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ISH2017 - 153.diseño Optimizado de Aisladores de Alta Tensión Con Respecto A La Contaminación Extrema para Las Zonas Costeras de América Del Sur
ISH2017 - 153.diseño Optimizado de Aisladores de Alta Tensión Con Respecto A La Contaminación Extrema para Las Zonas Costeras de América Del Sur
ISH2017 - 153.diseño Optimizado de Aisladores de Alta Tensión Con Respecto A La Contaminación Extrema para Las Zonas Costeras de América Del Sur
The 20 International Symposium on High Voltage Engineering, Buenos Aires, Argentina, August 27 – September 01, 2017
Abstract: The western coast of both North and South America is dominated by the Pacif-
ic stream resulting in mainly landwards winds with high salinity. In addition huge industrial
areas and sea ports (Valparaiso, Los Angeles, Panama channel) are located along the
shore leading to significant air pollution. Therefore the insulator design has to focus both
on extended corrosion of the fittings and high partial discharge activity. The phenomenon
of corrosion amplifies significantly in those geographies where the following aspects are
additionally present: one, there is few rain that may wash away the pollution and second-
ly, tropical latitudes result in overall higher ambient temperatures and humidity. These are
ideal conditions for the electrochemical reactions accelerating both corrosion processes
and partial discharging. An example is the Peruvian coast. ISA and LAPP are jointly de-
veloping an insulator design for these regions. This shall be presented in this case study.
Zinc-coated steel fittings from standard construction steels like S355J2+N do not exhibit
sufficient long-term stability under the given local corrosion conditions. Investigations in
the corrosion properties of different ferritic and austenitic steel types enabled ISA to
demonstrate that the duplex steel 2205 (1.4462) is a cost efficient alternative to the oth-
erwise required highly alloyed austenitic steels. 2205 is characterized by a chromium con-
tent of 22 % resulting in corrosion properties similar to 904L with respect to PREN num-
ber. However, due to the duplex microstructure only 5.7 % in nickel content is required to
stabilize the microstructure compared to 20 % in the case of 904L. The reduced Ni- con-
tent restricts the surcharges of the fittings. The main drawback of duplex steel – the 375
°C embrittlement – does not pose any problems, as the operation temperature is well be-
low the usual operation limit of 200 °C reported in the literature.
The standard composite insulator body is overloaded by the described pollution condi-
tions, too. The hydrophobic properties together with Aluminium Trihydrate (ATH) filling of
high-temperature vulcanized silicone – in general seen as superior – needs in this case
an improvement to ensure the usual design life time of 40 years. Pollution induced partial
discharges lead to hot spots resulting in accelerated local degradation of the silicone
sheath. The formation of so called “morning stars” (puncture of the silicone sheath) allows
water/ steam entering the GFRP rod. Stress corrosion cracking and treeing, respectively,
then lead to a rapid mechanical failure of the insulator. For such site conditions Lapp has
developed an additional layer featuring microvaristors. Microvaristors are semi-conductive
nanocomposites that switches at a materials- controlled threshold from insulating to con-
ductive. This feature enables to restrict electric field to the threshold value thus offering
an effective protection for the composite insulator.
ISA and LAPP plan to test this promising solution at selected sites in vicinity to the coast-
line to demonstrate their suitability for the long-term use in the harsh conditions of west-
ern parts of South and North America.
For the experimental process, five samples of Microvaristor layers have to be designed according
stainless steel fittings have been taken from ISA to geometric features as well as to the break-
Group transmission lines, located in areas of high through voltage. In the given case a breakthrough
corrosive aggressiveness. Figure 5 shows some of voltage of 500 V/mm has been selected. Nonlinear
the fittings used in the analysis. FEM has been developed based on the quasi-
static assumption and demonstrated to accurately
predict the behaviour of microvaristor layers [9]. The curves has been performed in a potentiostat
This tool has been used to design the insulators. AUTOLAB at a scanning range of 100 mV from the
Afterwards prototypical OHTL insulators have been cathode zone, up to 600 mV in the anode zone
produced using a microvaristor enhanced layer with respect to the open circuit potential. [1]
between the GFRP and the silicone sheath with a
microvaristor content of 75 wt.-%. These proto- In the case of austenitic stainless steel, a positive
types have been tested in the High-Voltage Labor- hysteresis has been observed on both electrodes
atory of TU Darmstadt [9]. While energizing the (return currents have been found to be little higher
insulators have been monitored using UV daylight than the departure ones). This means that if the
camera thus being able to determine the corona material is corroded by localized corrosion, re-
