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    LT amino acid

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    20 views8 pages

    LT Amino Acid

    Uploaded by

    Phong Nguyễn

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    Download as pdf
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    {HE OUTME-D FIAT Ka BuNa EON Ta HGH UE gp HATA NRUBLOT TETAS FT nex oot | se | at ouuen ey _ foam) som | ror] ae | st a 0 f 3 en eee "ay moo fe |e | me | sont om | se | ae | ei | woo Ww Te vuniny | w |xomsy | augrnegn | aw foe ‘jomuedendouque opm SupRSEORETAL TN ‘syoouedoadouyer- zap tp 429391, HOOD HD Tze PIA 20+ gop ita ye Bap Surg ou uoepeespy up vom + 20 qu pb gay fe ooEEADA (78°295 amp) HN wou in ya 98 + ape =aRTEORTUTY ‘gm dein io ugnqem, ‘woe ‘iy, Ww 000-H) 4 = HOD 2 Sup ug gD o00*10-w ADM “woo -1ap—e>pqU AN - OME oa inpenpmmuped gaan dé zsnarypp dou enysu quig (+e WD “Nae + HOOD “HNL 00H: aD = (DA HoCD-H0-Ni up SuQL HO HOH wear IrU PP BEE =A=© Ju ab «40a "CAN eget Bone pipBampen> ore aH UAL ts | U+H000~%9-08 © ‘OM HOO) Aa Toni vov'n- moms era urea ow eafa0c9~1O-NH PHN HOOD “HO-WHE si ofan wed Hoc) - oH Begun 9 vapor tt+"£00- Fro) -H}— nooo Fel -N ‘Suntu Sanaa wpa ER ep ETI HD TOTO a aage) ye aS URORTH NHL UR Ba PESTA A SMNRY » * a ary aR aS AB HoT [1 A UETTTOOTE TTY AMINO AXIT 1. Dinh nghia La hop chat hin co tap chitc ma phan tit chita dong thoi nhém amino -NH2 va nhém cacboxyl -COOH. 2. Cu tao phan tir: Ion long ewe ReAH.COOH a R-GH-COO: NH *NH3 phan tir ion hong eye 3, Danh phap © Tén thay thé: Amino axit = axit + s6 chi vj tri nh6m NH; (chtt s6 2, 3,...) + amino + tén hidrocacbon no twong ting véi mach chinh + oic. © Tén ban hé thong: Amino axit = axit + s6 chi vi tri nhém NHz (chit cdi Hi Lap o, 8,...) + amino + tn axit thong thong. Vidu: a 324 CH -CHH-COOH NH — Ten thay thé: Axit 2 - aminopropanoic. ‘Tén ban hé théng: Axit o.- aminopropionic. © Tén thudng: Em hay hoc thudc léng bang sau f ae |b Gi) | cheyenne H,N-CH, -COOH Glyxin Gly 75 khéng CH -CH-COOH Alanin Ala 89 khong NH, CH -CH-GH-COOH valin val 117 khéng CH3NH wo-€_)—chi,- cH - COOH ‘Tyrosin Tyr 181 khong NH, Ho00C {CH,|,-CH-COOH Axit glutamic Glu 147 as NH, | NH -{cH| ;CH-COOH Lysin Lys 146 xanh Ny 4, Tinh chat vatly o LAchat ran, khéng may, vi ngot, dé tan trong nwée. o Cac amino axit trong thién nhién 1a c-amino axi 5. Tinh chat héa hoc Y Tinh chat luéng tinh HN - CHo - COOH + HCl C1H,N - CH; - COOH H2N - CH2 - COOH + NaOH — H2N - CH2- COONa + H20 v Tinh axit - bazo cla dung dich amino axit a>b—xanh (Nily)q-R-(COOH)s + quy tim :| 2= > > KhOngdéi mau a H2N - CH2—COONa + 1,0 ¥ Tinh axit~ bazo-cita dung dich amino axit a>b-—>xanh (NHL),-R-(COOH), + quy tim: | *= b> khéngdéi mau ach Y Phan img tring ngung nHN-[CHy]5-COOH S24. LNH-(CHy]5-CO}, +nH,0 BAI TAP MAU va Co ban Cau 1: Phacbiéu khong ding 1 A. Trong dung dich, H:N-CH-COOH cdn tn tai & dang ion hong oye H, NCH, ~COO™ . B. Amino axit la hop chat