AITS 1920 FT VIII JEEA PAPER 1 Sol

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ALL INDIA TEST SERIES

FULL TEST – VIII
JEE (Advanced)-2020
PAPER – 1
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. A

Sol. V sn   v 0  x  ˆi  vj
L
time taken, t 
V
x t
dx dx
Now,   v 0  x      dt
dt 0 v 0  x 0
v 0  Lv 
x e  1
  
2. B
 Fdt  iLBdt
Sol. V 
m m
3. A
x
Sol. 4C0 T0x  C0  2T0 
x  2
Now, CT 2  4C0 T02
4C0 T02
C
T2
2T0
 dq   nCdT
T0
q  2nC0 T0
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AITS-FT-VIII (Paper-1)-PCM(Sol.)-JEE(Advanced)/20 2
4. B
Sol. V  R  v cos 
R
V
1  cos 
5. B, C, D
Sol. Use concept of motion
6. A, B, C
Sol. From A to B,
1 1
mg  5r  r  sin300  mv 20  I2
2 2
20g

7r
Apply energy equation between B and E
31r
h
7
7. A, C
Sol. For process AC;
P  a  bv  a,b  cons tan t 
  a  bv  v   RT
1
T 
R

av  bv 2 
dT a 2bv
  
dv R R
a 2bv a
0  v
R R 2b
Also,
 d2 T 
 2 0
 dv  a
2b
 For AC, T first increases and then decreases.

For AD, T ,  K.E 
8. A, B
Sol. Concept based
9. A, D
Sol. q1  q2  2Q0 ..... i 
A 0 A 0
C1  , C2 
d0  vt d0 vt
C1 d0  vt q1
   .......  ii 
C2 d0  vt q2
 from  i  and  ii ,
q0  d0  vt 
q2 
d0
3 AITS-FT-VIII (Paper-1)-PCM(Sol.)-JEE(Advanced)/20
and
dq2 q0 v
I 
dt d0
10. A, B
Sol. Use momentum conservation and impulse momentum equation.
11. B, C, D
Sol. For n1  n2
1  1 1
 A 2  2  ...... i 
1 n
 1 n2 
and For n2  n2  1
1  1 1 
 A 2  2
 ....... ii
2  n n2  1 
 
and it is given that,
1  102.8 nm
 2  97.5 nm
solving  i and  ii
n1  1, then n2  3 and n2 1  4
and A  2.174  1018 J  13.6 ev
12. A, B, C
Y
Sol. Path difference  x  between two consecutive wave = dsin   d  
L
2 4
For minimum, phase difference between two consecutive wave is or .
3 3
Hence,
2
  x

L 2L 4L
y  , , ...................
3d 3d 3d
SECTION – C
13. 00001.00
Sol. Use the concept of motional emf.
14. 00004.00
50
Sol. Time taken to reach the middle of the river form the river bank, t =  10 second.
5
 2 
Now, v x    t
 10 
x 10
1
0 dx  5 0 tdt
x  10 m
Hence total difference = 10  2 = 20 m.
15. 00003.00
Sol. 1.sin 450  2 sinr
r  300
Now,
At G, F  A
E

r '  1200    r
 For TIR,

2 sin 1200    1.sin900  r'
  750
Now
R 2R
AE  , AF 
3 3
 EF 
 2 1 R 
3
Hence,
Area, a 
 2 1  2 1 R
3 3
1 2 9
 R  3
2 3
16. 00007.00
Sol.  Ndt  mev   mv  0 0 .... i 
eV0
 ndt  mv ......  ii 
from  i  and  ii 
v
v  v 0 1  e  
N
Now,
2ev 0 N
t
g
dis tance, d  vt  7
17. 00007.00
2 2
Sol. Peq  2PL  Pm  
2R R
3
Peq 
R
Now,
2 3
 
