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Corosion
Corosion
Corosion
The practical value of corrosion countermeasures, no matter how perfect they may be in the theoretical or
laboratory sense, depends upon specific knowledge and attitudes on the part of supervisors, and
individuals with related responsibilities.
This course is directed at field operating personnel, in the hope that continued use will enhance the
knowledge and attitudes mentioned, specifically:
Appreciation of the enormous cost of Fertilizers industries corrosion.
Ability to recognize early indications of corrosion.
Awareness of the importance of early reporting.
Desire to take effective part in the solution.
The course makes full use of the simplest possible terms and descriptions.
The circumstances of corrosion vary widely, and technical advice should always be sought when causes
are obscure, or the cost or severity is high.
MERIM ENGINEERING
WHY
MEC is committed to deliver targeted learning aided by technology
and innovative solutions blended with unmatched quality services.
CHOOSE
CUSTOM-MADE: Training is tailored as per specific needs
ECONOMICAL: is a cost-effective for group of candidates
QUALITY Assurance Duties and Responsibilities
IMPORTANT: Well-adjusted to latest global industry standards and
US?
business requirements
OBJECTIVES
WHO SHOULD
JOIN? Upon completion of this course, participants will gain an
understanding of corrosion ramifications in oil and Gas industries
and how to;
OPERATORS / SR. OPERATORS Aim to understand the basics of Corrosion, different types of
/ASC/SCS corrosion, its control, risk and impacts of corrosion in Fertilizer
industry installations.
Describe corrosion mechanism and chemical reactions.
Interpret corrosion theory. Describe corrosion mechanism
INSPECTION CORROSION and chemical reactions.
STAFF & ENGINEERS
Describe corrosion prevention/ control techniques.
Differentiate between corrosion due to dissolved oxygen,
microbiological, CO2, H2S, etc.,
PROCESS ENGINEERS, Evaluate Corrosion inhibitors used in fertilizer industries, their
REFINERY CHEMISTS specs and work mechanism.
To present the advanced corrosion monitoring technologies.
Corrosion Testing methods
Describe Bacteria formation and effect
CHEMICAL ENGINEERS, To illustrate study cases pertaining to corrosion failures,
ENVIRONMENTAL SPECIALISTS mainly pipelines, storage tanks, pressure vessels, boilers and
heat exchangers.
Analyze corrosion coupons, corrosion rigs, corrosion probes,
etc., and suggest remedial measures for causes of corrosion
KEY MODULES
Why is corrosion control important?
INTRODUCTION TO CORROSION
Historical background
Definitions
Corrosive environment
1
Consequences of corrosion
Cost of corrosion
Breakdown of spending on corrosion
Corrosion science and corrosion engineering
Inter-disciplinary nature of corrosion
Corrosion education
Functional aspects of corrosion
Five good reasons to study corrosion
KEY MODULES
CORROSIVE ENVIRONMENTS
External Environments:
Atmospheric Corrosion, Water as a Corrosive Environment,
Soils as Corrosive Environments, Corrosion under Insulation,
4 Internal Environments:
Crude Oil, Natural Gas, Oxygen, CO2, H2S, Organic Acids, Scale,
Microbially Influenced Corrosion (MIC), Mercury, Hydrates, Fluid Flow Effects on Corrosion
FORMS OF CORROSION
General Corrosion,
Galvanic Corrosion:
Galvanic Coupling of Two or More Metals, Area Ratio, Polarity Reversal,
Conductivity of the Electrolyte, Control of Galvanic Corrosion,
Pitting Corrosion:
Occluded Cell Corrosion, Pitting Corrosion Geometry and Stress Concentration,
Pitting Initiation, Pitting Resistance Equivalent Numbers (PRENs),
5 Statistics, Prevention of Pitting Corrosion,
Crevice Corrosion:
Alloy Selection, Filiform Corrosion,
Intergranular Corrosion:
Stainless Steels, Corrosion Parallel to Forming Directions, Aluminum, Other Alloys,
Dealloying:
Mechanism, Selective Phase Attack, Susceptible Alloys, Control,
