Chemistry - Jeeadv Solutions

®
(ADVANCED) 2016
JEE (Advanced)
JEE 2021
22-05-2016
DATE: 03-10-2021
PAPER 1
Questions & Solutions
Time : 9:00 am – 12:00 pm | Duration : 3 Hrs. | Total Marks : 180
SUBJECT: CHEMISTRY
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PAPER-1 : INSTRUCTIONS TO CANDIDATES
 Question Paper-1 has three (03) parts: Physics, Chemistry and Mathematics.
 Each part has a total Nineteen (19) questions divided into four (04) sections (Section-1, Section-2, Section-3 & Section-4)
 Total number of questions in Question Paper-1 are Fifty Seven (57) and Maximum Marks are One Hundred and Eighty (180).
Type of Questions and Marking Schemes
SECTION-1
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.
SECTION 2
• This section contains THREE (03) question stems.

• There are TWO (02) questions corresponding to each question stem.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value corresponding to the answer in the designated place
using the mouse and the on-screen virtual numeric keypad.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
SECTION 3
• This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.

JEE (ADVANCED) 2021 | DATE : 03-10-2021 | PAPER-1 | CHEMISTRY
PART : CHEMISTRY
SECTION-1
• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
• For each question, choose the option corresponding to the correct answer.
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
1. The major product formed in the following reaction is

NaNH2
NA
liq.NH3
(A) (B)
(C) (D)
Ans. (B)
Sol. It is a birch reduction. In Birch reduction only internal Alkyne can reduced to trans alkene.
While terminal alkyne can’t be reduced to alkene.
2. Among the following, the conformation that corresponds to the most stable conformation of meso-
butane-2,3-diol is
OH OH
H Me H OH
(A) (B)
Me H H Me
OH Me
OH OH
Me OH H OH
(C) (D)
H Me Me H
H Me
Ans. (B)
Sol. C & D are not meso compound but A & B are meso compound and out of A and B. B is more stable due
to intramolecular hydrogen bonding.
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3. For the given close packed structure of a salt made of cation X and anion Y shown below (ions of
only one face are shown for clarity), the packing fraction is
packing efficiency
approximately (packing fraction = 100 )
(A) 0.74 (B) 0.63 (C) 0.52 (D) 0.48

Ans. (B)
Sol. 2[rx + ry] = 2a {a = 2ry ; ry = 0.59}
2[rx + ry] = 2 (2ry)
2rx = 2 2 ry – 2ry
rx = ry [ 2 – 1]
rx = 0.414 ry = 0.207 a
4 3 4 3
3 rx  ry
Packing fraction = 3 3 = 0.63
a3
4. The calculated spin only magnetic moments of [Cr(NH3)6]3+ and [CuF6]3– in BM, respectively, are
(Atomic numbers of Cr and Cu are 24 and 29, respectively)
(A) 3.87 and 2.84 (B) 4.90 and 1.73 (C) 3.87 and 1.73 (D) 4.90 and 2.84
Ans. (A)
Sol. [Cr(NH3)6]3+ Cr3+ 3d3 unpaired e– = 3
 = 3.87 BM
[CuF6]3– Cu3+ 3d8 unpaired e– = 2
 = 2.87 BM
SECTION 2
• This section contains THREE (03) question stems.

• There are TWO (02) questions corresponding to each question stem.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value corresponding to the answer in the designated place
using the mouse and the on-screen virtual numeric keypad.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.

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Question Stem for Question Nos. 5 to 6

Question Stem
For the following reaction scheme, percentage yields are given along the arrow:
red hot
NaNH2 iron tube
H2O MeI 873 K
Mg2C3 P Q R
(4.0 g) 75% 40% (x g)

Hg2+/H+
333 K 100%
Ba(OH)2 NaOCl
S T U (decolourises)
heat 80% Baeyer's reagent)
80% (y g)
x g and y g are mass of R and U, respectively.

(Use: Molar mass (in g mol–1) of H, C and O as 1, 12 and 16, respectively)
5. The value of x is ______.
Ans. (1.62)
6. The value of y is ______.

