OUT GOING SR(MPC) Date: 09-06-2022

Time: 3 Hrs Max. Marks: 300

09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL

PHYSICS -KEY SHEET

01-10 2 3 2 4 3 3 4 4 4 3
11-20 4 4 3 1 1 2 4 3 3 1
21-30 5 6 16 3 300 6 8 245 2 11

CHEMISTRY -KEY SHEET

31-40 3 4 4 2 2 2 4 3 2 1

41-50 3 2 4 2 2 1 3 2 1 3

51-60 2 18 45 8 2 2 82 112 117 300

MATHEMATICS -KEY SHEET

61-70 2 2 2 1 3 2 1 1 2 1
71-80 3 1 4 4 3 3 1 1 1 2
81-90 8 5 20 2 21 5 4 32 2 6
 Narayana IIT Academy 09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL

PHYSICS –SOLUTIONS
SECTION – I (SINGLE CORRECT ANSWER TYPE)
1.   35.72''  35.72'' 4.85 106 rad  1.73 104 rad
 Diameter of Jupiter
D  r  824.7 109 1.73 104
D  1.43 108 m  1.43 105 km
 mg
2. f min 
1 2
3. T1 cos 37 0  T2  cos 530
4 3
T1  T2
5 5
T 3
4T1  3T2  1 
T2 4
4. Tmax  4Tmin
mu 2  mv 2 
 mg  4   mg 
l  l 
2 2
u  v  4 gl
v  10 m / s

 a 2   0     a 2  a3
5. rcm 
   a 2    a 2 
6. Radius of gyration of a body depends upon its axis of rotation and also depends on mass
distribution about the axis.
110 Mg 63 10
7. P1  P0  105 Pa  4
 2 105 Pa ; P2  P0   105  4
 64 105 Pa
10 A 10
5 5
T T
For adiabatic process 11  21
 400  3 
T23
2 2
P1 P2
 2 10 
5 5
 64 105  3
2
T2  400  32   400  22 1600 K
5

d E d d V 
8. I D  0   0  E. A    0 A  
dt dt dt  d 
 A dV dV
Or I D  0 C
d dt dt
dV I D 2
   6  2 106 V / s
dt C 10
Hence the correct answer will be (4)
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h
9.   p  h Graph is rectangular hyperbola.
p
log e 2 log e 2 N log e 2
10. Tu2   
 Be A/ N A
It
Number of protons bombarded  N p  
q
Np it
N 
1000 q  1000
it ln 2
T1/2    8.66 106 sec
q 1000 A
i  de ie nh 7 5 5
11. Using vd  we get ;     
n  dh ih ne 4 7 4
Amax  Amin
12. Modulation Index,  
Amax  Amin
13. The potential difference between two concentric shells does not depend on the outer
shell charge so it will remain the same.
 r  r 
14.  eq   1 2 2 1  Clearly  eq is between 1 and  2 . 1   eq   2
 r1  r2 
15. Currents in same direction attract
16. The induced emf across the element of length dx is
de  Bvx dx  B  x  dx.

b
e  B  x dx =

B b 2  a 2 
The emf across the whole rod
a
2
17. Both V and I are in the same phase. So, let us calculate the time taken by the voltage to
change from peak value to rms value. Now 220  220 sin100 t1
 1 220
(or) 100 t1  (or) t1  s again,  220 sin100 t2
2 200 2
1 3 3
(or)  sin 100 t 2 (or) 100 t 2  (or) t2  s
2 4 400
1
Required time t 2  t1  s  2.5  10 3 s
400

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2 D
18. Width of central bright fringe 
a
D
Width of first bright fringe 
a
 V 
19. f min  f 0  
 V  r 
d2x
20. Use 2  2 x  0
dt

SECTION-II (NUMERICAL VALUE ANSWER TYPE)

2
V2 
21. a  a  a     aT2  32  42  5
2
C
2
T
 R 
v1 r 3V 1
22.  2  
v2 r1 v2 4
23. mT  Constant P T4
24. The charge on the capacitor before and after insertion of dielectric is given as
50 1
Q1  C1V Q2  C2 V   k=3
 