Rmeq R
2R
Rmeq 
3
2R
Hence, Image formed by the plane mirror is at a distance of  28 cm.
3
 d  21  28
d  7 cm
18. 00002.00
Sol. At time t,
30 30
hA  30  t, hB  30  t
4 6
Now,
hB  h A h  h
tan   
30 330
 h  30  20t
dh
  20 cm / hr  2 decimeter / hr
dt A B
30 cm 3m
Chemistry PART – II
SECTION – A
19. D
Sol. White precipitate = AgCl
Yellow precipitate = AgI
Black precipitate = Ag2O
20. C
Sol. Br
Br +
Br
O O cyclicbromoester
O
O
Intermolecular attack of bromide ion on the bromonium ion does not compete with the
intramolecular cyclisation step.
21. D
Sol. The brown ppt. is Fe  OH 3 on drying and heating it becomes Fe2 O3 carbon monoxide will
reduce it to iron metal.
0
700 c
Fe2O3  3CO   2 Fe  3CO2
22. A
Sol. [ I  ]  [ I  ] final  [ I  ]initial
 0.23  0.25  0.02molL1.
t  10  0  10 min
[ I  ] (0.02)
   0.002molL1 min 1
t 10
1 [ I  ] 0.002
 Rate of appearance of I 2     1 103 mol L1 min 1
2 t 2
23. BC
2
Hg NaBH4
Sol. 3  methyl  1  butyne 
H2 SO4
 3  methyl  2  bu tanone 
  3  methyl  2  bu tanol
24. ABD
Sol. (A) The magnitude of splitting energy increases down the group. Thus
Pt2+ – 5d8, Pd2+ – 4d8 and Ni2+ – 3d8.
(B) NH3 is a borderline ligand which forces pairing of electrons in Co3+, whereas H2O is a weak-
field ligand and it can not force the pairing in Ni2+.
3+ 3+ 6 0
Co in [Co(NH3)6] – 3d , 4s
2+ 2+ 8 0
Ni in [Ni(H2O)6] – 3d , 4s
So, there is no unpaired electron in [Co(NH3)6]3+ whereas there are unpaired electron in
2+ 3+ 2+
[Ni(H2O)6] . Thus [Co(NH3)6] is colourless and [Ni(H2O)6] is coloured due to d–d transition.
(C) O
NH2
O C
CH2
M(n – 1) + CH2
CH2
NH2 NH2
As en is symmetrical ligand thus there is no geometrical isomerism.
(D) In K3[Fe(CN)6], the oxidation state of Fe is +3.

3– 5 0
[Fe(CN)6] – 3d , 4s .
Number of unpaired electron = 1
 = n(n  2) B.M. = 1(1  2) B.M. = 3 B.M.
25. ABD
Sol. rK   rNa 
 K2CO3 is more ionic.
(CN)2 + NaOH  NaCN + NaOCN + H2O
Br2 + OH–  Br– + BrO– + H2O.
26. AB
Sol. Na2O has antifluorite structure, in which O-2 ions form ccp array and Na+ ions occupy all
tetrahedral voids.
27. ABCD
Sol. Alkyl isocyanate is R  N  C  O
(A) Curtius rearrangement (B) Schmidt rearrangement
(C) Lossen rearrangement (D) Hofmann rearrangement
28. ABC
Sol. a and b are obtained by normal Beckmann rearrangement
mechanism for product ‘c’ is
OH
N
O N C CH3
O CH3 O
PCl5
electrophilic aromat ic substitution

 O N
O O
CH3
29. ABC
Sol. CH3COONa  C2H6 (major)
CH2COOK
 CH2 = CH2
CH2COOK
HC — COOK
 CH  CH
HC — COOK
30. BCD
high T
Sol. For C  graphite  
high P
C  diamond ; H   ve and S   ve
SECTION – C
31. 00003.00
CH 3COCl
Sol. ROH   ROCOCH3
Here H is replaced by COCH3 i.e. one H of mass 1 is
replaced by one COCH3 of mass 43.
 Mass increased is 42.
237
 Mass of acylated product is = 92   218
100
 increase in mass = 218 – 92 = 126
 number of OH = 126/42 = 3
32. 00005.00
Sol. 2I  I2  2e
I2  2S2 O3  2I  S4 O62
2I  MnO 4  I2  Mn2
No. of eq. of KI electrolysed
= no. of eq. of I2 produced
= no. of eq. of Na2S2O3 = 0.25  37.2  1 10 3
= 9.3  103
It I  3  60
No. of eq.=   9.3  103
96500 96500
 I=5A
33. 00363.52
Sol. According to Raoult’s law:
0 0
PT = p1 x1  p2 x2
0 0
p1 + p2 = p1 (0.16)  p2 (0.84)  760mm
0 0
Also p1  p2  472mm
0 0
 760 = p1 (0.16)  ( p1  472)(0.84)
0 0
760 = 0.16 p1  0.84 p1  396.48
 p10 = 363.52 mm
34. 00000.00
Sol. no movement of D.P. towards any electrode in during electro-osmosis
35. 00006.40
Sol.  Ca   C 2 O 4– –
CaC 2 O 4 
S S
K sp  S  S  S2
w
s  K sp = (2.5 × 10–9)1/2 = 5 × 10–5 mol litre–1   5  105
128
 w = 6.4 × 10–3g = 6.4 mg
36. 00069.16
Sol. Let the mass of acetaldehyde is x g, then mass of ethanol is (0.535 – x)g. When acetaldehyde is
heated with Fehling solution, it gives 1.2 g of a red precipitate.
CH3CHO + 2CuO  CH3COO– + Cu 2 O
Re d ppt .
143 g of Cu2O is coming from = 44 g of CH3CHO
44
1.2 g of Cu2O is coming from  1.2 = 0.37 g of CH3CHO
143
0.37
% of CH3CHO =  100 = 69.16 %
0.535
Mathematics PART – III
SECTION – A
37. A
b  3c 
1  2a   2    2   2 2 1/ 5
 2  2    2a  b   3c  
Sol.        
5  2  2  
8
 ab2 c 2
9  5 5
38. D
1 1 1 1 1 4
Sol. P T       
3 4 
 3 2 
3 5
a b c
1  a 1 b 1 c  4  381
So, required probability=    
a bc  4 2 5  620
39. A
I 
 tan x  1  tan x   1  tan x  dx  x 
2 2
1  tan 2 x
Sol.
tan x  1  tan 2 x  1  tan x  tan 2 x dx
z  tan x dz  sec 2 xdx
dt 2  2 tan x  1 
I  x 2
 x tan 1  C
2
 1  3 3  3 
t     
 2  2 
40. A
ab ab
Sol. x  dx  2   dt 
t t
b2 t2
a 2 2
e t e a  ab 
I    2  dt   I
b
ab  t 
t
 2I  0 I 0
41. BC
Sol. x 2
 1  x 2   a  2  x  3  0
2
Since x   a  2  x  3  0 must have at least one positive real roots.
   3 both root must be positive
    a  2  0  a  2 & D  0   a  2   12  0
2
a2  
3 1
42. AB
2m1
Sol. m
1  m12
O1 P 2  r12  m12 2 y=mx
2 2
 9      6  m1   m12 2 P(
c2 y=m1x
 2  6  2m1  3   117  0 q1 c1
q2
  117 r1r2  m12  68 A B
12 221
m  
49
43. BD
 3 1   3 1     
    sin   co s  
 2 2  2 2  2  12    12   2
Sol.
sin x co s x sin x co s x
44. AD
Sol. ∴ Given
 