hiru co’ tap chitc, phan tir chira dBng thi nh6m amino va nhém cacboxyl C. Amino axit 1a nhitng chat ran, két tinh, tan tt trong nuéc va co vi ngot. D. Hop chit HeN-CHz-COOH:N-CH; a este ciia glyxin. Huéng dan giai A ding: NH,-CH,-COOH <= H,N-CH,-COO- B ating: Amino axit 1a hop chat hiru co’ tap chit, phan tir chita dOng thdi nhom amino -NHz va nhém cacboxyl -COOH (SGK 12 nang cao - trang 63). C ding (SGK 12 nang cao - trang 64). yp chat H2N-CH2-COOH:N-CHs tao nén tle phan tig axit-bazo clia glyxin HaN- CHz-COOH va amin CHsNHz nén kh6ng [a este cila glyxin HN-CHz-COOH + CHsNH2 —> HoN-CHz-COOH:N-CHts > ap dn D Cau 2; Amino axit ndo sau day lim xanh quy tim? A. Axit glutamic. B. Alanin. C. Lysin. D. Valin. Hwéng dan giai ‘Axit glutamic: HOOCCH (NH2)CH:CH:COOH Lysin: HaN[CHz]«CH(NH2)COOH Alanin: CHsCH(NH,)COOH Valin: (CHa)2CHCH(NH2)COOH = Lysin cé sé nhém NHz nhiéu hon sé nhém COOH nén lam gidy quy tim chuyén sang mau xanh. Dap An C Cau 3: $6 dong phan amino axit c6 cong thire phan tly CaH;02N 1 Al. B. 2. C3. D4. Hwong dan giai k= wot =0- CaHyO2NV la amino axit no, don chite mach hé. (4): H,NCH,CH,COOH Ce cng théte théa man: (2): CH,CHQVH, )COoH > Dap An B Cau 4: Trong cic chat dui day, chat nao la glyxin? A. H2N-CH2-COOH. B, CHs-CH(NH2)-COOH. C. HOOC-CH:CH(NH2)-COOH. D, HoN-CH2CH2-COOH. Hwéng dan giai Glyxin c6 cOng thie héa hgc la H2N-CH2-COOH. => Pap an A Cau 5: Monome nao sau day tring ngung tao ra policaproamit (nilon-6)? A. Axit €-aminocaproic. B. Hexametylendiamin. C.Axit @ -aminoenantoic. D, Caprolactam. Hwéng dan giai Monome tring ngung tao ra policaproamit (nilon-6) la axit ¢-aminocaproic nlI,N-[CH, ], -COOH “> €NH-[CH,], —CO}; + nH,O e~aminocaproic nilon-6 > Dap dn A Cau 6: COng thite chung cla amino axit no, mach hé, c6 hai nhém cacboxyl va mot nhém amino lA A. CyHapsiNO2. B. CaHanaNOs, ©. CaHasNOs, G. CaHlastiNOs, Huong din gidi Amino axit no, mach hé, c6 hai nhém cacboxy! (-COOH) va mot nh6m amino (-NH2) k=2 Goi cong thie téng quét ca aminoaxit trén la GyHnNOs vi ean SPASM 2 m= an ~ Céng thtte ctia amino axit trén la CrHon-1NOx. ~ DépénB v Van dung Cau 7: Trong cdc dung dich: CHs~CH2-NHz, HzN-CH-COOH, H2N-CH2-CH(NH2)-COOH, HOOC-CH2-CH2-CH(NHz)-COOH. Sé dung dich lam xanh quy tim 1a A.A, B.3. Gs D.2. Huong dan giai Dung dich lam quy tim chuyén sang mau xanh c6 pH>7: + Amin: CHa~CH2-NH2 + Amino axit c6 nhém — NHe nhiéu hon nhom ~COOH: HeN-CHe-CH(NH2)-COOH > C6 2 chat thoa man. > pap an D Cau 8: Phat biéu nao sau day 1a ding? A. Axit glutamic 1a thanh phan chinh cia bot ngot. B, Amino axit thuéc loai hgp chat httu co tap chirc. C. Cac amino axit thién nhién hau hét la céc B-amino axit. D. 6 nhiét dO thudng, cdc amino axit déu 1a nhikng chat long, Hwéng din giai Asai vi thanh phan chinh cla bét ngot a mudi mononatri cia axit glutamic. B diing amino axit cé 2 loai nhom chitc la - COOH va - NHz. C sal vi c4c amino axit thién nhién hau hét 1a cdc a-amino axit. D sai vi é nhiét dO thudng, cdc amino axit dtu la nhiing chat ran & dang tinh thé. > pap anB * Nang cao Cau 9: Amino axit X chtra m6t nhém -NH? va mot nh6m -COOH trong phan tir. ¥ la este cla X vi ancol don chitc, My = 89. Céng thitc cla X, ¥ [an uot 18 A. H2N-CH2-COOH, H2N-CH2-COOC:Hs. B. H2N-CHz-COOH, H:N-CHz-COOCHs. C.HgN-[CHz]2-COOH, HoN-[CH2}2-COOC2Hs.