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Non Edible Oil Seeds Based Livelihood22
Non Edible Oil Seeds Based Livelihood22
Non Edible Oil Seeds Based Livelihood22
based Livelihood
Non-Edible Oil Seeds based Livelihood
NON- EDIBLE OILSEEDS OF INDIA
Biomass: As renewable feedstock for Chemical
Industry
Chemicals from Petroleum and Biomass Feedstock
Petroleum as a Source of Fuels and Chemicals
Fuels
Resins
Fine chemicals
Fibers
Plastics
Synthesis of chemicals
Petroleum Refinery
Scenario of fossil resources
Increase in
CO2 Level
Petroleum
depletion Air Pollution
Sceneries
Associated
Economical with Fossil
issue Global
Resources warning
12
Type of Biofuel
First-generation biofuel: conventional biofuels are made
from food crops grown on arable land. With this biofuel
production generation, food crops are thus explicitly grown
for bio fuels production and not anything else. The sugar,
starch, or vegetable oil obtained from the crops is converted
into biodiesel or ethanol, using transesterification, or yeast
fermentation
Products:
Hydrotreating oil, bio-oil, FT oil, lignocellulosic ethanol, butanol, mixed alcohols.
Advantages:
• Not competing with food.
• Technology still under development to reduce the cost of conversion.
• Environmentally friendly.
Non-Edible Oil Seeds for Biodiesel Production
Indian Biofuels programme
Source. http://inhabitat.com/wp-content/blogs.dir/1/files/2010/08/Giant-traffic-jam.jpg
http://www.esds.ac.uk/international/images/co2agenda.gif
IITD
Contribution of different GHG from transport sector in India
Source: http://snfabr.brinkster.net/blog/wp-content/uploads/2008/07/08_07_07_carbon_emissions1.jpg
Production of Biofuel from Vegetable Oil
Green Jet Fuel
Green Diesel
Bio-oil/
Green Diesel
VEGETABLE OILS AS DIESEL FUEL
(BIO DIESEL)
H H
| |
H-C - OOR H - C - OH ROOCH3
| Catalyst | +
H-C - OOR' + 3 CH3OH H - C - OH + R'OOCH3
| | +
H-C - OOR" H - C - OH R"OOCH3
| |
H H
Non-edible oil Methanol Glycerol Fatty acid methyl
esters
(biodiesel)
VEGETABLE OIL DIESEL FUEL
IIT Delhi
Mangokernel 600.0 8.0 48.0
August
Karanja 18, 2004 111.0 27.0 30.0
Kusum 90.0 33.0 29.7
Khakan 46.0 33.0 15.2
Pinnai/Undi 18.6 60.0 11.2
Pisa 12.0 48.0 5.8
Rubberseed 30.0 18.5 5.6
Dhupa 30.0 17.0 5.1
Kokum 12.5 40.0 5.0
Maroti/Kavathi 12.0 33.0 4.0
• It can help reduce air pollution and related public health risks.
*Gestation period.
POTENTIAL MINOR OIL SEEDS IN INDIA
Opportunities Threats
▪ National Biodiesel policy ▪ The discovery of huge gas reserves in India may
push biofuels on the backfoot
▪ Keen interest of private players
▪ Food vs. fuel debate
▪ R&D across the sector
▪ Cost effectiveness of Biofuels
▪ Less dependency on depleting fossil fuels
▪ Raw material
53
National Biofuel Policy
• Goal
– To ensure that a minimum level of
biofuels become available to meet the
demand.
• Target
– 20% blending of biofuels by 2017
Biofuels Policies :Initiatives by Govt. of India
5 3.35 2.79
10 6.69 5.58
20 13.38 11.19
The existing TBOs available For Biodiesel are Jatropha, Karanja, Jojoba, Mahua,
Neem, Karanja, Wild apricot, Cheura, Kokum Simarouba, and Tung etc
Plantation of Non-Edible Oil Seeds for Biodiesel
Production
Extraction and
Processing of Oil Marketing End Use
Plantation on
for Production of and Trade
Waste lands
Biodiesel
Plantation of Biofuel Crops
(Jatropha)
Jatropha Plantation for oil production
Jatropha curcas (Ratanjot) non-edible semi-evergreen shrub
or small tree
Field and Poly-bag Preparation for Nursery raising
Nursery raising activity
Nursery raised from seeds and cuttings with
various treatments
Jatropha Plantation on Wastelands
Weeding in Jatropha Field in Initial
Establishment Phase
Agro forestry Model Initiatiative
Jatropha plants in IIT Delhi
Intercropping with Medicinal and Aromatic Plants
Oil cake 1-2 t Contains N (7.7-8.1%), P (1.07%) and K (1.24%) and can be
used as manure
Fruit pulp 8-10 t Contains 11% sugar and can be used for beverages, bioethanol
production
Manual Decortications of
Karanja fruits
Dehulling of Fruit
2 Seed Recovery, % 62
3 Husk, % 38
4 Machine Efficiency, 90
%
Manual Decorticator for Jatropha Seeds
Striking wall
Patented:
Indian Patent No.: 1592/DEL/2007
Controller
Outlet
Motor
Capacity 40 kg/h
Motor 0.5hp
Manual Vs Mechanical Decorticator for Karanja Fruits
* 1 Man = 0.1hp
1 hp = 0.746 kw
1 Man 1 day (8hr) work = 2 MJ
Tung seed Decorticator
Karanja Oil Expelling
Women SHG involved in oil extraction
Efficient Oil Expeller Unit for Jatropha
Seeds Developed by IIT Delhi
Extraction efficiency 80 %
The storage aspect of non-edible-oilseed & oil
Non-edible oil
Stock
Non-edible seed
stock
Biodiesel Production
Quality of bio diesel from different feed -stocks
Properties IS 15607- Palm oil methyl Karanja oil Jatropha oil
2005 esters methyl esters methyl esters
Density @15oC, kg/m3 860-900 873 880 879a
Kinematic Viscosity at 40oC, cSt 2.5-6.0 4.2 4.7 4.0
Flash point, oC, min 120 144 174 191a
Sulfur, ppm, max 50 <1 15 n.d.
Carbon Residue, % by mass, max 0.05
Sulfated Ash, % by mass t, max 0.02 0.009 0.001 0.014a
Water content, ppm, max 500 270 300 310
Total contamination, ppm, max 24 08 17 n.d.
Copper corrosion, 3h at 50oC, max 1 No. 1 No. 1 No. 1
Cetane number, min 51 64 56 51a
Acid Value, mhKOH/g, max 0.5 0.36 0.50 0.24
Methanol, % by mass, max 0.2 0.024 0.018 0.021
Ester content, % by mass, min 96.5 97.5 98.0 99.6a
Free Glycerol, % by mass, max 0.02 0.017 0.010 0.012
Total Glycerol, % by mass, max 0.25 0.20 0.19 0.18
Phosphorus, ppm, max 10 5.2 n.d. n.d.
Sodium and Potassium, ppm, max To report n.d. n.d. n.d.
Calcium and Magnesium, ppm, max To report n.d. n.d. n.d.
Iodine Value, gI2/100g, max To report 52.5 86.5 97.1
Oxidation Stability at 110oC, h, min 6 30.5 2.24 0.56
Different biodiesel properties measured in lab
Experimental set up