activity. passivation would be difficult. This situation is pre-
sented in the same way for martensitic and ferritic
4 RESULTS steels. The duplex stainless steel is the only mate-
rial that presented a trend of re-passivation in the
4.1 DUPLEX STEELS FITTINGS middle of chlorides.
4.1.1 Alternate corrosion test in saline environment 4.1.3.1 Potentiokinetic reactivation method.
The tests have been performed in NaCl solution at Potentiokinetic reactivation tests have been per-
5%, according to ASTM G44 standard, on all spec- formed in order to obtain the degree of sensitiza-
imens. Each material has been evaluated in tripli- tion of each material in the medium of exposure
cate. According to ASTM G44 standard, immer- suggested by the ASTM G 108 standard. This test
sion-drying cycles of 10 and 50 minutes, respec- has been performed on all samples, both without
tively, under controlled conditions of relative hu- and with mechanical stresses. The results obtained
midity (45 ± 10%) and temperature (27 ± 1 °C) are presented in Table 1. [8]
have been conducted. The specimens have been
inspected twice a week with the help of a magnify- Table 1: Electrochemical Reactivation [8]
ing glass, in order to look for signs of cracking in
the central area of the specimen. In total the sam- Corrosion Corrosion
Steel grade
ples have been exposed for 2160 cycles corre- potential [V] current [A]
sponding to 3 months of testing. None of the sam- -5
SAF2205 0.06 2x10
ples have exhibited any cracking. [8]
-5
AISI SAE 430 -0.40 5x10
4.1.2 Saline Fog Chamber Tests -5
17-4 PH -0.37 6x10
Conventional salt fog tests have been performed in 316L -0.31 8x10
-5
elonga- Hard-
tensile Yield
Steel tion at ness
strength strength
grade fracture Brinell
[MPa] [MPa]
[%] [HB]
However, according to [11] a microvaristor/ Sili- The reported investigations have been conducted
cone layer does not achieve the creepage re- to develop a solution that is able to withstand the
sistance seen as necessary for the use in highly specific site conditions of the Peruvian cost in the
polluted regions. LAPP is currently still engaged in long run. These dry, though very humid conditions
at high ambient temperatures in excess of 30 °C [6] H. Ye, M. Clemens, J. Schulte-Fischedick and
result in significant corrosion to standard construc- J. M. Seifert, „Investigation of Electrical Field
tion steels as well as significantly triggering partial Grading of Bushings with Microvaristor Filled
discharges on the silicon sheath. Thus lifetime of Epoxy Resin Components“, 2014 IEEE Int.
composite insulators is currently restricted to ap- Power Modulators and High Volt. Conf., Santa
proximately 10 years. Fé, USA, June 2014
[7] IEC 60137, “Insulated bushings for alternating
With respect to corrosion of fittings duplex steels voltages above 1 000 V”, 2008.
have been found as a promising solution. Corro- [8] C. Córdoba, J. Castaño, J. Calderón and F.
sion behaviour is superior to that of 316L stainless Echeverría, “Elaboración de Especificaciones
steels as confirmed by potentiometric measure- Técnicas de Control de Calidad para Herrajes
ments. I.e. it has been proven that in contrast to de Acero Inoxidable en Líneas de Transmisión
316L and other ferritic and martensitic candidates de Energía Eléctrica”, pp. 1- 75, 2012.
2205 is able to re-passivate even if it has been [9] D. Weida, J. Nevoigt, H. Ye, M. Clemens, D.
sensitized (for corrosion). This clearly demon- Stefanini and J. Seifert, "Effects of Microvaris-
strates its suitability for the given case, as 316(L) is tor Material on Partial Discharges upon Com-
generally seen as reference for applications in vi- posite Insulators in Rain Test," Int. Power
cinity of sea shores. However, in contrast to 316L Modulators and High Voltage Conf. (IPMHVC
duplex steels avoids high nickel contents thus limit- 2010), May 2010, Atlanta, USA.
ing alloy surcharges. Thus duplex steels can be [10]J. Maya, “Herrajes de Acero Inoxidable para
seen as a cost efficient and superior alternative to Líneas de Transmisión de Energía Expuestas
the otherwise required austenitic stainless steels. en Atmósferas Marinas Agresivas”, pp. 1- 8,
2015.
Microvaristors have been demonstrated to provide [11]J. Debus, Untersuchung der Anwendungsmög-
a mean to level electric fields to uncritical levels. lichkeiten mikrovaristorgefüllter Feldsteuerele-
Thus these particles significantly reduce the partial mente in der elektrischen Energietechnik, PhD
discharge activity. While in principal the mecha- thesis, 2014.
nisms have been proven, the design of the mi-
crovaristor- enhanced insulator is an optimization
challenge between creepage resistance and su-
pressing partial discharge activity. This optimiza-
tion has not yet satisfactorily been solved.
REFERENCES
[1] D. Gómez, J. Maya, J. Garcés and L. Porras,
“Especificaciones Técnicas de Aisladores Po-
liméricos para Zonas de Alta Agresividad Cor-
rosiva y Contaminación”, pp. 1- 8, 2015.
[2] Outokumpu Duplex Stainless Steel Datasheet,
"http://www.outokumpu.com/sitecollectiondocu
ments/outokumpu-duplex-stainless-steel-data-
sheet.pdf", last accessed: March 15, 2017.
nd
[3] A. J. Sedriks, Corrosion of Stainless Steels, 2
ed., Johns Wiles & Sons, New York, 1996.
[4] D. R. Clarke, “Varistor ceramics”, J. Am. Ce-
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[5] J. Schulte-Fischedick, F. Lehretz, H. Denn-
dörfer, J. Debus, V. Hinrichsen, H. Ye, M.
Clemens and M. Bornowski „Electric field grad-
ing using insulators with microvaristor filled sili-
th
con rubber”, 13 Int. Conf. Solid Dielectrics,
Bologna, Italy, July 2013.