150 k
25. V   E. r  100  2 cos 60 0 

1 1 1 1 7 1 1
26.  R 2  2  10
 1.097  10  2  2 
 n2  4
 n
 1 n2  970.6  10  1 n2 

n  n  1 4  3
 Number of emission lines N    6.
2 2
27. cot 2   cot 2 1  cot 2  2    cot 1 cot 2 1  cot 2  2
28. 1cm  
2

2 gh  70  10 6 h  2.45 cm
29. w    MB cos180     MB cos 0  ; w  2 MB ; w  2 Ni R 2 B
f hi
30. 
For real image m = f  16 h
0

 hi' f '
 For virtual hi  hi
h0 f 6

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f f
   2 f  22; f  11 cm
f  6 f  16
CHEMISTRY –SOLUTIONS
SECTION – I (SINGLE CORRECT ANSWER TYPE)
31. 1) NH 4 NO2  N2  2 H2O 2) NH 4 NO3  N2O  2 H2O
3) 4LiNO3  2Li2O  4 NO2  O2 4) 2 NaNO3  2 NaNO2  O2
1 1
32. v  RZ 2  2  2  ; v &v are directly related
n
 1 n 2 

On calculation v1  1, v2  4& v3  3
33. x millimoles of Na2CO3 and y millimoles of NaOH are present in initial mixture
x  y  20 ; x5 ; 2 x  y  25 ; y  15
x 1
 
y 3
34. 1)

(Planar distorted-T shape and polar)

2)

Xe

3)
Cl Cl

P
 Non  planar and non  polar 
Cl Cl
Cl
In genl. Strong ligands form low spin complexes and weak ligands form high spin
complexes.
36. This is due to increasing stability of lower species to which they have reduced
 3 2 
0.0591 
 Cr  1 
37. o
ECr O2 /Cr 3  ECr O2 /Cr 3  
 log 
2 7 2 7
6  Cr 2O72   H  14 
   

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0.0591 1
ECr O2 /Cr 3  1.33  log  1.0542V
2 7
6 (0.01)14
38. Ring activity towards further EAS.
1 Kb  salt 
39. PH  7 
2
P  log C  ; P OH  P K b  log
 Base 
  2
40. Au   2CN    Au  CN 2  (X) ; 2  Au  CN  2   Zn   Zn  CN  4  (Y)  Au
41. Atomic radius of noble gas is highest in the respective period
42. IMF are responsible for deviation from Raoult’s law.
43. Ref. NCERT, Tyndal effect.
44. TLC is solid –liquid type chromatography
45. Due to ortho effect of nitro group acidic strength increases
46. Due to strong bond
47.
OH
O OH
HIO4 NaBH 4
OH

O
dill H 2 SO4
CH 3CH 2  C  CH 3
48. (B) CH 3  CH 2  C  CH  H 2O HgSO4
49.

50. Barfoed’s reagent is the mixture of acetic acid and cupric acetate. It is useful to
distinguish reducible disaccharides from monosaccharides. On boiling with Barfoed’s
reagent, monosaccharides give red precipitate in 2-3 min but reducible disaccharides
take more than 3 min to form red precipitate  Cu2O 

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SECTION-II (NUMERICAL VALUE ANSWER TYPE)

51.

In amides, nitrogen lone pair is involved in conjugation

52.

53. Resonance energy  5  28.8  99  45 Kj / mol ; Expected enthalpy – actual enthalpy

54. At 00 C , Crystals of Cl2 .8H2O are formed
55. 4Zn  10HNO3  4Zn  NO3 2  N2O  5H 2O
Out of 10 moles of HNO3 , only two moles of HNO3 reduced and the remaining eight
moles are spectators
1.386
0.693 a 0.693 1.386 K0
56. K1  ; K0  ; K1  ; K0  ;  40  2
t1/ 2 2t1/ 2 40 2x20 K1 0.693
40
18
118 18 d theor 50
57. dtheor   Z  41 
0.0821 500 41 dExp 36 41
100
200
58. 10v of H2O2 =1.786N ; N1V1  N2V2 ; 1.786 x X=1 x 200 ; X=  112
1.786
r1 r1
59.  0.414 for octahedral void  0.225 tetrahedral void
r2 r2
r1 - radius of atoms in interstitial void r2 - radius of atom which from FCC
In FCC atoms touch each other along face diagonal 4r2  2a
Required diameter of interstitial sites  2r1   d  2  0.414r2