a  b  4 i   j  2 k  0
  
 
a  b 3 i  2 j   k cos   10
θ is the angle between 4 i   j  2 k & 3 i  2 j   k

   
 7 2  48  52  0
45. AC
 2 x  2h 
f  x  h  f  x
f   f  x
 2 
Sol. f '  x   lim  lim
h0 h h 0 h
f  2 x   f  2h   2 f  x 
 lim
h 0 2h
f  2 x   f  0 f  2 x   1
Let x  2 x & y  0 f  x  
2 2
2 f  x   1  2 f  2h   2 f  x  f  2h   1
 lim  lim
h 0 2h h 0 2h
f  2h   f  0 
 lim  f '  0   1  f '  x   1
h 0 2h  0
46. A
Sol. Use homogenization method
47. ABC
Sol. Use matrix property
48. ACD
Sol. 9x 3  7x  6  0
y  3x  2
y2
x
3
3
 y 2  y  2
9   7 6  0
 3   3 
3
 y  2  7  y  2   18  0
3 2
y  6y  5y  24  0
SECTION – C
49. 00007.50
Sol. Direction ratio of PQ
 3r2  3r1  6, 2r2  r1  6, 4r2  r1  2 
Now, 3  3r2  3r1  6   2  2r2  r1  16   4  4r2  r1  2   0
 7r1  29r2  22   (1)
3  3r2  3r1  6    2r2  r1  16    4r2  r1  2   0
7r2  11r1  4   (2)  r1  1, r2  1
a  3, b  2, c  5
c
 a  b   3  2  25  7.5
2
50. 00002.50
2
Sol. 12sin x  5cos x  2  y  2   13
by LHS  13, RHS  13
 y  2 12sin x  5 cos x  13 cos  x     1 x  2 x  
51. 00001.98
Sol. p  x    x  1 x  2  x  3  x     10 x
 p 12   p  8  19800  40
p 12   p  8  10
 1.98
10000
52. 00102.53
tan 8 1  8 tan 8  1 3
Sol. Let 2
  2
 tan 8  tan 8    tan 8  tan 24
1  3 tan 8 8 1  3 tan 8  8 8
∴ Solving LHS
81 1
tan108  tan 8  x 2  y 2
8 8
2 2
2
x y 2

81  1  102.53
64
53. 00000.50
n 1
Sol. 
n
n
CK  
n n!

 n !
K 1 K ! n  K  ! 2
K 0
1!2!...3!
n
    n  1  K  
n 1 2 K

 K 1 
n 1 2 K
 n 1 K 
n
 
K 1
 n 1 
 sin ce   n  1  2K   0
Taking log and limit we get
n
1  2K   K 
n
 1  n  1  ln 1  n  1 
K 1
1
1
  1  2 x  ln 1  x  dx 
0
2
54. 00017.86

Sol. f  x   2 x; 0  x 
2
 3
 ; x
2 2 p
3 
 4  2 x;  x  2
2
Required Area 0  3 2 4
2 2
 /2 3 / 2
 4    cos x  2 x  dx  2
0
     cos x   dx
 /2
2
  2  8   3.14   8  17.86

AITS 1920 FT VIII JEEA PAPER 1 Sol

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AITS 1920 FT VIII JEEA PAPER 1 Sol

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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

 For AC, T first increases and then decreases.

and For n2  n2  1

Sol.  Ndt  mev   mv  0 0 .... i 

(D) In K3[Fe(CN)6], the oxidation state of Fe is +3.

Number of unpaired electron = 1

 = n(n  2) B.M. = 1(1  2) B.M. = 3 B.M.

Mathematics PART – III

θ is the angle between 4 i   j  2 k & 3 i  2 j   k

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