Sec: OSR.

IIT_*CO-SC GTA-12(P2) Date: 18-08-22

Time: 3HRS 2020_P2 Max. Marks: 198
KEY SHEET
PHYSICS
1 75 2 3 3 5 4 5 5 6
6 2 7 ABCD 8 ACD 9 AC 10 AD
11 AC 12 ABC 13 9 14 66 15 2
16 2.74 17 5 18 5

CHEMISTRY
19 1 20 6 21 8 22 5 23 6

24 5 25 BC 26 A 27 ABD 28 BD

29 ABCD 30 ACD 31 6 32 13.32 33 1

34 10 35 448 36 36

MATHEMATICS
37 9 38 2 39 4 40 4 41 2

42 5 43 AD 44 ABC 45 AC 46 ABCD

47 ABD 48 AC 49 0.02 50 1007 51 1998

52 512 53 503.50 54 0.50

Narayana IIT Academy 18-08-22_OSR.IIT_*CO-SC_JEE-ADV_GTA-12(P2)_KEY&SOL
SOLUTIONS
PHYSICS
1.

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5.

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8.

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11.

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14.

15. Consider the motions of the bodies both in the original frame of reference and in another frame that
moves with velocity v0 relative to the first one. Apply the Relative motion formulae. If Ann were
sitting at the centre of the disc, she would see the whole world around her rotating with the same
angular speed  , but in the opposite direction. That means she would observe Bob standing 12 m
away from the centre of the disc, but moving with a speed of 1 / 6  12  2 ms 1 in a direction
perpendicular to the line joining him to the centre of the disc. Although Ann is not sitting at the centre
of the disc, but at its edge, the same conclusion applies.
16. Conceptual
17.

18. The FBD of plate is shown in figure,

For transitional equilibrium mg = R + T

 2
For rotational equilibrium, R   T 
3 3
2mg
R
3

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CHEMISTRY
110  230  196.5   2.4  106  1.4  106  
103
19.
C
103 mol 106 1mg
C ; S  143.5 gm   1.00
143.5 litre 143.5 litre
20. Na2 S 2O3  4Cl2  5H 2O  2 NaHSO4  8HCl
 Excess 
15.8
Mole of Na2 S2O3   0.1 mol
158
Mole of Cl2  0.428
Na2 S 2O3  Limiting reagent
Mol of NaHSO4  2 mol of Na2 S2O3  0.2
0.2 mol of NaHSO4  24 g
21.

22. Only 1 amines give positive carbylamines test.

23.

24. Conceptual
25.  1  iCRT1
 2  iCRT2
If given volume remains same, so iCR are constant.
 2 T2

 1 T1
 T
But 2  2
 1 T1
It means C decreases so moles of AB decreases due to heating. This is Schottky defect.

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26. The reaction which has greater activation energy is more sensitive to temperature.
27. If edge length of cube is = 1 cm
Surface area 6 cm 2
If edge length of cube  1cm  102 m
Volume  106 m3
After division let length become  l
So, Volume  l 3
Total volume  1012  l 3  106
l  106 m
Surface area of one divided cube = 6  l 2  6 1012 m2
Total area  6 1012 1012  6m2  6 104 cm2
28. G   H   T  S 
For C  s   O2  g   CO2  g 
S  0
Lower line can reduce the metal oxide of upper line.
29. For (A)
30. P4  10 SO2Cl2  4 PCl5  10SO2
 A  B

31. l2 sublimes because of weak molecular force of attraction and not because of the strength I  I bond or
lone – pair lone pair repulsion.
32. o
Ecell  EOo 2 / H 2O  E Ho  / H  1.23V
2

Gcell
o
  nFEcell
o

For 1mol of H 2
For 10 3 mol of H 2 with 70% efficiency

 2  965001.23  103  0.7  U  1 

3 
R   T  ;
2 

T  

4  96500 1.23 10  0.7 
3

 13.324
3 8.314
33. Alnico contains Al , Ni, Co only
34. Neutral and acidic amino acids have pI less than 7.
X 5
X  5  10
2.8  4
35.  0.4  n  
0.0821  273
36.

6 membered cyclic transition state

X 6
X 2  36
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MATHEMATICS
37.

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