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2  0.414  2a 0.414  1.414  400

; = 117 pm
4 2
60. S  100 J k 1 mol 1
H vap  H g  H L = –100 –( –130) = 30kJ
H
T
S
30 1000
T=  300
100

MATHMATICS –SOLUTIONS
SECTION – I (SINGLE CORRECT ANSWER TYPE)
61. (2)
If x  a : x 2  2 a  x  a   3a 2  0  
 x  a 1 2  x  a 1 2  
If x  a : x 2  2ax  5a 2  0 
 x  a 1  6   x  a 1  6
62. (2)
z1  2 , a circle of radius 2 and
1  i  z2  1  i  z 2  8
2 represents a straight line
 AB is minimum along a line y  x
A   
2, 2 , B  2 2,2 2 
 AB  OB  OA  16  4  2
63. (2)
a b  2  a 2  bc ab  bd 
A  A  2
and A  ad  bc ; Tr  A  a  d
 c d   ac  cd bc  d 
64. (1) Sum of last 20 coefficients  39C20  39C21  ..........  39C37  39C38  39C39  238  2P
P  38 divisible by 19
65. (3)
 a x 1   b x 1 
x x 2/ x Lt   
 a b     
Lt   6 e
x  0 x
 
x
 6  e log e a  log e b  6 ; ab = 6
x 0
 2 
 a, b   1, 6  ,  6,1 ,  2,3 ,  3, 2
4 1
Required probability = 
6 6 9
66. (2) a, ar , ar 2 , ar 3 ; ar 2  a  9; r  ar 3  18  r  2 a3
67. (1)
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A tautology is a logical expression that is always true expression  p  q    p  q 

p q  p  q pq  p  q   p  q
T T T T T
T F F F T
F T F T T
F F F T T

Verification  p  q    p  q  ~  p  q    ~ p  q    ~ p ~ q    ~ p  q 
~ p   ~ q  q  ~ p  t  t Hence  and  are  and 
68. (1)
Given x1  y1  8  y1  8  x1 ; x 2  y 2   8  y 2  8  x 2 ;
x 3  y3  8  y3  8  x 3 and
x1 8  x1 1
Now check x 2 8  x 2 1 value of this determinant comes out to be zero.
x3 8  x 3 1
69. (2)
a a a
y  mx   m 2 x  my  a  0 ; m1m2   x
m x 2
70. (1)

71. (3) Line r   2  3  i   1  4  j   2  2  k

 
Plane r. i  j  k  5
For point of intersection r   2  3 1  1 4  1  1 2  2   5    0
point of intersection = (2,-1,2)
The distance of point of intersection from the origin = x2  y 2  z 2  3

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cos  sin x   cos x 2  sin x  x   sin x  x 

72. (1) lim 4
; lim  4 sin   sin  
x 0 x x  0 x  2   2 
 sin x  x   sin x  x 
sin   sin   sin x  x sin x  x 1
2 2    
 lim  2  . 
  3 
x0  sin x  x   sin x  x   x  x 4
   
 2   2 
 x3 x5 
 x     x 
2  sin x  3! 5! 1  1 1
  1 1  Lt   1  lim  3   1  1     
4 x0
 x  x 0  x  2  6 6

 
73. (4)
f  x  is continuous at x  0  f  0   lim f  x   lim f  x 
x 0 x 0

Use the expansion of sinx , cosx ; We get   1 ,   4 ,   0 , e  3
74. (4)
For each value of x , the helicopter’s position is at a point  x, x 2  7  . Therefore, the
2 2
distance between the helicopter and soldier placed at  3, 7  is  x  3   x2  7  7  ,
2
i.e.,  x  3  x4 .
2
Let f  x    x  3  x 4 or f '  x   2  x  3   4 x 3  2  x  1  2 x 2  2 x  3
Thus f '  x   0 gives x  1 or 2 x 2  2 x  3  0 for which there are no real roots. Also there
are no end points of the interval to be added to the set for which f '  x   0 .
i.e., there is only one point, namely, x  1 at which f '  x   0 . The value of f at this point
2 2
is given by f 1  1  3  1  5.
Thus, the distance between the solider and the helicopter is f 1  5
Note that 5 is either a maximum value or a minimum value. Since
2 2
f  0   0  3   0   3  5,
It follows that 5 is the minimum value of f  x  . Hence, 5 is the minimum distance
between the soldier and helicopter.
75. (3)
9 y 2  x3 .............. 1
dy 3 x 2 x 2
  ; Given slope of normal  1
dx 18 y 6 y