—_D. H2N-[CHa]2-COOH, HaN-[CH:]2-COOCHs. Hwéng dan giai X: H,N-R-COOH Y:H,N-R-COOR' {i +M, = : + R#0; R'4H R#0; R'#H R#0; R'+H M, =89 +16+44=89 {n +My. X:H,N—CH, —COOH Y:H,N-CH, -COOCH, > Dap nB CAu 10: Hai hgp chat hiru co X va Y c6 cing céng thite phan tir 14 CoHNO2 déu 1a chat rn 6 divu kién thudng, Chat X phan ‘ng voi dung dich NaOH, giai phong hf, Chat Y c6 phan ting triing ngung. Cac chat X va ¥ Tan Iurgt A. vinylamoni fomat va amoni acrylat. B. amoni acrylat va axit o.-aminopropionic. C. axit a-aminopropionic va amoni acrylat D. axit o-aminopropionic va axit f-aminopropionic. Hwéng dan giai X 1a CHe=CHCOONH; (amoni acrylat) Y la CHs-CH(NH2)-COOH (axit o-aminopropionic), Phuong trinh héa hoc ciia phan ng: CH2=CHCOONH, + NaOH > CH2=CHCOONa + NH3f + H20. nCH, - CH- COOH EXO? Ss ENH-CH-CO}, + nH,0 NH Hy = Dap an B BAI TAP TU LUYEN 1 Cau 1: Amino axit X c6 phan tt khéi bing 75. Tén ciia XA A.alanin. B. glyxin. C.valin, D.lysin. Cau 2: Cho cae chat httu co: CH3CH(CHs)NH2 (X) va CHsCH(NH2)COOH (Y). Tén thay thé ola X va Yan lugt la A. propan-1-amin va axit 2-aminopropanoic. B. propan. C. propan-2-amin va axit aminoetanoic. amin va axit aminoetanoic, D. propan-2-amin va axit 2-aminopropanoic. CAu 3: Dung dich nao sau day lam phenolphtalein 46i mau? A, Axit axetic, B. Glyxin, CC. Alanin, D. Metylamin. Cau 4: Alanin ¢6 céng thie la A. CsHs-NE. B. CHy-CH(NH2)-COOH. C. HaN-CH2-COOH, D. H,N-CH2-CHz-COOH. Cau 5: $6 nhém amino va s6 nh6m cacboxyl cé trong mot phan tir axit glutamic twong ting 1a A.Lva2. B.1vai. caval, D.2va2. Cu 6; Cho day chuyén héa: Glyxin—™™"-y x, > x, Vay Xo la A. CIH:NCH,COOH. B, HyNCH2COONa. . H2NCH2COOH, D. CINHsCH,COONa. Cau 7: Trang thai va tinh tan cia amino axit | A, chat ran, khéng tan trong nuéc B. chat long khéng tan trong nuéec. C. chat ran, dé tan trong nuéc. D. chat long, dé tan trong nuréc. CAu 8: Cho che chat HN-CH2-COOH (X) HaC-NH-CH2-CHs (¥) CHs-CH2-COOH (Z) CeHs-CH(NHa)COOH (7) HOOC-CH2-CH(NH2)-COOH (@) HyN-CHo-CHo-CH2-CH(NH2)-COOH (P). Cac chat la amino axit A. (X), (1), @), (1). B. 00), (¥), (G), (P). £00, (0), P)- D. 9, (1), (), ). Cau 9%: Cd céc dung dich riéng bigt sau: CcHsNH=Cl, H2NCH:CH2(NH:)COOH, CIH3NCH2COOH, HOOCCH:CHCH(NHz)COOH, HzNCH2COONa. Sé lueng cdc dung dich 6 pH<71a A.2. B.5. C4, D.3. Cau 10: Cho so a3 chuyén héa sau; X—*SHOWEL_, y _+GH,OHINOL? 7 _srwoHav’_ -P, Biét X Ia axit glutamic, Y, Z, T li cdc chat hitu co’ chira nito, Céng thitc phan tir cla Y, T [an lot A. CoHs20.NCI va CsH704NaoN. B, CoH1204N va CsH04NazN. C. CrHsO.NCI va CsH7O,NaoN. D. C7HisO.NCI va CsHaO

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