Ans. (3.2)
Sol. (Q.5 & Q.6)
H3O+ NaNH2
Mg2C3 CH3–CCH CH3–CC–CH3
MeI
0.1 mol 0.1 × 0.75 = 0.075
Hg2+/H+ Red hot tube
CH3
CH3–C–CH3 CH3 CH3
O
CH3 CH3
Ba(OH)2
CH3
CH3–C–CH=C–CH3
0.075 × 0.4 ×1/3 = 1.62
O CH3
T 0.05 × 0.08 = 0.04 moles
NaOCl
CH3
CHCl3 + HO–C–CH=C
CH3
O
0.04×0.8 ×100 = 3.2 gm
So X = 1.62 ; Y = 3.2

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Question Stem for Question Nos. 7 and 8

Question Stem
pz 10 4
For the reaction, 𝐗(𝑠) ฀ 𝐘(𝑠) + 𝐙(𝑔), the plot of ln o
versus is given below (in solid line), where
p T
𝑝𝐙 is the pressure (in bar) of the gas Z at temperature T and po = 1 bar.
d(lnK ) H o pz
(Given,  , where the equilibrium constant, K  o and the gas constant, R = 8.314 J K–1
 1 R p
d 
T
mol–1)
7. The value of standard enthalpy, Ho (in kJ mol–1) for the given reaction is ___.
Ans. (166.28)
8. The value of S o (in J K–1 mol–1) for the given reaction, at 1000 K is ___.
Ans. (141.34)
Sol. (7 & 8)
Gº =Hº – TSº
–RTlnK = Hº – TSº
  Hº  1  Sº 
lnk =    
 R T  R 
y = mx + c
For given reaction K = (P2)
 Hº    7  ( 3) 
Slope =   10 4      2
 R   12  10 
= Hº = (2 × 104)R = 16.628 × 104 J = 166.28 kJ
(ii) y = mx + c
104 
– 3 = –2   +c
 T 
– 3 = –2 [10] + c
c = 17
S º
But c = = 17
R
Sº = 17 × 8.314 = 141.338 J/K

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Question Stem for Question Nos. 9 and 10

Question Stem
The boiling point of water in a 0.1 molal silver nitrate solution (solution A) is x C. To this solution A, an
equal volume of 0.1 molal aqueous barium chloride solution is added to make a new solution B. The
difference in the boiling points of water in the two solutions A and B is y × 10–2 C.
(Assume: Densities of the solutions A and B are the same as that of water and the soluble salts
dissociate completely.
Use: Molal elevation constant (Ebullioscopic Constant), 𝐾𝑏 = 0.5 K kg mol–1; Boiling point of pure water
as 100 C.)
9. The value of x is ___.

Ans. (100.1)
10. The value of |y| is ___.

Ans. (2.5)
Sol. (9 & 10)
Initially for solution A [0.1 m AgNO3]
Tb = i Kb m
Tb = 2 × 0.5 × 0.1
T’b – 100 = 0.1
T’b = 100.1°C
x = 100.1°C
(II) 2AgNO3 + BaCl2  Ba(NO3)2 + 2AgCl 
0.1V 0.1V
ion milimole
Ag+ 0.1V
NO3– 0.1V
Ba2+ 0.1V
Cl– 0.2V
Tb = i Kb × m
 0.1V  0.1V  0.1V 
= 0.5  
 2V 
0 .3
= 0.5 ×
2
T’b – 100 = 0.075
T’b = 100.075
Differece in Tb = 100.1 – 100.075 = 0.025 = 2.5 × 10–2
y = 2.5

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SECTION 3
• This section contains SIX (06) questions.

• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Zero Marks : 0 If unanswered;
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.
11. Given :
CHO
H OH
HO H HNO3
P
H OH
[D = +52.7º]
H OH
CH2OH
D-Glucose
The compound(s), which on reaction with HNO3 will give the product having degree of rotation,
[]D = –52.7º is (are)
CHO CHO
HO H HO H
(A) HO H (B) HO H
H OH H OH
H OH HO H
CH2OH CH2OH

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CHO CHO
HO H H OH
(C) H OH (D) H OH
HO H HO H
HO H H OH
CH2OH CH2OH
Ans. (CD)
12. The reaction of Q with PhSNa yields an organic compound (major product) that gives positive Carius
test on treatment with Na2O2 followed by addition of BaCl2. The correct option(s) for Q is (are)
O2N
(A) O2N F (B) I
NO2 O2N
MeS
(C) Br (D) O2N

Cl
O2N MeS
Ans. (AD)
13. The correct statement(s) related to colloids is(are)

(A) The process of precipitating colloidal sol by an electrolyte is called peptization.
(B) Colloidal solution freezes at higher temperature than the true solution at the same concentration.
(C) Surfactants form micelle above critical micelle concentration (CMC). CMC depends on temperature.
(D) Micelles are macromolecular colloids
Ans. (C)
Sol. Surfactants form micelle above critical micelle concentration (CMC). CMC depends on temperature.
14. An ideal gas undergoes a reversible isothermal expansion from state I to state II followed by a
reversible adiabatic expansion from state II to state III. The correct plot(s) representing the changes
from state I to state III is(are)
(p: pressure, V: volume, T: temperature, H: enthalpy, S: entropy)
(A) (B)
(C) (D)