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6 y
2
  1, 6 y  x 2      (2)
x
Solving (1) and (2), we get P  4, 8  .
 3
Equation of the tangent at ‘P’ is 3 x  3 y  4  0
76. (3)
1 2e 2 x ex
2  e2 x  1  e x 2  1 dx
dx  2
 
1 d  e  1 d ex  1
2x

  2x 2  log e  e 2 x  1  2Tan 1  e x   c

2  e  1 2
e   1 2
x

77. (1)
1
xdx
Let I   , put x  t  x  t 2 ; dx  2tdt
0 
1  x  3  x 
1
2t 2dt
1
3 1  t 2    3  t 2  1
3dt
1
dt 3  t  1
I  dt    tan 1   / 0  tan 1 t /10
0 1  t  3  t  1  t 2  3  t 2 
2 2 2 2
0 0
3  t 0 1 t 3  3
       2 
 3       2 3  3    1
 6  4 2 3 4 12 4 3 
78. (1)
 dx dy   x 2 dy  y 2 dx 
Rearranging the terms of differential equation, we get      0
 x y    x  y 2 
Observing the complete differentials, by method of inspection
  dy dx      dy dx 
     1   y2  x2 
 dx dy    y 2 x 2  
   0 d  
y    1 1 2   1  1    1 1  
2
 x      y x     
  y x      y x 
1 x xy
 ln x  ln y  C  ln     C is the general solution
1 1  y   x  y
x y
 
79. (1)
Let P  2  cos x  sin 2 x  2  cos x  1  cos 2 x  3   cos 2 x  cos x 
2 2
 1  1  13  1
 3   cos x        cosx  
 2  4  4  2
13 1 13 9
Pmax  , when cos x   Pmin    1 when cos x  1
4 2 4 4
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Pmax 13
 
Pmin 4
80. (2)
x2  x
y (or) x 2  x  y  axy (or) x 2  x  ay  1  y  0
1  ax
Since x is real we get
2
 ay  1  4 y  0 (or) a 2 y 2  2 y  2  a   1  0y  R ; So, as a 2  0 ,
2
4  2  a   4a 2  0
(or) 4  4a  0 (or) a  1,  
When a =1, the function is not onto.
SECTION-II (NUMERICAL VALUE ANSWER TYPE)
INTEGER MODEL QUESTIONS

81. (8)
a b 
M   ; a  b  1  a  2b  1 ; c  d  2  c  2d  0 ; a  1, b  0 c  4, d  2
 c d 
82. (5)
Let A, B,C be the sets of arrangements in which blocks 34,45,678 appear respectively.
Then n( A)  8!, n( B)  8!, n(C )  7!
n( A  B)  7!, n( B  C )  6!; n(C  A)  6!n( A  B  C )  5!
The required number of arrangements = 9! (8! 8! 7!)  7! 6! 6! 5! k  5
83. (20)
2
The total number of reflexive relations  2n  n
84. (2)
12  14 122  142 2
For 12, 14 : Mean   13 ; 2   13  170  169  1
2 2
12  14    
For 12,14,  ,   13 (Given) ; 26      52 ;     26
4
122  142   2   2 2
 13  1 Given  ; 340   2   2  4 170
4
2 2
    680  340 ;  2   2  340
2
      2   2  2 ; 676  340  2 ; 336  2 ;   168
2 2
      2   2  2  340  2 168 ;     4 ;   2
85. (21)
a  b  c 1
2 2 2 2 2 2 2 2 2
a  2b  b  2c  c  2a  a  4 b  4a.b  b  4 c  4b.c  c  4 a  4c.a

