Skin (rabbit):20 mg/24hr- Moderate
Oral (human) LDLo:1400 mg/kg Skin (rabbit):400 mg (open)- Mild
Oral (man) TDLo:50 mg/kg Eye (rabbit):100mg/24hr- Moderate
Oral (man) TDLo:1.40 mg/kg Eye (rabbit):500 mg SEVERE
Oral (woman) TDLo:256 mg/kg/12 wks
Inhalation (rat) LC50:20, 000 ppm/10h
Inhalation (rat) LC50:64000 ppm/4h
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin
redness, swelling, the production of vesicles, scaling and thickening of the skin.
SKIN
methylcyclohexane GESAMP/EHS Composite List - GESAMP Hazard D1: skin 1
Profiles irritation/corrosion
ethanol GESAMP/EHS Composite List - GESAMP Hazard D1: skin 1
Profiles irritation/corrosion
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
A317LP Version No:3.1.1.1
CD 2013/2 Page 13 of 18
METHYLCYCLOHEXANE:
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
ETHANOL:
HEPTANE:
DO NOT discharge into sewer or waterways.
METHYLCYCLOHEXANE:
NAPHTHA PETROLEUM, LIGHT, HYDROTREATED:
HEPTANE:
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high
water mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
HEPTANE:
Marine Pollutant Yes
Fish LC50 (96hr.) (mg/l): 4924
log Kow (Sangster 1997): 4.66
BOD5: 1.92
COD: 0.06
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
For n-Heptane: Log Kow: 4.66; Koc: 2400-8100; Half-life (hr) Air: 52.8; Half-life (hr) Surface Water: 2.9-312;
Henry's atm m3 /mol: 2.06; BOD 5 (if unstated): 1.92; COD: 0.06; BCF: 340-2000; Log BCF: 2.53-3.31.
Atmospheric Fate: Breakdown of n-heptane by sunlight is not expected to be an important fate process. If
released to the atmosphere, n-heptane is expected to exist entirely in the vapor phase, in ambient air.
Reactions hydroxyl radicals in the atmosphere have been shown to be important. Night-time reactions with
nitrate radicals may contribute to the atmospheric transformation of n-heptane, especially in urban
environments. n-Heptane is not expected to be susceptible to direct breakdown by sunlight
Terrestrial Fate: n-Heptane is expected to be broken down by biological processes in the soil; however,
evaporation and adsorption from soil are expected to be a more important fate processes. n-Heptane will be
slightly mobile to immobile in soil.
Aquatic Fate: Breakdown of n-heptane by water is not expected to be an important fate process.
Biological breakdown may occur in water; however, evaporation is expected to be a more important fate
process. The evaporation half-life for the substance from a model river is 2.9 hours and from a model pond is
13 days. In aquatic systems, n-heptane may partition from the water column to organic matter in sediments and
suspended solids.
Ecotoxicity: Concentration of the substance in aquatic life may be important in aquatic environments. The
substance is moderately toxic to goldfish; however n-heptane has low toxicity to golden orfe, western
mosquitofish, Daphnia magna water fleas, and snail. The substance is toxic to opossum shrimp.
METHYLCYCLOHEXANE:
Marine Pollutant Yes
Fish LC50 (96hr.) (mg/l): 72
log Kow (Sangster 1997): 3.88
Algae IC50 (72hr.) (mg/l): 26- 88
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
For Hydrocarbons: log Kow 1. BCF~10.
For Aromatics: log Kow 2-3.
BCF 20-200. For C5 and greater alkanes: log Kow 3-4.5. BCF 100-1,500.
For Alkanes, Benzene, Toluene, Ethylbenzene, Xylene (BTEX):
Environmental Fate: Microbes found in many natural settings (e.g., soils, groundwater, ponds) have been shown
to be capable of degrading organic compounds. Some hydrocarbons will become associated with marine sediments
likely to be spread over a fairly wide area of sea floor. Under aerobic conditions, hydrocarbons degrade to
water and carbon dioxide, while under anaerobic processes, they produce water, methane and carbon dioxide.
Anaerobic degradation is slower than aerobic. Biodegradation can eliminate the contaminants without
dispersing them throughout the environment. The rate of hydrocarbon degradation depends on the chemical
composition of the product released to the environment as well as site-specific environmental factors.