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Ans. (ABD)
Sol. (i) For isothermal process T constant and for reversible adiabatic process entropy is constant.
(ii) For isothermal process H = 0
(iii) Slope of adiabatic process is  times of isothermal process
So, graph AD is correct.
15. The correct statement(s) related to the metal extraction processes is(are)
(A) A mixture of PbS and PbO undergoes self-reduction to produce Pb and SO2.
(B) In the extraction process of copper from copper pyrites, silica is added to produce copper silicate.
(C) Partial oxidation of sulphide ore of copper by roasting, followed by self-reduction produces blister
copper.
(D) In cyanide process, zinc powder is utilized to precipitate gold from Na[Au(CN) 2].
Ans. (ACD)
Sol. (A) PbS + PbO  Pb + SO2
(Self reduction of Pb)
(B) In extraction process of Cu SiO2 is added to make FeSiO3
(C) Zn + Na[Au(Cu)2]  Au(s) + Na2[Zn(CN)4]
16. A mixture of two salts is used to prepare a solution S, which gives the following results:
white Dilute NaOH(aq) S Dilute HCl(aq) White

precipitate(s) (aq solution precipitate(s)
only Room temperature of the salts) Room temperature only
The correct option(s) for the salt mixture is (are)

(A) Pb(NO3)2 and Zn(NO3)2 (B) Pb(NO3)2 and Bi(NO3)3
(C) AgNO3 and Bi(NO3)3 (D) Pb(NO3)2 and Hg(NO3)2
Ans. (ABC)
Pb+2
PbCl2  White
HCl
Ag+
AgCl  White
Sol. Zn+2 Zn(OH)2  White
Hg+2
NaOH HgO  Red brown
Bi+3
Bi(OH)3  White

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SECTION 4
• This section contains THREE (03) questions.

• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
17. The maximum number of possible isomers (including stereoisomers) which may be formed on mono-
bromination of 1-methylcyclohex-1-ene using Br2 and UV light is _____ .
Ans. 13
Sol. This is allylic substitution at  – carbon
Cl
• Cl
Cl2 Cl
UV + + + +
(553K) Cl
1 2 Cl 2 2
2
Cl
+ +
2 2
18. In the reaction given below, the total number of atoms having sp 2 hybridization in the major product P is
______.
(1) O3 (excess)
then Zn/H2O
P
(2) NH2OH (excess)
Ans. 12
Sol.
O O
O O
NH2 – OH
N – OH N – OH
HO – N N – OH

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19. The total number of possible isomers for [Pt(NH3)4Cl2]Br2 is ______ .
Ans. (6)
Sol. Total number of isomer of complex [Pt(NH3)4Cl2]Br2
(1) Cis - [Pt(NH3)4Cl2]Br2, (2) Trans - [Pt(NH3)4Cl2]Br2,
NH3 Cl
NH3 Cl NH3 NH3
Pt Pt
NH3 Cl NH3 NH3

NH3 Cl
Cis form Trans form

(3) Cis - [Pt(NH3)4BrCl]ClBr (4) Trans - [Pt(NH3)4BrCl]ClBr
NH3 Br
NH3 Br NH3 NH3
Pt Pt
NH3 Cl NH3 NH3

NH3 Cl
Cis form Trans form

(5) Cis - [Pt(NH3)4Br2]Cl2 (6) Trans - [Pt(NH3)4Br2]Cl2
NH3 Br
NH3 Br NH3 NH3
Pt Pt
NH3 Br NH3 NH3

NH3 Br
Cis form Trans form

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SECTION 4
• This section contains THREE (03) questions.

• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.


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• This section contains THREE (03) question stems.

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1. The major product formed in the following reaction is

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(A) 0.74 (B) 0.63 (C) 0.52 (D) 0.48

• This section contains THREE (03) question stems.

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Question Stem for Question Nos. 5 to 6

x g and y g are mass of R and U, respectively.

6. The value of y is ______.

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Question Stem for Question Nos. 7 and 8

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Question Stem for Question Nos. 9 and 10

9. The value of x is ___.

10. The value of |y| is ___.

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• This section contains SIX (06) questions.

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(A) O2N F (B) I

(C) Br (D) O2N

13. The correct statement(s) related to colloids is(are)

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white Dilute NaOH(aq) S Dilute HCl(aq) White

The correct option(s) for the salt mixture is (are)

Sol. Zn+2 Zn(OH)2  White

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• This section contains THREE (03) questions.

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NH3 Cl NH3 NH3

Cis form Trans form

NH3 Cl NH3 NH3

Cis form Trans form

NH3 Br NH3 NH3

Cis form Trans form

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• This section contains THREE (03) questions.

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