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
 15  4 a.b  b.c  c.a 
3
a  b  c  0 
 3  2 a.b  b.c  c.a  0  
  a.b  b.c  c.a   2
=15+6=21
86. (5)
x1  x2 y1  y2 z1  z2
If A, B, C, D are coplanar x1  x3 y1  y3 z1  z3  0
x1  x4 y1  y4 z1  z4
1 x2 4
1 0 3  0  1 0  9    x  2  2  9   4  3  0   0
3 3 2
 9  7  x  2   12  0  9  7 x  14  12  0  7 x  35  x  5

87. (4)

3 2 2
3 cos 3x  3cos x 3  sin 3x  2 3  1 
 cos x dx  6  cos3 xdx  6  dx    3sin x     3  4
0 0 0
4 2 3 0 2  3 
88. (32)

(0,7)

(0,1)
(4,3)

(-2,0) (2,0) (4,0)

(-7,0) (7,0)
2 4
  x2    x2 
2   7  x   1    dx  2  7  x     1dx  32 sq.units
0  4  2  4 
89. (2)
20
  1 
1
Since,   sin xi  and
2 2
 sin
i 1
xi  10  sin 1 xi 
2
, ;  1  i  20
20
 xi  1, 1  i  20. Thus xi 1
i  20

90. (6)
Centre of circle S1 = (2, 4) ; Centre of circle S2 = (4, 2)
Radius of circle S1 = radius of circle S2 = 4  equation of circle S2
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(x – 4)2 + (y – 2)2 = 16
 x2 + y2 – 8x – 4y + 4 = 0 . . . (i)
Equation of circle touching y = x at (1, 1) can be taken as
(x – 1)2 + (y – 1)2 + (x – y) = 0
(or) x2 + y2 + x ( – 2) + y(–  – 2) + 2 = 0 . . . (ii)
As this is orthogonal to S2
2   2 
 2  (– 4) + 2   (– 2) = 4 + 2
 2   2 
 – 4 + 8 + 2 + 4 = 6
 required equation of circle is
x2 + y2 + x – 5y + 2 = 0.
1 25 26  8 18 3 3
Radius =  2    2  2
4 4 4 4 2 2

09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL

Q.NO SUBJECT TOPIC SUB TOPIC

1 PHYSICS Physical world Measurements
2 PHYSICS LAWS OF MOTION Friction
3 PHYSICS LAWS OF MOTION Equilibrium
4 PHYSICS WORK, ENERGY& POWER Circular motion in vertical plane
5 PHYSICS SYSTEM OF PARTICLES & ROTATION Centre Of Mass
6 PHYSICS SYSTEM OF PARTICLES & ROTATION Moment of Inertia
7 PHYSICS Thermodynamics Workdone
8 PHYSICS Electro Magnetic Waves Energy density
9 PHYSICS Dual Nature and Radiation Matter Waves
10 PHYSICS Nuclei Radioactivity
11 PHYSICS SEMI CONDUCTOR DEVICES Drift velocity
12 PHYSICS Communication systems Modulation
ELECTROSTATIC POTENTIAL AND
13 PHYSICS CAPACITANCE Electric Potential
14 PHYSICS CURRENT ELECTRICITY Cells
15 PHYSICS Magnetic Effect Of Current Force between currents
16 PHYSICS ELECTROMAGNETIC INDUCTION Induced emf
17 PHYSICS ALTERATING CURRENT rms value
18 PHYSICS WAVE OPTICS Diffraction
19 PHYSICS Waves Doppler effect
20 PHYSICS Oscillations Differential Equation of SHM
21 PHYSICS Motion in a plane Horizontal circular motion

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 Narayana IIT Academy 09-06-2022_OUTGOING SR _JEE MAIN MODEL GTM-7 _QP FINAL