Hydrocarbons with condensed ring structures, such as PAHs (polycyclic aromatic hydrocarbons) with four or
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SIKA ACTIVATOR
Chemwatch Independent Material Safety Data Sheet (REVIEW)
Issue Date: 29-Jan-2010 CHEMWATCH 5079-28
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CD 2013/2 Page 14 of 18
Section 12 - ECOLOGICAL INFORMATION
more rings, have been shown to be relatively resistant to biodegradation. PAHs with only 2 or 3 rings (e.g.,
naphthalene, anthracene) are more easily biodegraded. In almost all cases, the presence of oxygen is
essential for effective biodegradation. Straight chain hydrocarbons and aromatics degrade more readily than
highly branched aliphatic compounds. The n-alkanes, n-alkyl aromatics, and the aromatics in the C10-C22 range
are the most readily biodegradable; n-alkanes, n-alkyl aromatics, and aromatics in the C5-C9 range are
biodegradable at low concentrations by some microorganisms, but are generally preferentially removed by
volatilization and thus are unavailable in most environments; n-alkanes in the C1-C4 ranges are biodegradable
only by a narrow range of specialized hydrocarbon degraders; n-alkanes, n-alkyl aromatics, and aromatics
above C22 are generally not available to degrading microorganisms. The ideal pH range to promote
biodegradation is close to neutral (6-8). For most species, the optimal pH is slightly alkaline, that is,
greater than 7. Generally, as the temperature increases, biological activity tends to increase up to a
temperature where enzyme denaturation occurs.
Atmospheric Fate: Alkanes, isoalkanes, and cycloalkanes have half-lives on the order of 1-10 days, whereas
alkenes, cycloalkenes, and substituted benzenes have half-lives of 1 day or less. Photochemical oxidation
products include aldehydes, hydroxy compounds, nitro compounds, and peroxyacyl nitrates. Alkenes, certain
substituted aromatics, and naphthalene are potentially susceptible to direct photolysis.
Aquatic Fate: Volatilization half-life predicted as 7 days (ponds), 1.5 days (rivers), 6 days (lakes).
Volatilization rate of naphthalene and its substituted derivatives estimated to be slower.The lower molecular
weight hydrocarbons are expected to form a "slick" on the surface of waters after release in calm seas which
is expected to evaporate and enter the atmosphere where it will be degraded through reaction with hydroxy
radicals. Ecotoxicity: Effects on freshwater/saltwater organisms: Hydrocarbons are hydrophobic. Such
substances produce toxicity in aquatic organisms by a mechanism referred to as "non-polar narcosis" or
"baseline" toxicity. Toxic effects are often observed in species such as blue mussel, water fleas, freshwater
green algae, marine copepods and amphipods.
Drinking Water Standards: hydrocarbon total: 10 ug/l (UK max.).
BCF: 150
controlled ozone depleting gases: freeze by 1995 (C)
ETHANOL:
Fish LC50 (96hr.) (mg/l): 13480
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Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity
Ingredient Persistence: Persistence: Air Bioaccumulation Mobility
Water/Soil
heptane LOW No Data HIGH MED
Available
methylcyclohexane LOW No Data LOW MED
Available
naphtha petroleum, light, No Data No Data No Data No Data
hydrotreated Available Available Available Available
ethanol LOW MED LOW HIGH
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FLA M M A B LE
L IQ U ID
3
HAZCHEM:
•3YE (ADG7)
ADG7:
Class or Division: 3 Subsidiary Risk: None
UN No.: 1866 Packing Group: II
Special Provision: * Limited Quantity: 5L
Portable Tanks & Bulk T4 Portable Tanks & Bulk TP1 TP8
Containers - Containers - Special
Instruction: Provision:
Packagings & IBCs - P001 IBC02 Packagings & IBCs - PP1
Packing Instruction: Special Packing
Provision:
Name and Description: RESIN SOLUTION, flammable
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Indications of Danger:
F Highly Flammable
N Dangerous for the environment
Xn Harmful
POISONS SCHEDULE
REGULATIONS
naphtha petroleum, light, hydrotreated (CAS: 64742-49-0) is found on the following regulatory
lists;
"Australia Exposure Standards","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","Australia Hazardous
Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances (AICS)","Australia Standard for the Uniform
Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule
5","FisherTransport Information","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO
Provisional Categorization of Liquid Substances - List 2: Pollutant only mixtures containing at least 99% by weight of components already assessed by IMO","IMO
Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least 99% by weight of components already assessed by IMO,
presenting safety hazards","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","International Council of Chemical
Associations (ICCA) - High Production Volume List","International Fragrance Association (IFRA) Survey: Transparency List","International Maritime Dangerous
Goods Requirements (IMDG Code) - Substance Index","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List of Candidates for Substitution –
Norway","Sigma-AldrichTransport Information"
have been suggested as an additional standard. These have been established after a literature search for the
reproductive no-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level (LOAEL).
In addition the US EPA's procedures for risk assessment for hazard identification and dose-response
assessment as applied by NIOSH were used in the creation of such limits. Uncertainty factors (UFs) have also
been incorporated.
Ingredient ORG UF Endpoint CR Adeq TLV
ethanol 1880 mg/m3 NA NA NA Yes
These exposure guidelines have been derived from a screening level of risk assessment and should not be
construed as unequivocally safe limits. ORGS represent an 8-hour time-weighted average unless specified
otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
Classification of the preparation and its individual components has drawn on official and authoritative
sources as well as independent review by the Chemwatch Classification committee using available literature
references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors
determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined
by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering
controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.