Professional Documents
Culture Documents
Physical Chemistry 1 Exercise Chapter 3 4
Physical Chemistry 1 Exercise Chapter 3 4
CHAPTER 3:
THE SECOND LAW OF THERMODYNAMICS & ENTROPY
Email: nvdung@hcmut.edu.vn
1
Entropy Changes for Adiabatic Processes
QT V2 P2 P1 V1 V2
ΔS = = nRln = −nRln = ln
T V1 P1 T1 V1
Email: nvdung@hcmut.edu.vn
30
ENTHALPY - A COMBINATION PROPERTY
➢ The properties of the saturated liquid are the same whether it exists
alone or in a mixture with saturated vapor.
Ideal cycle for vapor power cycle, consists of the following four processes:
1-2 Isentropic compression in a pump
2-3 Constant pressure heat addition in a boiler
3-4 Isentropic expansion in a turbine
4-1 Constant pressure heat rejection in a condenser
Dr. Nguyen Van Dung, Faculty of Chemical Engineering, HCMUT
43
VAPOR POWER CYCLE (RANKINE CYCLE)
Boiler (w = 0) qin = h3 − h2
Turbine (q = 0) wturb ,out = h3 − h4
Condenser (w = 0) qout = h4 − h1
Energy blance:
Adiabatic process
q=0