22 PHYSICS GRAVITAION Orbital velocity

23 PHYSICS Thermal properties of matter Radiation
24 PHYSICS Capacitors Dielectric
25 PHYSICS Electrostatics Electric potential
26 PHYSICS ATOMS Bohr’s Atomic model
27 PHYSICS Magnetism & Matter Elements of Earth magnetism
28 PHYSICS Properties of Fluids Equation of continuity
29 PHYSICS Magnetism Magnetic material
30 PHYSICS Ray Optics And Optical Instruments Lenses
31 CHEMISTRY 15th Group OXIDES OF NITROGEN
32 CHEMISTRY ATOMIC STRUCTURE SPECTRUM
33 CHEMISTRY STOICHIOMETRY ACID BASE TITRATION
34 CHEMISTRY CHEMICAL BOND VSEPR
35 CHEMISTRY COMPLEX COMPOUNDS VBT
36 CHEMISTRY D & F BLOCK ELEMENTS OXIDISING AGENT STRENGTH
37 CHEMISTRY ELECTRO CHEMISTRY SINGLE ELECTRODE POTENTIAL
38 CHEMISTRY EXPERIMENTAL CHEMISTRY acetanilide PREPARATION
39 CHEMISTRY IONIC EQBM SALT HYDROLYSIS
40 CHEMISTRY METALLURGY LEACHING
41 CHEMISTRY PERIODIC CLASSIFICATION PERIODIC PROP.
42 CHEMISTRY SOLUTIONS LIQUID SOLUTIONS
43 CHEMISTRY SURFACE CHEMISTRY COLLOIDS
44 CHEMISTRY Purification and identification Purification
45 CHEMISTRY GOC Acidic Strength
46 CHEMISTRY Aliphatic hydrocarbons Preparation of Alkanes
47 CHEMISTRY Alcohols, Phenols Properties of Alcohols
48 CHEMISTRY Aliphatic Hydrocarbons Properties of alkynes
49 CHEMISTRY Multiple Concepts Multiple concepts
50 CHEMISTRY Biomolecules Identification Tests
51 CHEMISTRY Chemistry in everyday life Drugs
52 CHEMISTRY Benzene and Phenols Properties of phenol
53 CHEMISTRY GOC Resonance
54 CHEMISTRY 17th Group CHLORINE
55 CHEMISTRY STIOCHIOMETRY REDOX REACTIONS
56 CHEMISTRY CHEMICAL KINETICS ZERO AND FIRST ORDER
57 CHEMISTRY GASEOUS STATE COMPRESSIBILITY FACTOR
58 CHEMISTRY HYDROGEN H2O2
59 CHEMISTRY SOLID STATE VOIDS IN FCC LATTICE
60 CHEMISTRY THERMODYNAMICS Delta G & Delta S
61 MATHS STRIGHT LINES CENTRES
62 MATHS HYPERBOLA PROPERTIES OF ASYMPTOTES
63 MATHS VECTOR ALGEBRA SCALAR TRIPLE PRODUCT
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64 MATHS 3-D LINES DISTANCE FROM PT TO LINE

65 MATHS FUNCTIONS DOMAINS
66 MATHS DERIVATIVES I.T.F DERIVATIVES
67 MATHS INEQUALITIES A.M , G.M
68 MATHS A.O.D MEAN VALUE THEOREMS
69 MATHS INDIFINITE INTEGRATION TRIGONOMETRY INTIGRATION
70 MATHS AREAS AREAS UNDER PARABOLA , LINE
71 MATHS TRIGONOMETRY TRANSFORMATIONS
72 MATHS CIRCLES RADICAL AXIS
73 MATHS PROGRESSIONS A.P, G.P, H.P
74 MATHS DETERMINANTS PROPERTIES
75 MATHS BINOMIAL THEOREM GENERAL TERM
76 MATHS P&C SELECTION FROM SIMILAR ITEAMS
77 MATHS PROBABILITY BAYE’S THEOREM
78 MATHS SEQUENCE & SERIES G.P.
79 MATHS SETS SUBSETS, CARDINAL NUMBERS
80 MATHS STATEMENTS BI- IMPLICATIONS
81 MATHS PARABOLA No. of INTERSECTIONS OF PARABOLA WITH CIRCLE
82 MATHS 3-D PLANES FAMILY OF PLANES
83 MATHS LIMITS INDERMINANT FORM (0/0)
84 MATHS DEFINITE INTEGRATION KINGS PROPERTY
85 MATHS DIFFERNTIAL EQUATION SOLVING FUNCTIONAL EQUATION
86 MATHS I.T.F SUM OF TWO I.T.F.S
87 MATHS COMPLEX NUMBERS ARGUMENTS PROPERTIES
88 MATHS MATRICES SYSTEM OF EQUATIONS
89 MATHS STATISTICS VARIENCE
90 MATHS PROBABILIY ADDITION THEOREM

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