Erosion Corrosion: Mechanism, Velocity Effects, Materials, Cavitation, Areas of Concern, Control,
Environmentally Induced Cracking:
SCC, HE and H2S-Related Cracking, Hydrogen Attack, Liquid Metal Embrittlement (LME), Corrosion
Fatigue,
Microbiologically induced corrosion (MIC)
Mechanical and Metal failures as per API 571
KEY MODULES
Corrosion Mechanism:
Uniform Corrosion, Selective (localized) Corrosion, Crevice Corrosion
Intergranular corrosion, Stress Corrosion Cracking (SCC), Galvanic Corrosion
Corrosion Fatigue, Erosion
Hydrogen, High Temperature Hydrogen Attack (HTHA)
Hydrogen Induced Cracking (HIC), Hydrogen Induced Stress Cracking (HISC)
Sulphide Stress Corrosion, Hydrogen Embrittlement, Measures to Prevent Damages Caused by
Hydrogen Attacks, High Temperature Corrosion (HTC)
6 Oxidation
Sulphur Attack
Nitriding
Carburization and Metal Dusting
Material Selection Philosophy for different Corrosion Mechanisms:
Hydrogen, H2S, CO2 Wet Corrosion, Metal Dusting, MDEA, Cooling water, Chlorides in the
atmosphere
Desulphurization and Air-Compression
Steam Reforming
CO Conversion and Methanation
CO2 Removal : CO2 Removal Potassium Carbonate, CO2 Removal MDEA
Syngas Compression
NH3 Synthesis
Refrigeration
NH3 & H2 Recovery
Steam and Condensate System
KEY MODULES
CORROSIVE ENVIRONMENTS
Effect of pH on corrosion of carbon steel
Sea water
Sodium chloride and sea water
Sea water immersion
Fresh water
O2 solubility and effect on corrosion rate
7 Effect of temperature on corrosion rate
Effect of sulfates, chlorides and carbonates on corrosion rate
Effect of velocity on corrosion rate
Effect of H2S
Effect of CO2
Exposure time versus corrosion arte
Microbiological effects
MATERIALS
Metallurgy Fundamentals
Forming Methods,
Materials Specifications:
API,
8
AISI—The American Iron and Steel Institute,
ASTM International—formerly the American Society for Testing and Materials,
ASME,
SAE International,
UNS,
NACE—The Corrosion Society,
Carbon Steels, Cast Irons, and Low-Alloy Steels,
Corrosion Resistant Alloys CRAs,
Polymers, Elastomers, and Composites,
KEY MODULES
CATHODIC PROTECTION
Basis of cathodic protection
Working of cathodic protection system
Factors leading to corrosion of underground metallic structures
Electrical basis of cathodic protection
Electrochemical theory of cathodic protection
Anodic polarization
Cathodic protection systems
Components of galvanic systems
Impressed current system
Components of impressed current systems and AC/DC systems
Types of ground-beds
Major impressed current anodes
Protection of submarine pipelines
9 Design parameters in cathodic protection
Current requirements
Backfill
Measurements in cathodic protection
Pipe-to-soil potential
Factors affecting pipe-to-soil potential
Potential survey
Measurement of current flow
Reference electrode
Coating resistance tests
Current requirement tests
Current density requirement for a bare structure
Stray current corrosion
Cathodic protection interference's, Design charts
Ground-bed design, Soil resistivity and pipe-to-soil potential survey
Calculations in cathodic protection design, Important formulae in cathodic protection calculations
KEY MODULES
CORROSION CONTROL
CORROSION CONTROL METHODS:
Approaches to Corrosion Control
Alter Material Composition
Alter Electrolyte Composition
Physical Alteration of the System
Isolate the Metal from the Electrolyte
11 Chemical Inhibitors
Cathodic Protection
Method Selection:
Cost of Materials, Labor Costs, The Present Value of Money
12 Description of inhibitors
Inorganic anodic inhibitors
Organic inhibitors
Synergistic inhibitors
Scavengers
Neutralizers
Scale inhibitors
Rebar inhibitors
Biocides
Inhibitor application techniques
Vapor phase inhibitors
Inhibitor efficiency and inhibitor concentration
KEY MODULES
CONTACT US
MERIM ENGINEERING CONSULTING FZCO
Dubai Silicon Oasis DDP, Building A2, Office 103
P.O. Box 7800 Dubai, United Arab Emirates